Characteristics Of Oil Research Articles

Contact Characteristics and Characterization Methods of CO2 and Crude Oil in Visual Porous Medium

In this article, the vertical static variation characteristics of CO2 and crude oil in porous medium under different experimental pressures are studied by using the CO2 miscible visual displacement device jointly developed. The process of change at the CO2 and crude oil interface is characterized by relative height and dissolution expansion rate. Experimental results demonstrate that with the increase of pressure, CO2 gradually reaches a supercritical state with strong extraction and mass transfer capacity, and CO2‐crude oil exhibits different contact forms under different pressures. Under the same pressure, there are also significant differences in contact forms between visual tube and porous medium. The existence of porous medium weakens the mass transfer and diffusion abilities between CO2 and crude oil and reduces the extraction of light components by CO2. In porous medium, the relative height of crude oil is a power function of time, which is 1/5 ≈ 3/10 of that in visual tube. And the dissolution expansion rate of CO2 and crude oil exhibits a negative logarithmic correlation with time, which is 1/4 ≈ 2/5 of that in visual tube. The impact of porous media on relative height and dissolution expansion rate of crude oil becomes more pronounced as the pressure decreases.

Effect of extraction temperature and roasting time on quality characteristics of sesame oil

Effect of extraction temperature and roasting time on quality characteristics of sesame oil

Factors that Affect the Quality of Olive Oil Produced Using Olives from Traditional Orchards in the Middle East

Traditional olive (Olea europaea) orchards have been grown for thousands of years and still occupy most of the world’s cultivated olive areas. To compete with olive oil produced in the higher-yielding intensive orchards, the oil from traditional orchards must be of high quality. We evaluated oil quality—potential and actual (under commercial conditions)—and tested the stages in the production chain that are likely to reduce oil quality in the traditional sector in the Middle East region. Our findings show a clear negative impact of growers’ traditional practices on both the chemical and sensory characteristics of olive oil. The oil originating from the commercial process had higher free fatty acid and lower polyphenol and carotenoid contents, lower stability, lower pungency, lower fruitiness, lower bitterness, and a higher prevalence of organoleptic defects than oil that originated from fruit picked from the same trees during the experimental procedure. The current common harvesting technique of pole beating significantly increased fruit injury and fruit with mold, leading to a reduction in oil polyphenols and an increase in free fatty acid levels compared with those resulting from manual picking. In addition, after harvest, storing the fruit for more than 48 hours in plastic bags dramatically reduced the oil quality. The traditional olive orchard could be a source of high-quality extra virgin olive oil. However, fruit handling—from the trees until the end of the oil extraction process—is performed incorrectly, thus adversely affecting the oil quality.

Numerical and experimental investigation on two-phase flow and oil capture efficiency of under-race lubrication for high-speed bearings

The increasing rotational speed and temperature levels in modern aeroengines impose higher demands on the lubrication and cooling design of the roller bearings supporting the main shaft. To design a compact and efficient under-race lubrication system, a comprehensive understanding of the characteristics of oil–air two-phase flow and the variations in oil capture efficiency is necessary. This study experimentally investigated the oil capture efficiency and employed numerical simulations to elucidate the mechanisms of oil–air two-phase flow. The results reveal a favorable consistency between the numerical simulations and experimental findings, both in terms of the oil capture efficiency and the oil–air distribution. The decreasing trend of oil capture efficiency gradually stabilizes when the jet distance exceeds 10 mm. To ensure stable and effective testing results for oil capture efficiency, the jet distance should be maintained within the range of 10–14 mm during experiments. Under different operating conditions, there exists an optimal jet angle that maximizes the oil capture efficiency. The corresponding optimal jet angle becomes smaller with lower oil supply pressure and higher rotational speed of the radial oil scoop. Within a momentum flux ratio range of 5–870, an innovative predictive correlation for the optimal jet angle is derived, with a maximum relative error between predicted and experimental values being 4.0%. The proposed correlation provides theoretical support and methodological basis for refining the design of radial under-race lubrication in aeroengines.

Adsorption Characteristics of Illite and Kerogen Oil Phase: Thermodynamics Experiments

In order to study the adsorption process and adsorption characteristics of shale oil at the macro scale, the isothermal adsorption experiments of illite and kerogen on a heptadecane (oil phase) solution were carried out by infrared spectrophotometry and gas chromatography–mass spectrometry. Based on the adsorption isotherm model and adsorption thermodynamic model, the characteristics of heptadecane adsorbed by illite and kerogen at different temperatures and oily solution concentrations were studied. The experimental results show that the concentration and temperature of the alkane solution help to enhance the adsorption and increase the saturated adsorption capacity. The difference is that the concentration will have a certain effect on the adsorption rate, while the temperature will not. Based on the three adsorption isotherm models, it was found that Langmuir and Freundlich were more suitable for describing the adsorption process of the heptadecane solution by illite and kerogen, and the adsorption characteristics of heptadecane molecules at different temperatures and adsorbents were evaluated. Heating leads to an increase in the collision efficiency between adsorbate molecules and adsorbents, thereby accelerating the migration rate of alkanes. Therefore, increasing temperature helps to enhance the adsorption capacity of rocks and increase the saturated adsorption capacity of minerals. The research results clarify the adsorption characteristics of shale oil heavy components from the macro level and fill the research gap in the application of solid–liquid isothermal adsorption physical experiments on the adsorption and occurrence of shale oil.

The Role of Amphiphilic Nanosilica Fluid in Reducing Viscosity in Heavy Oil

Heavy oil accounts for a considerable proportion of the world’s petroleum resources, and its exploitation helps to mitigate reliance on conventional oil resources and diversify energy supply. However, due to the high viscosity and high adhesion characteristics of heavy oil, conventional methods such as thermal recovery, emulsification, and dilution have significant limitations and cannot meet the growing demands for heavy oil production. In this study, 3-propyltrimethoxysilane (MPS) was used to modify and graft amphiphilic surfactants (AS) onto nanosilica to prepare a salt-resistant (total mineralization > 8000 mg/L, Ca2+ + Mg2+ > 1000 mg/L) and temperature-resistant (250 °C) nanosilicon viscosity reducer (NSD). This article compares amphiphilic surfactants (AS) as conventional viscosity-reducing agents with NSD. FTIR and TEM measurements indicated successful bonding of 3-propyltrimethoxysilane to the surface of silica. Experimental results show that at a concentration of 0.2 wt% and a mineralization of 8829 mg/L, the viscosity reduction rates of thick oil (LD-1) before and after aging were 85.29% and 81.36%, respectively, from an initial viscosity of 38,700 mPa·s. Contact angle experiments demonstrated that 0.2 wt% concentration of NSD could change the surface of reservoir rock from oil-wet to water-wet. Interfacial tension experiments showed that the interfacial tension between 0.2 wt% NSD and heavy oil was 0.076 mN/m. Additionally, when the liquid-to-solid ratio was 10:1, the dynamic and static adsorption amounts of 0.2 wt% NSD were 1.328 mg/g-sand and 0.745 mg/g-sand, respectively. Furthermore, one-dimensional displacement experiments verified the oil recovery performance of NSD at different concentrations (0.1 wt%, 0.15 wt%, 0.2 wt%, 0.25 wt%) at 250 °C and compared the oil recovery efficiency of 0.2 wt% NSD with different types of demulsifiers. Experimental results indicate that the recovery rate increased with the increase in NSD concentration, and 0.2 wt% NSD could improve the recovery rate of heavy oil by 22.8% at 250 °C. The study of nano-demulsification oil recovery systems can effectively improve the development efficiency of heavy oil.

Modeling and process optimization of extraction conditions on the quality characteristics of oil from cashew kernel using Response Surface Methodology

The quest for edible oil for consumption could not be over-emphasized and problems encountered during the conventional shelling of cashew kernel are the exposure to extremely high levels of temperature which may affect the quality of the extracted oil. The effects and optimization of extraction conditions on the properties of cashew kernel oil was investigated. The oil was processed from the cashew kernel using varying sample weight (10, 30, 50 g), extraction time (1, 2, 3 h) and solvent volume (75, 200, 325 ml). The extracted oil was evaluated for physicochemical properties and oil yield. Result showed that the physicochemical properties of cashew oil were significantly (p < 0.05) influenced by the extraction conditions. Increase in extraction time and solvent volume increased the chemical properties (peroxide value, saponification value, iodine value) but decreased free fatty acid. The study optimization of the combined effects of the process conditions was achieved using sample weight of 10 g, extraction time of 2 h and solvent volume of 75 ml. These variables are important consideration for optimal quality of cashew kernel oil with maximum yield of 44.6 % and could therefore be utilized commercially as a source of edible oil for human consumption.

Application of functionalized carbon nanofibers as a modifying additive to motor oil

Due to the widespread of lubricants, improving their tribological characteristics remains an important practical task. Among the promising modifying additives, carbon nanomaterials attract special attention. Such materials are found to improve the antifriction characteristics of lubricants and oils. In the present research, carbon nanofibers were synthesized via catalytic pyrolysis of a mixture of light hydrocarbons (C2-C4) over the NiCu catalyst. In order to form functional groups on the surface of carbon nanofibers, they were treated with diluted acids HCl, HNO3, and H2SO4 as well as with concentrated HNO3. The functionalized samples were comprehensively characterized by a set of physicochemical methods including atomic absorption spectroscopy, scanning and transmission electron microscopies, low-temperature nitrogen adsorption, X-ray photoelectron spectroscopy, temperature-programmed desorption/oxidation, and Raman spectroscopy. As defined, the surface oxygen concentration in the samples varies from 3.5 to 16.3 at.%. It was shown that the addition of modified carbon nanofibers to a motor oil leads to an improvement in its tribological characteristics. In particular, the most effective additive was the sample treated with diluted HNO3. The motor oil with this modifying additive exhibited the heating temperature decreased by 10 °C and the contact spot area on the stationary body decreased by 20 %.

Effect of deodorization conditions on fatty acid profile, oxidation products, and lipid-derived free radicals of soybean oil

Oxidative stability is a key quality characteristic of edible oils, and the oil’s antioxidant capacity decreases during the deodorization stage. This study explores the changes in radical formation, molecular structure, oxidative characteristics, fatty acids, and main bioactive compounds in soybean oil during deodorization. The lag phase decreased, whereas the total amount of spins of free radicals increased as the deodorization time increased from 90 to 150 min. The total amount of spins and percentage of alkyl radicals varied dramatically under different times and temperatures (220 ∼ 260 ℃). Results showed that identifying and quantifying the formed radicals can provide useful information for monitoring and controlling oil oxidation in vegetable oil refining systems. Therefore, to control early oxidation events, maximize refined oil product yield, and reduce energy consumption in the refining plant, the priority should be to minimize temperature during the oil refining process and then shorten the deodorization time.

Study on demulsification characteristics of crude oil based on orthogonal dual frequency ultrasonic standing wave field

In this paper, we conducted an experimental study on the demulsification and dewatering characteristics of water-in-oil emulsions under orthogonal dual-frequency ultrasonic standing wave fields. Firstly, the absolute and relative dehydration rates are defined as the evaluation criteria to measure the effect of demulsification and dehydration; then, the influence laws of absolute and relative dehydration rates of water-in-oil emulsions under the action of single frequency standing wave field and orthogonal dual-frequency standing wave field by ultrasonic frequency, power, irradiation time, initial water content and concentration of emulsifier are analyzed in detail, and through data comparison and analysis, it was found that By comparing and analyzing the data, it was found that the relative water content remained between 1.0 and 2.0 in most cases under the action of orthogonal dual-frequency standing wave field, and the ratio of 1.2–1.8 is large, which highlighted the advantages of orthogonal dual frequency ultrasonic standing wave field.

A review of the flow characteristics of shale oil and the microscopic mechanism of CO2 flooding by molecular dynamics simulation

Shale oil is stored in nanoscale shale reservoirs. To explore enhanced recovery, it is essential to characterize the flow of hydrocarbons in nanopores. Molecular dynamics simulation is required for high-precision and high-cost experiments related to nanoscale pores. This technology is crucial for studying the kinetic characteristics of substances at the micro- and nanoscale and has become an important research method in the field of micro-mechanism research of shale oil extraction. This paper presents the principles and methods of molecular dynamics simulation technology, summarizes common molecular models and applicable force fields for simulating shale oil flow and enhanced recovery studies, and analyzes relevant physical parameters characterizing the distribution and kinetic properties of shale oil in nanopores. The physical parameters analyzed include interaction energy, density distribution, radial distribution function, mean-square displacement, and diffusion coefficient. This text describes how molecular dynamics simulation explains the mechanism of oil driving in CO2 injection technology and the factors that influence it. It also summarizes the advantages and disadvantages of molecular dynamics simulation in CO2 injection for enhanced recovery of shale oil. Furthermore, it presents the development trend of molecular dynamics simulation in shale reservoirs. The aim is to provide theoretical support for the development of unconventional oil and gas.

Microencapsulation of fish oil by spray drying, spray freeze-drying, freeze-drying, and microwave freeze-drying: Microcapsule characterization and storage stability.

The objective of this paper was to evaluate the effect of spray drying (SD), spray freeze-drying (SFD), freeze-drying (FD), and microwave freeze-drying (MFD) on the characteristics of fish oil (FO) microcapsules. The physicochemical properties, morphology, fatty acid composition, and stability of the microcapsules were analyzed. The encapsulation efficiencies of microcapsules dried by SD, SFD, FD, and MFD were 86.98%, 77.79%, 63.29%, and 57.89%, respectively. SD microcapsules exhibited superior properties in terms of effective loading capacity, color, and flowability. Conversely, SFD microcapsules demonstrated improved solubility. Microencapsulation positively affected the thermal stability of FO, but the content of unsaturated fatty acids decreased. The findings from the storage experiment indicated that the oxidative stability of SD fish oil microcapsules was marginally lower compared to microcapsules produced through three alternative drying techniques, all of which were based on the FD concept. The comparison of various drying methods and their effects on the quality of FO microcapsules offers valuable insights that can serve as a foundation for the industrial production of high-quality microcapsules.

Evaluation of Agronomic and Oil Characteristics of Selected Turkish Poppy Genotypes under Ankara’s Climate Conditions

Poppy is a minor agronomic field crop that is cultivated under a UN license. It is known for its alkaloids and seeds, and, rarely, for the latter’s use in ethnomedicine. Changing climate conditions could lead to the need for alternate areas for poppy cultivation in Türkiye. This experiment was conducted in Ankara, which is not a poppy production area. The morphological characteristics and oil characteristics of 19 Turkish poppy genotypes were determined over two years. According to the results, the emergence time was between 10 and 22 days, the flowering time ranged from 197 to 214 days, while the harvest maturation time was between 250 and 269 days. The plant height varied from 75.8 to 97.5 cm, the weight of 1000 seeds ranged from 305.0 to 428.0 mg, and the weight of the seeds per plant was between 2.95 and 5.78 g. Furthermore, the yield ranged from 100.7 to 202.3 kg da−1, the fat content was between 38.8 and 44.1%, and the protein content ranged from 15.9 to 18.4%. The linoleic acid content ranged from 66.77% to 75.60%, the oleic acid content ranged from 10.78% to 19.46%, and the palmitic acid content ranged from 8.38% to 9.90%. The highest yield in Ankara was obtained from the Çelikoğlu cultivar.

Research on the thermal flow characteristics of viscosity oil in hydrodynamic torque converter

The increase in power density of hydrodynamic torque converters (HTCs) leads to a sharp rise in temperature within flow channels, affecting the reliability. In order to accurately predict the thermal effect and temperature distribution characteristics of the HTC internal viscosity oil, a multi-physics computational fluid dynamics (CFD) model is proposed. A specialized test bench was established, and the macro and internal flow temperature data were obtained. HTCs with different working conditions and wheel sets were studied. The results indicate that CFD model considering energy equation can accurately predict the overall hydrodynamic performance and the flow field temperature characteristics under different rotating conditions. The prediction error of the overall temperature rise is within 4.92%, and the flow field temperature prediction error of the stator is under 14.3%. The hydraulic characteristics is improved by 6.02%. The analysis of internal flow and energy exchange characteristics indicates the thermal effects and temperature distribution mechanisms caused by energy loss in the flow field within the HTC. The study provides an effective computational model for the prediction and control of the heat generation of the HTC and enhances the depth of research on the flow mechanism of inhomogeneous flow fields caused by thermal effects.

The effect of fir wood SLS surfactant concentration on the characteristics of light crude oil

As time progresses, oil production will gradually depletes considering limited oil reserves. This is why, an advanced stage method known as tertiary oil recovery is required. One of these methods is known as Enhanced Oil Recovery method. In this laboratory study, one specific surfactant fluid was used, namely Fir wood sodium lignosulfonate (SLS) with varying concentrations of 0.50; 1.00; 1.50; 2.00; 2.50; and 3.00% each crude oil 39 ° API. This study aims to witness the stability of SLS surfactant fluid in chemical injection. SLS surfactant injection is carried out to increase oil production in the reservoir. In this study, there are various stages in order to test the characteristics of the SLS surfactant, so it can be declared as effective in oil sweeping, namely phase behaviour test, density testing, phase behaviour test, interfacial tension test, and adsorption test. Density test is carried out to determine the density of a fluid. Phase behaviour test is intended to see the stability of emulsion obtained from the utilization of SLS surfactant. The main objective of surfactant utilization is to reduce interfacial tension which leads to IFT test. The IFT (interfacial tension) results of the SLS surfactant fluid are determined from the results of the stable phase behaviour test which evidently shows the critical micelle concentration (CMC) point, so it can properly reduce the interfacial tension of oil and formation water in the reservoir. Interfacial tension test was carried out to determine the interfacial tension between SLS surfactant and oil. Adsorption test is carried out to witness the level of fluid adsorption onto the rock surface. On static adsorption test, the result showed for 2 % surfactant concentration is 9.526 mg/gr. Dynamic adsorption test was conducted on the same concentration show results of respectively 1.865 mg/gr.

Research on Monitoring of Oil Metal Particle Pollution in Operation of Hydroelectric Generating Units Based on Internet of Things

Abstract Environmental protection has become very important in recent years. Traditional methods ignore the characteristics of metal particle pollution extraction in operating oil, which leads to low monitoring accuracy and low efficiency. Therefore, a monitoring method based on soft computing for oil pollution and metal pollution in the operation of a hydro-generator set is proposed in this article. The signal characteristics of oil and metal particles in the operation of a hydro-generator set are extracted by combining the maximum overlapping discrete wavelet transform method and the optimal decomposition level method to complete monitoring. The results show that the proposed method can accurately monitor the metal particle pollutants in the operating oil of hydroelectric generating units and has high execution efficiency. The proposed method will certainly assist in protecting the environment by monitoring carbon emissions and pollution through metal particles in the oil.

The characteristics of produced oils in the miscible CO2 displacement process

CO2 flooding is an effective technique for enhancing oil recovery by changing the hydrocarbon fluid’s characteristics. One of the fundamental mechanisms of the interaction between CO2 and hydrocarbon fluid by miscible CO2 injection is the extraction phenomenon of the hydrocarbon components by CO2. It results in altered produced and residual oil characteristics. This study aims to examine the characterizations of produced oil during the process of CO2 displacement. It is critical to anticipate any issues that can arise from miscible CO2 flooding, such as asphaltene deposition. A light-dead oil sample from an Indonesian oil field was used in this investigation. The miscible CO2 displacement process was conducted by a slim tube experiment at operating temperature of 90°C and 70°C, which represents the reservoir and surface temperature, respectively. The properties of produced oil were further characterized by analyzing the composition based on its polarity, including saturate, aromatic, resin, and asphaltene. The results show that increasing injection pressures decrease resin and asphaltene fractions in produced oil. Furthermore, the proportions of asphaltene and resin fractions in the crude sample exhibit a significant decrease when conducted at a lower temperature in comparison to when carried out at a higher temperature. This study helps to explain how the displacement process by CO2 affects the properties of the produced oil.

Enhancing Quality Characteristics of Cold-Pressed Sesame Oil with Ethanolic Extract of Quince (Cydonia oblonga), alongside with Exploring the Interaction of Trans Fatty Acids with Key Proinflammatory Cytokines via Molecular Docking

Currently, there is a growing trend of replacing synthetic antioxidants with natural alternatives to prevent the oxidation of edible oils. Herein, we assessed the phenolic compounds and antioxidant properties of ethanolic extracts that are obtained from Cydonia oblonga (SQ). Furthermore, we incorporated SQ at two different concentrations (1% and 2%) into cold-pressed sesame oil, storing it for 30 days under ambient conditions. We then assessed the peroxide value (PV), acid value (AV), oxidative stability using the Rancimat apparatus, and the fatty acid (FA) composition. Additionally, we performed the molecular docking analyses to explore the interaction between trans fatty acids (TFAs; C18:1 and C18:2) and key proinflammatory cytokines such as tumor necrosis factor-alpha (TNF-α), interleukin-6 (IL-6), and C-reactive protein (CRP). The total phenol, flavonoid content, and antioxidant activity of SQ were found to be 95.33±5.03 mg GAE/g, 343.67±16.44 mg QE/g, and 465.67±5.51 mmol Fe2+/g, respectively. The presence of SQ exhibited a significant impact on reducing PV and AV when compared to the control group. Furthermore, the addition of SQ resulted in a significant increase in the induction period (IP) compared to the control. The predominant FAs in the samples were 18:2n-6, 18:1n-9, 16:0, and 18:0, respectively. The levels of TFAs in all samples at 30 days were higher than those at 0 day. TNF-α and IL-6 showed a higher binding affinity for the trans-C18:1 ligand, with a docking score of -6.81 and -5.82, respectively, compared to the trans-C18:2 ligand. In this context, SQ can be proposed as a natural antioxidant to enhance the oxidative stability of sesame oil. Additionally, the binding preferences and specific interactions of TFAs with these proinflammatory cytokines indicate their potential role in modulating inflammation.

EXTRACTION, OPTIMIZATION AND QUALITY CHARACTERIZATION OF OIL FROM HASS AVOCADO (PERSEA AMERICANA) VARIETY GROWN IN ETHIOPIA (WONDOGENET)

The purpose of this research was to extract, optimize and characterizethe qualityof oil from Hass avocado variety which is grown in Wondogenet, Ethiopia. Oil was extracted from Hass avocado pulp using soxhlet and ultrasonic extraction and some process parameter for optimization were carried out. Hass avocado is rich in fat (22.80±0.00%). The effects of three factors (particle size, solvent to sample ratio and extraction time) on the oil yield were considered. The optimum extraction conditions for soxhlet extraction were found to be at 8 h reaction time, particle size of 1.4mm and solvent to solid ratio of 20:1 with a maximum yield of 69.7%, while the optimum extraction conditions for ultrasonic extraction were found at 1.5 h reaction time, particle size of 2mm and solvent to solid ratio of 15:1 with a maximum percentage yield of 67.2%. The analyses of the oil characteristics demonstrated that the oil extracted by soxhlet extraction shows lower PV, FFA, MVM and Alkalinity than oil extracted using Ultrasonic extraction. The results of fatty acid profile displayed that the oleic and linoleic acid contents of the soxhlet extracted oil were higher than that of the Ultrasonic extracted oil while palmitic and butanoic acid were higher in ultrasound extracted oil. Generally, ultrasound assisted extraction showed a promising oil yield regarding short extraction time and low solvent consumption but its oil quality is lower than that of soxhlet extracted oil.

Oil-Air Distribution Prediction Inside Ball Bearing with Under-Race Lubrication Based on Numerical Simulation

Oil/air two-phase flow distribution in the bearings is the basis for bearing lubrication status identification and precise thermal analysis of the bearing. In order to understand the fluid behavior inside the under-race lubrication ball bearing and obtain an accurate oil volume fraction prediction model. A numerical study of ball bearing with under-race lubrication is carried out to study oil-gas two-phase distribution inside the bearing, and the influence of several parameters is quantified, like bearing rotating speed, oil flow rate, oil viscosity, and oil density. The results indicate that the oil fraction in the bearing cavity between the inner and outer ring shows a periodic distribution along the circumference direction, and the period is the same as the number of under-race oil supply holes. Oil distribution alone radial direction is affected by the outer-ring-guiding cage and centrifugal force, leading to oil accumulation near the outer ring. Different bearing running conditions and oil characteristics do not change the oil distribution trend alone in circumference and radial direction, but the difference ratio. Finally, based on the numerical simulation results, a formula for the average oil volume fraction prediction in the bearing ring cavity is constructed.