UDC 536.24,614.83 The results of numerical investigation of the influence of wind velocity and degree of atmospheric stability on the process of toxic cloud formation on outpouring ejection of liquefied chlorine are presented. The computa- tional procedure is realized with the use of the hydrodynamic analysis package FLUENT. The proposed model describes the distribution of two clouds: primary and secondary. The primary aerosol cloud is formed as a result of instantaneous boiling up of a part of the liquid phase, and the secondary one, on evaporation (boiling) of a spill. Introduction. An analysis of the danger of emergencies often requires estimation of the propagation of toxic or explosive substances in the atmosphere. The source of information for predicting the evolution of the cloud is the intensity of entrance of the dangerous substance into the environment as a result of vaporization. The processes of va- porization and scattering of vapor in air are noted for the complex interrelation, which can hardly be taken into ac- count within the framework of simplified analytical and empirical relations. This requires using methods of numerical simulation based on packages of hydrodynamic analysis CFD for the solution of the above-mentioned problems. Within the framework of numerical simulation, the mutual effect of heat- and mass transfer processes that accompany the development of the emergency is taken into account directly by jointly solving differential equations of transfer of mass, momentum, energy, components, and turbulent characteristics. The problems of numerical simulation of the propagation of gaseous substances in the atmosphere were con- sidered in a large number of works, e.g., (1-9), however, in the existing models the description of the vaporization process is schematic only, which can be an obstacle to the reliable estimation of the zones of toxic injury or the di- mensions of a dangerous explosive cloud. With regard to the aforesaid, the problem of developing the mathematical apparatus for simulating the forma- tion of a vapor-air cloud in the case of emergency ejection of a liquefied gas as applied to the description of the source of ejection would seem urgent. In the present work, for determining the zones of toxic damage on outpouring ejection of liquefied chlorine, we suggest a model based on the program complex FLUENT. The model includes description of basic physical phe- nomena that determine the dynamics of formation of a toxic cloud: evaporation of aerosol in a cloud, vaporization in boiling (evaporation) of a spill, scattering of gas with droplet inclusions in the atmosphere, and condensation of steam in the cloud. Mathematical Model of Vaporization. On breakake of a vessel with a superheated liquid, instantaneous boil- ing up of a certain portion of the liquid phase takes place as a result of the sharp decrease in pressure and violation of the thermodynamic balance through the liberation of internal energy. This is followed by establishment of a new equilibrium state, with the temperature of the remaining portion of the liquid phase decreasing to the boiling point at atmospheric pressure. The instantaneous evaporation of liquid leads to the formation of the primary vapor cloud. To es- timate the fraction of substance x v that "instantaneously" converts into vapor, the following relation can be used (10):
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