Magnetic Characteristics Research Articles

Environmental Magnetic and Morphological Characteristics of Topsoils from the Coal Capital of India-Dhanbad

Environmental Magnetic and Morphological Characteristics of Topsoils from the Coal Capital of India-Dhanbad

Effects of transition metals (V, Cr, Mn, Fe and Ni) doping on magnetic properties of Co-based amorphous alloys

Amorphous alloys exhibit numerous interesting and abundant magnetic properties due to their disordered structural traits and have been extensively studied by researchers. In this work, the effects of a small amount of transition metals doping on the magnetic properties of Co80-xMxB20 (x = 0, 2, 4, 6, 8, 10; M = V, Cr, Mn, Fe, Ni) amorphous alloys were systematically investigated by utilizing first-principles molecular dynamics. The trend of the magnetic moment change in the simulated calculation conforms well to the experimental results. The doping of V atoms leads to the fastest rate of decrease in the magnetic moment of the surrounding Co atoms, and there is only an antiferromagnetic interaction between the V and Co atoms. When doped with Cr and Mn atoms, there is mutual competition between ferromagnetic and antiferromagnetic coupling in the amorphous alloy, Cr reduces the magnetic moment of the surrounding Co atoms, while the change in the magnetic moment of the Co atoms around Mn is small. The doping of Fe and Ni causes an increase in the magnetic moment of the surrounding Co atoms. The reason may be due to the charge transfer between atoms. The doping of Fe and Ni has a small effect on the average magnetic moment of the Co atoms in the amorphous alloy. The results provide necessary theoretical support for the development of the Co-based amorphous alloys with excellent magnetic characteristics.

Silk Fibroin Film Decorated with Ultralow FeCo Content by Sputtering Deposition Results in a Flexible and Robust Biomaterial for Magnetic Actuation.

Magnetically responsive soft biomaterials are at the forefront of bioengineering and biorobotics. We have created a magnetic hybrid material by coupling silk fibroin─i.e., a natural biopolymer with an optimal combination of biocompatibility and mechanical robustness─with the FeCo alloy, the ferromagnetic material with the highest saturation magnetization. The material is in the form of a 6 μm-thick silk fibroin film, coated with a FeCo layer (nominal thickness: 10 nm) grown by magnetron sputtering deposition. The sputtering deposition technique is versatile and eco-friendly and proves effective for growing the magnetic layer on the biopolymer substrate, also allowing one to select the area to be decorated. The hybrid material is biocompatible, lightweight, flexible, robust, and water-resistant. Electrical, structural, mechanical, and magnetic characterization of the material, both as-prepared and after being soaked in water, have provided information on the adhesion between the silk fibroin substrate and the FeCo layer and on the state of internal mechanical stresses. The hybrid film exhibits a high magnetic bending response under a magnetic field gradient, thanks to an ultralow fraction of the FeCo component (less than 0.1 vol %, i.e., well below 1 wt %). This reduces the risk of adverse health effects and makes the material suitable for bioactuation applications.

Investigating phase and magnetic properties in Co-2 wt.% MWCNT nano-composites prepared by mechanical alloying

MWCNT nano-composites with a cobalt content of 2 weight percent were created by mechanically alloying during different times. Modern techniques, including x-ray diffraction (XRD), differential thermal analysis (DTA), field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM) and superconducting quantum interference device (SQUID), were used to examine the effects of CNT addition on the Co morphology and magnetic characteristics of the samples. It was shown that the characteristics of Co in 2 weight percent MWCNT nano-composites were retained in a sample that was milled for 60 min. Agglomerates of nanoparticles were the end result, with CNTs evenly distributed throughout the cobalt matrix 60 min after mechanical alloying. Analysis of magnetic hysteresis loops revealed that the inclusion of CNTs altered the magnetic characteristics of nano-composite samples. Analysis of magnetic hysteresis loops revealed that the inclusion of CNTs altered the magnetic characteristics of nano-composite samples. The well-developed interfacial structure in this work significantly improved the cobalt-MWCNT nano-composites’ magnetic characteristics.

Customizable Induction Heating Profiles: from Tailored Colloidally Stable Nanoparticles Toward Multi‐Stage Heatable Supraparticles

AbstractMagnetic nanoparticles (NPs) are efficient heat mediators in induction heating. Originally explored for hyperthermia, their applications have broadened to industrial processes where temperature control is crucial. By adjusting the NP composition or morphology, magnetic characteristics such as Curie temperatures can be tailored, allowing control over maximum heating thresholds. These NPs are, however, usually designed for maximum heating rates at specific magnetic fields. In this work, the synthesis is presented for colloidally stable Co and ZnCo ferrite NPs with customizable maximum heating temperatures, and their combination within micron‐scaled supraparticles (SPs). Maximum induction heating temperatures of ZnCo ferrite NPs are tuned between 150 and 220 °C, while customization of Co ferrite species yields temperatures between 200 and 350 °C. These distinct magnetic properties are exploited in the selective multi‐stage heating of SPs consisting of both species. Here, ZnCo ferrite components heat up to a first temperature plateau at low alternating magnetic fields (AMF), while Co ferrite NPs reach higher temperatures at increased AMF. The precise control of induction heating thresholds through the adaptability of NPs offers a high degree of customizability which makes induction heating particularly attractive for applications requiring sequential or spatial heating, such as catalysis or debonding on demand.

The impact of cobalt oxide additions and heat treatment on wollastonite for magnetic applications

Magnetic nanocomposite was prepared using the wet chemical precipitation approach with varying amounts of cobaltous oxide (CoO). The concentrations of CoO were 0.5, 3.5, 6.5, and 9.5 g per 100 % wollastonite composition. Samples were sintered separately at 1000 and 1200 °C. X-ray diffraction analysis (XRD) of the sintered parent sample revealed the formation of wollastonite CaSiO3 and larnite Ca2SiO4, as well as a minor silicon oxide SiO2 phase. In CoO-doped samples, Co-åkermanite Ca2CoSi2O7 and other phases were formed. The XRD and scanning electron microscope SEM confirm the samples' submicron and nanocrystalline microstructure. The Fourier transform infrared spectroscopy (FTIR) and Raman spectra (RS) of investigated samples sintered at 1000 and 1200 °C revealed their bond structure. Both analyses confirmed that incorporating CoO into CaSiO3 significantly improved its vibrational modes, reflecting structural modifications. By increasing the cobalt oxide content from 3.5 to 9.5 wt%, the samples attain the ideal paramagnetic state, as demonstrated by the magnetic hysteresis (M − H) curve, which is linearly reversible. Formation of the Ca2CoSi2O7 significantly alters the magnetic characteristics of the samples, whether through increasing the cobalt oxide concentration up to 9.5 wt% or modifying the sintering temperature. This enables the prepared nonocomposites to be suitable for novel magnetic applications.

Photocatalytic degradation of rhodamine B using Yb3+-Doped Zn-Mg ferrites synthesized via conventional sol-gel auto-combustion method

The primary goal of our research is to develop a photocatalyst capable of degrading organic molecules in water, achieved through the rare earth Yb3+ doping of Zn-Mg spinel ferrites. A key element of our approach is the use of the conventional sol-gel auto-combustion process, which has proven to be an effective method for synthesizing a high-performing, visible light-driven Zn0.9Mg0.1Fe2-xYbxO4 (x = 0.000, 0.015, 0.030, 0.045, 0.060 and 0.075) nano-ferrites. Many analytical techniques were employed to evaluate the material's physicochemical characteristics, including P-XRD, EDX, FE-SEM, HR-TEM, FTIR, UV–vis, BET, VSM, EIS, and photocatalysis was carried out against the RhB. The impact of Yb3+ ion doping on the material's crystallite size and lattice parameter has been evaluated. It was found that all the samples' crystallite sizes increased between 33 and 41 nm. These magnetite nanoparticles have spherical forms and nanometric particle sizes, as revealed through field scanning electron microscopy (FE-SEM). The FTIR spectra bands at ʋ1 (518–535) and (401–411) ʋ2 subsequently revealed the spinel structure of the synthesized nano-ferrites. The band gap in zinc manganese ferrite increases from 2.51 eV to 2.92 eV after adding ytterbium. The surface area of the Yb3+-doped Zn-Mg ferries ranges from 23.6 m2/g to 27.8 m2/g, making them an excellent choice for data storage. The investigation of magnetic behavior shows the superparamagnetic behavior of all the samples. The produced sample's determined squareness value indicates the magnetostatic interaction between the particles. Because of the low produced coercive field value, these materials can be used in ferrofluids and hyperthermia therapy applications. Furthermore, with a higher RhB removal of 93.80 %, the Yb3+-doped sample photocatalyst successfully separated carriers generated by sunlight. The Yb3+-doped sample (ZMY-5) photocatalyst showed outstanding stability after one cycle of the stability test, obtaining an outstanding RhB elimination of 93.80 %. Zn0.9Mg0.1Yb0.075Fe1.925O4 photocatalyst has substantial promise for large-scale pollutant treatment due to its simple synthesis method, superior magnetic characteristics, exceptional photocatalytic activity for RhB, and excellent stability.

Exploring β12-Borophene magnetic response through Monte Carlo simulations

ABSTRACT In this work, we used Monte Carlo simulations under the Metropolis algorithm to study the magnetic characteristics of β12-Borophene. We investigated the effects of temperature, coupling interaction parameters, and external magnetic fields on changes in the magnetic response. We investigated the blocking temperature and coercive field evolution under the given conditions. The β12-Borophene under investigation exhibits a remarkable magnetic response at low temperatures, suggesting possible uses in a range of low-temperature technologies.

Spin chain orientation and magneto-optical coupling in twisted NiPS3 homostructures

Magnetic two-dimensional (2D) materials have garnered significant attention due to their unique electronic, magnetic, and optical properties and their potential applications in next-generation electronic and optoelectronic devices. However, the magneto-optical effects of oligolayer antiferromagnetic materials remain inadequately understood. Here, we investigate the magnetic properties of few-layer nickel phosphorus trisulfide (NiPS3) and its twisted heterostructures, emphasizing the observation of optical phenomena at low temperatures (1.65 K). By stacking few-layer NiPS3 to fabricate twisted homostructures, we probe their magnetic characteristics using photoluminescence (PL) spectroscopy. Our results reveal that sharp exciton peaks emerge at low temperatures and that the spin chain orientation in oligolayer NiPS3 can be discerned through the polarization dependence of exciton PL intensity. Notably, fewer-layered NiPS3 exhibits a significant magneto-optical effect under an applied magnetic field, allowing the modulation of the polarization angle of its exciton PL spectrum. Additionally, the polarization-dependent Raman spectrum of NiPS3 shows substantial changes under the influence of a magnetic field. These findings underscore the potential of few-layer NiPS3 for future magneto-optical device applications.

Magnetic properties, critical behavior, and magnetocaloric effect of Nd1−xSrxMnO3 (0.2 ≤ x ≤ 0.5): The role of Sr doping concentration

Magnetic characteristics, magnetocaloric effect, and critical behavior of Nd1−xSrxMnO3 compounds by Sr doping (x = 0.2, 0.3, 0.4, 0.5) were studied. All samples maintained orthorhombic structures, but the space group changed from Pnma (No. 62) for x = 0.2, 0.3 to Imma (No. 74) for x = 0.4, 0.5. As Sr doping increased, the Curie temperature (TC), Curie–Weiss temperature (TCW), and magnetization increased, attributed to the double exchange (DE) interaction. A discrepancy between TCW and TC was observed due to the competition between polarons and DE interaction. The critical behavior was investigated systematically using the self-consistent (modified Arrott plots, MAP) method and the Kouvel–Fisher (KF) relation. The KF relation was suitable for the samples with x = 0.2 and 0.5, while the MAP method was suitable for the samples with x = 0.3 and 0.4. Among the Ising, XY, Heisenberg, and mean-field models, the samples with x = 0.2, 0.3, and 0.4 aligned more closely with the mean-field model, except for the x = 0.5 sample. Entropy change (−ΔSM) of Nd1−xSrxMnO3 (0.2 ≤ x ≤ 0.5) increased with the applied field, with the maximum value observed around TC. For the sample with x = 0.3, (−ΔSM) reached 4.315 J/kg K at μ0ΔH = 50 kOe, corresponding to a relative cooling power (RCP) of 280.48 J/kg. Remarkably, the x = 0.4 sample displayed (−ΔSM) of 3.298 J/kg K at μ0ΔH = 50 kOe near room temperature, with the RCP of 283.64 J/kg. These findings underscore the role of Sr doping in tuning the magnetic properties, critical behavior, and magnetocaloric effect of NdMnO3.

Microwave absorption performance of La1.5Sr0.5NiO4/SrFe12O19 composites with thin matching thickness

The global focus on electromagnetic interference and pollution is undeniable. To counter these challenges, high-performance microwave-absorbing materials (MAMs), typically composed of dielectric and magnetic components, offer effective solutions by ensuring favorable impedance matching. Leveraging these MAMs has proven beneficial across various sectors, including 5G technology, information security, energy harvesting, diminished radar cross-section, and advancements in military applications. We successfully synthesized composites of La1.5Sr0.5NiO4 (LSNO) and SrFe12O19 (SrM) composites through ball milling and heat treatment. With the escalation of SrM weight percentage in the composites, noticeable alteration in structural, morphological, and static magnetic characteristics was ensured.Moreover, the amalgamation of these components bolstered the EM properties, consequently yielding exceptional microwave absorption capabilities in the composites. The composites with 40, 60, and 80 wt% of SrM (named S4, S6, and S8) exhibited excellent microwave absorption performance with an absorption rate of over 99.9 % for a thin thickness. The S4 and S8 composites attained reflection loss (RL) values of −34.75 dB and −36.93 dB, with 2.0 and 1.6 mm thicknesses, respectively. Meanwhile, the S6 composite achieved an RL value of −44.24 dB with a thickness of 1.9 mm. These composites' outstanding microwave absorption performance can be attributed to their significant magnetic loss, remarkable dielectric loss, and synergistic effects.

Comprehensive study on the structural and magnetic characteristics of Na0.5Bi0.5TiO3-Y3Fe5O12 particulate composites

Comprehensive study on the structural and magnetic characteristics of Na0.5Bi0.5TiO3-Y3Fe5O12 particulate composites

Application of mechanical separation method with filtration for nanodispersed FeNi powders with carbon coating

It was shown that the method of mechanical separation with filtration could be used to separate metal nanoparticles in a carbon shell. The method was used for separation of FeNi nanoparticles with a carbon shell, previously isolated from carbon condensate by boiling in acids. The particles had a crystalline structure and magnetic characteristics (Mr/Ms = 0.30, Hc = 270 Oe). Method of mechanical separation with filtration made it possible to separate the sample into particles coated with a carbon shell (particles size 40–50 nm, size of the metal core 10–15 nm), and into metal particles with a diameter of 6–15 nm, dispersed in a carbon matrix. The work shows that the samples have similar magnetic properties (Mr/Ms = 0.27, Hc = 236 Oe) and chemical composition (Ni ∼ 10 wt.%, Fe ∼ 12 wt.%, C ∼ 57 wt.%). However, the samples differ in structure, one contains FeNi(220), FeNi(200), FeNi(111) and C(002) phases, while the other contains only FeNi(200) and C(002) phases.

Impact of substituting Cu2+/Ce3+ cations on the structural, magnetic and electrical properties of cobalt nano ferrites

The nano ferrite compounds Co1-xCuxFe2-yCeyO4 (with x values of 0.0, 0.25, 0.5, and 0.75, and y values of 0.0, 0.03, 0.06, and 0.09) were synthesized through the sol-gel auto-combustion method. The characteristics of spinel ferrites were tailored by creating nano ferrites with desirable properties, which were then sintered at 1150 °C for 2 h in the presence of rare earth (Ce3+) and transition metals (Cu2+). They were investigated using dielectric, FTIR, FESEM, XRD, VSM, and DC electrical resistivity experiments. XRD examination verified the samples' cubic spinel structure by measuring the average crystallite size, x-ray density, and lattice constant. FESEM images revealed grain sizes ranging from 41.07 to 156 nm. FTIR spectra in the range of 415 cm−1 to 430 cm−1 further supported the substitution of Cu2+/Ce3+ ions in the tetrahedral sites, indicated by an increase in the lattice parameter. Measurements of the remanence ratio, saturation magnetization, anisotropy constant, coercivity, and magnetic moment, among other magnetic characteristics, were made. Higher concentrations of Cu2+/Ce3+ ions were found to considerably reduce magnetic saturation (Ms), coercivity (Hc), and remanence (Mr). These materials were semiconducting because their activation energy varied between 0.52 and 0.62 eV, and their DC resistivity increased with increasing Cu2+/Ce3+ concentration. Above 1 MHz, the dielectric properties became frequency-independent and decreased with increasing frequency. These ferrites seem highly potential for devices working at high frequency.

Modification to traditional vertical axis wind turbine system to implement permanent magnet propelling phenomenon as measure of performance enhancement

The environmentally friendly, easily available and affordable alternative energy sources are one of the important requirements for the growth of the modern world. This research work explains how the magnetic repulsion characteristics of permanent magnets could be used as the energy source to meet energy demands. The wok is carried out on the permanent magnet propelled vertical axis wind turbine and its performance is compared with the traditional vertical axis wind turbine. The results show that the permanent magnet propelled wind turbine will function much better than the traditional one, even at slower wind speeds. The magnetic repulsive properties are used as a supplementary energy source in a permanent magnet propelled vertical axis wind turbine, which add kinetic energy to the turbine’s rotational momentum, while transforming wind power to mechanical movement.

Time Series of Magnetic Field Parameters of Merged MDI and HMI Space-weather Active Region Patches as Potential Tool for Solar Flare Forecasting

Solar flare prediction studies have been recently conducted with the use of Space-Weather MDI (Michelson Doppler Imager on board Solar and Heliospheric Observatory) Active Region Patches (SMARPs) and Space-Weather HMI (Helioseismic and Magnetic Imager on board Solar Dynamics Observatory) Active Region Patches (SHARPs), which are two currently available data products containing magnetic field characteristics of solar active regions (ARs). The present work is an effort to combine them into one data product, and perform some initial statistical analyses in order to further expand their application in space-weather forecasting. The combined data are derived by filtering, rescaling, and merging the SMARP and SHARP parameters, which can then be spatially reduced to create uniform multivariate time series. The resulting combined MDI–HMI data set currently spans the period between 1996 April 4 and 2022 December 13, and may be extended to a more recent date. This provides an opportunity to correlate and compare it with other space-weather time series, such as the daily solar flare index or the statistical properties of the soft X-ray flux measured by the Geostationary Operational Environmental Satellites. Time-lagged cross correlation indicates that a relationship may exist, where some magnetic field properties of ARs lead the flare index in time. Applying the rolling-window technique makes it possible to see how this leader–follower dynamic varies with time. Preliminary results indicate that areas of high correlation generally correspond to increased flare activity during the peak solar cycle.

A Study on the Structural, Magnetic, and Electrical Characterization of Nickel-Iron-Cobalt Films and [FeNiCo/Cu]30 and [FeNiCo/Cu]60 Multilayers

A Study on the Structural, Magnetic, and Electrical Characterization of Nickel-Iron-Cobalt Films and [FeNiCo/Cu]30 and [FeNiCo/Cu]60 Multilayers

Dynamic magnetic characteristics of the kinetic Ising model under the influence of randomness.

In this paper, we propose to solve the issues of long-range or next-neighbor interactions by introducing randomness. This approach is applied to the square lattice Ising model. The Monte Carlo method with the Metropolis algorithm is utilized to calculate the critical temperature T_{C}^{*} under equilibrium thermodynamic phase transition conditions and to investigate the characterization of randomness in terms of magnetization. In order to further characterize the effect of this randomness on the magnetic system, clustering coefficients C_{p} are introduced. Furthermore, we investigate a number of dynamic magnetic behaviors, including dynamic hysteresis behaviors and metamagnetic anomalies. The results indicate that noise has the effect of destabilizing the system and promoting the dynamic phase transition. When the system is subjected to noise, the effect of this noise can be mitigated by the addition of a time-oscillating magnetic field. Finally, the evolution of anomalous metamagnetic fluctuations under the influence of white noise is examined. The relationship between the bias field corresponding to the peak of the curve h_{b}^{peak} and the noise parameter σ satisfies the exponential growth equation, which is consistent with other results.

Low-cycle fatigue of welded joint from steel of X70 strength class

Steels of X70 strength class are particularly widely used in the field of heavy engineering. One of the most important issues when choosing steel for structures is its behavior under cyclic loads. It is difficult to find a description of the behavior of all zones of the welded joint under fatigue. The purpose of this study was to determine the fatigue characteristics of welded joints made of the Russian analogue of S690QL steel with fixation of acoustic and magnetic parameters for their use in the diagnosis. The objects of the study were the samples from domestic steel of X70 strength class. The chemical composition was determined using optical emission spectrometry. The grinds for microstructural analysis were prepared according to the standard technique with etching in the metal. The fatigue test was carried out on a specialized test bench. The authors used the acoustic system AIS NRK-3 for acoustic measurements and the acoustic parameter D – as an informative parameter. A MA-412MM coercitimeter was applied to evalua­te the magnetic characteristics. The following were evaluated: residual magnetization Br , coercive force Hc , Hc/Br ratio. The smallest number of cycles corresponds to the deposited metal zone. The decrease in amplitude showed a significant variation in the behavior of the material depending on the junction zone. However, the curves for heat affected zone (HAZ) and the deposited metal are practically the same. HAZ differs to a lesser extent from the base metal than the deposited metal zone. The graph of the acoustic parameter in its form is the reverse of the magnetic characteristics graph. Thus, there is a minimum for the acoustic parameter, depending on the operating time, and a maximum for the magnetic characteristics. For both graphs, the extremum is the point corresponding to the operating time of 0.6.

Coating of Carbon Black (CB) and Graphene Oxides (GOs) with Magnetite (Fe3O4)

Composites containing iron oxides are obtained by the co-precipitation of iron(II) and iron(III) compounds in the presence of different substrates in an alkaline environment. Newly synthesized graphene oxide (GO), reduced graphene oxide (rCO) and carbon black (CB) are used as substrates. Methods of obtaining GO–amorphous iron compound, rGO–Fe3O4, and CB–Fe3O4 composites are developed. It is determined that rGO–Fe3O4 and CB–Fe3O4 magnetic composites can be obtained at 70–75°C, while in the presence of GO, a non-magnetic composite containing an amorphous iron compound is formed under the same conditions. This composite, when heated in vacuum at 170–175°C, undergoes exfoliation, in result of which a powder composite rGO–amorphous iron compound is formed, the volume of which is 2.7 times greater than that of initial powder. Partial reduction of the formed composite takes place at 550°C and rGO–Fe3O4 is obtained. Formation of the magnetite phase is determined by XRD (X-Ray Diffraction) analysis. The structural-morphological study of the synthesized composites is carried out by the SEM (Scanning Electron Microscopy) method. Their magnetic characteristics are studied using VSM (Vibrating Sample Magnetometry) method.