Characteristic Wavelength Research Articles

A CARS-SPA-GA Feature Wavelength Selection Method Based on Hyperspectral Imaging with Potato Leaf Disease Classification.

Early blight and ladybug beetle infestation are important factors threatening potato yields. The current research on disease classification using the spectral differences between the healthy and disease-stressed leaves of plants has achieved good progress in a variety of crops, but less research has been conducted on early blight in potato. This paper proposes a CARS-SPA-GA feature selection method. First, the raw spectral data of potato leaves in the visible/near-infrared light region were preprocessed. Then, the feature wavelengths were selected via competitive adaptive reweighted sampling (CARS) and the successive projection algorithm (SPA), respectively. Then, the two sets of wavelengths were reorganized and duplicates were removed, and secondary feature selection was conducted with genetic algorithm (GA). Finally, the feature wavelengths were fed into different classifiers and the parameters were optimized using a real-coded genetic algorithm (RCGA). The experimental results show that the feature wavelengths selected by the CARS-SPA-GA method accounted only for 9% of the full band, and the classification accuracy of the RCGA-optimized support vector machine (SVM) classification model reached 98.366%. These results show that it is feasible to classify early blight and ladybug beetle infestation in potato using visible/near-infrared spectral data, and the CARS-SPA-GA method can substantially improve the accuracy and detection efficiency of potato pest and disease classification.

Quantitative Prediction of Acid Value of Camellia Seed Oil Based on Hyperspectral Imaging Technology Fusing Spectral and Image Features.

Acid value (AV) serves as an important indicator to assess the quality of oil, which can be used to judge the deterioration of edible oil. In order to realize the quantitative prediction of the AV of camellia seed oil, which was made from camellia oleifolia, hyperspectral data of 168 camellia seed oil samples were collected using a hyperspectral imaging system, which were related to their AV content measured via classical chemical titration. On the basis of hyperspectral full wavelengths, characteristic wavelengths, and fusing spectral and image features, the quantitative prediction AV models for camellia seed oil were established. The results demonstrating the 2Der-SPA-GLCM-PLSR model fusing spectral and image features stood out as the optimal choices for the AV prediction of camellia seed oil, with the correlation coefficient of calibration set (Rc2) and the correlation coefficient of prediction set (Rp2) at 0.9698 and 0.9581, respectively. Compared with those of 2Der-SPA-PLSR, the Rc2 and Rp2 were improved by 2.11% and 2.57%, respectively. Compared with those of 2Der-PLSR, the Rc2 and Rp2 were improved by 5.02% and 5.31%, respectively. Compared with the model based on original spectrum, the Rc2 and Rp2 were improved by 32.63% and 40.11%, respectively. After spectral preprocessing, characteristic wavelength selection, and fusing spectral and image features, the correlation coefficient of the optimal AV prediction model was continuously improved, while the root mean square error was continuously decreased. The research demonstrated that hyperspectral imaging technology could precisely and quantitatively predict the AV of camellia seed oil and also provide a new environmental method for detecting the AV of other edible oils, which is conducive to sustainable development.

Rapid on-site multi-indicator detection of Polygonatum cyrtonema Hua by handheld near-infrared spectroscopy with wavelength selection

The rapid, accurate, and on-site quantitative evaluation of the 3 components (total polysaccharide, total flavonoid, and total saponin) of Polygonatum cyrtonema Hua (PCH) is of great significance to ensure the value of its medicine and food, for this purpose, a handheld near-infrared (NIR) spectrometer was used. The raw NIR spectra were preprocessed by seven methods and their combinations, then three kinds of wavelength selection algorithms, the competitive adaptive reweighted sampling (CARS), random frog (RF) sampling, and Monte Carlo uninformative variable elimination (MCUVE) were applied, and the characteristic wavelengths for total polysaccharide, total saponin, and total flavonoid in PCH were obtained, respectively. Subsequently, the partial least squares (PLS) regression models were developed. The results showed that the combination of first derivative and standard normal variate was the optimal pretreatment method, and CARS had the highest performance of the wavelength selection for total polysaccharide and total flavonoid, while RF was the highest for total saponin. With these selected wavelengths, 3 PLS prediction models were built, and their performances were validated with unknown samples, the results showed that the determination coefficient of the prediction set (R2P) of total polysaccharide, total saponin, and total flavonoid were 0.980, 0.948, and 0.942, respectively, and the corresponding root mean square error of prediction set (RMSEP) were 0.162, 0.142, and 0.052. Furthermore, the residual prediction deviations (RPDs) of the three components were all larger than 3, demonstrating the prediction performance of the models was high. Therefore, the three active functional components in PCH could be rapidly determined by a handheld NIR spectrometer, which would be beneficial for ensuring the quality of PCH.

Predicting water content in engine oil using SPA-ISSA-BP methods  

Contamination of engine oil with water can accelerate oil oxidation and decomposition, resulting in oil degradation. Therefore, the detection and prediction of water content in engine oil is crucial to ensure the long-term safe operation of engines. In this study, near-infrared spectroscopy was used to analyse engine oils with varying water contents. Spectral data were obtained, and various methods, including Savitzky-Golay (SG) smoothing, orthogonal signal correction (OSC), and successive projection algorithm (SPA) were employed to compare the performance differences of principal component regression models. An Improved Sparrow Searches Algorithm (ISSA) was then applied to optimise the Back-Propagation Neural Network (BPNN) for predicting water content in SAE 10W-30 engine oil. The results showed that the performance of the principal component regression model constructed from spectral data after SG smoothing, OSC, and the SPA feature wavelength selection had improved. The BPNN optimised by the improved Sparrow Search Algorithm accelerated the convergence speed of the model and effectively improved the prediction accuracy of the BPNN. The obtained coefficient of determination (R2) was 0.99103, the root mean square error (RMSE) was 2. 2136 10-4, and the mean absolute error (MAE) was 1. 8889×10-4. These results provide an effective method for detecting and predicting the water content in engine oil.

Rapid Identification of the Geographical Origin of the Chinese Mitten Crab (Eriocheir sinensis) Using Near-Infrared Spectroscopy.

The Chinese mitten crab (Eriocheir sinensis) is highly valued by consumers for its delicious taste and high nutritional content, including proteins and trace elements, giving it significant economic value. However, variations in taste and nutritional value among crabs from different regions lead to considerable price differences, fueling the prevalence of counterfeit crabs in the market. Currently, there are no rapid detection methods to verify the origin of Chinese mitten crabs, making it crucial to develop fast and accurate detection techniques to protect consumer rights. This study focused on Chinese mitten crabs from different regions, specifically Hongze Lake, Tuo Lake, and Weishan Lake, by collecting near-infrared (NIR) diffuse reflectance spectral data from both the abdomen and carapace regions of the crabs. To eliminate noise from the spectral data, pretreatment was performed using Savitzky-Golay (SG) smoothing, Standard Normal Variate (SNV) transformation, and Multiplicative Scatter Correction (MSC). Key wavelengths reflecting the origin of Chinese mitten crabs were selected using Competitive Adaptive Reweighted Sampling (CARS), Bootstrap Soft Shrinkage (BOSS), and Uninformative Variable Elimination (UVE) algorithms. Finally, Support Vector Machine (SVM), Convolutional Neural Network (CNN), and Back Propagation Neural Network (BP) models were developed for rapid detection of crab origin. The results demonstrated that MSC provided the best preprocessing performance for NIR spectral data from both the abdomen and back of the crabs. For abdomen data, the SVM model developed using feature wavelengths selected by the CARS algorithm after MSC preprocessing achieved the highest accuracy (Acc) of 90.00%, with precision (P), recall (R), and F1-score for crabs from Weishan Lake at 89.29%, 86.21%, and 87.72%, respectively; for crabs from Tuo Lake at 86.96%, 95.24%, and 90.91%; and for crabs from Hongze Lake at 90.00%, 93.10%, and 91.53%. For carapace data, the SVM model based on wavelengths selected by the BOSS algorithm after MSC pretreatment achieved the best performance, with an Acc of 87.50%, and P, R, and F1 for crabs from Weishan Lake at 77.14%, 93.10%, and 84.38%; for Tuo Lake crabs at 100%, 90.47%, and 95.00%; and for Hongze Lake crabs at 92.31%, 80.00%, and 85.71%. In conclusion, NIR spectroscopy can effectively detect the origin of Chinese mitten crabs, providing technical support for developing rapid detection instruments and thereby safeguarding consumer rights.

Nondestructive intelligent detection of total viable count in pork based on miniaturized spectral sensor

Changes in the freshness of pork due to microbial action during complex transportation and storage indicate an urgent need for in-situ, real-time monitoring techniques for chemical spoilage of meat. This study reported the use of a portable detection device based on a miniaturized visible/near-infrared spectrometer, combined with data noise reduction and machine learning methods, to predict the total viable count (TVC) in pork samples. A rapid detection device for pork TVC was designed based on the miniaturized spectrometer; a spectral preprocessing method based on the resolution of the spectrometer was proposed; the effects of different preprocessing methods on the full-wavelength modeling effect were compared; and four different feature wavelength extraction algorithms were utilized for the feature wavelengths of pork TVC. The modeling effects of different simplified models were compared. The results showed that resolution interval correction combined with standard normal variation was the most effective in full-wavelength modeling, with correlation coefficients of prediction set (RP), root mean square errors in prediction set (RMSEP), and relative percent deviation (RPD) of 0.918, 0.464 (lg CFU/g), and 2.508, respectively; interval random frog − partial least squares regression (iRF-PLSR) had the best predictive ability among all simplified models, the number of wavelengths used in the simplified model was reduced by 85.45% compared with the full-wavelength model. In contrast, the model performance was improved with RP, RMSEP, and RPD of 0.948, 0.392 (lg CFU/g) and 2.970, respectively. The combination of a rational spectral acquisition setup and a data processing methodology, the miniaturized spectrometer showed competitive results with the complex detection system in predicting meat TVC.

Early detection and lesion visualization of pear leaf anthracnose based on multi-source feature fusion of hyperspectral imaging.

Pear anthracnose, caused by Colletotrichum bacteria, is a severe infectious disease that significantly impacts the growth, development, and fruit yield of pear trees. Early detection of pear anthracnose before symptoms manifest is of great importance in preventing its spread and minimizing economic losses. This study utilized hyperspectral imaging (HSI) technology to investigate early detection of pear anthracnose through spectral features, vegetation indices (VIs), and texture features (TFs). Healthy and diseased pear leaves aged 1 to 5 days were selected as subjects for capturing hyperspectral images at various stages of health and disease. Characteristic wavelengths (OWs1 and OWs2) were extracted using the Successive Projection Algorithm (SPA) and Competitive Adaptive Reweighted Sampling (CARS) algorithm. Significant VIs were identified using the Random Forest (RF) algorithm, while effective TFs were derived from the Gray Level Co-occurrence Matrix (GLCM). A classification model for pear leaf early anthracnose disease was constructed by integrating different features using three machine learning algorithms: Support Vector Machine (SVM), Extreme Learning Machine (ELM), and Back Propagation Neural Network (BPNN). The results showed that: the classification identification model constructed based on the feature fusion performed better than that of single feature, with the OWs2-VIs-TFs-BPNN model achieving a highest accuracy of 98.61% in detection and identification of pear leaf early anthracnose disease. Additionally, to intuitively and effectively monitor the progression and severity of anthracnose in pear leaves, the visualization of anthracnose lesions was achieved using Successive Maximum Angle Convex Cone (SMACC) and Spectral Information Divergence (SID) techniques. According to our research results, the fusion of multi-source features based on hyperspectral imaging can be a reliable method to detect early asymptomatic infection of pear leaf anthracnose, and provide scientific theoretical support for early warning and prevention of pear leaf diseases.

Development of an online prediction system for soil organic matter and soil moisture content based on multi-modal fusion

Realizing accurate determination of in situ soil organic matter (SOM) content and soil moisture (SM) content in the field is of great importance for improving agricultural production efficiency. However, the feature information of a single sensor is limited, and there is still a certain gap in modeling accuracy compared to traditional laboratory methods. The variations of SM in the field also interfere with data collection, limiting the application of single sensor. In order to realize the efficient detection of in-situ SOM and SM content, this study developed an online detection system for SOM and SM content based on the fusion of characteristic wavelengths, visible images and thermal imaging image features. Firstly, based on a vehicle-mounted platform, a visible-thermal imaging camera and a characteristic wavelength integration device were integrated in a deep pine plow to realize the simultaneous acquisition of in-situ soil multi-sensor data. Then, a lightweight multimodal network was constructed to obtain thermal visible light image features and characteristic wavelength features through branch networks, achieving deep fusion of different modal data and predicting SOM and SM content. Finally, output the forecasting results of SOM and SM content, and transmit the predictive information to the cloud platform for storage. It was verified that the Multi-modal proposed in this study worked best in the laboratory environment, with a predicted R2 of 0.91 and RMSE of 2.9 g/kg for SOM, and a predicted R2 of 0.92 and RMSE of 0.77 % for SM. Compared with single image or characteristic spectral data, the fusion of visible image and characteristic wavelength effectively improved the prediction accuracy of SOM. The real-time prediction of SM was realized by fusing thermal imaging data, and the elimination of the moisture effect of visible images and characteristic wavelengths was also realized with the help of deep fusion of Multi-modal network. After field validation, the R2 of the Multi-modal system was 0.84 and the RMSE was 5.0 g/kg for SOM, and the R2 of the SM was 0.88 and the RMSE was 1.03 %. Despite the differences in soil types between the validation field and the sampling field, the system still demonstrated strong generalization and achieved high accuracy prediction of in-situ SOM and SM in the field, which effectively improves the efficiency and applicability of field. The efficiency and applicability of soil testing effectively improve the efficiency and provide technical guidance for precision management in the field.

Ringing mountain ranges: Teleseismic signature of the interaction of high-frequency wavefields with near-source topography at the Degelen nuclear test site

Summary Over the last decade there has been an international effort to find methods to recover and digitize recordings from historical earthquakes and explosions that occurred during the 1950’s through to the 1980’s. Making these recordings accessible in digital format offers opportunities to study what signatures are encoded in the data, and to apply state-of-the-art techniques and methods to historical data. In this study we employ unsupervised machine learning to cluster historical teleseismic waveforms from nuclear explosions conducted at the former USSR Degelen test site, in Kazakhstan, recorded at seismic arrays in the UK (EKA), Canada (YKA), Australia (WRA) and India (GBA). In particular, we use two unsupervised algorithms to cluster waveforms using shape-based clustering: kernel k-means and k-Shape. The algorithms clearly split waveforms into distinct clusters that are spatially related, even when waveform differences are subtle, and we show with local and teleseismic numerical simulations that the clusters are related to the topography. The topography at the Degelen test site has characteristic wavelengths of 2-4 km and local simulations highlight that the seismic wavefield is trapped in reverberating mountain peaks. The location of the explosion is crucial in determining which section of the mountain range reverberates, influencing the outgoing wavefield. Teleseismic waveform simulations confirm that it is this superposition of energy leaving the reverberating peaks that results in the observed teleseismic waveform differences we observe.

Non-destructive detection of male and female information in ducklings based on near-infrared spectral wavelength selection and deep learning

The technology for sex identification in ducklings can contribute to increased revenue and cost savings in modern duck farming. However, traditional manual identification techniques require high skill levels and involve significant labor intensity. In this study, a non-destructive, user-friendly, and efficient duckling sex identification technique was proposed using near-infrared spectroscopy and deep learning algorithms. Spectral data from 600 groups of newly hatched ducklings were collected. These data were divided into training, testing, and validation sets in a ratio of 7:2:1. The raw spectral data was preprocessed using the Savitzky-Golay convolution derivative method, which was employed for subsequent spectral feature wavelength extraction and modeling. The characteristic wavelengths were extracted using competitive adaptive reweighted sampling (CARS), successive projections algorithm (SPA), and uninformative variable elimination combined with SPA (UVE-SPA). Conventional machine learning methods − support vector machine (SVM) and different deep learning models, including multilayer perceptron (MLP), mobile network version 2 (MobileNetV2), and residual neural network (ResNet), were studied and compared. The experiment showed that deep learning algorithms outperform traditional spectral analysis models in terms of classification performance. Furthermore, conducting feature wavelength extraction before constructing the classification model could reduce the model’s testing time and even improve its classification performance. Finally, the four models with better classification performance were validated using a validation set, and the combination of MobileNetV2 model UVE-SPA was selected as the optimized model for ducklings’ gender determination, with a classification accuracy of 98.3 % and an average validation time of 1.1 ms. In summary, the detection model established using near-infrared spectroscopy and MobileNetV2 can achieve non-destructive identification of the gender of ducklings. The findings can provide a preliminary research foundation and technical support for the subsequent design of related online intelligent detection systems.

Screening the characteristic hyperspectral wavelength variables of peanut leaves based on coupled algorithms to predict SPAD value in peanut

ABSTRACT The accurate acquisition and prediction of the chlorophyll content in peanuts can provide reference for scientifically sound planting and management of peanut crops. In this study, peanut canopy leaves analysed during the flowering and pegging period were taken as the research object, and the spectral data collected by a portable hyperspectral spectrometer were used as the data source to study the inversion model of peanut leaf soil and plant analyser development (SPAD). To address the issues of randomness, the need for multiple iterations, and strong subjectivity in threshold selection in the initial variable set of the random frog (RF) algorithm, an improved RF algorithm was developed based on the sparse group lasso tool. By analysing and comparing the results of variable extraction of the improved RF algorithm and six characteristic wavelength screening algorithms, three algorithms were selected for pairwise coupling. These six algorithms were the correlation coefficient method (CC), successive projections algorithm, iteratively retains informative variables (IRIV), uninformative variable elimination (UVE), competitive adaptive reweighed sampling, and a genetic algorithm. The results show that: (1) the results of CC, UVE, and IRIV algorithms are better in a single algorithm experiment; and (2) in the coupled algorithms experiment, CC-UVE, CC-IRIV, and UVE-IRIV methods can effectively reduce dimensions, and the model has a certain level of stability. Among them, the UVE-IRIV-Extreme gradient boosting model had the highest accuracy, R 2 = 0.652, RMSE = 1.867, and the variable compression rate was as high as 97.84%. The research results can provide a theoretical basis for rapid and accurate monitoring of the SPAD values of peanut leaves.

Predicting leaf nitrogen content of coffee trees using the canopy hyperspectral reflectance feature bands, vegetation index and machine learning

ABSTRACT Leaf nitrogen content (LNC) is an essential indicator of crop nitrogen status. To rapidly and correctly estimate the LNC using hyperspectral remote sensing, the canopy hyperspectral reflectance of coffee trees treated with five levels of nitrogen fertilization in a greenhouse was obtained in this study. Five methods were used for hyperspectral data preprocessing, namely, Savitzky–Golay (SG) smoothing, a combination of SG and standard normal variate transformation (SG-SNV), a combination of SG and first-order derivative (SG-FD), a combination of SG and second-order derivative (SG-SD), and a combination of SG and multiplicative scatter correction (SG-MSC). Feature wavelengths were extracted using variables combination population analysis (VCPA), competitive adaptive reweighted sampling (CARS), and the combination (CARS-SPA) of CARS and successive projections algorithm (SPA). Vegetation indexes (VIs) were constructed and subjected to correlation analysis and variance inflation factor (VIF) analysis. Linear and nonlinear models including partial least squares regression (PLSR), back propagation neural network (BPNN), extreme learning machine (ELM), random forest regression (RFR), and support vector regression (SVR), were adopted to construct LNC retrieval models for coffee trees. The results indicated that SG-MSC could increase the signal-to-noise ratio of hyperspectral data well. The wavelengths selected by CARS-SPA were more relevant to LNC, and combined with ELM resulted in the best performance of LNC prediction (R2 P = 0.901, RMSEP = 0.825 g·kg−1, RPD = 3.229). Ten VIs were obtained through correlation analysis and VIF, and the VIs-based ELM prediction model also performed moderately well (R2 P = 0.814, RMSEP = 1.131 g·kg−1, RPD = 2.354). By comparing the coffee LNC prediction models established by different methods, two coffee LNC inversion models with better prediction accuracy were obtained, which provide a scientific basis for accurate diagnosis of coffee trees LNC, and are of great significance for optimizing the field management.

Comprehensive influence of dimensionless wave velocity and expansion ratio on energy absorption characteristics of variable wavelength traveling wave turbine

Based on the traveling wave motion of fish, this paper introduces a new type of variable wavelength traveling wave turbine that significantly differs from traditional turbine designs in its mechanical structure. By developing a two-dimensional traveling wavy plate model and conducting numerical simulations, this study investigates the relationship between the dimensionless wave velocity, variable wavelength coefficient, and expansion ratio, as well as their combined effects on the energy absorption characteristics of the variable wavelength traveling wave turbine. The results reveal that energy absorption efficiency peaks at an optimal dimensionless wave velocity, which is unaffected by changes in the variable wavelength coefficient. Furthermore, the expansion ratio significantly influences both the dimensionless wave velocity and the variable wavelength coefficient, with an optimal ratio of π∗ = 2.5 achieving 90.42 % efficiency. The energy absorption characteristics of the plate with a larger variable wavelength coefficient are found to be constrained by the expansion ratio. Additional analysis reveals that flow characteristics, such as the pressure distribution, vortex street, and velocity field surrounding the traveling wavy plate, are closely related to its energy absorption performance. These findings provide valuable insights for the design of variable wavelength traveling wave turbine.

Estimation on powdery mildew of wheat canopy based on in-situ hyperspectral responses and characteristic wavelengths optimization

Wheat powdery mildew (WPM) mainly damages leaves, which leads to yield reduction. Although spectroscopy has been considered as one of the effective methods to detect crop diseases, the severity estimation of WPM is challenged by complex changes of wheat canopy reflection, wavelength redundancy in hyperspectral data, et al., so that to reduce the accuracy of disease index (DI) estimation. Aiming to estimate DI of WPM, an optimization method combined of band intervals and sensitive wavelengths screening was proposed by in-situ reflected spectral responses. Field experiments were conducted in 2022 and 2023. With regards to data processing, after preprocessing by Savitzky-Golay (SG) and multiplicative scatter correction (MSC) methods, the backward interval partial least squares (Bipls) method was used to featuring band interval. Then, the characteristic wavelengths in the selected interval were optimized by the variable important in projection (VIP), maximal information coefficient (MIC) and variable importance measure based on random forest (RFVIM) method, separately. Finally, partial least squares regression (PLSR) was used to establish the DI estimating model of WPM, and the best model was selected by comparing the performance among the models. The results indicate that the Bipls-VIP-PLSR model has the best performance (2022: =0.78, RMSEV =10.94%; 2023: =0.75, RMSEV=11.73%), and it was used to estimate the DI changes in the field. The distribution map of DI provided a potential for WPM monitoring and plant protection decision-making.

The Observational and Numerical Analysis of the Rayleigh–Taylor Instability beneath a Hedgerow Prominence

Using Swedish 1 m Solar Telescope Crisp Imaging Spectro-Polarimeter 6563 Å (Hα) observations and Mancha3D simulations, we analyze the formation and evolution of falling knots beneath a hedgerow prominence. By comparing the observed knot widths and kinematics to those of a parametric survey of simulations, we estimate the range of magnetic field values and characteristic wavelengths to test if the magnetic Rayleigh–Taylor instability (MRTI) can provide a physically meaningful explanation. We recover observational parameters using a novel semiautomated method and find knot velocities with a mean of −9.68 km s−1 and a mean width of 614 km. Our simulations survey a range of critical wavelengths, λ c , of 100 to 500 km, and magnetic field strengths, B 0, of 1 to 20 G, finding the closest match to observations around λ c = 300 km, and B 0 = 2 to 6 G. As both the observational and simulated values match expected values, we conclude that the MRTI can provide a physically meaningful explanation of this observation. Additionally, we also predict that the Daniel K. Inouye Solar Telescope will be able to observationally recover secondary instabilities on the leading edge of the falling mass through applying a point-spread function to an example from the simulated results.

Non-Destructive Identification of Virgin Cashmere and Chemically Modified Wool Fibers Based on Fractional Order Derivative and Improved Wavelength Extraction Algorithm Using NIR Spectroscopy and Chemometrics

ABSTRACT Virgin cashmere is highly prized for its superior quality, and chemically modified wool is often used to fake it. However, traditional spectral analysis and image processing methods struggle to identify the two fibers. To address this, combining chemometrics with near-infrared (NIR) spectroscopy is proposed to identify virgin cashmere and chemically modified wool based on fractional order derivatives and improved wavelength extraction algorithm. The original spectra of the two fibers are very close, making identification difficult. Therefore, fractional order derivatives are used to amplify tiny spectral differences, which are often overlooked in conventional analysis. Meanwhile, common wavelength extraction algorithms few consider inherent relationship between spectral features and chemical properties, so an improved wavelength extraction algorithm using Shuffled Frog Leaping Algorithm (SFLA) and Beluga Whale Optimization (BWO) is employed to explore the connection of the two. The proposed method with Partial Least Squares Discriminant Analysis (PLS-DA) achieves an accuracy of 94.4%. Experimental results demonstrate that fractional order derivatives enhance tiny spectral features and differences, while extracted feature wavelengths correspond to main chemical characteristic bands of the fibers. This study shows the feasibility of identifying virgin cashmere and chemically modified wool and offers a novel idea for identifying fibers in the textile industry.

A venting resonator emitting monochromatic periodic traveling waves in dispersive media

Dynamically stable traveling periodic waves are notoriously difficult to realize experimentally. Manifestations of such waves inherently become unstable in any dispersive medium, whether it be at continuum length scales in fluid mechanics, in electrodynamics, or in nonlinear optics. Here, a simple experimental system is proposed where Stokes waves are emitted from a resonator whose cavity accommodates standing waves of same wavelength that is emitted out. A single characteristic wavelength is found for each driving frequency despite the coexistence of standing and traveling waves, external noise, and potentially parasitic reflections. The system's response is shown to be reliable at very small values of quality factor. A unique utility of this model system is suggested in that such a venting resonator can be used as an inhibitor of modulation instability in dispersive medium where an engineering application demands stable periodic traveling waves. Some parallels are drawn with other unbounded resonators found in society, whereby their leakiness is central to their application, such as the role of air-filled cavity to achieve impedance matching in stringed musical instruments, or energy harvesting from oscillating fluid columns in nature.

Ratiometric optical temperature sensing properties based on up-conversion luminescence of novel NaLaTi2O6:Yb3+,Er3+/Ho3+ phosphors

To satisfy the increasing necessity of contactless optical thermometry, utilizing both thermally coupled (TCLs) or non-thermally-coupled (NTCLs) energy levels of rare earth ions in novel phosphors has significant potential for devising the optical thermometers with high temperature sensitivity. Herein, a sequence of novel Yb3+,Er3+/Ho3+ doped NaLaTi2O6 (NLTO) phosphors were sintered using a high-temperature solid-state reaction approach. Structure, phase component and luminescence performance were identified in detail. Upon 980 nm near-infrared (NIR) excitation, the obtained materials presented typical Er3+/Ho3+ characteristic emission wavelengths in visible region, which include two green emission bands around 522 and 543 nm, as well as a weaker red band around 661 nm for Er3+ doped NLTO, a green emission band around 545 nm and a red band around 657 nm for Ho3+ doped NLTO. Besides, a unusual emission band around 757 nm of Ho3+ in visible edge region was also clearly found. The temperature sensing properties of representative NLTO:Yb3+,Er3+/Ho3+ samples were assessed based on the fluorescence intensity ratio (FIR) technique of TCLs or NTCLs energy levels. The maximal absolute sensitivity (Sa) and relative sensitivity (Sr) were determined to be 0.0374 K-1 (293 K) and 0.970% K-1 (293 K) by taking the FIR of NTCLs 2H11/2→4I15/2 and 4F9/2→4I15/2 transitions in NLTO:Yb3+,Er3+. Simultaneously, the maximal Sa and Sr were 0.0306 K-1 (573 K) and 0.776% K-1 (373 K) using the FIR of NTCLs 5F5→5I8 and 5F4,5S2→5I7 transitions in NLTO:Yb3+,Ho3+. Consequently, the temperature sensitivities above can be compared to reported results, which indicate that as-prepared materials have a promising application in optical temperature sensors field.

Scanning Probe Nano‐Infrared Imaging and Spectroscopy of Biochemical and Natural Materials

The mid‐infrared with a characteristic wavelength of 3–20 μm is important for a wealth of technologies. In particular, mid‐infrared spectroscopy can reveal material composition and structure information by fingerprinting chemical bonds’ infrared resonances. Despite these merits, state‐of‐the‐art mid‐infrared techniques are spatially limited above tens of micrometers due to the fundamental diffraction law. Herein, recent progress in the scanning probe nanoscale infrared characterization of biochemical materials and natural specimens beyond this spatial limitation is reviewed. By leveraging the strong tip–sample local interactions, scanning probe nano‐infrared methods probe nanoscale optical and mechanical responses to disclose material composition, heterogeneity, orientation, fine structure, and phase transitions at unprecedented length scales. These advances, therefore, revolutionize the understanding of a broad range of biochemical and natural materials and offer new material manipulation and engineering opportunities close to the ultimate length scales of fundamental physical, chemical, and biological processes.

Detection of Chicken Freshness Utilizing VNIR, SWIR Spectroscopy, and Data Fusion

In light of the escalating demand for enhanced chicken quality and safety, there is an imperative need for an advanced methodology that can accurately and expeditiously ascertain the freshness of chicken. This study endeavors to harness hyperspectral imaging (HSI) technology, in synergy with machine learning and deep learning algorithms, to innovate a non-destructive method for the assessment of chicken freshness. In this study, chicken freshness was categorized into three distinct levels based on a comprehensive range of evaluation criteria specific to chicken freshness. Subsequent to preprocessing the spectra data, a discriminative model for chicken freshness predicated on Visible and Near-Infrared (VNIR,400-1000 nm) and Short-Wave Infrared (SWIR, 900-1700 nm) spectra was formulated utilizing both the raw and the preprocessed datasets. Consequently, key wavelengths were discerned via feature wavelengths selecting within the full spectra wavelengths, culminating in the establishment of the feature-wavelength model. The outcomes indicate that the VNIR-ResNet model, incorporating Normalization preprocessing, outperforms other full-spectra models, boasting an accuracy rate of 98.31%. Following feature wavelengths modeling, the precision of the feature selecting augmented by CARS and SPA was enhanced to 98.87%, respectively. Subsequently, a fusion model is developed through the application of a data fusion technique, the accuracy of data-layer fusion modeling was 98.87%, surpassing that derived from a singular data source, albeit the efficacy of feature-layer fusion modeling fell short of ideal. In summary, considering factors such as the cost and volume of hyperspectral data, the models such as MN-ResNet based on VNIR and MN-CARS-ResNet based on feature selecting emerge as more cost-effective and pragmatic solutions.