The deformation mechanism of artificial muscle materials based on the natural method has always been one of the frontier topics in the field of biophysics. Electroactive PVC gel is a composite material that mimics the response of natural muscles, making it highly advantageous for various bionic mechanical applications. The existing literature primarily focuses on enhancing the performance and exploring applications of PVC gel, with particular emphasis on optimizing its ability to simulate muscle deformation. However, the existing literature lacks research on the theoretical mechanism and modeling of large deformation, particularly regarding the investigation of nonlinear dynamic behavior under state-varying electromechanical parameters. The present research establishes a novel theoretical model for PVC gel and investigates its dynamic response to voltage, mechanical force, and inertia force. Firstly, the electromechanical constitutive model of PVC gel actuator was elucidated, and the nonlinear dynamics control equation of PVC gel actuator was established based on the Gent model. Secondly, we investigate the vibration characteristics of PVC gel material by analyzing four key parameters: size, tensile strength, applied voltage amplitude, and excitation frequency. Through this analysis, we determine the relevant parameters and operational range of the PVC gel actuator when subjected to voltage excitation. Meanwhile, the phase trajectories and Poincaré maps were generated based on the control equation calculation results to investigate the vibration stability and chaotic characteristics of the PVC gel actuator under electromechanical coupling conditions. The deformation of PVC gel is influenced by various nonlinear factors, wherein the alteration in frequency induces harmonic, subharmonic, and super-harmonic resonance phenomena within the frequency response. By revising the size, voltage, and frequency of these three factors, with particular emphasis on regulating the frequency, chaotic behavior in the PVC gel will be facilitated. Finally, the bifurcation analysis of the electromechanical vibration behavior of the PVC gel actuator was carried out, and the stability of the PVC gel vibration was further quantitatively determined by the Lyapunov exponent.