Changes In Properties Of Water Research Articles

A Review on Groundwater Pollution in India and their Health Problems

Any change in the physical, chemical, and biological properties of water makes it unfit for consumption. Currently, the main sources of groundwater pollution in India are water from domestic, industrial, and agricultural sources, which enter and contaminate the groundwater mainly through soil leaching. As India's industry continues to expand, pollution from groundwater exploitation and groundwater depletion are becoming an issue. Chemicals and road salts, air pollutants, contaminated soils, heavy metals, acidification, landfills, microbial contaminants, pesticides, and nitrate contamination from groundwater, sewage, wastewater, and septic tanks are the major groundwater pollution problems in India. The same elements of inorganic contaminants: are aluminum, nickel, arsenic, barium, cadmium, dissolved particles, iron, lead, and zinc—potential health problems. Organic contaminants - Volatile organic compounds (VOCs), pesticides, plasticizers, chlorinated solvents, dioxins, pharmaceuticals, and antibiotics are present in water and affect its quality. Drinking contaminated water can cause kidney damage, liver damage, cancer, skin damage, skin inflammation, weight loss, nervous system damage, respiratory problems, etc. problems for healthy people. This review is to identify the Major Groundwater Contamination Problems in India and their Potential health problems.

Tuning Water at the Solid–Liquid Interface for Durable Electrocatalysis

The solid–liquid interface is one of the oldest and most fundamental concepts in electrochemistry. However, the interface consists of various elements — such as electrode, solvent, cation, anion, reactant, product, etc. — and its microscopic structure remains elusive and a great challenge. Here, we show that the ionomer can selectively control the water properties at the electrode-electrolyte interface, which directly or indirectly affects electrocatalytic performance. Advanced online spectroscopic studies revealed that the change in water properties due to introduction of the ionomer layer led to superior stability of the carbon-supported catalyst with alleviated carbon corrosion. Overall, in this work, we elucidate that interfacial water is one of the key factors for electrocatalytic performance and consider the introduction of an ionomer layer as an appropriate methodology to selectively control it at the solid-liquid interface.

The Potential of Micro-Dictum Preparation in Surface Water Reclamation Subject to Strong Anthropogenic Pressure

The aim of this research was to analyze the potential of e micro-dictum preparation containing compositions of beneficial microorganisms using this product in surface water reclamation. The experiments were carried out in 2016. The scope of this research included the analysis of the physical and chemical properties of a solid preparation; tests of the microbiological parameters of micro-dictum; an analysis of the spread of microorganisms in the aquatic environment; a study of water quality with the solid preparation; and tests of the formulation in real conditions and its potential in the reclamation of surface waters. Tests on the produced formulation were carried out in the laboratory in containers and under real conditions. Laboratory tests have shown that the analyzed preparation may introduce certain amounts of nitrogen and phosphorus into the water. However, they are not important in the case of water reclamation. Analyses of the micro-dictum preparation showed that the content of lactic acid bacteria in the center of the ball is lower compared to the outer layers. The results describing an increase in the number of lactic acid bacteria correlate with a decrease in pH and oxygen dissolved in the water with the preparation. The tests showed no negative impact on changes in the physical and chemical properties of water at the site of application. Changes in physical parameters were recorded, in particular dissolved oxygen and pH at the bottom, where the greatest microbiological activity occurred.

Spatial Distribution of Physical and Chemical Properties of Deep Sea Water in Xisha, South China Sea

Deep sea water (DSW) is a globally utilized source of renewable energy and other resources. To understand the characteristics of DSW resources in the South China Sea, in July 2022, the Guangzhou Marine Geological Survey (GMGS) investigated temperature, salinity, pH, dissolved oxygen (DO), inorganic salts (DIN, PO43−-P, and SiO3-Si), heavy metals (Hg, Pb, As, and Cd), trace elements (Cu, Zn, Fe, Mn, Ni, Se, and Mo), and other related indicators. The results of this investigation elucidate the horizontal and vertical changes in the physical and chemical properties of deep sea water in the Xisha Sea. The surface seawater quality in Xisha was found to be excellent and to meet first-class seawater survey standards. However, the concentrations of various nutrient salts in the surface layer were relatively low. As the seawater depth increased, different trace elements and heavy metals exhibited variations, and the concentrations of various nutrients also gradually increased.

Different patterns of bacterioplankton in response to inorganic and organic phosphorus inputs in freshwater lakes - a microcosmic study

Phosphorus (P) is a limiting factor in fresh waters and is also the main cause of water eutrophication and deterioration, However, the practical effect of elevated P level on bacterioplankton is less evaluated. In this study, we investigated the bacterioplankton in a 96 hours microcosm experiment with P additions in two forms (organic/inorganic P, OP/IP) and three levels (final conc., 0.040, 0.065 and 0.125 g/L), aiming to find out the response pattern of bacterioplankton in coping with the increasing P levels. Results showed a more dramatic change of water properties and bacterioplankton between P forms (OP and IP) than among the addition levels, and a more remarkable effect of OP addition than the IP. Both OP and IP treatments significantly decreased the water pH, dissolved oxygen (DO), Electrical Conductivity (EC), Nitrate Nitrogen (NO3--N) and Total Organic Carbon (TOC), and reduced the α-diversity of bacterioplankton and relative abundance of Cyanobacteria, but increased the abundance of Proteobacteria. The IP addition decreased Actinobacteria abundance (especially for HgcI) and showed higher denitrification potentials, while the OP addition depressed the Bateroidota and exhibited lowed methylotrophic functions, but such trends decreased with increasing addition concentrations. The network analysis showed that both IP and OP additions increased the proportion of positively correlated edges and reduced the network complexity and stability, but the OP network was more stable than the IP network. The study clarifies the response pattern of bacterioplankton to the P input with different forms and levels, and deepens our understanding of the eutrophication process, which provides a scientific basis for the management and control of freshwater lakes facing eutrophication.

Influence of Mobile Phone Electromagnetic Radiation Exposure on Behavior of Protozoan Population

For the first time, the effect that mobile phone electromagnetic radiation had on water in the presence of protozoan population and induced a significant change in water properties has been experimentally studied. The results of our experiment demonstrate that changes that occur in the “water–protozoa population” system are the biological effects the cells have in response to the direct effect of radiation. This conclusion is supported by the fact that the calculated order of magnitude of a time interval during which information exchange takes place between some microorganisms of the protozoan population is the same as that over course of the experiment. The minimum concentration of protozoa (1000 pcs/liter) at which this effect was observed was determined. It is concluded that the proposed technique for alteration of physical properties of water in the presence of protozoan population after exposure to electromagnetic fields can be used to uncover the mechanisms of the interaction of biological systems with electromagnetic fields.

Ensuring the normalization of the aero-ionic regime in production areas by means of ultrasonic air ionization

The results of studies on the normalization of the aeroionic regime in rooms under ultrasonic ionization of humidified air are presented. The increase in the concentration of negative aeroions under these conditions by the combined effect of the balloelectric effect and ultrasonic cavitation is substantiated. It has been established that when distilled water is used as a source of air ions under the action of a 10 W ultrasonic generator at a distance of 0.5 m, the concentration of negative air ions increases almost sixfold. At the same time, due to the joint effect of ultrasonic cavitation in the surface layer of water and the balloelectric effect, no generation of ozone and nitrogen oxides is caused. It is proved that with a decrease in the degree of water mineralization, the concentrations of negative and positive aeroions increase due to changes in the physicochemical properties of water and the resulting mechanochemical phenomena. The mechanism of formation of air ions in the air of industrial premises under the combined action of the balloelectric effect and ultrasound is proposed. It is substantiated that the quality of the air ionic composition of industrial premises air improves at a temperature of demineralized water of 20-25 °C and a directed air flow of 6 m/s towards the working area with the combined effect of ultrasound and balloelectric effect, which contributes to the improvement of sanitary and hygienic working conditions. The structure of an automated system for controlling the aeroionic regime of the working area of industrial premises with artificial ionization of humidified air using an aeroion generator and a ventilation system is proposed. This will allow monitoring and processing of information on technological, electrical and microclimatic parameters, adjusting, coordinating and jointly controlling the ventilation system devices and the ultrasonic generator of air ions.

Is the Regime Shift in Gulf Stream Warm Core Rings Detected by Satellite Altimetry? An Inter‐Comparison of Eddy Identification and Tracking Products

AbstractDownstream of Cape Hatteras, the vigorously meandering Gulf Stream forms anticyclonic warm core rings (WCRs) that carry warm Gulf Stream and Sargasso Sea waters into the cooler, fresher Slope Sea, and forms cyclonic cold core rings (CCRs) that carry Slope Sea waters into the Sargasso Sea. The Northwest Atlantic shelf and open ocean off the U.S. East Coast have experienced dramatic changes in ocean circulation and water properties in recent years, with significant consequences for marine ecosystems and coastal communities. Some of these changes may be related to a reported regime shift in the number of WCRs formed annually, with a doubling of WCRs shed after 2000. Since the regime shift was detected using a regional eddy‐tracking product, primarily based on sea surface temperatures and relies on analyst skill, we examine three global eddy‐tracking products as an automated and potentially more objective way to detect changes in Gulf Stream rings. Currently, global products rely on altimeter‐measured sea surface height (SSH), with WCRs registering as sea surface highs and CCRs as lows. To identify eddies, these products use either SSH contours or a Lagrangian approach, with particles seeded in satellite‐based surface geostrophic velocity fields. This study confirms the three global products are not well suited for statistical analysis of Gulf Stream rings and suggests that automated WCR identification and tracking comes at the price of accurate identification and tracking. Furthermore, a shift to a higher energy state is detected in the Northwest Atlantic, which coincides with the regime shift in WCRs.

Agitation dredging of silt and fine sand with Water Injection Dredging, Tiamat and Underwater Plough: a case study in the Port of Rotterdam

PurposeAgitation dredging has gained popularity as an environmentally friendly and cost-effective method for port maintenance. One of the advantages of agitation dredging is the ability to transport sediments out of the port area using natural currents. The effect of the different agitation methods on sediment and water properties has rarely been investigated in a single pilot project. This research aims to study the effects of agitation methods in silt and sand-dominated areas that are frequently maintained.MethodsThe effects of water injection dredging, (WID) underwater ploughing (UWP) and Tiamat on sediment properties are investigated in the Port of Rotterdam. In-situ measurements and laboratory measurements are carried out to determine changes in the bed level, the particle size distribution of the bed, the turbidity in the water column and the dispersion distance of the sediment plume due to agitation dredging.ResultsThe results of the in-situ monitoring of the agitation pilots allow a comparison of the changes in sediment and water properties before, during and after agitation dredging. The production, advantages and limitations of the tested agitation dredging methods are discussed.ConclusionThe in-situ measurements show that WID, Tiamat and UWP can be successfully used for the agitation of sediments and their removal from the silt and sand-dominated areas. The production of the tested agitation methods is higher for silty than sandy sediments. In general, the selection of the agitation equipment can be made based on environmental regulations, sediment properties and hydrodynamic conditions.

Application of Natural Functional Additives for Improving Bioactivity and Structure of Biopolymer-Based Films for Food Packaging: A Review.

The global trend towards conscious consumption plays an important role in consumer preferences regarding both the composition and quality of food and packaging materials, including sustainable ones. The development of biodegradable active packaging materials could reduce both the negative impact on the environment due to a decrease in the use of oil-based plastics and the amount of synthetic preservatives. This review discusses relevant functional additives for improving the bioactivity of biopolymer-based films. Addition of plant, microbial, animal and organic nanoparticles into bio-based films is discussed. Changes in mechanical, transparency, water and oxygen barrier properties are reviewed. Since microbial and oxidative deterioration are the main causes of food spoilage, antimicrobial and antioxidant properties of natural additives are discussed, including perspective ones for the development of biodegradable active packaging.

From Agriculture to Clinics: Unlocking the Potential of Magnetized Water for Planetary and Human Health.

Magnetized water (MW) is a form of liquid water that has been exposed to a magnetic field to alter its hydrogen bonding structure, resulting in the formation of water molecule clusters of various sizes and configurations connected by hydrogen bonds. This magnetization process induces several changes in the physicochemical properties of water, such as increased pH, electrical conductivity, and dissolved oxygen content, as well as decreased surface tension, density, and evaporation temperature compared to untreated water. In this narrative review, we explore the effective utilization of MW in agriculture, where it has a well-established history of applications, and its potential for direct applications in the medical field, which are currently at the forefront of research. MW is one of the most promising innovations for facilitating the transition from unsustainable to sustainable agriculture, which is expected to yield positive human health outcomes by promoting the consumption of less processed foods and reducing resource consumption. In addition to these indirect effects on human health, preclinical research utilizing animal models has demonstrated that water magnetization exerts beneficial effects on diabetes, renal function, bone health, and fertility. These health benefits appear to stem from the ability of MW to increase the activity of antioxidant enzymes while decreasing lipid peroxidation and inflammatory markers. In terms of direct human applications, MW has been primarily studied in the fields of dentistry and dermatology. MW mouthrinse has consistently shown efficacy against Streptococcus mutans, with studies reporting comparable effects to chlorhexidine. In dermatology, the topical application of MW has demonstrated improvements in skin biophysical parameters, increased hair count and hair mass index, and promoted the healing of challenging wounds. Intriguingly, these effects on human skin seem to be mediated by local activation of autophagy, potentially through mild alkaline stress. In conclusion, this review underscores the promising role of MW in promoting a holistic approach to planetary and human health. Future studies should focus on standardizing the magnetization process, exploring the molecular mechanisms underlying MW-induced autophagy, and investigating the potential of MW as a complementary strategy for treating human diseases characterized by impaired autophagy.

Study of the Influence of Cavitation and Magnetic Field on the Change of Water Properties and its Purification in a Vibrating Machine with Determination of Drive Modes

Study of the Influence of Cavitation and Magnetic Field on the Change of Water Properties and its Purification in a Vibrating Machine with Determination of Drive Modes

Global mapping and evolution of persistent fronts in Large Marine Ecosystems over the past 40 years

Ocean fronts, characterized by narrow zones with sharp changes in water properties, are vital hotspots for ecosystem services and key regulators of regional and global climates. Global change is reshaping the distribution of material and energy in the ocean; however, it remains unclear how fronts have varied in the last few decades. Here, we present a global, fine-scale digital atlas of persistent fronts around Large Marine Ecosystems and demonstrate significant global increases in both their occurrence and intensity. In subtropical regions (around boundary currents and upwelling systems) and polar regions, persistent frontal occurrence and intensity are rapidly increasing, while in tropical regions, they remain stable or slightly decrease. These enhancements may be respectively related to changes in boundary currents, upwelling, and sea ice retreat. This spatially heterogeneous trend holds important implications for the redistribution of front-related ecosystem services and air-sea interactions but has not been captured by representative high-resolution climate projections models or observation-assimilated ocean models.

Physicochemical properties of water in the Nida valley, Poland

The investigation of Nida Valley water aimed to assess fluctuations in physicochemical properties. In this study, environmental monitoring method was utilized to evaluate the changes in physicochemical properties of water. Over a 24-month period, from June 2021 to May 2023, a total of 228 water samples were collected from 10 sampling sites, with a monthly sampling frequency. Statistical analyses were utilized including the Shapiro–Wilk test (α = 0.05), Kruskal–Wallis test and Wilcoxon (Mann–Whitney) rank sum test (α = 0.05), Pearson correlation analysis (α = 0.001) and principal component analysis (PCA). Statistical analyses revealed significant differences between months in GW samples for for temperature, dissolved oxygen, pH, total nitrogen, total phosphorus, chloride, manganese, and zinc in GW samples and for T and DO in SW samples. Pearson correlation coefficient analysis (α = 0.001) identified strong positive correlations within the SW dataset. Similarly, significant positive correlations were observed among the GW dataset. Noteworthy positive correlations were also detected between the GW and SW datasets. Principal component analysis (PCA) revealed a substantial dissimilarity between GW2 samples compared to others, characterized by elevated manganese, iron, and Sulfate content. Two distinct groups emerged: Group 1 included samples at GW1, GW2, GW3, GW5, and SW2, while Group 2 comprised all other samples. This study demonstrated the stability in the physicochemical properties of SW and underscore a discernible correlation between the hydrochemical compositions of both SW and GW in the riparian area. Outstanding characteristics in hydrochemical component of sample waters have been indicated.

Confined Water Dynamics in the Scaffolds of Polylactic Acid.

Resorbable polylactic acid (PLA) ultrathin fibers have been applied as scaffolds for tissue engineering applications due to their micro- and nanoporous structure that favor cell adhesion, besides inducing cell proliferation and upregulating gene expression related to tissue regeneration. Incorporation of multiwalled carbon nanotubes into PLA fibers has been reported to increase the mechanical properties of the scaffold, making them even more suitable for tissue engineering applications. Ideally, scaffolds should be degraded simultaneously with tissue growth. Hydration and swelling are factors related to scaffold degradation. Hydration would negatively impact the mechanical properties since PLA shows hydrolytic degradation. Water absorption critically affects the catalysis and allowance of the hydrolysis reactions. Moreover, either mass transport and chemical reactions are influenced by confined water, which is an unexplored subject for PLA micro- and nanoporous fibers. Here, we probe and investigate confined water onto highly porous PLA microfibers containing few amounts of incorporated carbon nanotubes by Fourier transform infrared (FTIR) spectroscopy. A hydrostatic pressure was applied to the fibers to enhance the intermolecular interactions between water molecules and C=O groups from polyester bonds, which were evaluated over the wavenumber between 1600 and 2000 cm-1. The analysis of temperature dependence of FTIR spectra indicated the presence of confined water which is characterized by a non-Arrhenius to Arrhenius crossover at T0 = 190 K for 1716 and 1817 cm-1 carbonyl bands of PLA. These bands are sensitive to a hydrogen bond network of confined water. The relevance of our finding relies on the challenge detecting confined water in hydrophobic cavities as in the PLA one. To the best of our knowledge, we present the first report referring the presence of confined water in a hydrophobic scaffold as PLA for tissue engineering. Our findings can provide new opportunities to understand the role of confined water in tissue engineering applications. For instance, we argue that PLA degradation may be affected the most by confined water. PLA degradation involves hydrolytic and enzymatic degradation reactions, which can both be sensitive to changes in water properties.

Control of overgrowth of Potamogeton crispus in shallow lakes by light shading and artificial introductions

Potamogeton crispus is a common submersed aquatic plant in shallow lakes in China, and its overgrowth and rapid decomposing have become an important environmental problem affecting the water quality of lakes every summer. Introducing other submersed plants to substitute Potamogeton crispus can improve the structure of the aquatic plant community and to reduce the growth of Potamogeton crispus to some degree, but the effect is poor and short-lived. Considering the fact that Potamogeton crispus is sensitive to changes in light intensity, the two methods of shading the water surface and introduction of other submerged plants were used synergistically. In a large simulated experimental pool, light intensity was reduced by placing black polyethylene floating spheres on the water surface and planting three species of submerged plants, namely, Vallisneria natans, Hydrilla verticillata and Potamogeton wrightii. Changes in the physico-chemical properties of the experimental pool water and the physiological and biochemical characteristics (morphology, chlorophyll, biomass, antioxidant enzymes and malondialdehyde) of the submerged plants during the period of 0–40 d were analyzed. The results showed that: (1) After the light intensity was reduced by 85%, Potamogeton crispus seedlings showed a significant decrease in biomass and chlorophyll content and died in large numbers within 20–30 days. (2) Catalase is the main tool for Potamogeton crispus to cope with low light stress. The activities of various antioxidant enzymes and the malondialdehyde content of Potamogeton crispus showed a decreasing trend under shade conditions, but the catalase activity increased dramatically. (3) Vallisneria natans is more tolerant of low light conditions than the other two submersed plant species. Therefore, we tried to reduce the biomass of Potamogeton crispus by combing introduction of other submersed plants and shading treatment. (4) The water quality objectives remained stable over the period of the trial, indicating that short-term shading does not have a negative impact on the quality of the water quality.

Ecological condition of marine waters in the area of dredging operations of the kashagan field, Kazakhstan

To determine the hydrophysical and hydrochemical parameters of sea water and their changes during dredging works in the north‐eastern part of the Caspian Sea along the Western Approach Route and near/inside block D, islands EPC‐2, EPC‐3, EPC‐4 and island A of the Kashagan field.Measurement of hydrophysical parameters: salinity, temperature, turbidity, dissolved oxygen concentration, electrical conductivity, pH of seawater was carried out using a portable multi‐parameter analyser "Horiba‐U53" directly in the water column. Water transparency was determined using a Secchi disc. The depth of the water layer was determined using a sounder. Hydrochemical investigations were carried out for seven parameters, with all components sampled in the near‐surface and benthic horizons. Water samples were taken using probes or bathometers: BM‐48, GR‐18 or their analogues.Hydrochemical analyses of seawater samples for: biogens (NO2, NO3, NH4, Ntotal, and Ptotal), synthetic surfactants, phenols, hydrocarbons including polyaromatic hydrocarbons (PAHS), heavy metals, chemical oxygen demand (COD) and biochemical oxygen demand (BOD5). These were carried out in laboratory conditions using analytical equipment according to scientifically accepted methods.The data obtained as a result of the research allow us to draw the following conclusion: changes in the amount of suspended sediment in sea water lead to changes in physical and chemical properties of water (increase in turbidity, disturbance of sediment composition and properties), changes in biotopes, deterioration of oxygen regime, optical properties of water and temperature regime.

The Response of the Upper Ocean to Tropical Cyclones in the South Pacific

AbstractConsecutive Argo float profiles are used to observe upper ocean changes resulting from the passage of tropical cyclones (TCs) in the South Pacific between 2001 and 2023. Cross‐sectional composites of the ocean response are produced by normalizing the distance between the profile and cyclone track by the 34‐knot wind radius (R34) of each TC to better resolve the average changes in water properties. Surface cooling in the initial mixed layer (ML) extends from the center to about twice R34 and is stronger to the left of the TC track. Subsurface warming at the base of the ML is observed between 0.4 and 2 R34 on both sides of the track. Strong cooling is observed in a distinct core directly under the TC path, reaching temperature changes of over −1.6°C between 70 and 450 m depth. Significant upwelling of over 40 m displacement is observed within ±0.05 R34, extending to 1,000 m depth. Surface cooling (and subsurface warming at the base of the ML) are positively correlated with wind stress on the ocean from the TC, quantified by the Local Wind Power Dissipation (PDL), and negatively correlated with the energy required to destratify the upper ocean, defined by a Cooling Inhibition index (CI). Subsurface warming is common with low CI but is not observed with high CI. We demonstrate an improved method to analyze Argo float data for measuring TC‐upper ocean interaction in remote oceans and the usefulness of PDL and CI in calibrating the TC‐ocean interaction.

Degradation of dissolved sulfide in water using multi-hole dielectric barrier discharge

Biogas obtained from livestock manure is used as fuel for solid oxide fuel cells. Although H2S is a typical biogas, it is a fatal disadvantage for fuel-cell power generation and, thus, must be removed. In this study, we proposed an effective method for sulfide removal from water using a multi-hole dielectric barrier discharge (DBD) system. In this system, active species, such as ozone, ultraviolet rays, hydroxyl radicals, and hydrogen peroxide, were simultaneously generated. Under optimal conditions, dissolved sulfide (initial concentration: 120 mg/L) was completely degraded within 10 min in air plasma and 6 min in oxygen plasma. Changes in the physical properties of the sulfide-treated water were confirmed by measuring the pH, oxidation-reduction potential, and dissolved oxygen. Results of the by-product analysis showed that sulfide was converted into sulfate by reacting with a large amount of ozone, and the active species were emitted from the multi-hole DBD system. In summary, multi-hole DBD technology has demonstrated merit as a water-contaminant purification technology and for the removal of dissolved sulfide.

Structural effects of water clusters on viscosity at high shear rates.

In this study, we use molecular dynamics simulations of liquid water to investigate how shear thinning affects the viscosity of liquid water by structural changes of the hydrogen bond network. The effect of shear on viscosity can be divided into two parts: shear-induced destruction of the hydrogen bond network and the influence of the water structure on shear viscosity. First, strong shear destroys tetrahedral structures and thus reduces the connectivity of the hydrogen bond network. It is mainly because shear deformation, characterized by compression and expansion axes, respectively, triggers the destruction and formation of hydrogen bonds, resulting in anisotropic effects on water structures. At the same time, shear destroys large clusters and enhances the formation of small ones, resulting in a decrease in average cluster sizes. Second, the change of viscosity obeys a power law relationship with the change of hydrogen bond structures, highlighting a one-to-one correspondence between structure and property. Meanwhile, in order to explain why the structure affects viscosity, we define hydrogen-bond viscosity and find that the cooperative motion of the water structures can promote momentum transfer in the form of aggregations. Hydrogen-bond viscosity accounts for 5%-50% of the total viscosity. Our results elucidate that water structures are the important structural units to explain the change of water properties.