Changes In Modulus Research Articles

Mechanisms of hardness enhancement in CrB2 thin films with varying VB2 concentrations

Transition metal borides are well-known for their high hardness, excellent wear resistance, chemical inertness, and electrical conductivity, making them promising for a wide range of applications. Understanding the interconnections between material structure, composition, and mechanical properties is essential for designing and synthesizing effective coatings. This study systematically investigates the structural and mechanical properties of CrB₂ thin films with varying concentrations of VB₂ (0–10 wt%), focusing on structure, hardness, elastic behavior and deformation characteristics mechanisms through atomic force microscopy and nanoindentation measurements. The results show that increasing VB₂ content leads to the formation of island cluster structures, which significantly strengthens atomic bonds and, in turn, enhances the hardness of the thin films. As particle size decreases, the higher proportion of surface atoms and increased surface energy have a more pronounced effect on the mechanical properties. In particular, the addition of VB₂ up to 10 wt% in CrB₂ thin films results in a marked improvement in superhard properties. 26 % increase in hardness value is also influenced directly by the changes in Young's modulus and Poisson's ratio that depend on the VB₂ concentration.

Experimental study on axial compressive properties of bamboo scrimber after high temperature

This study examines the uniaxial compressive mechanical properties of after high temperature bamboo scrimber, taking into account the combined effects of temperature, constant temperature duration, and moisture content. A series of 46 uniaxial compression tests were conducted on bamboo scrimber under various conditions to investigate the failure modes after high temperatures. The analysis focuses on the changes in compressive elastic modulus and peak stress of bamboo scrimber parallel and perpendicular to the grain, in relation to temperature, constant temperature duration, and moisture content. The findings reveal that below 180℃, diagonal shear failure and Y-type shear failure are the primary failure modes for specimens parallel to the grain, while diagonal shear failure predominates for specimens perpendicular to the grain. Above 180℃, bond failure and eccentric crushing become the main failure modes for specimens parallel and perpendicular to the grain, respectively. The peak compressive stress decreases significantly beyond 180℃, with a slower decrease observed as moisture content increases. Constant temperature duration has a notable impact on peak stress, with longer durations resulting in lower peak stress at the same temperature. Although temperature has a lesser effect on the elastic modulus compared to peak stress, empirical formulas were derived to establish the relationship between compressive elastic modulus and peak stress reduction coefficient with variations in temperature, constant temperature duration, and moisture content based on the experimental data.

Mechanical properties of reactive powder concrete under compression at ultra-low temperatures

In this paper, the mechanical properties of reactive powder concrete (RPC) at ultra-low temperatures were studied. RPC prisms (300 mm × 100 mm × 100 mm) were tested at ultra-low temperatures (20 °C, 0 °C, −20 °C, −40 °C, −80 °C, −120 °C, −165 °C) and resulting prism compressive strength, compressive stress-strain curve, and toughness were determined. The increase in prismatic compressive strength of RPC at ultra-low temperatures is greater than that of ordinary concrete, with an overall strength of about 2.12 times that of ordinary concrete. Pore water freezing behavior was also studied to assess the effects on the mechanical properties of RPC in ultra-low temperatures. The water-ice phase transition further improved the RPC strength. With the reduction in temperature, The change in elastic modulus of RPC change is small, the peak strain of specimens at different temperatures increases with the decrease in temperature. The peak strain of RPC showed an overall linear increase with decreasing temperatures, and the water-ice phase transition at negative temperature increases the peak strain of RPC, adding steel fibers improves the RPC ductility, limiting the fracture. With the temperature reduction, RPC toughness first increases and then decreases. The toughness is lowest at room temperature, and highest at −120 °C, which is 2.26 times higher than at room temperature. RPC has better toughness than normal concrete at different temperatures, the reduction of temperature relatively improves the toughness of RPC, and the addition of steel fibers plays a vital role in improving the toughness. This study can serve as technical support for using RPC to design liquefied natural gas full-capacity tanks.

Analyzing the Reinforcement of Multiwalled Carbon Nanotubes in Vulcanized Natural Rubber Nanocomposites Using the Lorenz–Park Method

In this study, multiwalled carbon nanotubes (MWCNTs) were incorporated into vulcanized natural rubber (VNR) matrixes to create nanocomposites with improved mechanical, thermal, and electrical properties. The interfacial interaction of the MWCNTs with the VNR matrix was quantitatively evaluated based on the crosslink density value calculated using the Flory–Rehner methodology. Various rheometric parameters were influenced by the addition of the MWCNTs, including minimum torque (ML), maximum torque (MH), and scorch time (tS1). The MWCNTs significantly enhanced the vulcanization of the composites based on the VNR matrix. This study highlights the impact of MWCNTs on crosslink density, improving mechanical properties and reducing swelling in the VNR matrix. We discovered that the MWCNTs and the VNR matrix interact strongly, which improved the mechanical properties of the matrix. The MWCNTs improved the hardness, tensile strength, and abrasion resistance of the VNR/MWCNT nanocomposites. Based on dynamic mechanical analysis, MWCNT incorporation improved stiffness as indicated by a change in storage modulus and glass transition temperatures. The addition of MWCNTs to the VNR/MWCNT nanocomposites significantly improved their electrical properties, reaching a percolation threshold where conductive pathways were formed, enhancing their overall conductivity. Overall, this study demonstrates the versatility and functionality of VNR/MWCNT nanocomposites for a variety of applications, including sensors, electromagnetic shielding, and antistatic blankets.

Simultaneous Color- and Dose-Controlled Thiol-Ene Resins for Multimodulus 3D Printing with Programmable Interfacial Gradients.

Drawing inspiration from nature's own intricate designs, synthetic multimaterial structures have the potential to offer properties and functionality that exceed those of the individual components. However, several contemporary hurdles, from a lack of efficient chemistries to processing constraints, preclude the rapid and precise manufacturing of such materials. Herein, the development of a photocurable resin comprising color-selective initiators is reported, triggering disparate polymerization mechanisms between acrylate and thiol functionality. Exposure of the resin to UV light (365nm) leads to the formation of a rigid, highly crosslinked network via a radical chain-growth mechanism, while violet light (405nm) forms a soft, lightly crosslinked network via an anionic step-growth mechanism. The efficient photocurable resin is employed in multicolor digital light processing 3D printing to provide structures with moduli spanning over two orders of magnitude. Furthermore, local intensity (i.e., grayscale) control enables the formation of programmable stiffness gradients with ≈150× change in modulus occurring across sharp (≈200µm) and shallow (≈9mm) interfaces, mimetic of the human knee entheses and squid beaks, respectively. This study provides composition-processing-property relationships to inform advanced manufacturing of next-generation multimaterial objects having a myriad of applications from healthcare to education.

Constructing stable emulsion gel from gelatin and sodium alginate as pork fat substitute: Emphasis on lipid digestion in vitro

This study aimed to develop a gelatin-sodium alginate (G-SA) emulsion gel that can efficiently hold corn oil, as a substitute for pork fat while controlling the digestive behaviors of lipids in vitro. UV, fluorescence, and circular dichroism spectra and surface hydrophobicity measurements of the G-SA mixtures indicated that gelatin and sodium alginate primarily form aggregates through hydrogen bonds and hydrophobic interactions, and the optimum gelatin-to-sodium alginate w/w ratio was identified as 1.9. The final emulsion gel contained 3.15% gelatin and 1.65% sodium alginate (w/w) with a corn oil content of 40% (w/w). G-SA emulsion gel had a higher proportion of polyunsaturated fatty acids (PUFAs, 53.95 g/100 g) than pork fat (15.17 g/100 g). In addition, the G-SA emulsion gel exhibited stable viscoelastic properties without storage and loss moduli changes at increasing shear rates. The G-SA emulsion gel had a higher melting temperature (42.63 °C) than pork fat (35.07 °C). In vitro digestion studies showed that corn oil had a higher free fatty acid release (40.32%) compared to the G-SA emulsion gel (12.66%) and pork fat (8.53%) (P<0.05), indicating that the digestibility of corn oil was reduced in the G-SA emulsion gel. Calcein release experiments revealed that G-SA emulsion gel released the least amount of calcein (P<0.05) during digestion at a slow rate. The G-SA emulsion gel, similar to pork fat, contained evenly distributed digestive particles encapsulating corn oil after in vitro gastric digestion, with the smallest particle size among the treatments. After the in vitro small intestinal digestion phase, the G-SA emulsion gel maintained small droplet sizes with bridging flocculation. The in vitro digesta of the G-SA emulsion gel contained a significantly higher proportion of PUFAs compared to pork fat (P<0.05). Consequently, the G-SA emulsion gel can be a potential substitute for pork fat, offering higher proportions of PUFAs, lower fat content, and controlled lipid digestion with reduced lipid digestibility.

Characterization of sulfate-driven deterioration through the microstructural and nanomechanical characteristics of the components of cement paste

The hydration reaction products of Portland cement are primarily responsible for all the characteristics of concrete. When sulfate agents attack the reaction products, their chemical and microstructural alterations are highly complex, necessitating fundamental knowledge across various length–time scales. In this study, nanomechanical properties were incorporated into microstructural and chemical analyses at varying sulfate exposure levels to investigate the sulfate-driven deterioration of Portland cement paste. The nanomechanical characteristics were observed using a nanoindentation test following cement paste was exposed to MgSO4. Microstructural and chemical analyses of the impact of sulfate exposure on the hydration products were performed. According to the statistical deconvolution of the nanoindentation data, the elastic modulus of the calcium silicate hydrate (C-S-H) gel progressively declined with increasing exposure period to MgSO4 solution according to the statistical deconvolution of the nanoindentation data. In contrast, the volume percentage of pores gradually increased. The changes in the elastic modulus were linearly related to the Ca/Si molar ratio of the C-S-H gel. New phases and microcracks due to exposure to MgSO4 were observed. The experimental research undertaken in this study suggested that one of the primary reasons for the decrease in the macroscopic characteristics of cement concretes when they encounter MgSO4 is the decalcification of C-S-H gel, which is mechanically, morphologically, and chemically described.

Quantitative assessment of corneal biomechanical changes in vivo after photorefractive intrastromal corneal cross-linking using optical coherence elastography.

Photorefractive intrastromal corneal cross-linking (PiXL) treatment corrects myopia by enhancing localized central corneal biomechanics. However, the dose-effect relationship between the changes in corneal biomechanics and alterations in corneal curvature resulting from this treatment remain unclear. We therefore developed an acoustic radiation force optical coherence elastography (ARF-OCE) technique to investigate the dose-effect relationship in PiXL. ARF-OCE measurements and corneal topography were performed 3 days before and 1 week after PiXL treatment. Depth-resolved Young's modulus images of the in vivo corneas were obtained based on the phase velocity of the Lamb wave. PiXL treatments with five ultraviolet-A (UVA) energy doses (5.4, 15, 25, 35, and 45 J/cm2) were administered to rabbit corneas in vivo (n=15). The percentage change in Young's modulus (ΔE%) of the cornea increased from 0.26 to 1.71 as the UVA energy dose increased from group I (5.4 J/cm2) to group V (45 J/cm2). Meanwhile, the change in the mean keratometry (ΔKm ) of the cornea increased from 0.40 to 2.10 diopters (D) as the UVA energy dose increased from group I to group IV (35 J/cm2). Furthermore, a statistically significant positive correlation was observed between ΔE% and ΔKm in groups I to IV. With increasing UVA energy dose, the corneal Young's modulus significantly increased. Given the observed correlation, ΔE% holds promise as a new quantitative biomechanical parameter for determining the dose-effect relationship in PiXL treatment. It should be emphasized that there may be an inflection point of ΔE%, at which corneal keratometry ceases to flatten and begins to increase. The ARF-OCE system has demonstrated its efficacy in quantitatively assessing changes in corneal biomechanics in vivo following PiXL treatment. This technique has great potential in facilitating the quantitative determination of the dose-effect relationship in PiXL treatment.

The effect of rock mechanical heterogeneity on induced stress and initiation pressure of multi-cluster fracturing

The stress interference between fracturing clusters in horizontal wells is key in affecting the initiation and propagation of multi-cluster fractures. However, in reservoirs such as shale, there are often changes in the mechanical properties of the rock along the direction of the wellbore. Such changes are often not considered in models for multi-fracture propagation. As a result, the impact of rock mechanical heterogeneity on induced stress is not fully understood. Therefore, in this paper, a prediction model of the three-dimensional induced stress field of hydraulic fractures is established, taking into account mechanical heterogeneity. Combined with the prediction model of fracturing pressure, the changes in induced stress and initiation pressure under different conditions are analyzed. The results indicate a significant difference between the induced stress results considering mechanical heterogeneity and those considering only a single homogeneous region. The change in elastic modulus has a profound influence on induced stress and initiation pressure. Perforating at locations with low elastic modulus in situ can help reduce initiation pressure. Additionally, temporarily blocking the wellbore and reducing the flow rate to decrease the net pressure in the fractures can facilitate more fractures to initiate.

Study of multiscale mechanical properties of Al-Pd-Mn quasicrystals

Based on the quantum mechanics and molecular mechanics scales, the elastic and tensile mechanical properties of Al-Pd-Mn quasicrystals (QCs) are investigated by utilizing the first-principles and molecular dynamics (MD) methods. The density functional theory (DFT) is adopted to obtain all elastic constants, stability, elastic modulus, Poisson's ratio, anisotropy, Debye temperature of Al57Pd16Mn3 QCs. Simultaneously, the MD simulations are conducted to analyze the influence of temperature and strain rate on the stress-strain curves, atomic structures, and deformation mechanism. The results indicate that Al57Pd16Mn3 QCs are stable orthogonal structures and satisfy the Cauchy conditions. Additionally, the mechanical properties of Al-Pd-Mn QCs obtained by the first-principles are consistent with the MD and experimental results. The elastic properties of Al57Pd16Mn3 QCs are approximately isotropic. The elastic modulus and ultimate tensile strength of Al57Pd16Mn3 QCs always decrease with increasing temperature. An increase in the strain rate results in a negligible change in the elastic modulus but in a noticeable enhancement in the ultimate tensile strength and strain. The current results could provide essential theoretical insights for studying the mechanical properties of QCs, and extend the scope of multi-scale study in the field of QCs at microcosmic scale as well.

Elastic modulus, water stability and resistivity for loess solidified with white mud based solid waste cementing material: Mechanism analysis and relationship establishment

To increase the engineering application value of white mud based solid waste cementing materials: white mud-slag and white mud-slag-Calcium Carbide Residue (CCR), this paper explored the changes in elastic modulus, water stability and resistivity of loess solidified with white mud based solid waste cementing material. Furthermore, relationships between elastic modulus, water stability and resistivity were established. The following conclusions can be obtained: The alkaline activation effect of CCR was stronger than white mud, therefore the formation rate of C-S-H and C-A-(S)-H cementitious products in CCR-containing solidified loess was more faster than that without CCR. At the same time, white mud not only served as an alkaline activator, but its finer CaCO3 components also helped fill pores, while the irregular fine particles provided nucleation sites for the formation of cementitious products. Consequently, slag-white mud-CCR solidified loess exhibited the best performance in terms of elastic modulus and water stability coefficient. This was followed by slag-white mud solidified loess and lime solidified loess. In addition, the analysis of the relationship between the resistivity of solidified loess and factors such as curing age, dry density, water content, elastic modulus, and water stability coefficient revealed that the main reasons for the increased resistivity of solidified loess were the consumption of internal water and the increase in cementitious products with poor conductivity. Furthermore, the modified resistivity formula was applied to establish the fitting relationships between the resistivity of solidified loess and various parameters. The formula has been successfully applied in the slag-white mud-CCR solidified loess, where the fitting of resistivity with various parameters yielded an R2 of 0.94. This paper facilitates the resistivity method (non-destructive testing) of loess treated with slag, white mud, CCR and promotes the application of these curing agents, contributing to their broader adoption in geotechnical engineering.

Mechanical Profiling of Biopolymer Condensates through Acoustic Trapping.

Characterizing the mechanical properties of single colloids is a central problem in soft matter physics. It also plays a key role in cell biology through biopolymer condensates, which function as membraneless compartments. Such systems can also malfunction, leading to the onset of a number of diseases, including many neurodegenerative diseases; the functional and pathological condensates are commonly differentiated by their mechanical signature. Probing the mechanical properties of biopolymer condensates at the single particle level has, however, remained challenging. In this study, we demonstrate that acoustic trapping can be used to profile the mechanical properties of single condensates in a contactless manner. We find that acoustic fields exert the acoustic radiation force on condensates, leading to their migration to a trapping point where acoustic potential energy is minimized. Furthermore, our results show that the Brownian motion fluctuation of condensates in an acoustic potential well is an accurate probe for their bulk modulus. We demonstrate that this framework can detect the change in the bulk modulus of polyadenylic acid condensates in response to changes in environmental conditions. Our results show that acoustic trapping opens up a novel path to profile the mechanical properties of soft colloids at the single particle level in a non-invasive manner with applications in biology, materials science, and beyond.

Phage display–based acoustic biosensor for early cancer diagnosis

The probability of a cancer patient being cured depends largely on the stage of disease at the time of diagnosis. It is therefore very important to develop methods for early cancer diagnosis that would allow screening of a large number of samples in a short time. Here, a unique method is presented for rapid immunodetection of heat shock proteins (HSPs). The method uses a compact acoustic sensor based on a lateral-field piezoelectric resonator and specific phage antibodies. The phage antibodies for the first time were developed against HSPs of P3X63Ag8.653 mouse myeloma cells. The change in the electric impedance modulus of resonator after recording of phage antibody–HSP interaction served as the analytic signal with analysis time less than 5 min. Antibody-HSP interaction confirmed by microscopic analysis and flow cytometry. This study establishes a new strategy for early cancer diagnosis by compact acoustic sensor with phage antibodies as sensing element. The results can be used to develop a noninvasive rapid method of early cancer diagnosis on basis of HSP determination and to control the content of HSPs in the monitoring of tumor therapy.

Experimental study on fracture failure characteristics evaluation of wooden pallets in humid-cold environment based on piezoelectric technology

Wooden pallets often suffer mechanical damage during transportation, stacking, forklifting, and on-site handling in cold supply chain logistics. In humid-cold environments, the fracture properties of wooden pallets change, increasing the risk of sudden fracture failure. Understanding the fracture failure characteristics of wooden pallets is essential to prevent further damage to goods. Nevertheless, evaluating and identifying these characteristics currently presents significant challenges. This study investigates the changes in modulus of elasticity (MOE) and fracture failure characteristics including modulus of rupture (MOR), brittleness and toughness of wooden pallets and impact toughness of wood material under humid-cold conditions. The piezoelectric technology was applied to evaluate and identify fracture risk of wooden pallets used in various humidity and cold conditions. Quarter-sized wooden pallets and standard wood specimens were examined by laboratory study. The experimental results showed that the MOE, MOR, toughness of wooden pallets and impact toughness of wood with higher moisture content (MC) increased with decreasing temperature, while brittleness increased as temperature decreased. These results indicate that the maximum carrying ability of wooden pallets increases in humid-cold environments while the ability to resist fracture was reduced with a higher brittle rupture risk. The toughness and its corresponding piezoelectric voltage exhibited good consistency with changes in temperature and MC. The relationship between toughness and piezoelectric voltage was established with good coefficient of determination (over 0.81). It indicates that the risk of wooden pallets could be predicted effectively using piezoelectric technology.

Investigating the role of solvents in modulating glass transition and dynamic mechanical characteristics of polystyrene film

This study investigates how different solvents impact the glass transition and dynamic mechanical properties of polystyrene (PS) films. Using FTIR spectroscopy, it analyzes solvent-induced variations in molecular vibrations, particularly in the phenyl ring region. Results show solvent-specific effects on the 750 cm-1 peak, associated with the "meta-substituted aromatic ring," influencing phenyl ring vibrations. DSC analysis highlights solvent effects on the glass transition temperature (Tg), revealing complexities in PS films prepared with chloroform, tetrahydrofuran (THF), and toluene. Varied Tg behavior suggests solvent-driven structural modifications and gradual solvent removal. Dynamic Mechanical Analysis (DMA) demonstrates solvent-dependent changes in storage modulus, loss modulus, and tan δ, indicating solvent polarity role in polymer chain dynamics. Toluene-induced plasticization reduces Tg and increases creep compliance, revealing PS film sensitivity to solvents. These findings stress solvent selection importance in tailoring thermal and mechanical properties of polymer films for specific applications.

Stress-strain state of ceramic shell mold during formation of spherical steel casting in it. Part 2

The paper presents the results of numerical calculations of the solution to the problem of modeling the process of possible cracking in a spherical shell mold when pouring liquid steel into it and cooling the solidifying casting. The numerical scheme of the axisymmetric problem and the algorithm for its solution were given in Part 1. The crack resistance is estimated by magnitude of the normal stresses in the ceramic shell during its co-cooling with a solidifying casting. The results detailed analysis considered: fields of displacement, stresses, and temperatures both on spherical surface and in growing crust of solidified metal. The solution took into account the change in the shear modulus of the mold material from temperature, and an assessment of this refinement was given. The problem was solved in two ways. The first – with a constant shift modulus of the shell mold; the second – with its temperature-dependent shift modulus. There is a significant difference between these variants in terms of magnitude of the normal stresses arising in the shell mold. The authors analyzed resistance of the shell mold spherical geometry to external influences from its support filler and filling funnel. The problem of determining the contact and free surfaces at the boundary of the shell mold and support filler was solved. The results are presented graphically in the form of diagrams of stresses and temperatures over the studied area in its different sections and time intervals for cooling of the growing metal crust. The role of compressive normal stresses σ22 , σ33 on the surface of contact of the shell mold with liquid metal at the initial moment of cooling on probability of cracking in a spherical mold is shown. The level of strain-stress state in a spherical shell mold when cooling a steel casting in it is significantly determined by dependence of shift modulus of the shell mold on temperature.

Understanding mechanism on carbonation curing for Portland cement through phase profiling via QXRD analysis and thermodynamic modeling

The mechanism of early age accelerated carbonation cured ordinary Portland cement mixtures is evaluated using experimental and thermodynamic modeling. This study considered three early precuring conditions, two carbonation curing periods, four CO2 concentrations, and a 0.5 w/c ratio. The investigation was conducted using phase profiling of mixtures based on QXRD results and developed a thermodynamic model that simulated the experimental conditions. The mechanical characteristics of carbonation-cured mortar specimens, including compressive strength, elastic modulus, shrinkage, and mass change, were evaluated. The results revealed that short precuring durations hindered carbonation, resulting in lower CO2 uptake, strength, elastic modulus and higher shrinkage. Increasing the precuring period from six-hours to one or three days resulted significant amount of CaCO3 precipitation on the surface of the specimen and appropriate mechanical properties. One day precuring followed by one day carbonation with a 10 % CO2 exposure resulted in a higher calcite precipitation on the surface with less depth of penetration. It was found that a balance between drying-induced degradation and microstructure densification due to calcite precipitation is crucial. An appropriate precuring duration, for each binder type and mix proportion, should be applied to achieve desired properties and CO2 uptake in carbonation-cured cementitious materials.

Micro-morphology and fractal characteristics of pore structure of aeolian sand concrete under long-term semi-immersion with chloride solution

To investigate the influence of chloride exposure on hydraulic concrete, we investigated the microstructural changes and pore evolution of aeolian sand concrete (ASC) during prolonged semi-immersion in chloride solution. Our analysis included examining the mass loss rate, relative dynamic elastic modulus, and maximum depth of chloride erosion. Utilizing scanning electron microscopy (SEM), X-ray diffraction (XRD), and nuclear magnetic resonance (NMR), we assessed the microscopic morphology and pore structure evolution. Additionally, we employed fractal theory to evaluate pore structure heterogeneity in ASC before and after exposure to chloride erosion. After 450 days of chloride erosion, ASC displayed minimal changes in mass loss rate and relative dynamic elastic modulus, with a maximum erosion depth of 9.8 mm. Chlorides adhered to the immersed end at the concrete's base and migrated from the surface to the exposed top end during erosion. The erosion depth at the top end ranged from 23.9 % to 25.9 % of that at the bottom end. Within ASC, hydration products reacted with chlorides, resulting in the formation of Friedel's salt, a characteristic corrosion crystal. Following erosion, the total porosity of ASC increased, accompanied by shifts in pore size distribution. The internal structure of ASC underwent distinctive evolution, transitioning from small to large pores. ASC consistently exhibited fractal properties both before and after erosion. The fractal dimension D1 demonstrated an inverse relationship with pores of radius (r) less than 0.01 μm, while D2 was directly proportional to pores with r ≤ 0.01 μm and 0.01 <r ≤ 0.1 μm, and inversely proportional to pores with 1 <r ≤ 10 μm and r > 10 μm. This study significantly contributes to the theoretical understanding of ASC's endurance mechanisms in chloride environments.

Oligo-cyclic loading-induced evolution of stress distribution and apparent amorphous modulus in lamellar stacks of high-density polyethylene

Assessing the resistance of high-density polyethylene (HDPE) against earthquake-like loads involves understanding the changes in structure and properties induced by oligo-cyclic loading at various length scales. To study the evolution of stress distribution and intrinsic properties within lamellar stacks from pristine to oligo-cyclic loading pre-conditioned materials, simultaneous in-situ SAXS/WAXS measurements were performed. During the elastic deformation of each pristine and preconditioned sample, crystal strain was tracked using the in-situ WAXS technique. Based on the established elastic tensor of the crystalline structure in polyethylene, we calculated the microscopic stress values within crystalline lamellae. In the pristine sample, lamellar stacks exhibit closely series-like coupling in the equatorial region and parallel-like coupling in the polar region of the spherulite. In the pre-conditioned sample, stress is primarily concentrated in the intra-fibrillar region, where the crystalline and amorphous phases are series-coupled, and strong strain concentration occurs in the inter-fibrillar region. By combining the local strain in the amorphous layer within the lamellar stacks in the equatorial region of the spherulite and the intra-fibrillar region with series-coupled lamellar stacks, measured by in-situ SAXS tests, the apparent amorphous modulus at the lamellar stack scale can be determined. This modulus changes from 71 to 106 MPa in the equatorial region of pristine spherulites to a notable 2000–7000 MPa in the intra-fibrillar region under the influence of oligo-cyclic pre-loading. Importantly, this apparent modulus is affected by both crystallization conditions and molecular structure, with molecular parameters exerting the primary influence.

Origins of Giant Anisotropic Phonon Heat Transfer in True‐1D van der Waals Material

AbstractThermal rectification devices, which facilitate preferential heat flow in a singular direction, stands as pivotal tools in the realization of solid‐state thermal circuits. 1D atomic chains, exhibit heightened thermal rectification efficiency owing to their exceptional directional heat conduction properties. These will find widespread utility in many applications, encompassing areas such as cooling, energy harvesting, and thermal isolation systems. However, unlike quasi‐1D materials, the intrinsic anisotropic heat transport in true‐1D atomic chains is yet to be systematically studied. Herein, the origins of the anisotropic heat transfer in three representative 1D structures (TaSe3 and BaTiS3 marked as quasi‐1D, MoI3 labeled as true‐1D) is first investigated by integrating a first‐principles density functional theory‐based framework of two‐channel heat conduction model. In contrast to quasi‐1D, MoI3 exhibits a giant anisotropy of lattice thermal conductivity (κL) in chain‐ and cross chain‐directions with a high ratio up to ≈20, which far exceeds the previous report for HfTe5 and ZrTe5. Such unique heat transfer reveals comprehensively by charge‐sharing and transferred charges, p‐‐d orbital hybridization and Young's modulus changes, induces an exceptionally large anisotropy. This study presents a high‐performance implementation of thermal rectification designed to regulate directional heat current, demonstrating its potential applicability in solid‐state thermal circuits.