Changes In Groundwater Quality Research Articles

Assessment of groundwater quality variation characteristics and influencing factors in an intensified agricultural area: An integrated hydrochemical and machine learning approach

The decline in groundwater quality in intensive agricultural areas in recent years, driven by environmental change and intensified human activity, poses a significant threat to agricultural production and public health, requiring attention and effective management. However, distinguishing the specific impacts of various factors on groundwater quality remains challenging, which hinders the effective management and prevention of groundwater pollution. This research integrates a hydrochemical analysis with the Entropy-weighted Water Quality Index, Self-Organizing Map (SOM) approach, and Boruta algorithm to investigate groundwater chemical variations and their influencing factors in the Sanjiang Plain, an important grain-producing region in China. The findings reveal that, compared to 2012, the deep groundwater quality has improved, while the shallow groundwater quality has markedly deteriorated. This decline in shallow groundwater quality is primarily attributable to human activities and is characterized by elevated levels of chloride, sulfate, and nitrate and a shift in the groundwater hydrochemical facies from an HCO3−Ca·Mg type to a mixed HCO3−Ca·Mg and SO4·Cl−Ca·Mg type. The SOM results suggested that land use type significantly affects shallow groundwater quality. Further analysis with the Boruta algorithm identified increased sewage and manure emissions from expanding livestock operations as well as enhanced pollutant leakage from the expansion of paddy fields as the primary contributors to the decline in shallow groundwater quality. These findings offer new insights into the mechanisms of groundwater quality changes in agriculturally intensive regions and provide a foundation for improved groundwater pollution management in the Sanjiang Plain and similar areas.

Long term changes in Chalk groundwater quality in East Anglia, UK

Groundwater abstraction quantity from the Chalk is limited to what is sustainable. Water quality data collected in the 1970s and 1980s have been compared with modern water quality monitoring data for 25 public supply abstraction sites. This comparison has established that there has been both substantial (magnitude) and significant (statistical) change in composition at all sites. Identified changes generally represent real changes in groundwater composition. At some sites in the south of the area considered, water that is not the result of present-day recharge processes is being replaced by water from present-day recharge. It is also clear that, at those sites where ancient brackish water is known to be present at depth, it is generally not being mobilised by pumping. In the north of the area, changes are more subtle but there is a tendency of groundwater composition to approach the regional average, apart from calcium which is trending higher. Nitrate has not increased here, suggesting that reduction is a still-active process. Thus, although quantity has been sustained, quality is changing but not to a degree that impacts potable use.

Evaluation of groundwater quality for drinking and irrigation purposes, ionic sources and land use/land cover impacts in the Kathua region of Jammu and Kashmir, India

Kathua is one of the fast-growing industrial districts of the Union Territory of Jammu and Kashmir, northern India. The primary source of water in Kathua is groundwater, which is widely used for industrial, agricultural, drinking, and building purposes. The groundwater system is changing significantly both in terms of quantity and quality in the study area due to recent industrial and infrastructural developments. Thus, 40 groundwater samples were collected from different wells in the pre-monsoon season, May 2022, and analyzed for physicochemical variables to determine the impact of geogenic and anthropogenic activities on the groundwater. The drinking groundwater quality appears to be excellent to good. Of the variables that were examined, two—TH and HCO3—had concentrations higher than the recommended limits of the BIS and WHO guidelines. Groundwater contains alkaline earth metals and weak acids, and its hydrochemistry is controlled by rock‒water interactions (silicate weathering or cation exchange and reverse-ion exchange processes). Several parameters (electrical conductivity, sodium percentage, sodium adsorption ratio, permeability index, magnesium adsorption ratio, residual sodium carbonate, and the Kelly’s ratio) were used to evaluate groundwater suitability for irrigation. The permeability index, magnesium adsorption ratio, and residual sodium carbonate indicate that the groundwater of a few samples is unsuitable for irrigation purposes. Land use/land cover (LULC) change analysis was used to determine the potential impacts of LULC changes on groundwater. Anthropogenic interventions are a major cause of LULC changes that are considerably reducing groundwater recharge zones, increasing surface runoff, and artificially polluting groundwater through domestic and industrial wastes, according to the LULC analysis conducted using satellite data for the year 2017 and 2022. Therefore, to minimize the effects of LULC on groundwater, prompt action must be taken, requiring regular monitoring of groundwater quality and LULC changes. The results of the study may be useful to the general public, farmers, and policy makers in the sustainable development and management of groundwater.

Integrated assessment of groundwater quality dynamics and Land use/land cover changes in rapidly urbanizing semi-arid region

Rapid urbanization worldwide, poses numerous environmental challenges between escalating land use land cover (LULC) changes and groundwater quality dynamics. The main objective of this study was to investigate the dynamics of groundwater quality and LULC changes in Sargodha district, Punjab, Pakistan. Groundwater hydrochemistry reveals acceptable pH levels (<8) but total dissolved solids (TDS), electrical conductivity (EC) and HCO3− showed dynamic fluctuations by exceeding WHO limits. Piper diagrams, indicated dominance by magnesium and bicarbonate types, underscoring the influence of natural processes and anthropogenic activities. Major ion relationships in 2010, 2015, and 2021 showed a high correlation (R2 > 0.85) between Na+ and Cl−, suggesting salinization. whereas, the poor correlation (<0.17) between Ca2+ and HCO3− does not support calcite dissolution as the primary process affecting groundwater composition. The examination of nitrate contamination in groundwater across the years 2010, 2015, and 2021 was found to be high in the municipal sewage zone, suggesting a prevailing issue of nitrate contamination attributed to urban activities. The Nitrate Pollution Index (NPI) reveals a concerning trend, with a higher proportion of samples classified under moderate to high pollution categories in 2015 and 2021 compared to 2010. The qualitative assessment of nitrate concentration on spatiotemporal scale showed lower values in 2010 while a consistent rise from 2015 to 2021 in north-east and western parts of district. Likewise, NPI was high in the north-eastern and south-western regions in 2010, then reduced in subsequent years, which may be attributed to effective waste management practices and alterations in agricultural practices. The health risk assessment of 2010 indicated Total Health Hazard Quotient (THQ) within the standard limit, while in 2015 and 2021, elevated health risk was observed. This study emphasizes the need to use multiple approaches to groundwater management for sustainable land use planning and regulations that prioritize groundwater quality conservation.

Modeling of Non-Stationary Mass Transfer Process in Groundwater

Purpose. Infiltration of contaminated water and accidental spills of chemically hazardous substances into groundwater lead to the formation of large zones of man-made pollution in aquifers. Therefore, it is important to develop protection systems against groundwater pollution. To analyze the effectiveness of such protection systems at the design stage, it is necessary to have scientifically based information on the dynamics of changes in groundwater contamination zones. Such information can be obtained using the method of mathematical modeling. The study aims to create a numerical model for calculating the non-stationary process of geomigration when using chemical protection of groundwater from pollution. Methodology. To describe the dynamics of groundwater flows, two filtration equations are considered, which allow mathematical modeling of the filtration process both for solving planned problems and for solving problems of specialized filtration. A two-dimensional geomigration equation was used to analyze changes in groundwater quality. This equation takes into account the convective transfer of impurities in the filtration flow, dispersion, and the intensity of impurity infiltration into the groundwater flow. This equation is also used to calculate the movement of the neutralizer in groundwater. The numerical integration of the filtration equation was performed using finite difference methods. An implicit splitting scheme was used to numerically integrate the geomigration equation. Findings. A fast-applicable numerical model for calculating groundwater dynamics has been built. The model is also a platform for solving another important task – the calculation of geomigration processes. A numerical model for calculating the unsteady-state geomigration process is proposed, which makes it possible to assess not only the process of formation of contamination zones in the groundwater flow, but also to determine the effectiveness of the method of neutralizing the impurities in the groundwater flow. Originality. Effective numerical models for rapid assessment of changes in groundwater dynamics and quality under the influence of anthropogenic sources have been developed. These models take into account a set of important physical factors that affect the process of geomigration and the process of neutralizing the impurity in the groundwater flow. Practical value. A computer program has been developed that allows determining the effectiveness of the process of neutralizing an aggressive impurity in groundwater by a computational experiment to protect it from anthropogenic pollution.

MODELING OF GROUND WATER DYNAMICS AND ITS POLLUTION

Problem statement. Large accumulators of liquid waste (e.g., mine water ponds, tailing ponds, etc.) are long-term sources that change the hydrological regime. A negative consequence of this process is flooding of the territory. In addition, the infiltration of contaminated water from such hazardous sources changes the quality of groundwater. Therefore, it is important to analyze the impact of such anthropogenic sources on the process of flooding and deterioration of groundwater quality. To solve this problem, it is very important to use the method of mathematical modeling as an effective mean of researching problems of this class, since the use of physical modeling is practically impossible within the scope of problems of this class. The purpose of the article. Development of numerical models for predicting changes in the hydrological regime (flooding of the territory) and groundwater quality under the influence of anthropogenic pollution sources. Methodology. To assess the dynamics of changes in the hydrological regime, a two-dimensional equation of filtration of a non-pressure groundwater flow is used. A two-dimensional geomigration equation (planned model) is used to analyze changes in groundwater quality during infiltration of contaminated water from the settling pond. This equation takes into account the convective transfer of contaminants in the filtration flow, dispersion, and the intensity of contaminant infiltration into the groundwater flow. The method of total approximation is used for numerical integration of the filtration equation. For the numerical integration of the geomigration equation, an implicit splitting scheme is used. Scientific novelty. Effective numerical models for rapid assessment of changes in groundwater dynamics and quality under the influence of anthropogenic sources that change the hydrological regime are proposed. The constructed numerical models take into account a set of important physical factors that affect the process of geomigration and flooding of the territory, namely: filtration coefficient, variable depth of free-flowing groundwater, dispersion, intensity of the source of impurity emission into the groundwater flow. This makes it possible to obtain a comprehensive assessment of the process of flooding and groundwater pollution.. Practical significance. A computer code has been created that allows practical usage of the developed numerical models. This code is an effective tool for theoretical study of non-stationary processes of territory flooding and anthropogenic groundwater pollution. Conclusions. A numerical model for calculating groundwater dynamics has been developed. The model allows to predict the level of groundwater rise under the influence of a man-made source of wastewater infiltration from a settling pond. A numerical model for calculating the process of geomigration from an anthropogenic source of emissions has been developed. The model makes it possible to predict the dynamics of contamination zone formation in a non-pressure groundwater flow. The developed numerical models take into account the most important parameters that affect the formation of flooding zones and groundwater contamination.

Process-Based and Probabilistic Quantification of Co and Ni Mobilization Risks Induced by Managed Aquifer Recharge.

Managed aquifer recharge (MAR) is an increasingly used water management technique that enhances water availability while commonly generating water quality benefits. However, MAR activities may also trigger adverse geochemical reactions, especially during the injection of oxidant-enriched waters into reducing aquifers. Where this occurs, the environmental risks and the viability of mitigating them must be well understood. Here, we develop a rigorous approach for assessing and managing the risks from MAR-induced metal mobilization. First, we develop a process-based reactive transport model to identify and quantify the main hydrogeochemical drivers that control the release of metals and their mobility. We then apply a probabilistic framework to interrogate the inherent uncertainty associated with adjustable model parameters and consider this uncertainty (i) in long-term predictions of groundwater quality changes and (ii) in scenarios that investigate the effectiveness of modifications in the water treatment process to mitigate metal release and mobility. The results suggested that Co, Ni, Zn, and Mn were comobilized during pyrite oxidation and that metal mobility was controlled (i) by the sediment pH buffering capacity and (ii) by the sorption capacity of the native aquifer sediments. Both tested mitigation strategies were shown to be effective at reducing the risk of elevated metal concentrations.

Assessing groundwater quality dynamics in Madhya Pradesh: Chemical contaminants and their temporal patterns

Groundwater is essential for maintaining ecosystem health and overall well-being as a pivotal resource for plants and animals. The increasing public consciousness of the deterioration of groundwater quality has emphasized the significance of undertaking extended evaluations of groundwater water quality, particularly in regions undergoing substantial hydrological alterations. This study primarily aims to investigate the spatio-temporal variations in groundwater quality and evaluate its suitability for potable purposes in the region of Madhya Pradesh. The study combines the Mann-Kendall (MK) test and Sen's Slope (SS) to analyze the changes in groundwater quality of all 51 districts of Madhya Pradesh, India, utilizing 12 water quality indices using MATLAB. Data was sourced from the Central Ground Water Board (CGWB) in India from the year 2001–2021. The data was then tested for homogeneity at all 1154 sampling stations using the software XLSTAT. Piper plot clustering characterized the state's groundwater as bicarbonate-calcium-magnesium (HCO3−-Ca2+-Mg2+) type. The study found that the groundwater in the area is heavily impacted by high levels of nitrate and hardness, which is caused by an increase in multivalent cations. The water was classified as ranging from hard to extremely hard, and approximately 25.49% of the state's groundwater has nitrate levels that exceed the acceptable limits. The MK test showed a significant increasing correlation in trends for parameters such as nitrate, sulfate, fluoride, chloride, bicarbonate, total hardness, and electrical conductivity. It also showed a significant decreasing correlation for calcium, magnesium, potassium, and sodium. These results were observed at a confidence level of 95%. The analysis of trends has shown that human-related factors have a considerable effect on the characteristics of groundwater quality. It is therefore recommended that such human-related factors be taken into consideration when developing policies for managing groundwater resources. Consequently, these policies should emphasize the strict enforcement of rules and standards that limit the overuse of fertilizers, ensure the appropriate disposal of municipal solid and liquid wastes, and regulate industrial pollutants.

Groundwater microbial communities reflect geothermal activity on volcanic island.

Studies of the effects of volcanic activity on the Hawaiian Islands are extremely relevant due to the past and current co-eruptions at both Mauna Loa and Kīlauea. The Big Island of Hawai'i is one of the most seismically monitored volcanic systems in the world, and recent investigations of the Big Island suggest a widespread subsurface connectivity between volcanoes. Volcanic activity has the potential to add mineral contaminants into groundwater ecosystems, thus affecting water quality, and making inhabitants of volcanic islands particularly vulnerable due to dependence on groundwater aquifers. As part of an interdisciplinary study on groundwater aquifers in Kona, Hawai'i, over 40 groundwater wells were sampled quarterly from August 2017 through March 2019, before and after the destructive eruption of the Kīlauea East Rift Zone in May 2018. Sample sites occurred at great distance (~80 km) from Kīlauea, allowing us to pose questions of how volcanic groundwater aquifers might be influenced by volcanic subsurface activity. Approximately 400 water samples were analyzed and temporally split by pre-eruption and post-eruption for biogeochemical analysis. While most geochemical constituents did not differ across quarterly sampling, microbial communities varied temporally (pre- and post-eruption). When a salinity threshold amongst samples was set, the greatest microbial community differences were observed in the freshest groundwater samples. Differential analysis indicated bacterial families with sulfur (S) metabolisms (sulfate reducers, sulfide oxidation, and disproportionation of S-intermediates) were enriched post-eruption. The diversity in S-cyclers without a corresponding change in sulfate geochemistry suggests cryptic cycling may occur in groundwater aquifers as a result of distant volcanic subsurface activity. Microbial communities, including taxa that cycle S, may be superior tracers to changes in groundwater quality, especially from direct inputs of subsurface volcanic activity.

SiO2 and microparticle transport in a saturated porous medium: effects of particle size and flow rate

SiO2 and polystyrene (PS) are carriers of microorganisms and metals in porous media, which can produce changes in groundwater quality and cause issues related to clogging of the porous medium. Although SiO2 and PS particle transport in porous media has been previously studied, what influences transport at various particle sizes and flow rates remains unclear. Here, we looked at how pH and ionic strength affected the surface zeta potentials as well as how particle size and flow rate affected the transport of suspended SiO2/PS particles in a porous media. The results indicate that increasing pH and decreasing ionic strength increased the negative surface charges on both the SiO2 and PS particles, thereby yielding greater electrostatic repulsion between particles. At the same flow rate, the retention rate of 10 μm PS particles in the porous medium was 46.1% better than that of 2 μm particles, whereas the retention rate of 10 μm SiO2 particles was 7.88% better than that of 2 μm particles. For the same particle size, increasing the flow rate decreased SiO2 and PS retention in the porous medium. Thus, particle size and flow rate substantially impact the transport of SiO2 and PS-suspended particles in a porous media.

Sensing the dependable surficial signatures of temporal groundwater variations in arid coastal regions through geospatial techniques with respect to microclimate changes

Reports on Groundwater level variations and quality changes have been a critical issue, especially in arid regions. An attempt has been made in this study to determine the surface manifestations of groundwater variations through processing imageries for determining the changes in land use, Normalized Differential Building Index (NDBI), Normalized Difference Vegetation Index (NDVI), Land Surface Temperature (LST), along with Groundwater level (GWL) and Electrical conductivity (EC). Decadal variation between these parameters for 2013 and 2023 shows that the average water level had increased by 1.03amsl, while the EC values of groundwater decreased by 418 μS/cm. The decrease in EC values indicates freshwater recharge, promoting natural vegetation, thus reducing the LST values by 3.28 °C. In addition, urban landscaping and relatively lesser emissivity from built-up surfaces than the sandy desert have further reduced the LST. The interrelationship of the parameters indicates that an increase in LST correlates with an increase in NDBI and with less significant changes in NDVI. The lowering of the LST along the coastal regions was inferred to be due to the influence of Sea breeze, adjacent moisture from the ocean, shallow water level, and the shadow effect of the buildings. Further, the increase in water level was mainly attributed to the recent increase in rainfall and the extreme event in 2018. The higher EC in the lesser NDBI regions is attributed to the anthropogenic contamination from agriculture and landfill leachates. Though there was an increase in NDBI, the LST of the region was inferred to be reduced mainly due to the increase in water level and reduction of emission from desert sand by recent urban developments.

Multivariate analysis of seasonal changes of chemical elements in groundwater around Solous lll dumpsite, Lagos, South-West Nigeria

The study of changes in groundwater quality across the study areas became necessary to track the sources of the contamination in the water sources. Assessment of the physiochemical parameters of groundwater samples obtained from both borehole and hand-dug wells were conducted around the Solous III dumpsite, Lagos, South-western, Nigeria. Multivariate statistics such as correlation coefficient analysis, Hierarchical cluster analysis (HCA) and principal component analyses (PCA) were utilised to assess the mode of association of parameters and their interrelationships to establish possible sources of groundwater contamination. Eight groundwater samples were obtained around the dumpsite during the wet and dry seasons for analyses of their physicochemical properties. The results of the analyses of water samples indicated seasonal changes for the various elemental constituents analysed. There was generally an increase in mean concentration of total dissolved solid (TDS), pH, temperature and hardness in the dry season study, and a corresponding increase in the mean concentration of Ca2+, Mg2+, Na+, SO42−, NO32−, Pb, and Cr, when compared with the wet season. On the other hand, there was reduction in the mean concentration of electrical conductivity (EC), K+, Cl−, PO43−, Fe, Zn, Mn, Cu, and Ni in the dry season when compared with the wet season. Some of the water sample parameters exhibited high concentration when compared with the World Health Organisation (WHO)/Standard Organisation of Nigeria (SON) standards, which may be due to the impact of leachate migration from the dumpsite. Five varimax rotated factor loadings and communalities were responsible for 30 % and 35 % of the total variance in the data set during wet and dry seasons respectively. The PCA parameters identified to be influencing the quality of water are perhaps related to anthropogenic activities from the dumpsite, soluble mineral dissolution, rock–groundwater interaction and weathering activities while PCA performed on samples of groundwater during wet and dry seasons indicated 2 and 3 important clusters, respectively. The clusters of parameters as observed in the parameters dendrograms clearly validates the results earlier obtained in the correlation analysis component of this research. The dendrogram was also able to reflect variation in the quality of water with season as indicated in the difference in the number of clusters during both wet and dry seasons. The outcome of this research should help highlight and focus water quality management on key chemical elements of concern and prioritize efforts to mitigate their release into groundwater around the study area. By extension, this research work offers specific contribution to achieving the Africa's Union's Agenda 2063 Goal No. 7 i.e. Environmentally sustainable and climate resilient economies and communities, with Priority Area of Water Security.

Balancing urban growth and the sustainability of groundwater and agricultural land: Case of the berrechid-settat area

Urbanization is an inevitable global phenomenon characterized by the exponential growth of urban areas in terms of both population and infrastructure. However, this rapid urban expansion often comes at a significant environmental cost. This article explores the multifaceted consequences of urbanization, shedding light on its role in contributing to desertification, compromising water quality, and depleting groundwater resources. To assess the scale of urbanization’s impact, comprehensive landuse studies are crucial. Geographic Information Systems (GIS) and remote sensing techniques offer valuable tools for mapping and monitoring land-use changes over time. These methods enable the quantification of the conversion of agricultural land into urban areas and identify trends in urban sprawl, providing essential data for understanding the scale of the issue. Water quality assessments are equally vital; we can employ water sampling and laboratory analyses to quantify pollutant concentrations in urban runoff and groundwater. Monitoring the presence of contaminants such as oil, chemicals, and litter, as well as their effects on water quality; helps measure the environmental impact of urbanization. Groundwater studies can utilize hydrogeological investigations, including the use of monitoring wells and geophysical methods, to evaluate changes in groundwater levels and quality. These data are instrumental in gauging the depletion of groundwater reserves and their potential contribution to water scarcity issues. In conclusion, the consequences of urbanization extend far beyond the confines of urban areas, affecting agriculture, ecosystems, and water resources. As urbanization continues to advance, it is imperative to develop sustainable urban planning and management strategies that mitigate its environmental impact, preserve agricultural land, protect groundwater resources, and ensure the long-term health of the planet.

Determination of Groundwater Quality Index in Rural Area: The Case of Bartın City

The aim of the study is to determine the change of groundwater quality in rural areas in rainy and dry periods with respect to physicochemical parameters. pH, total dissolved solids, electrical conductivity, nitrate, sulfate, phosphate hardness, chloride, turbidity and color parameters were investigated. The water quality index (WQI) is widely used for detecting and evaluating water pollution. Water quality index was determined to be 35 and 32 in rainy and dry periods for drinking water. It was also calculated to be 37 for the rainy and dry periods according to the irrigation water limit values. As a result, since WQI

Spatial–Temporal Changes in Shallow Groundwater Quality with Human Health Risk Assessment in the Luxi Plain (China)

Groundwater is an essential water source for drinking, domestic, irrigation and industrial production in Luxi Plain, Shandong Province, China. Understanding the spatial–temporal changes in groundwater quality and its influencing factors in the region were required for better utilization of groundwater resources and efficient design of groundwater management strategies. In this study, the hydrochemical characteristics of groundwater in the study area were analyzed, and significant evolution was found from 2018 to 2020 due to silicate and carbonate weathering, evaporation and human activities. Moreover, the entropy water quality index (EWQI) was used to assess groundwater quality from 2018 to 2020. The EWQI values in 2018–2020 were 129.5, 90.5 and 94.0, respectively, and 31.7% of the groundwater in 2019 and 20.0% in 2020 can be used directly for drinking in the study area; others can be used for domestic water or irrigation. The potable groundwater, with an EWQI value of &lt;50 (ranked as class Ⅰ or Ⅱ water quality), was mainly distributed in the west and southeast of the study area. The potential health risk due to oral intake and dermal intake was further assessed based on the human health risk assessment (HHRA) model. The results showed that, 37.3%, 6.7% and 3.3% of the groundwater samples for adults exceeded the acceptable limit for non-carcinogenic risk of 1.0 in 2018–2020, while for children, they were 88.2%, 30.0% and 56.7%, respectively. The high non-carcinogenic risks virtually all occurred in the counties or districts with higher agricultural or economic values. This work may provide useful information for local groundwater conservation and management and help to ensure a sustainable and healthy water supply for drinking, domestic and agricultural needs.

Thirty years of regional groundwater-quality trend studies in the United States: Major findings and lessons learned

Changes in groundwater quality have been evaluated for more than 2,200 wells in 25 Principal Aquifers in the United States based on repeated decadal sampling (once every 10 years) from 1988 to 2021. The purpose of this study is to identify contaminants with changing concentrations, the locations and magnitude of those changes, the factors driving those changes, the obstacles to interpreting the changes, and approaches to ameliorate those obstacles. Sampling was conducted in 89 networks of 20–30 wells each that represent various geographic regions, aquifer types and land use types. Each network, and the wells that comprise them, are sampled on a rotating basis once every 10 years. Of the 28 constituents evaluated for trends, concentrations of Na, Cl, dissolved solids, SO4, and NO3 exhibited statistically significant increases at the network level more frequently than other constituents. Factors affecting trends in Cl and NO3 are emphasized in this study. Regional patterns show large increases of Cl in urban areas in the Northeast and Midcontinent, where road-deicing salt application rates are 10 to 100 times greater than in other regions of the country, and in semiarid and arid regions of the western United States, where evaporation concentrates solutes in recharge. The largest increases in NO3 were in agricultural areas of the semiarid west, arid west and Pacific regions which are characterized by oxic groundwater, long-term increases in nitrogen fertilizer usage, and high rates of irrigation. However, finding a direct relation between increasing contaminant sources and corresponding groundwater quality response, particularly when sampling once every 10 years, can be complicated by factors such as uncertainty in the timing, mass, and location of contaminant sources, groundwater residence time (recharge date), geochemical conditions in the aquifer that affect contaminant transport, and variability in water quality due to climatic factors such as seasonality and hydrologic conditions. Understanding groundwater residence time allows the changes in groundwater quality to be evaluated in the context of recharge date rather than the sample date. Likewise, information on geochemical characteristics of the aquifer can be helpful for understanding relations between contaminant source inputs and groundwater concentrations. For example, oxic geochemical conditions in the aquifer may allow for conservative transport and accumulation of NO3 in groundwater, whereas reducing environments could favor NO3 degradation. Differences in hydrologic conditions (wetter or drier than average) on the date of sampling could impact the statistical results of sampling at decadal intervals and obscure long-term patterns. Samples collected under substantially different hydrologic conditions can be identified, and high-frequency sampling can improve interpretation of measured results in these cases. Although decadal sampling and associated water-quality interpretations have limitations, repeated, scheduled sampling of thousands of wells over multiple decades has great value for identifying and understanding long-term, regional groundwater-quality trends. Despite these limitations, the concepts presented herein provide options that could be used to interpret trends or changes when sampling over longer timespans, which is less common than trend networks with higher frequency sampling intervals.

Hydrogeochemical evolution of groundwater impacted by acid mine drainage (AMD) from polymetallic mining areas (South China)

Mining activities have long-term impacts on the groundwater of surrounding areas and deserve in-depth analysis and study. Herein, the geochemical mechanisms of acid mine drainage (AMD)-affected groundwaters were examined, and groundwater quality was assessed through water quality indices. 15 water samples from 7 domestic and 4 groundwater monitoring wells were tested for physical and chemical parameters in 2022, and multivariate statistical analysis was carried out with monitoring data from 21 domestic wells in 2010. The groundwater chemical composition varied from a predominantly Ca-HCO3 type in 2010 to a Ca-SO4 type in 2022. The isotopic values of δ18O and δD indicate that groundwater has not been significantly affected by evaporation. Changes in groundwater sulfate and total dissolved solids (TDS) levels over the twelve-year period confirmed the AMD infiltration impact on groundwater quality. The groundwater chemical properties changed more slowly than those of surface waters affected by AMD based on a cumulative increase in sulfate concentration of 29.94 mg/L. Changes in groundwater quality were investigated, namely, the spatiotemporal distribution of potentially toxic elements (PTEs), including Fe, Mn, Cd, Pb, and As. Mn concentrations in upstream groundwater areas near the mine decreased by 61.8% between 2010 and 2022. Conversely, groundwater in midstream areas had Mn concentrations of 2.25 mg/L and arsenic concentrations of 11.8 μg/L, both exceeding the WHO, 2022 standard. According to multivariate statistical analysis, Mn, Cd, and Pb originated from polymetallic minerals, whereas As was likely derived from the reduction of Fe/Mn hydroxyl oxides. AMD remediation improved contaminated upstream groundwater quality over 12 years, with a 36.8% improvement in WQI values. PTE distribution determined water quality changes; therefore, PTE contamination should be treated in mid- and downstream regions while contaminated groundwater should be treated upstream.

Safe Groundwater Level Estimation in Pingtung Plain, Taiwan

The groundwater resources in the Pingtung Plain are crucial water sources in southern Taiwan. However, they have been significantly impacted by climate change, resulting in changes in groundwater quality and quantity in the region. To effectively manage groundwater extraction, this study utilized runs theory to analyze the safe groundwater levels at six groundwater level observation stations located in the proximal fan, mid fan, and distal fan areas of the Pingtung Plain. The methodology involved dividing the range between the maximum and minimum groundwater levels at each station into 20 equal intervals. The groundwater levels were then sorted in ascending order, and the cumulative frequency percentiles of groundwater levels in each interval were calculated to determine the truncation levels for runs theory. Subsequently, the groundwater over-extraction duration and severity were computed. By comparing the results with the groundwater management levels set by the Water Resources Agency of the Ministry of Economic Affairs, it was found that the safe groundwater levels in the proximal fan and distal fan areas were the average of observation data plus 0.5 times the standard deviation. The over-withdrawn duration for these areas was approximately 8 to 10 months and 8 months, respectively. In the mid fan area, the safe groundwater level was based on the average of observation data, and the over-withdrawn duration ranged from 6 to 9 months.

Temporal and spatial estimation of groundwater electrical conductivity using soft computing approaches: Analysis of East Azerbaijan Province, Iran

Abstract The evaluation of groundwater quality plays an important role in the management of groundwater. The main objectives of the present work are to develop a novel soft computing framework including Adaptive Neuro-Fuzzy Inference System (ANFIS), Wavelet-ANFIS (WANFIS), Gene Expression Programming (GEP), and Wavelet-GEP (WGEP) for the temporal and spatial estimation of groundwater electrical conductivity (EC) in the East Azerbaijan province, Iran over 2001–2020. The results demonstrate the importance of wavelet transform application; the performance percentage enhancement of the WANFIS and WGEP models compared to the ANFIS and GEP, using the RMSE criterion, ranged from 15.48 to 51.09% and from 5.06 to 86.95%, respectively. All the developed models showed the WGEP superior compared to others. The impact of land use characteristics, climatic conditions, and geological features on groundwater quality showed that there is a direct relationship between the extent of agricultural land, semi-arid climate conditions and groundwater EC amounts. The results demonstrated that the values of EC increase from east to west, indicating the direct exchange of surface and groundwater in the study area. Moreover, groundwater quality changes significantly across the width of the fault, with groundwater EC in the northern part of the fault higher than that in the southern part.

Hydrogeochemical changes during artificial groundwater well recharge

Artificial groundwater recharge is a relatively economic and efficient method for solving shortages and uneven spatial-temporal distribution of water resources. Changes in groundwater quality during the recharge process are a key issue that must be addressed. Identifying the hydrogeochemical reactions that occur during recharge can be vital in predicting trends in groundwater quality. However, there are few studies on the evolution of groundwater quality during artificial recharge that comprehensively consider environmental, chemical, organic matter, and microbiological indicators. Based on an artificial groundwater recharge experiment in Xiong'an New Area, this study investigated the hydrogeochemical changes during groundwater recharge through a well. The results indicate that (1) as large amounts of recharge water (RW) were injected, the groundwater level initially rose rapidly, then fluctuated slowly, and finally rose again. (2) Water quality indicators, dissolved organic matter (DOM), and microbial communities were influenced by the mixture of RW and the background groundwater before recharge (BGBR), as well as by water-rock interactions, such as mineral dissolution-precipitation and redox reactions. (3) During well recharge, aerobic respiration, nitrification, denitrification, high-valence manganese (Mn) and iron (Fe) minerals reduction dissolution, and Mn2+ and Fe2+ oxidation-precipitation occurred sequentially. (4) DOM analysis showed that protein-like substances in the BGBR were the main carbon sources for aerobic respiration and denitrification, while humic-like substances carried by the RW significantly enhanced Mn and Fe minerals reduction dissolution. Therefore, RW quality significantly affects groundwater quality after artificial groundwater well recharge. Controlling indicators, such as dissolved oxygen (DO) and DOM, in the RW can effectively reduce harm to groundwater quality after recharge. This study is of theoretical and practical significance for in-depth analysis of the evolution of groundwater quality during artificial well recharge, prediction of trends in groundwater quality during and after recharge and ensuring groundwater quality safety.