Chamber Materials Research Articles

Design, construction and performance analysis of a four-fold pyramid shaped solar still with different insulation materials and activated carbon

A four-fold pyramid-shaped solar desalination system has been constructed to produce fresh water for the coastal residents in Bangladesh. To evaluate the heat-storage effectiveness of activated carbon from sugarcane bagasse which was synthesized by KOH activation method and confirmed through SEM/EDS analysis was assessed in a prototype desalination setup. Among the four different insulating materials in the drawer-style chamber of solar still, the PE (polyethylene) foam combined with aluminum foil showed the most effective material for heat retention since it has a low emissivity with a minimum conductive heat transfer loss of 1.65 ± 0.44 W. With a solar radiation of 13.73 MJm−2day−1, the system produced 1.35 kgm−2 of water on November 22, 2023, in Bangladesh. After analyzing the freshwater properties, the salinity, pH, TDS, SG, ORP, and EC of fresh water have been found 0 %, 6.95, 50 ppm, 1.003, −36mV, and 26 μScm−1 respectively. Moreover, the device has an efficiency of 22.64 % with a payback period of 3.3 years. The average distillation value of developed solar still has been found 65 % greater when activated carbon is present. The study also highlights technical optimization and economic feasibility and this solar desalination system presents a promising solution to alleviate freshwater scarcity in Bangladesh.

Effect of Mixing Methods and Black Conductive Fillers on Properties of Natural Rubber Composites

Carbon black, graphite, carbon nanofibers, carbon nanotubes, and metal fillers increase composite conductivity in natural rubber, which is electrically insulating. Depending on dispersion, conductive filler lowers insulating material resistivity. These materials are frequently used for electromagnetic/radio frequency interference (EMI/RFI) shielding, conductive flexible seals gaskets, and conductive mats used to prevent electrostatic damage to electronic devices. These elastomers could be used to make flexible solar cells or mechanical-to-electricity devices. Temperature, mixing time, shear rate, and cross-linking during vulcanization affect rubber electrical conductivity of composite. To study shear rate effects, vulcanizate of Natural Rubber-based composites filled with carbon black, millable carbon fiber powder, and synthetic graphite powder was prepared by open mixing (two roll mill) and close mixing (internal mixer). We compared how shear rate affects cure, stress-strain, and volume resistivity of conductive filler-based Natural Rubber composites. Increment in clearance of two roll mill during addition of rubber additives along with rubber of reduced the shearing force resulted in less dispersive and distributive mixing and stagnant points due to band formation on roll surface compared to intermix where compound movement had no stagnation point and long wings pushed material axially and two nogs pushed material in other chamber. Compared to two roll mill samples, the compound reached every point of the mixing chamber for best homogeneity, reducing cure time and improving stress-strain and volume resistivity.

Power production characteristics of binary particles pulsed anaerobic fluidized bed microbial fuel cell

A novel binary particulate pulsating anaerobic fluidized bed microbial fuel cell (BPFB-MFC) was designed and constructed in order to improve the efficiency of low-grade energy conversion in sewage. The effects of pulsed liquid flow rate and bed filling rate on the electricity production performance and effluent treatment characteristics of the BPFB-MFC were investigated experimentally. The results showed that when the pulsed liquid flow was u=1.95sin(π/3)t cm·s-1 and when the bed materials in the anode chamber consisted of 10% bed height activated carbon particles and 10% bed height ceramic particles, the highest voltage produced was 519.7mV, the highest power density was 587.5mW·m-2, and the lowest internal resistance was 171.2Ω, which was the optimal experimental working condition. It was found that the electricity production performance and effluent treatment efficiency of the mixed particles system were better than those of a system with single particles. This work held promise of promoting the industrialization of MFC.

A device for dynamic testing of the refractory ceramic resistance to biomass ash

The corrosive effects of biomass ash on refractory materials in combustion chambers pose challenges. Development of new castable refractory materials which are more resistant to corrosion requires tests that accurately reflect the conditions occurring in real devices. This article describes the Computational Fluid Dynamics (CFD) design and construction of a device for evaluating the corrosion of refractory materials in dynamic regime. The device allows to simulate combustion chamber conditions accurately, to regulate an injection of corrosive medium on the tested material surface under the specified conditions (temperature, time, and flow). In the present investigation the conventional refractory material was exposed to attack of biomass ash at the temperature of 1300 °C for 3 h to test the functionality of the device. A burner with technology oxygen–enriched combustion was used to heat the device. The corrosion tests were conducted in accordance with the standard P CEN/TS 15,418 and the standard STN EN ISO 21404. The operational state required for corrosion tests at 1300 °C was achieved within 1.12 h. The extent of refractory material degradation in the dynamic corrosion regime was evaluated using electron microscopy-energy dispersive spectroscopy (EM-EDS) and compared with the results of a static crucible test (3 h at 1300 °C). The dynamic test provided sufficient information on the interactions of corrosion medium with the refractories. Its main advantages are the maintenance of non-equilibrium conditions by controlled deposition of the corrosion medium in quantity from 1 to −100 g/h, fast heating rate to operating temperature (20 °C/min), and the possibility of conditions variability during tests (temperature, ox-red. atmosphere, fuel gas flow etc.).

Investigation of low temperature effects on the surface of TI–C composite material – textile blend

A method for the formation of a composite material is demonstrated, which involves applying titanium to one side of the textile blend 07S11‑KV (produced by OJSC “Mogotex”) and carbon to the other side of the fabric. Tests were conducted on the obtained material in a climatic chamber at temperatures ranging from –20 °C to –40 °C. It is shown that the developed composite material withstands low temperatures well, with no additional deformation of the composite material or structural defects observed. This composite material can be considered as promising for special applications in low‑temperature conditions (antistatic, microwave absorbing, biomedical).

Limits of pressure-based ice detection during isochoric vitrification

Vitrification under isochoric (constant-volume or volumetrically confined) conditions has emerged as an intriguing new cryopreservation modality, but the physical complexities of the process confound straight-forward interpretation of experimental results. In particular, the signature pressure-based ice detection used in many isochoric techniques becomes paradoxical during vitrification, wherein the emergence of a sharp increase in pressure reliably indicates the presence of ice, but avoidance of this increase does not necessarily indicate its absence. This phenomenon arises from the rich interplay between thermochemical and thermovolumetric effects in isochoric systems, and muddies efforts to confirm the degree to which a sample has vitrified. In this work, we seek to aid interpretation of isochoric vitrification experiments by calculating thermodynamic limits on the maximum amount of ice that may form without being detected by pressure, and by clarifying the myriad physical processes at play. Neglecting kinetic effects, we develop a simplified thermodynamic model accounting for thermal contraction, cavity formation, ice growth, solute ripening, and glass formation, we evaluate it for a range of chamber materials and solution compositions, and we validate against the acutely limited data available. Our results provide both counter-intuitive insights— lower-concentration solutions may contract less while producing more pressure-undetectable ice growth for example— and a general phenomenological framework by which to evaluate the process of vitrification in isochoric systems. We anticipate that the model herein will enable design of future isochoric protocols with minimized risk of pressure-undetectable ice formation, and provide a thermodynamic foundation from which to build an increasingly rigorous multi-physics understanding of isochoric vitrification.

Experimental study of opening location affecting the delay time of backdraft

Backdraft is a special phenomenon in fire research because of its explosive consequence and the occurrence of uncertainty. The delay time of occurrence has been of interest in recent years as this influences the safety and efficiency of firefighting. This paper investigated the location of the opening and whether it affects the delay time of the backdraft. Results show that the location of the opening dramatically dominates the delay time. The hot/cold air mixing path and instantaneous localized fire ignitions determine the delay time. A ‘curtain-like’ effect for the backdraft time delay was observed. The lower opening demonstrates about 50–70 % delay time compared to the upper and middle locations. In the presence of identical fire conditions and door closure control, the extended flammable gas dilution resulting from the upper opening does not significantly impact the onset of backdraft. Hence, the effective volume above the ignition location determines the delay time of the backdraft. Furthermore, the choice of chamber material is a crucial factor influencing the likelihood of backdraft occurrence. Utilizing a material with enhanced cooling capacity reduces the probability of backdraft. This provides insight into the firefighting and intervention tactics when ventilation-restricted compartment fire occurs.

Lack of evidence for GWAS signals of exfoliation glaucoma working via monogenic loss-of-function mutation in the nearest gene.

Exfoliation syndrome (XFS) is a systemic disease of elastin-rich tissues involving a deposition of fibrillar exfoliative material (XFM) in the anterior chamber of the eye, which can promote glaucoma. The purpose of this study was to create mice with CRISPR/Cas9-induced variations in candidate genes identified from human genome-wide association studies (GWAS) and screen them for indices of XFS. Variants predicted to be deleterious were sought in the Agpat1, Cacna1a, Loxl1, Pomp, Rbms3, Sema6a, and Tlcd5 genes of C57BL/6J mice using CRISPR/Cas9-based gene editing. Strains were phenotyped by slit-lamp, SD-OCT imaging, and fundus exams at 1-5 mos of age. Smaller cohorts of 12-mos-old mice were also studied. Deleterious variants were identified in six targets; Pomp was recalcitrant to targeting. Multiple alleles of some targets were isolated, yielding 12 strains. Across all genotypes and ages, 277 mice were assessed by 902 slit-lamp exams, 928 SD-OCT exams, and 358 fundus exams. Homozygosity for Agpat1 or Cacna1a mutations led to early lethality; homozygosity for Loxl1 mutations led to pelvic organ prolapse, preventing aging. Loxl1 homozygotes exhibited a conjunctival phenotype of potential relevance to XFS. Multiple other genotype-specific phenotypes were variously identified. XFM was not observed in any mice. This study did not detect XFM in any of the strains. This may have been due to species-specific differences, background dependence, or insufficient aging. Alternatively, it is possible that the current candidates, selected based on proximity to GWAS signals, are not effectors acting via monogenic loss-of-function mechanisms.

Physicochemical characteristics and discolouration potentials of Pulpine mineral® and Pulpine NE®

ABSTRACT Aim: To compare the physicochemical properties (solubility, pH, radiopacity and crown discoloration) of Pulpine mineral (PMIN) and Pulpine NE (PNE) with the conventional material, mineral trioxide aggregate (MTA). Methodology: Specimens of the tested materials were prepared according to the manufacturer’s instructions using split Teflon ring molds. Solubility was evaluated by the percentage of material mass loss over 24 h and one week. The alkalinity was measured after each evaluation period using a pH meter. Other specimens were digitally radiographed on a size 2 sensor plate along with an aluminum step wedge to analyze the radiopacity by the Image J software. Finally, crown discoloration was assessed after applying the tested materials in the pulp chamber of sound human premolars using spectrophotometer. All data were statistically analyzed. Results: Compared to MTA, both materials had significantly higher solubility and lower radiopacity (P<0.05). The alkalinity of PMIN was higher than that of MTA and PNE. Unlike PMIN, PNE and MTA caused crown discoloration. Conclusions: PMIN exhibits promising results related to high alkalinity and adequate color stability but it needs modifications for radiopacity and solubility.

Evaluation of novel PCR-based method to assess gill injuries in fish caused by the cnidarian Ectopleura larynx

Gill disease is a major threat to aquaculture of Atlantic salmon, with an unknown and likely underestimated contribution from cnidarians such as jellyfish and biofouling hydroids. To better understand the risk and thus enable mitigation, technology for the certain identification of cnidarian-related gill damage is needed. We used the hydroid Ectopleura larynx in a case study to determine whether the exposure of salmon to nematocyst-bearing hydrozoans can be deducted via non-destructive PCR-based methods. In a field experiment, we evaluated (i) whether swabbing the inside of the gill operculum in farmed Salmo salar and subsequent PCR analysis can provide quantifiable information about the presence of E. larynx material in the gill chamber and, if so, (ii) whether the screening results correlate with histological assessments of gill damage. The developed PCR methods were able to detect the presence of biofouling hydroids in ambient water. However, despite exposure to suspended hydroid particle concentrations that did result in gill damage in some salmon, quantitative PCR results did not correlate with histological gill assessments. For opercular swabs to serve as a diagnostic tool for detecting biofouling-mediated gill damage in live salmon, increased specificity of genetic markers and improved sampling methods are needed.Animal trial permit no. 24252 (granted 06.07.2020, Norwegian Food Safety Authority).

Gear-Shaped High-g Combustion Chamber for Micro Turbojet Engine Applications.

Enhancing combustion efficiency and optimizing the thrust-to-weight ratio are critical technical challenges encountered in the development, application, and growth of micro turbojet engines. The high-centrifugal (high-g) combustion chamber, as an innovative combustion chamber system, has the capability to replace the primary combustion chamber of the traditional turbojet engine, reducing the length of the combustion chamber while maintaining engine performance. Previous studies on the structure of the high-g combustor (HGC) have shown problems such as uneven temperature distribution of the turbojet rotor. To improve the feasibility of HGC integration into micro turbojet engines, this study conducts relevant experiments on a 120 N thrust engine. Subsequently, the results of these experiments were used to analyze the structural design of HGC through a simulation approach. Including six main configurations, the first four structural designs focused on establishing a suitable highly centrifugal environment to stabilize and improve the combustion performance, which was successfully achieved by designing the outer ring gear-shaped inlet with four different angles. Subsequent structural designs were based around improving the uniformity of the temperature distribution at the combustion chamber outlet. The final design of the HGC combustion efficiency is not much different from the original combustion chamber, and it can shorten the axial length of the combustion chamber by nearly 30%. The design of the air inlet holes and the baffle plate effectively improves the temperature uniformity at the outlet of the combustion chamber. Moreover, without changing the combustion chamber material, the corresponding engine weight can be reduced by about 10.7%, and the engine thrust-to-weight ratio can be improved by up to 12% with the same thrust, which provides design ideas for further lightweight applications.

Infective Endocarditis Presenting as Endogenous Endophthalmitis and Multiple Cerebral Infarcts

A 60-year-old housewife as admitted with fever, pain and redness in her right eye for 2 days. She had right eye redness with haziness of the cornea, white fibrinous material in the anterior chamber, and vitreous in the posterior segment. She was evaluated and found to have Endogenous Endophthalmitis (EE) with multiple cerebral infarcts due to methicillin-sensitive coagulase-negative Staphylococcus endocarditis. The patient received intravitreal injections of vancomycin and ceftazidime. She received cefazolin 2 g thrice daily intravenously. The plan of vitrectomy was suggested as per the advice from the ophthalmologist but the relatives opted for conservative management. The patient went into multiorgan failure with disseminated intravascular coagulation and despite all efforts, she succumbed to her illness. Our patient had two extracardiac manifestations of IE together. The presence of any of these manifestations should raise suspicion of infective endocarditis (IE). We report a case of native mitral valve methicillin-sensitive coagulase-negative Staphylococcus endocarditis presenting with extracardiac manifestations. Our case reminds readers to be aware of endocarditis when evaluating patients with extracardiac manifestations like EE.

A combined combustion and conjugate heat transfer analysis of a hybrid draft biomass cookstove

A cookstove comprises both fluid and solid regions, with combustion gases representing the fluid domain and the combustion chamber wall and insulation forming the solid regions. These solid regions are made of different materials and make significant contributions to stove performance. So far, most studies conducted on biomass stoves have only analysed the fluid domain, neglecting solid regions. The current study integrates combustion and conjugate heat transfer analysis, encompassing both fluid and solid domains, to investigate the fluid flow and heat transfer behaviour of a hybrid draft biomass cookstove (HDBC) using CFD. This analysis aims to gain insights into the impact of stove materials on its performance. The study analysed six cases of HDBC, testing different combinations of materials: two for the combustion chamber (ceramic-cement and stainless-steel) and three for insulation (ceramic wool, perlite, and vermiculite). The combustion of biomass and the formation of soot are modelled using reaction kinetics and a one-step soot model, respectively. The CFD findings for thermal efficiency, CO, and PM2.5 emissions derived using combustion and soot model demonstrated closed alignment with the experimental result with variations of 3%, 19%, and 23%, respectively. It was observed that stoves with stainless-steel combustion chamber material exhibit better thermal and emission performance compared to ceramic-cement stoves, with perlite taking the edge over other insulation materials. The success of these materials is attributed to their superior thermophysical properties, which play a significant role in material selection.

Convection flow of nano-encapsulated phase change material in wavy chamber with double sliding walls, flame-shaped heating source, and magnetic force

This article aims to improve the convection flow within a two-dimensional chamber by utilizing nano-encapsulated phase change material (NEPCM). The chamber center contains a flame-shaped heating source, and the bottom wall is wavy. Forced convection occurs due to the motion of the chamber's side walls, while natural convection arises from the thermal gradient across the side walls. The Galerkin-finite element (GFEM) approach was employed to analyze the system's governing equations. The study investigates the impact of the following factors on heat transfer: wall velocity (Re = 10–1000), wall movement directions (both walls moving in a positive direction, both walls moving in a negative direction, and one wall negative and the other positive), intensity of the magnetic field (Ha = 0–100), and cavity porosity (Da = 10−5 – 10−2). The results demonstrate that increasing Re and Da improves the average Nusselt number (NuAvg). Conversely, raising the intensity of the magnetic field and moving the side walls in the opposite direction reduces NuAvg. At Re = 1000, increasing Da (10−2 instead of 10−5) leads to a 139% increase in NuAvg, and decreasing Ha and moving walls in the same directions increase NuAvg by 11.5% and 640%, respectively.

Fully discrete model of kinetic ion-induced electron emission from metal surfaces

Ion-induced electron emission (IIEE) is an important process whereby ions impinging on a material surface lead to net emission of electrons into the vacuum. While relevant for multiple applications, IIEE is a critical process of electric thruster (ET) operation and testing for space propulsion, and, as such, it must be carefully quantified for safe and reliable ET performance. IIEE is a complex physical phenomenon, which involves a number of ion-material and ion-electron processes, and is a complex function of ion mass, energy, and angle, as well as host material properties, such as mass and electronic structure. In this paper, we develop a discrete model of kinetic IIEE to gain a more accurate picture of the electric thruster chamber and facility material degradation processes. The model is based on three main developments: (i) the use of modern electronic and nuclear stopping databases, (ii) the use of the stopping and range of ions in matter to track all ion and recoil trajectories inside the target material, and (iii) the use of a scattering Monte Carlo approach to track the trajectories of all mobilized electrons from the point of first energy transfer until full thermalization or escape. This represents a substantial advantage in terms of physical accuracy over existing semi-analytical models commonly used to calculate kinetic IIEE. We apply the model to Ar, Kr, and Xe irradiation of W and Fe surfaces and calculate excitation spectra as a function of ion depth, energy, and angle of incidence. We also obtain minimum threshold ion energies for net nonzero yield for each ion species in both Fe and W and calculate full IIEE yields as a function of ion energy and incidence angle. Our results can be used to assess the effect of kinetic electron emission in models of full ET facility testing and operation.

Numerical simulation of charged characteristics of scramjet combustion products

The combustion of the engine in the air vehicle causes the presence of charged particles in the jet stream, and the electric field displayed varies with engine type and fuel characteristics. In order to show the magnitude and distribution of charged particles in combustion products during scramjet operation, we constructed microphysical model and fluid calculation model based on the physical characteristics of supersonic combustion to simulate the variation of charged particles concentration in the scramjet combustion chamber and the charge density distribution outside the combustion chamber. The obtained results show that the charged particles in combustion products are mainly composed of ions, electrons, ion clusters, and charged soot particles. The electron concentration can be almost negligible at the exit of the combustion chamber. The other charged particles in the combustion products are ejected into the atmosphere with the jet. The charge density distribution of the jet has a certain symmetry in a short time due to the influence of the flow field. It is found that the type of fuel and the conductivity of the surface materials in the combustion chamber affect the electrified properties of the combustion products to some extent. This study has a reference value for further analysis of the detectable electric field generated during scramjet operation.

CFD design of a novel device for temperature profile measurement in Waste-to-Energy plants

Monitoring the flue gas temperature is a crucial issue for Waste-to-Energy (WtE) plants companies, since it is essential to preserve the materials in the post-combustion chamber, the energy efficiency of the plants as well as to control the emissions of pollutants. As of today, the temperature of flue gases in such plants is commonly monitored by means of thermocouples, infrared pyrometers or aspirated thermocouples. However, all these instruments show limitations in terms of accuracy and reliability inside post-combustion chambers. In this paper, the authors present the thermo-fluid dynamics design of a novel device aimed at mitigating the issues of existing technologies, realised by using the modern CFD techniques. Numerical analyses, performed with the open-source OpenFOAM code, allowed to find a suitable shape for the device and to give a first estimate of the measuring errors, which are of the order of 2% (∼26 K at the typical working temperature of WtE plants’ post-combustion chambers).

Influence of minimally invasive cavities on color stability of dental crowns with different filling sealers.

The minimally invasive endodontic access is not directly associated with tooth discoloration in the presence of bioceramic or epoxy resin-based root canal sealers. This study aimed to evaluate the influence of minimally invasive access and endodontic sealer composition on the color stability of endodontically-treated teeth, the restorative material adaptation, and the presence of remaining filling material in the pulp chamber. Endodontic access surgery was performed in maxillary central incisors, either through conservative or minimally invasive approaches, and the root was filled with AH Plus or Bio-C Sealer. The crown color was measured with a spectrophotometer at baseline and after root obturation, restoration, and specimen storage for one year in an oven. The occurrence of voids in the restoration and the remaining filling material was analyzed using micro-CT scans. The Yellowness Index (YI) and color changes (∆E00) were calculated after each color measurement. Data of micro-CT were submitted to 2-way ANOVA, and YI and ∆E00 were analyzed with repeated-measures ANOVA. Pair-wise comparisons were performed with Tukey's test (α = 0.05). The experimental conditions had no effect on the presence of the remaining material. The minimally invasive access associated with Bio-C Sealer resulted in more voids between the restoration and the remaining filling material. Only the evaluation time affected YI and ∆E00 values. Specimens became more yellow after filling and storage in the oven (the highest ∆E00 values). The present study showed that sealer and minimally invasive cavities are not associated with crown color stability following endodontic treatment.

Revolutionizing Spray Drying: An In‐Depth Analysis of Surface Stickiness Trends and the Role of Physicochemical Innovations in Boosting Productivity

Spray drying is a widely utilized method in the pharmaceutical, food, and chemical industries for producing powdered products. However, a recurring challenge in this process is the persistent issue of surface stickiness, which diminishes product quality and operational efficiency. This paper examines the current trend of surface stickiness in spray drying and explores physicochemical approaches to mitigate fouling and enhance overall productivity. The stickiness is often attributed to the formation of lumps on drying chamber surfaces, adversely affecting the final product’s characteristics. The paper reviews existing literature on the causes and consequences of surface stickiness, emphasizing the need for innovative strategies to address this challenge. Promising solutions are emerging in the form of physicochemical approaches, involving the modification of drying chamber materials, applying different operational approaches, optimization of process parameters, and the introduction of drying aids. Researchers aim to alter the surface properties of drying chamber components, minimizing particle and wall deposition to prevent surface stickiness. The present review also delves into the impact of various physicochemical factors on spray drying performance, including temperature, airflow dynamics, and formulation composition. Understanding these factors is crucial for developing effective strategies to reduce fouling and enhance overall productivity in spray drying processes. This review sheds light on the prevalent issue of spray drying surface stickiness and underscores the significance of physicochemical approaches in overcoming this challenge. By addressing stickiness issues through innovative strategies, researchers and industry professionals can improve the efficiency and reliability of spray drying processes, ultimately elevating the quality of powdered products in pharmaceutical, food, and chemical manufacturing.

Thermal energy storage control using phase change materials in a rectangular energy storage chamber with metal foam gradient and magnetic field

Considering the low thermal conductivity of phase change materials (PCM) and the slowness of the melting process in the thermal energy storage chamber (TESC), a comprehensive study on the use of magnetic field and porous foam gradient in the phase change process of PCM in a rectangular chamber with a cylinder is presented. The numerical solution is done using the finite volume method. PCM, metal foam and nanoparticles are respectively lauric acids, aluminum and iron oxide. Porosity coefficient changes have been examined in the positive and negative directions of the coordinate axes during melting and compared to a uniform porosity coefficient in the common case. As a result of a constant magnetic field, melting does not take place as much, but when a non-uniform magnetic field is used, the process of melting in the TESC increases by about 35 times, and the intensity of the magnetic field can be used between 0.025 and 0.05 mT. The average thawing fraction of the PCM has augmented by 5.046, 6.86, 7.66 and 7.819 %, respectively, compared to the no-field. The metal foam gradient has an imperative efficacy in enhancing the process of melting and up to about 97 % reduces melting time. When the porosity coefficient is higher near the active wall, the heat transfer and liquifying are quicker. In the chamber, temperature changes of the cylinder can have a momentous efficacy on the thawing process. The greatest effect is observed when the changes of cylinder temperature with time are stepwise. The sensitivity analysis was done based on the Sobol method, which shows that the porosity coefficient has the greatest effect on the melting rate.