CH3OH Masers Research Articles

Masers and Star Formation Activities in W51A

Concurrently with the maser flare observed in W51-North during the 3 month monitoring of H2O, NH3, and CH3OH maser variability from 2020 January to April using the Tianma 65 m Radio Telescope, we conducted Very Large Array mappings for these three maser species across the entirety of W51A region. After finding the ring-shaped H2O maser which might trace the disk surrounding the protostar residing in W51-North, the NH3 (9,6) maser delineated a jet which might be illuminated in the luminosity outburst possibly caused by the infalling streamer’s interaction with the protostar’s disk. An analysis of the comprehensive distribution of maser spots allowed us to affirm that W51N4 or ALMAmm31 serves as the primary source of the Lacy jet. Furthermore, we observed that class I methanol maser spots may extend beyond the locations of the H2O and NH3 (9,6) masers within the outflow. Additionally, emissions from other NH3 maser transitions coincided with specific 1.3 mm continuum sources. The arrangement of H2O maser spots in the vicinity of W51e2-E potentially indicates episodic accretions in this source. Combining the data from the Atacama Large Millimeter/submillimeter Array data archive for W51-North, W51e2, and W51e8, we have discovered that the H2O, NH3, and CH3OH masers, as well as the HC3N and SiO emissions are found to be good tools for tracing outflow in this work for W51A.

Thermal Properties of the Hot Core Population in Sagittarius B2 Deep South

We report the discovery of nine new hot molecular cores in the Deep South (DS) region of Sagittarius B2 using Atacama Large Millimeter/submillimeter Array Band 6 observations. We measure the rotational temperature of CH3OH and derive the physical conditions present within these cores and the hot core Sgr B2(S). The cores show heterogeneous temperature structure, with peak temperatures between 252 and 662 K. We find that the cores span a range of masses (203–4842 M ⊙) and radii (3587–9436 au). CH3OH abundances consistently increase with temperature across the sample. Our measurements show the DS hot cores are structurally similar to Galactic disk hot cores, with radii and temperature gradients that are comparable to sources in the disk. They also show shallower density gradients than disk hot cores, which may arise from the Central Molecular Zone’s higher density threshold for star formation. The hot cores have properties which are consistent with those of Sgr B2(N), with three associated with Class II CH3OH masers and one associated with an ultra-compact H ii region. Our sample nearly doubles the high-mass star-forming gas mass near Sgr B2(S) and suggests the region may be a younger, comparably massive counterpart to Sgr B2(N) and (M). The relationship between peak CH3OH abundance and rotational temperature traced by our sample and a selection of comparable hot cores is qualitatively consistent with predictions from chemical modeling. However, we observe constant peak abundances at higher temperatures (T ≳ 250 K), which may indicate mechanisms for methanol survival that are not yet accounted for in models.

The Discovery of the Zeeman Effect in 38 GHz Class II Methanol Masers

Magnetic fields likely play an important role in star formation, but the number of directly measured magnetic field strengths remains scarce. We observed the 38.3 and 38.5 GHz Class II methanol (CH3OH) maser lines toward the high-mass star-forming region NGC 6334 F for the Zeeman effect. The observed spectral profiles have two prominent velocity features that can be further decomposed through Gaussian component fitting. In several of these fitted Gaussian components we find significant Zeeman detections, with zB los in the range from 8 to 46 Hz. If the Zeeman splitting factor z for the 38 GHz transitions is of the order of ∼1 Hz mG−1, similar to that for several other CH3OH maser lines, then magnetic fields in the regions traced by these masers would be in the range of 8–46 mG. Such magnetic field values in high-mass star-forming regions agree with those detected in the better-known 6.7 GHz Class II CH3OH maser line. Since Class II CH3OH masers are radiatively pumped close to the protostar and likely occur in the accretion disk or the interface between the disk and outflow regions, such fields likely have significant impact on the dynamics of these disks.

A kinematic study of the disc-outflow system around a high-mass protostar G59.783+0.065 probed by methanol and water masers

ABSTRACT Class II CH3OH masers are used as a convenient tracer of disc-like structures in high-mass star formation. However, more than half of them show a complex distribution in Very Long Baseline Interferometry (VLBI) maps. The origin of such a complex distribution is still unknown. We conducted VLBI monitoring observations to unveil the origin of a complex class II CH3OH maser in the high-mass star-forming region G59.783+0.065. We observed the CH3OH maser at 6.7 GHz and the H2O maser at 22 GHz to probe detailed circumstellar kinematics and structures by the Japanese VLBI network and the VLBI Exploration of Radio Astrometry. We found similar bipolar distributions in both masers, specifically two clusters located 2000 au apart along the east–west direction. We detected a linear distribution of CH3OH masers in the western cluster. A position–velocity diagram shows that the western CH3OH masers trace a rotating disc-wind or infalling component inside an edge-on disc-like structure. In contrast to the simple bipolar expanding motions of the H2O masers, the CH3OH masers exhibited complex motions despite their spatial coincidence. Some of the eastern CH3OH masers showed bipolar expansions similar to the H2O masers, while others displayed random or even inward motions. Such complex kinematics and their close association with the H2O maser could occur at the boundary between outflow and inflow. We suggest that the complex distribution of class II CH3OH masers, like G59.783+0.065 arises from several distinct circumstellar structures that simultaneously achieve maser excitation.

ALMA observations of the Extended Green Object G19.01–0.03 – ii. A massive protostar with typical chemical abundances surrounded by four low-mass pre-stellar core candidates

ABSTRACT We present a study of the physical and chemical properties of the Extended Green Object (EGO) G19.01−0.03 using sub-arcsecond angular resolution Atacama Large Millimetre/submillimetre Array (ALMA) 1.05 mm and Karl G. Jansky Very Large Array (VLA) 1.21 cm data. G19.01−0.03 MM1, the millimetre source associated with the central massive young stellar object (MYSO), appeared isolated and potentially chemically young in previous Submillimetre Array observations. In our ∼0.4 arcsec-resolution ALMA data, MM1 has four low-mass millimetre companions within 0.12 pc, all lacking maser or outflow emission, indicating they may be pre-stellar cores. With a rich ALMA spectrum full of complex organic molecules, MM1 does not appear chemically young, but has molecular abundances typical of high-mass hot cores in the literature. At the 1.05 mm continuum peak of MM1, N(CH3OH) = (2.22 ± 0.01) × 1018 cm−2 and $T_{\mathrm{ex}} = 162.7\substack{+0.3 \\ -0.5}$ K based on pixel-by-pixel Bayesian analysis of LTE synthetic methanol spectra across MM1. Intriguingly, the peak CH3OH Tex = 165.5 ± 0.6 K is offset from MM1’s millimetre continuum peak by 0.22 arcsec ∼ 880 au, and a region of elevated CH3OH Tex coincides with free–free VLA 5.01 cm continuum, adding to the tentative evidence for a possible unresolved high-mass binary in MM1. In our VLA 1.21 cm data, we report the first NH3(3,3) maser detections towards G19.01−0.03, along with candidate 25 GHz CH3OH 5(2, 3) − 5(1, 4) maser emission; both are spatially and kinematically coincident with 44 GHz Class I CH3OH masers in the MM1 outflow. We also report the ALMA detection of candidate 278.3 GHz Class I CH3OH maser emission towards this outflow, strengthening the connection of these three maser types to MYSO outflows.

Spectral Survey of a Hot Core with an Eruptive Accretion in S255IR NIRS3 (SHEA): The Discovery of Class I and II Millimeter Methanol Maser Transitions

We report the detection of the millimeter CH3OH masers including a new detection of class I (110,11–101,10A) and class II (61,5–52,4E) maser transitions toward the high-mass protostar S255IR NIRS3 in postburst phase. The CH3OH emissions were detected as a mixture of maser and thermal characteristics. We examine the detected transitions using an excitation diagram and local thermodynamic equilibrium model spectra and compare the observed properties with those of thermal lines. Class II CH3OH maser transitions showed distinctive intensity and velocity distributions from those of thermal transitions. Bright, distinct emission components in addition to the fragmented and arc-shaped emissions are only detected in class I CH3OH maser transitions toward southern and western directions from the protostellar position, implying the presence of the slow outflow shocks.

A Multitransition Methanol Survey toward a Large Sample of High-mass Star-forming Regions

We carried out a spectral line survey of CH3OH toward a large sample of 175 high-mass star-forming regions in the 3 mm, 2 mm, and 1.3 mm bands with the Institut de Radioastronomie Millimétrique (IRAM) 30 m telescope. Out of our 175 targets, 148 sources were detected with one or more CH3OH transition lines. Nineteen CH3OH transition lines, including 13 thermal lines and 6 maser lines, were detected. The 80 → 71 A+ (∼95.169 GHz) CH3OH maser line, one of the strongest class I CH3OH maser lines, was detected in 52 sources. Forty-two of them are previously reported masers and the other 10 are new detections. Through analyzing the rotational diagram of the detected CH3OH emission lines (nonmasing lines), we obtained the rotational temperature and the column density for 111 sources. Our results show that E-type CH3OH tends to have lower column density than A-type CH3OH. The column density ratio of E/A was derived in 55 sources with the majority having a ratio less than 1.0 (about 70%), with a peak ratio of ∼0.6. This is consistent with theoretical predictions, i.e., overabundance of A-type CH3OH at low temperature leading to a low E/A ratio. Furthermore, we found that CH3OH abundance decreases beyond T dust ∼ 30 K, which is supported by modeling results. All these support the fact that CH3OH is easily formed at low-temperature environments, via successive hydrogenation of CO on cold dust surfaces.

Multi-wavelength maser observations of the Extended Green Object G19.01—0.03

AbstractWe report the detections of NH3(3,3) and 25 GHz and 278.3 GHz class I CH3OH maser emission associated with the outflow of the Extended Green Object G19.01–0.03 in sub-arcsecond resolution Atacama Large Millimeter/submillimeter Array (ALMA) and Karl G. Jansky Very Large Array (VLA) observations. For masers associated with the outer outflow lobes (> 12.5 ″ from the central massive young stellar object; MYSO), the spatial distribution of the NH3(3,3) masers is statistically indistinguishable from that of previously known 44 GHz Class I CH3OH masers, strengthening the connection of NH3(3,3) masers to outflow shocks. In sub-arcsecond resolution VLA observations, we resolve the 6.7 GHz Class II CH3OH maser emission towards the MYSO into a partial, inclined ring, with a velocity gradient consistent with the rotationally supported circumstellar disc traced by thermal gas emission.

A Multiwavelengh study towards Galactic HII region G10.32-0.26

AbstractWe present the results of high-resolution continuum and molecular line observations towards the Galactic HII region, G10.32-0.26. The continuum map with ALMA reveals the five cores with masses ranging from 2.5–9.2 Me. The results show that the brightest peak, Peak 1, is an HCHII region with an excitation temperature of : 12000 K, an electron density of 3.4×107 cm3, and a radius of 14 au. The central object is estimated to be a B0.5 star. The class II 6.7 GHz CH3OH maser coincides with Peak 1, implying class II CH3OH maser is associated with a later evolutionary stage of star formation. Using KaVA and KVN observation, we detect the class I 44 and 95 GHz CH3OH masers near the weakest peak, Peak 5. We successfully imaged class I 95 GHz CH3OH masers with VLBI for the first time. In Peak 5, the high-velocity SiO emission also exists. The continuum emission can be modelled with grey-body dust emission with Td∼30 K, and the molecular species are poor near Peak 5, suggesting Peak 5 is in an early stage of star formation.

New Methanol Maser Transitions and Maser Variability Identified from an Accretion Burst Source G358.93-0.03

The high-mass young stellar object G358.93-0.03 underwent an accretion burst during the period from 2019 January to June. Given its extraordinary conditions, a number of new maser transitions may have been naturally excited during the burst stage. Searching for new maser lines and monitoring maser variability associated with the accretion burst event are important for understanding the complex conditions of the massive star formation toward G358.93-0.03. In this work, using the Shanghai 65 m Tianma Radio Telescope, we continuously monitored the multiple maser (including methanol and water) transitions toward G358.93-0.03 during the burst in the period from 2019 March 14 to May 20. There were 23 CH3OH maser transitions and one H2O maser transition detected from the monitoring. Nearly all the detected maser transitions toward this source have dramatic variations in their intensities within a short period of ∼2 months. Eight new methanol transitions from G358.93-0.03 were identified to be masering in our observations based on their spectral profile, line width, intensity, and the rotation diagram. During the monitoring, the gas temperature of the clouds in the case of saturated masers can show a significant decline, indicating that the maser clouds were going through a cooling process, possibly associated with the propagation of a heat wave induced by the accretion burst. Some of the maser transitions were even detected with the second flares in 2019 April, which may be associated with the process of the heat-wave propagation induced by the same accretion burst acting on different maser positions.

Complex Organic Molecules Detected in 12 High-mass Star-forming Regions with Atacama Large Millimeter/submillimeter Array

Recent astrochemical models and experiments have explained that complex organic molecules (COMs; molecules composed of six or more atoms) are produced on the dust grain mantles in cold and dense gas in prestellar cores. However, the detailed chemical processes and the roles of physical conditions on chemistry are still far from understood. To address these questions, we investigated 12 high-mass star-forming regions using Atacama Large Millimeter/submillimeter Array (ALMA) Band 6 observations. They are associated with 44/95 GHz class I and 6.7 GHz class II CH3OH masers, indicative of undergoing active accretion. We found 28 hot cores with COM emission among 68 continuum peaks at 1.3 mm and specified 10 hot cores associated with 6.7 GHz class II CH3OH masers. Up to 19 COMs are identified including oxygen- and nitrogen-bearing molecules and their isotopologues in cores. The derived abundances show a good agreement with those from other low- and high-mass star-forming regions, implying that the COM chemistry is predominantly set by the ice chemistry in the prestellar core stage. One clear trend is that the COM detection rate steeply grows with the gas column density, which can be attributed to the efficient formation of COMs in dense cores. In addition, cores associated with a 6.7 GHz class II CH3OH maser tend to be enriched with COMs. Finally, our results suggest that the enhanced abundances of several molecules in our hot cores could be originated by the active accretion as well as different physical conditions of cores.

A global view on star formation: The GLOSTAR Galactic plane survey

Class II methanol (CH3OH) masers are amongst the clearest signposts of recent high-mass star formation (HMSF). A complete catalogue outlines the distribution of star formation in the Galaxy, the number of young star-forming cores, and the physical conditions of their environment, made possible by the Global View on Star Formation (GLOSTAR) survey. This blind survey of the radio regime of 4–8 GHz maps the Galactic mid-plane in the radio continuum, 6.7 GHz methanol line, the 4.8 GHz formaldehyde line, and several radio recombination lines. We present an analysis of the observations of the 6.7 GHz CH3OH maser transition using data from the D-configuration of the Very Large Array (VLA). We analysed data covering Galactic longitudes from –2° < l < 60° and Galactic latitudes of |b| < 1°. We detected a total of 554 methanol masers, out of which 84 are new, and we catalogued their positions, velocity components, and integrated fluxes. With a typical noise level of ~18 mJy beam−1, this is the most sensitive unbiased methanol survey for methanol masers to date. We also searched for dust continuum and radio continuum associations, finding that 97% of the sources are associated with dust and 12% are associated with radio continuum emission.

Evidence for an Interaction between the Galactic Center Clouds M0.10–0.08 and M0.11–0.11

We present high-resolution (∼2–3″; ∼0.1 pc) radio observations of the Galactic center cloud M0.10−0.08 using the Very Large Array at K and Ka band (∼25 and 36 GHz). The M0.10−0.08 cloud is located in a complex environment near the Galactic center Radio Arc and the adjacent M0.11−0.11 molecular cloud. From our data, M0.10−0.08 appears to be a compact molecular cloud (∼3 pc) that contains multiple compact molecular cores (5+; <0.4 pc). In this study, we detect a total of 15 molecular transitions in M0.10−0.08 from the following molecules: NH3, HC3N, CH3OH, HC5N, CH3CN, and OCS. We have identified more than sixty 36 GHz CH3OH masers in M0.10−0.08 with brightness temperatures above 400 K and 31 maser candidates with temperatures between 100 and 400 K. We conduct a kinematic analysis of the gas using NH3 and detect multiple velocity components toward this region of the Galactic center. The bulk of the gas in this region has a velocity of 51.5 km s−1 (M0.10−0.08) with a lower-velocity wing at 37.6 km s−1. We also detect a relatively faint velocity component at 10.6 km s−1 that we attribute to being an extension of the M0.11−0.11 cloud. Analysis of the gas kinematics, combined with past X-ray fluorescence observations, suggests M0.10−0.08 and M0.11−0.11 are located in the same vicinity of the Galactic center and could be physically interacting.

Cyanopolyyne line survey towards high-mass star-forming regions with TMRT

Context. Cyanopolyynes (HC2n+1 N, n = 1,2,3), which are the linear carbon chain molecules, are precursors for the prebiotic synthesis of simple amino acids. They are important for understanding prebiotic chemistry and may be good tracers of the star formation sequence. Aims. We aim to search for cyanopolyynes in high-mass star-forming regions (HMSFRs) at possibly different evolutionary stages, investigate the evolution of HC3N and its relation with shock tracers, and detect the existence of HC5N and HC7N in HMSFRs with a formed protostar. Methods. We carried out a cyanopolyyne line survey towards a large sample of HMSFRs using the Shanghai Tian Ma 65 m Radio Telescope (TMRT). Our sample consisted of 123 targets taken from the TMRT C band line survey. It included three kinds of sources, namely those with detection of the 6.7 GHz CH3OH maser alone, with detection of the radio recombination line (RRL) alone, and with detection of both (hereafter referred to as Maser-only, RRL-only, and Maser-RRL sources, respectively). For our sample with detection of cyanopolyynes, their column densities were derived using the rotational temperature measured from the NH3 lines. We constructed and fitted the far-infrared (FIR) spectral energy distributions (SED; obtained from the Herschel FIR data and the Atacama Pathfinder Experiment data at 870 µm) of our HC3N sources. Moreover, by analysing the relation between HC3N and other shock tracers, we also investigate whether HC3N is a good tracer of shocks. Results. We detected HC3N in 38 sources, HC5N in 11 sources, and HC7N in G24.790+0.084, with the highest detection rate being found for Maser-RRL sources and a very low detection rate found for RRL-only sources. The mean column density of HC3N was found to be (1.75 ± 0.42) × 1013, (2.84 ± 0.47) × 1013, and (0.82 ± 0.15) × 1013 cm−2 for Maser-only, Maser-RRL, and RRL-only sources, respectively. Based on a fit of the FIR SED, we derive their dust temperatures, H2 column densities, and abundances of cyanopolyynes relative to H2. The mean relative abundance of HC3N was found to be (1.22 ± 0.52) × 10−10 for Maser-only, (5.40 ± 1.45) × 10−10 for Maser-RRL, and (1.65 ± 1.50) × 10−10 for RRL-only sources, respectively. Conclusions. The detection rate, the column density, and the relative abundance of HC3N increase from Maser-only to Maser-RRL sources and decrease from Maser-RRL to RRL-only sources. This trend is consistent with the proposed evolutionary trend of HC3N under the assumption that our Maser-only, Maser-RRL, and RRL-only sources correspond to massive young stellar objects, ultracompact H ii regions, and normal classical H ii regions, respectively. Our detections enlarge the sample of HC3N in HMSFRs and support the idea that unsaturated complex organic molecules can exist in HMSFRs with a formed protostar. Furthermore, a statistical analysis of the integrated line intensity and column density of HC3N and shock-tracing molecules (SiO, H2CO) enabled us to find positive correlations between them. This suggests that HC3N may be another tracer of shocks, and should therefore be the subject of further observations and corresponding chemical simulations. Our results indirectly support the idea that the neutral-neutral reaction between C2H2 and CN is the dominant formation pathway of HC3N.

Discovery of recurrent flares of 6.7 GHz methanol maser emission in Cepheus A HW2

Context.Class II methanol masers at 6.7 GHz originate close to high-mass young stellar objects (HMYSOs). Their high sensitivity to local condition variations makes them a useful marker of the activity of the emerging massive stars.Aims.We aim to closely examine the variability of the 6.7 GHz CH3OH masers in Cep A HW2 using the new and archival single-dish and high-resolution Very-Long-Baseline Interferometry (VLBI) datasets.Methods.We monitored 6.7 GHz methanol masers towards the target between 2009 and 2021 using the Torun 32m radio telescope, and analysed nine datasets of VLBI observations taken over 16 yr.Results.Faint, extremely redshifted maser emission located close to the presumed central star position and coincident with the radio jet shows flaring activity with a period of ~5 yr. Flares have an asymmetric profile with a rise-to-decay time ratio of 0.18 and relative amplitude higher than 10. The velocity of the flaring cloudlets drifts at a rate of 3–4 × 10−5km s−1d−1for about 11.5 yr of the monitoring. The time-lag between the peaks of the two flaring features implies a propagation speed of the exciting factor of ~1000 km s−1. Synchronised and anticorrelated variations of the flux density of blue- and redshifted features begin ~2.5 yr after flares of the extremely redshifted emission.Conclusions.Our observations suggest that the recurrent flares are the response of low-gain unsaturated maser regions to a relatively low increase in luminosity, which has little effect on the behaviour of most maser regions of higher gain.

An Excited-state OH Maser Survey toward WISE Point Sources

We report a survey of excited-state hydroxyl (ex-OH) masers at the 4.7 and 6.0 GHz transitions toward a sample consisting of 3348 massive star-forming region candidates selected from the all-sky Wide-field Infrared Survey Explorer point-source catalog. The survey was conducted with the Shanghai Tianma Radio Telescope. In total, 6, 9, and 30 sources were detected with the ex-OH masers at the 4766, 6031, and 6035 MHz transitions, respectively. Among them, one 4766 MHz, one 6031 MHz, and five 6035 MHz ex-OH maser sources are newly identified. A series of statistical analyses derived that the ex-OH masers were detected efficiently toward the subsamples associated with both the 6.7 GHz CH3OH maser and radio recombination lines (RRLs), whereas compared to the CH3OH masers, the ex-OH masers are more likely to be produced toward the sources with stronger 22 μm band emission. A significant luminosity correlation is found between the ex-OH masers and RRLs. In addition, we found that the magnetic field strength of most sources with the 6.7 GHz CH3OH maser was stronger relative to that of sources without the CH3OH maser. Combined with these, it demonstrates that the ex-OH maser is associated with more evolved star-forming regions, likely associated with thicker dust envelopes. Meanwhile, the ex-OH masers might be a potential tracer for measuring the Galactic magnetic field information on the large-scale views using their Zeeman pairs.

ALMA Observations of Molecular Complexity in the Large Magellanic Cloud: The N 105 Star-forming Region

The Large Magellanic Cloud (LMC) is the nearest laboratory for detailed studies on the formation and survival of complex organic molecules (COMs), including biologically important ones, in low-metallicity environments—typical of earlier cosmological epochs. We report the results of 1.2 mm continuum and molecular line observations of three fields in the star-forming region N 105 with the Atacama Large Millimeter/submillimeter Array. N 105 lies at the western edge of the LMC bar with ongoing star formation traced by H2O, OH, and CH3OH masers, ultracompact H ii regions, and young stellar objects. Based on the spectral line modeling, we estimated rotational temperatures, column densities, and fractional molecular abundances for 12 1.2 mm continuum sources. We identified sources with a range of chemical makeups, including two bona fide hot cores and four hot core candidates. The CH3OH emission is widespread and associated with all the continuum sources. COMs CH3CN and CH3OCH3 are detected toward two hot cores in N 105 together with smaller molecules typically found in Galactic hot cores (e.g., SO2, SO, and HNCO) with the molecular abundances roughly scaling with metallicity. We report a tentative detection of the astrobiologically relevant formamide molecule (NH2CHO) toward one of the hot cores; if confirmed, this would be the first detection of NH2CHO in an extragalactic subsolar metallicity environment. We suggest that metallicity inhomogeneities resulting from the tidal interactions between the LMC and the Small Magellanic Cloud might have led to the observed large variations in COM abundances in LMC hot cores.

EVN observations of 6.7 GHz methanol maser polarization in massive star-forming regions

Context. Although the role of magnetic fields in launching molecular outflows in massive young stellar objects has been convincingly demonstrated by theoretical arguments, observationally, the alignment of the magnetic field lines with the molecular outflows is still under debate. Aims. We aim to complete the measurements of the direction of the magnetic fields at milliarcsecond resolution around a sample of massive star-forming regions to determine whether the magnetic field and outflows are aligned. Methods. In 2012, we started a large very long baseline interferometry campaign with the European VLBI Network to measure the magnetic field orientation and strength toward a sample of 31 massive star-forming regions (called the flux-limited sample) by analyzing the polarized emission of 6.7 GHz CH3OH masers. In the previous papers of the series, we have presented 80% of the sample. Here, we report the linearly and circularly polarized emission of 6.7 GHz CH3OH masers toward the last five massive star-forming regions of the flux-limited sample. The sources are G30.70-0.07, G30.76-0.05, G31.28+0.06, G32.03+0.06, and G69.52-0.97. Results. We detected a total of 209 CH3OH maser cloudlets, 15% of which show linearly polarized emission (0.07–16.7%), and 2% of which show circularly polarized emission (0.2–4.2%). As reported in previous papers, in the last five sources of the flux-limited sample, we also measured well-ordered linear polarization vectors. Zeeman splitting was measured toward G30.70-0.07, G32.03+0.06, and G69.52-0.97. Conclusions. The statistical analysis of the entire flux-limited sample shows that the observations are consistent with a bimodal distribution in the difference between the 3D magnetic field direction and the outflow axis, with half the magnetic field directions being perpendicular and the other half being parallel to the outflow. In addition, we determined that typical values of the linear and circular polarization fractions for 6.7 GHz CH3OH masers are Pl = 1.0–2.5% and PV = 0.5–0.75%, respectively. From the circularly polarized spectra of the CH3OH maser features, we found that a typical Zeeman splitting is in the range between 0.5 m s−1 and 2.0 m s−1. This would correspond to 9 mG &lt; |B||| &lt; 40 mG if F = 3 → 4 is the most favored of the eight hyperfine transitions that might contribute to the maser emission.

Modelling cosmic masers in C-type shock waves – the coexistence of Class I CH3OH and 1720 MHz OH masers

ABSTRACT The collisional pumping of CH3OH and OH masers in non-dissociative C-type shock waves is studied. The chemical processes responsible for the evolution of molecule abundances in the shock wave are considered in detail. The large velocity gradient approximation is used to model radiative transfer in molecular lines. We present calculations of the optical depth in maser transitions of CH3OH and OH for a grid of C-type shock models that vary in cosmic ray ionization rate, gas density, and shock speed. We show that pre-shock gas densities nH, tot = 2 × 104–2 × 105 cm−3 are optimal for the pumping of methanol maser transitions. A complete collisional dissociation of methanol at the shock front takes place for shock speeds us ≳ 25 km s−1. At high pre-shock gas density nH, tot = 2 × 106 cm−3, the collisional dissociation of methanol takes place at shock speeds just above the threshold speed us ≈ 15–17.5 km s−1, corresponding to sputtering of icy mantles of dust grains. We show that the methanol maser transition E 4−1 → 30 at 36.2 GHz has an optical depth |τ| higher than that of the transition A+ 70 → 61 at 44.1 GHz at high cosmic ray ionization rate $\zeta _\mathrm{H_2} \gtrsim 10^{-15}$ s−1 and pre-shock gas density nH, tot = 2 × 104 cm−3. These results can be applied to the interpretation of observational data on methanol masers near supernova remnants and in molecular clouds of the Central Molecular Zone. At the same time, a necessary condition for the operation of 1720 MHz OH masers is a high ionization rate of molecular gas, $\zeta _\mathrm{H_2} \gtrsim 10^{-15}$ s−1. We find that physical conditions conducive to the operation of both hydroxyl and methanol masers are cosmic ray ionization rate $\zeta _\mathrm{H_2} \approx 10^{-15}$–3 × 10−15 s−1 and a narrow range of shock speeds 15 ≲ us ≲ 20 km s−1. The simultaneous observations of OH and CH3OH masers may provide restrictions on the physical parameters of the interstellar medium in the vicinity of supernova remnants.

VLA Observations of Nine Extended Green Objects in the Milky Way: Ubiquitous Weak, Compact Continuum Emission, and Multi-epoch Emission from Methanol, Water, and Ammonia Masers

Abstract We have observed a sample of nine Extended Green Objects (EGOs) at 1.3 and 5 cm with the Very Large Array (VLA) with subarcsecond resolution and ∼7–14 μJy beam−1-sensitivities in order to characterize centimeter continuum emission as it first appears in these massive protoclusters. We find an EGO-associated continu um emission—within 1″ of the extended 4.5 μm emission—in every field, which is typically faint (order 101–102 μJy) and compact (unresolved at 0″.3–0″.5). The derived spectral indices of our 36 total detections are consistent with a wide array of physical processes, including both non-thermal (19% of detections) and thermal free–free processes (e.g., ionized jets and compact H ii regions, 78% of sample) and warm dust (1 source). We also find an EGO-associated 6.7 GHz CH3OH and 22 GHz H2O maser emission in 100% of the sample and a NH3 (3,3) masers in ∼45%; we do not detect any NH3 (6,6) masers at ∼5.6 mJy beam−1 sensitivity. We find statistically-significant correlations between L radio and L bol at two physical scales and three frequencies, consistent with thermal emission from ionized jets, but no correlation between L H 2 O and L radio for our sample. From these data, we conclude that EGOs likely host multiple different centimeter continuum-producing processes simultaneously. Additionally, at our ∼1000 au resolution, we find that all EGOs except G18.89−0.47 contain 1 ∼ 2 massive sources based on the presence of CH3OH maser groups, which is consistent with our previous work suggesting that these are typical massive protoclusters, in which only one to a few of the young stellar objects are massive.