Cenozoic Volcanic Province Research Articles

Cenozoic Volcanic Provinces and Shallow Asthenospheric Volumes in the Circum‐Mediterranean: Evidence From Magmatic Geochemistry, Seismic Tomography, and Integrated Geophysical‐Petrological Thermochemical Inversion

AbstractWe compile an extensive catalog comprising geochemistry and ages of Cenozoic volcanic provinces in the Mediterranean region, distinguishing between three groups according to the geochemistry of magmatic rocks: intraplate (IVP), subduction‐related (SRVP), and mixed‐origin volcanic provinces (MVP; intraplate with subduction imprint). In order to relate their spatial distribution to properties of the lithosphere‐asthenosphere system, we determine temperature‐depth profiles by integrated geophysical‐petrological inversion at representative locations, using Rayleigh and Love wave phase velocities, heat flow, rock densities, and accounting for thermochemical conditions. The results confirm the occurrence of thin lithosphere (<100 km) above warm asthenosphere (>1,300°C) in areas of low shear‐wave velocities in the shallow upper mantle. Nine shallow asthenospheric volumes (SAVs) between 70 and 300 km depths are identified, forming a partly interconnected belt across the Circum‐Mediterranean. A remarkable colocation exists between the SAVs and the intraplate and mixed‐origin volcanic provinces (IMVPs). Whereas dense networks of IMVPs have formed above the SAVs, IMVPs are absent in areas of thick mantle lithosphere. Magmatic activity in IMVPs at 60–70 Ma indicates that several SAVs existed already in the Paleogene (Central European, Adriatic, Western Mediterranean, and Moesian SAVs). The formation of SAVs is related either to asthenospheric upwelling caused by slab rollback and back‐arc extension (Aegean‐Anatolian, Moesian, Pannonian, Western Mediterranean SAVs), or to thermal upwelling (Adriatic, Central European, Middle East [MEA], North African, Rhine‐Rhone SAVs), with some of the latter coupled partly with continental rifting (Central European, MEA, North African, Rhine Rhone SAVs).

The structure of a continental intraplate volcanic system and controls from shear zones: Insights into the central Hoggar Cenozoic volcanic province, Northwest Africa, from electrical resistivity images

Continental intraplate volcanic systems, with their locations far from plate tectonic boundaries, are not well understood: the crustal and lithospheric mantle structure of these systems remain enigmatic and there is no consensus on the mechanisms that cause melt generation and ascent. The Cenozoic saw the development of numerous volcanic provinces on the African plate, including within the Central Hoggar, located in Northwest Africa, part of the Tuareg shield. The magmatic activity began at approximately 34 Ma and continued throughout the Quaternary. In order to understand the origins and potential mechanisms that generated the intraplate volcanic activity in the Central Hoggar we aim to image the subsurface architecture, in terms of electrical resistivity, from the surface to the lithospheric mantle. To do so we use magnetotelluric measurements from 40 locations to generate a 3-D electrical resistivity model, over an area of about 100 km by 160 km. Low-resistivity features (i.e., conductors) are observed in the crust that are narrow, linear structures congruent with the boundaries of terranes and prominent fault zones (e.g., Azrou N’Fad). They likely reflect the Pan-African mega-shear zones, which were reactivated throughout the tectonic evolution of the region. The model reveals that these faults are lithospheric-scale. The low-resistivity features likely represent the signatures of past fluid pathways and mineralization. A deeper low-resistivity feature is observed in the upper lithospheric mantle directly beneath the Manzaz and Atakor volcanic districts. It may represent local, small-scale metasomatism of the sub-continental lithospheric mantle, and low-percent partial melting, that sits above a regional, large-scale asthenospheric upwelling associated with the Hoggar swell. It is likely the origin point of the fluids responsible for the overlying anomalies. The results highlight the control of the lithospheric-scale, mega-shear zones on the spatial distribution of the recent Cenozoic volcanic activity, which was influenced by the location of pre-existing structural weaknesses.

The petrogenesis of Cenozoic basalts from Daihai, western North China Craton: Constraints from 40Ar-39Ar chronology, major and trace elements, and Sr-Nd-Pb-Hf isotopes

The Daihai Cenozoic intraplate basalts are distributed in the western North China Craton (NCC), which is a part of the Cenozoic volcanic province in eastern China, and they are all alkaline basalts. The fine-scale determination of their mantle source region properties, partial melting mechanisms, and petrogenesis can provide crucial information for exploring lithospheric destruction and thinning in the western NCC. 40Ar-39Ar dating of potassium feldspar grains from the Daihai alkaline basalts yielded plateau ages of 18.22 ± 1.84 Ma and 26.86 ± 0.72 Ma, indicating that the Daihai basalts underwent multiple eruptive cycles during the Late Oligocene-Middle Miocene. These basalts exhibit ocean island basalt (OIB)-like geochemical features and were subjected to negligible crustal contamination. Moreover, basaltic magmas underwent intense fractional crystallization of olivine and clinopyroxene. The geochemical differences in the Daihai basalts were controlled by partial melting. The Daihai basaltic magmas were composed of at least two types (type I-enriched mantle and prevalent mantle) of mantle end-members that partially melted and then mixed, and the lithology of the mantle source region was predominantly peridotite. Under enriched mantle conditions, the mixing of garnet lherzolite partial melts (<1%) and spinel lherzolite partial melts (2-5%) can reasonably explain the elemental variations characteristic of the Daihai basalts. Most importantly, the melting depth and lithospheric thickness of the Daihai basalts were < 70 km or even close to 50 km, implying that the western NCC underwent lithospheric destruction and thinning during the Cenozoic. However, these effects were spatially heterogeneous. The most plausible genetic mechanism for the generation of the Daihai basalts was the coupled effects of subduction of the Pacific slab and subduction–collision of the Indo–Eurasian Plate since the Oligocene. The mantle flows generated by these two events convected, blocked and triggered upwelling mantle flows at the eastern margin of the Ordos Block. The upwelling mantle flows resulted in frequent magmatism in the region.

Pliocene-to-Holocene volcano-tectonic activity on Mohéli Island (Comoros archipelago) constrained by new K[sbnd]Ar ages

The volcanism of the Comoros archipelago (from west to east: Grande Comore, Mohéli, Anjouan, and Mayotte islands) has been under renewed scientific scrutiny since the eruption of a new submarine volcanic edifice (Fani Maoré) which begun in May 2018 east of Mayotte. West of Mayotte, Mohéli island has received little attention from the geoscience community, despite its largely uneroded volcanic landscapes suggesting a recent activity that has not been dated. Here we address this gap in knowledge by applying KAr geochronology on groundmass and major-trace element analyses to subaerial and submarine rocks, in an attempt to reconstruct the volcano-tectonic and geochemical evolution of Mohéli. Our results show that Mohéli's volcano-tectonic evolution proceeded in two constructional stages, including a primary edification along a N070°E axis from before ca. 3.8 Ma to ca. 3 Ma (Stage 1), and a second construction along a N110°E ridge shaping the present-day island since ca. 2 Ma (Stage 2). The two stages were separated by an increased subsidence (≥0.2 mm/yr) that drowned a large part of the N070°E primary edifice. The two identified volcano-tectonic stages are reflected also in the geochemical evolution of emitted magmas, which were moderately silica-undersaturated in Stage 1 and moderately to highly silica-undersaturated in Stage 2. Silica undersaturation increases with time up to the olivine melilitite field, together with enrichments in Ca, P, and incompatible trace elements, suggesting the increasing contribution of a metasomatized mantle in melts. The coeval changes of construction orientations and magmas compositions of Mohéli suggest a modification in the tectonics of the Comoros related to magmatism at about 2 Ma. The most recent volcanic morphology investigated is an olivine nephelinite lava flow on the north coast of the island dated at 8 ± 2 ka. This finding of Holocene volcanism on Mohéli implies that the entire Comoros archipelago should be considered as an active zone in any volcanic hazard assessment. The melilite-bearing rocks of Mohéli share geochemical similarities with those of Mayotte and of the Cenozoic volcanic provinces of Madagascar, further pointing to similar melting sources and magmatic processes over the Mozambique channel.

Advances in the modeling of the Iberian thermal lithosphere and perspectives on deep geothermal studies

Renewable energy sources are key to achieve the transition toward clean energy system. Among them, the geothermal energy has a production whose effectiveness requires sufficient understanding of the temperature distribution and fluid circulation at depth, as well as of the lithological and petrophysical properties of the crust. The focus of this paper is twofold: first, we summarize the main advances in the development of new methodologies and numerical codes to characterize the properties of the thermal lithosphere in terms of its, temperature, density and composition; second, based on the compilation of available thermal modelling results, we present the depth of the thermal Lithosphere–Asthenosphere Boundary (LAB) of the Iberian Peninsula and the temperature distribution at crustal depths of 5, 10, and 20 km, in addition to at Moho level. At 5 km depth, the temperature is above 110 °C with local anomalies (> 130 °C) located in the Iberian Massif and Cenozoic volcanic provinces. A similar pattern is observed at 10 and 20 km depth, where temperatures are above 190 °C and 350 °C, respectively. At 20 km depth, anomalies above > 500 °C, delineate the SE and NE Cenozoic volcanic provinces. At Moho depths, temperature ranges from 450 to 800 °C with hot regions mainly located along the Iberian Massif and the SE and NE volcanic provinces. The compiled results do not show any lithospheric anomaly that could give rise to high temperatures at shallow depths, but they do show an acceptable exploitation potential at intermediate depths. With regard to the direct use of district and greenhouse heating and for industrial processes, the potential is great throughout the Peninsula, the main challenges being the availability of groundwater and drilling costs.

Conditions of Rock Formation and Magma Sources of the Late Cenozoic Udokan Volcanic Plateau

The Udokan volcanic plateau (UVP), like other areas of the Late Cenozoic volcanic province of Central Asia, formed in the interval from the Middle Miocene to the Pleistocene. Its products have high alkalinity and vary in composition from alkaline picrobasalts and basanites to alkaline trachytes. Compositional changes were controlled by two differentiation trends, which corresponded to different conditions of the original magmas generation. Rocks with low SiO2 contents (45 wt. %) were formed from melts of low melting degrees that arose under conditions of elevated pressures and temperatures. Formation of rocks corresponding to the composition range 45–61 wt. %. % SiO2 was associated with the differentiation of basalt melts, which arose at shallower depths and at lower temperatures. The geochemical characteristics of the UVP basaltoids make them similar to OIB-type basalts. They are also close in Sr, Nd, and Pb isotopic composition, corresponding to the parameters of a moderately depleted mantle, which is close to the composition of oceanic basalt sources corresponding to the mantle of deep mantle plumes. The corresponding mantle component is present in the sources of other volcanic regions of the Late Cenozoic intraplate volcanic province of Central Asia, which indicates the involvement of the lower mantle plume in the formation of these regions.

Geology, Petrology and Amazing Geoforms of the Late Cenozoic Volcanic Province Erusheti Plateau (Lesser Caucasus) Georgia

These Erusheti Plateau is an integral part of the volcanic highland of Southern Georgia. It is located northern part of the Lesser Caucasus in the convergence zone of the Afro-Arabian and Eurasian lithosphere tectonic plates. The territory is almost totally covered with strong volcanic and volcano-sedimentary formations of Goderdzi suite with different lithologies and facies. The suite is formed in the Late Miocene - Early Pliocene Age, about from 11.8±4 to 13.6±3.1 Ma. Erusheti Plateau overall, are not characterized by many centers of eruption; Here we discuss eruption histories of the large polygenic volcanic massive Dokhuz-Puar and a monogenic volcano Datvistskaro are clearly seen among the volcanogenic structures of Erusheti Plateau. The eruption products of Dokhkuz-Puar volcano are dacitic-containing tuff-breccias and lava flows. The activity of Datvistskaro volcano was expressed only by the eruption of pyroclastic deposits containing andesite basalts. The main constituent minerals are: plagi­oclase and hornblende mega-crystals in dacites; augite-olivine and base plagioclase – in andesite basalts. With their geochemical properties, all the rocks of the rocks of a calc-alkali series. Dacites and andesite-basalts do not feed from a common magmatic source and consequently, are not the product of differentiation of the same magma. The work is the first to describe the natural amazing natural geoforms developed in pyroclastolites of Datvistskaro volcano: gigantic stone columns, mushroom-shaped stone caps and stone lances.Should be noted that no detailed mine­ralogical-petrological study of the rocks common in the study area has done to date. The main purpose of the given work is filling this gap.

Sources of Magmas and Conditions of Rock Formation in the Late Cenozoic Udokan Volcanic Plateau

The Udokan volcanic plateau differs from other volcanic regions of the Late Cenozoic volcanic province of East Asia in the high alkalinity of volcanic rocks, their potassium specialization, and rock composition, varying from melaleucytitis and melanephelinites to alkaline trachytes. The presence of alkaline-salic rocks in volcanic associations makes it unique to the province. The reasons that determined the unique magmatism of the Udokan plateau are considered. The data of geochemical and isotopic studies have shown that the moderately enriched magma of the mantle plume served as a melt source in the region. The initial melts were formed under conditions of garnet stability at low degrees of melting. This contributed to their enrichment in alkalis and other incompatible elements that is especially characteristic of ultramafic rocks. It is established that fractionation processes controlled the distribution of the trace elements in the rocks of volcanic associations. Deep differentiation of the magmas to alkaline trachytes occurred in the peripheral magma chambers. Here, magmas interacted with intracrustal waters, which led to a change in their oxygen isotopic composition. It is shown that contamination did not play a decisive role in the formation of lava plateau rocks.

Animated reconstructions of the Late Cretaceous to Cenozoic northward migration of Australia, and implications for the generation of east Australian mafic magmatism

Details of the Late Cretaceous–Cenozoic migration of the Australian continent have been sources of contention since the 1960s. Two types of apparent polar wander paths (APWPs) have emerged from previous paleomagnetic studies: one group based on sedimentary and lateritic data that includes relatively linear northward motion of Australia away from Antarctica, and a second group, based on basaltic and lateritic data, that includes significant longitudinal movement of the Australian continent. This study compares the migration and evolution of the Australian plate over the past 100 m.y. using these two competing paths. Our animated reconstructions illustrate the relative motion of the Australian plate, the formation of Cenozoic volcanic provinces in eastern Australia, the opening of the Coral and Tasman Seas, and the docking of the Ontong Java Plateau with the Solomon Islands. The reconstructions incorporate new 40 Ar/ 39 Ar and previously published geochronology data from Late Cretaceous to Cenozoic east Australian mafic to felsic vol­canism in order to evaluate potential relationships between volcanism, changes in the motion of the Australian plate, and the opening of the Tasman and Coral Seas. We conclude that the APWP that includes significant longitudinal movement is more compatible than the linear path with both observable geological features (such as volcanic tracks) and the global moving hotspot reference frame. Our reconstructions reveal little correspondence between opening of the Tasman and Coral Seas and eruption of east Australian lava fields. However, the reconstructions and new 40 Ar/ 39 Ar geochronology illustrate that the formation of east Australian Late Cretaceous to Cenozoic central volcanoes and lava fields were closely linked, both temporally and spatially, and we suggest that edge-driven convection was an important process in the generation of both types of east Australian volcanic provinces.

Origin of Late Cenozoic Abaga–Dalinuoer basalts, eastern China: Implications for a mixed pyroxenite–peridotite source related with deep subduction of the Pacific slab

Continental intraplate basalts (15.42–0.16Ma) from Abaga–Dalinuoer volcanic field (ADVF) in central Inner Mongolia of eastern China, as a part of Cenozoic volcanic province along eastern margin of the Eurasian continent, provide a good opportunity to explore potential links between deep subduction of the Pacific slab and continental intraplate volcanism. In this study, we report an integrated dataset of whole-rock K–Ar ages, major and trace elements and Sr–Nd–Pb isotopes, and olivine major and minor elements for the Abaga–Dalinuoer basalts (ADBs), and propose that mantle source lithology of the ADB magmas may consist of both pyroxenite and peridotite. The ADBs display low SiO2 (42.3–50.2wt.%), high MgO (7.3–11.4wt.%) and moderate K2O+Na2O (3.8–6.4wt.%), and can be subdivided into basanites, alkali basalts and tholeiitic basalts that are all characterized by ocean island basalt (OIB)-like rare earth elements (REE) and enrichment in both large ion lithosphile elements (LILE) and high field strength elements (HFSE). Olivine phenocrysts have higher Ni and Fe/Mn and lower Mn, Ca and Ca/Fe relative to those from peridotite melts, but exhibit clearly lower Ni contents (<2500ppm) compared with expected Ni range (>3000ppm) for olivines crystallized from olivine-free pyroxenite melts. Estimated compositions of the ADB primary magmas, together with olivine compositions, suggest an iron-rich mantle source related with silica-deficient pyroxenite that is most likely derived from deeply subducted Pacific oceanic crust. Additionally, peridotite and recent subducted sediments are also required to account for high Ni and MgO in primary magmas together with their trace elements and Sr–Nd–Pb isotope systematics. We suggest that a mixed pyroxenite–peridotite source lithology can better match observed whole-rock and olivine signatures in the ADB, compared with either peridotite only or olivine-free pyroxenite only source lithology. In our model, pyroxenite melts would either react with or mechanically mix with peridotite, and the proportion of pyroxenite melts may range from 30% to 45% for mechanical mixing scenario. A continuous spectrum from tholeiitic to alkali melts revealed by melt-peridotite reaction experiment can explain formation of primary magmas of basanites, alkali basalts and tholeiitic basalts by increasing melting degree of a similar mantle source. Relatively higher 206Pb/204Pb of the ADB may suggest more significant role of recent (<0.5Ga) subducted Pacific oceanic materials, in contrast to other Cenozoic basalts in eastern China (e.g., Changbai basalts) that exhibit varying contributions from ancient (>1.5Ga) subducted continental sediments. We emphasize that coupled geochemical and geodynamic links (i.e., subduction polarity) between deeply subducted Pacific slab and continental intraplate volcanism in eastern China may exist, which directly support the involvement of deeply subducted Pacific materials in petrogenesis of the ADB. From the perspective of plate motion kinetics, decompression partial melting of upwelling fragmented Pacific slab (silica-deficient pyroxenite+recent subducted sediments) may be triggered by rollback of deeply subducted Pacific slab during Late Cenozoic times. Continental intraplate volcanism in the ADVF generally started with termination of opening of the Japan Sea, suggesting that deep subduction of the Pacific slab may have been an important geodynamic mechanism responsible for tectono-magmatic evolution of northeastern Asia. We suggest that the ADBs have the potential to shed light on genetic links between continental intraplate volcanism and deep subduction of the Pacific slab in geochemical and geodynamic processes.

The Cenozoic volcanic province of Tibesti (Sahara of Chad): major units, chronology, and structural features

Using both field relationships and some absolute ages, the sequence of volcanic units in the Cenozoic Tibesti Volcanic Province (TVP) (Chad) is established as follows: (1) plateau volcanism, between at least 17 and 8 Ma, consisting of flood basalts and silicic lava plugs, with intercalated ignimbritic sheets in the upper basalt succession increasing in amount upwards. Ages decrease from NE to SW, following the migration of the small NW-SE flexures concentrating the feeding dike swarms; (2) Late Miocene large central composite volcanoes exhibiting diverse and original structures. Some of them (Tarso Toon, Ehi Oye, and Tarso Yega) are located along a major NNE fault, representing the main tectonic direction in Tibesti since Precambrian times; (3) construction of three large ignimbritic volcanoes, associated with significant updoming of the basement, ending with the collapse of large calderas: Voon (about 5–7 Ma), Emi Koussi (2.4–1.33 Ma), and Yirrigue (0.43 Ma); (4) basaltic activity, starting at about 5–7 Ma, and essentially consisting of cinder cones and associated lava flows (Tarso Toh, Tarso Ahon, and Tarso Emi Chi); and (5) final volcanic activity represented by post-Yirrigue caldera activity in the Tarso Tousside Volcanic Complex, and especially Ehi Tousside (the only active volcano in Tibesti), plus Ehi Timi and Ehi Mousgou volcanoes, similar to Ehi Tousside. The two tectonic directions controlling some volcanic features of the province correspond to the major old lithospheric structures delimiting the volcanic province, namely, the great NW-SE Tassilian flexure to the SW and a major NE-NNE fault zone to the E. Unusual conditions of uplift and erosion in the TVP enable exceptional exposure of the internal structure of its volcanoes.

Insights from the basalts of SE Lebanon into the nature of the Middle East Cenozoic Volcanic Province

Insights from the basalts of SE Lebanon into the nature of the Middle East Cenozoic Volcanic Province

Late Cenozoic volcanic province in Central and East Asia

The paper presents materials on the inner structure of the Late Cenozoic within-plate volcanic province in Central and East Asia, in which two subprovinces are distinguished: Central Asian and Far Eastern, which comprise a number of autonomously evolving volcanic areas. Some of the volcanic areas are proved to have evolved for a long time, starting in the Late Mesozoic. In spite of differences in their age and structural setting, the volcanic areas evolved according to similar scenarios in the Late Cenozoic. Magmatism in the province was related to a mantle source of the within-plate type. The magmatic associations are dominated by mafic alkaline high-K rocks. The rocks are geochemically close to basalts of the OIB type, and their isotopic composition corresponds to a combination of mantle sources of the PREMA, EMI, and EMII types at the predominance of PREMA. Geological, geochemical, and isotopic lines of evidence suggest that magmatism in the province was related to mantle plumes. This is consistent with geophysical data, which testify that the volcanic areas are underlain by upwellings of the asthenospheric mantle or plumes. Seismic tomography data indicate that the “stems” of the plumes can be traced down to the upper and lower mantle. The province is thought to have been produced when the eastern margin of the Asian plate overlapped one of the branches of the Pacific superplume at approximately 160 Ma. This branch of the superplume is pronounced in the modern mantle structure as a cluster of mantle plumes that control (according to seismic tomography data) the interaction zone of the Pacific and Asian lithospheric plates.

Geochemical characteristics of the high- and low-Ti basaltic rocks from the uplifted shoulder of the Ohře (Eger) Rift, Western Bohemia

High-Ti melanephelinite (3.8–5.9 wt% TiO 2), medium-Ti (phono)tephrite (2.7–3.1 wt% TiO 2), and low-Ti olivine melanephelinite/basanite (1.9–2.3 wt.% TiO 2) are subordinate rock types in the central European Cenozoic Volcanic Province. A contrasting melanephelinite to (phono)tephrite series occurs in the Loučná–Oberwiesenthal Volcanic Centre (37–28 Ma) and also as satellite volcanic bodies (26–12 Ma) together with olivine melanephelinite/basanite (17–20 Ma) on the southwestern periphery of the Krušné hory mountains (Erzgebirge). The volcanic rocks intrude the Variscan basement of the uplifted shoulder of the Ohře/Eger Rift in the Krušné hory mountains of the Bohemian Massif. Low Mg# (44–59) and Cr, Ni contents and enrichment of LILE, Zr, Hf, Nb, Ta, U, Th and LREE in the high-Ti melanephelinites contrast with the composition of primitive low-Ti olivine melanephelinites/basanites displaying high Mg# (63–74) and high contents of compatible elements. The high-Ti melanephelinites reveal a wide range in initial 87Sr/ 86Sr of ca. 0.7034–0.7038 and ε Nd of 2.4–4.9. The low-Ti melanephelinites show an overlapping range of initial 87Sr/ 86Sr of ca. 0.7035–0.7036 and ε Nd of 4.3–5.5. The large variation in initial 87Sr/ 86Sr ratios at similar ε Nd values in those rock types is interpreted as evidence for melting of metasomatized lithospheric mantle sources comprising K-bearing phases with radiogenic Sr. Modification of the olivine-free alkali basaltic magmas by differentiation or crustal contamination could give rise to the medium-Ti (phono) tephrites. The initial isotope ratios of all samples are consistent with HIMU-mantle sources and contributions from lithospheric mantle. The olivine-free melanephelinitic rocks often contain alkali pyroxenite–ijolite xenoliths with initial 87Sr/ 86Sr ratios of ca. 0.7036 and ε Nd of 3.0. We interpret these xenoliths as samples of an intra-crustal alkali complex derived from similar mantle sources as those for the basaltic volcanic rocks.

The Euphrates volcanic field, northeastern Syria: petrogenesis of Cenozoic basanites and alkali basalts

AbstractThe Plio-Quaternary Euphrates volcanic field of NE Syria includes large discontinuous exposures of basanitic and basaltic lava flows (1200 km2in area). It represents the northern segment of the Cenozoic volcanic province of the Middle East and is located near the Bitlis collision suture. The rocks consist of olivine (15–20%), clinopyroxene (30–35%), plagioclase (45–55%) and opaque phases. Chemically, the rocks are largely ultrabasic (SiO238.2–45.5 wt%, MgO 8.7–13.0 wt% and average Mg number of 0.65). They are enriched in incompatible trace elements such as Zr (133–276 ppm), Nb (25–71 ppm) and Y (17–28 ppm). The REE patterns are strongly fractionated ((La/Yb)N= 19.6), indicative of a garnet-bearing source. The143Nd/144Nd isotopic compositions range from 0.512868 to 0.512940 (εNd= 4.5 to 5.9), and87Sr/86Sr from 0.70309 to 0.70352. These chemical and isotopic compositions reflect strong affinities to OIB. Elemental ratios such as K/P (3.4), La/Ta (13) and La/Nb (0.77), and the low SiO2values, suggest that the Euphrates magma was subjected to minimal crustal contamination. Petrogenetic modelling has been carried out using a variety of mantle source materials, different degrees of partial melting (0.1 to 10%), and a number of scenarios including metasomatized sources. Modelling suggests that the magma could have been produced as a result of a small degree of partial melting of either (1) a garnet-bearing depleted source enriched with a small addition of metasomatizing fluids, or (2) a garnet-bearing fertile source. The overall chemical and petrological characteristics are more consistent with the generation of the Euphrates magma by a small degree of partial melting (F = 1%) of a primitive, garnet-lherzolite mantle source, possibly containing a minor spinel component. The Neogene collision of the Arabian plate with Eurasia along the Bitlis suture resulted in reactivation (beneath the Euphrates basin) of deep-seated fractures, along which lavas may have penetrated the crust.

Mantle upwellings and convective instabilities revealed by seismic tomography and helium isotope geochemistry beneath eastern Africa

The relationship between intraplate volcanism and continental tectonics has been investigated for North and East Africa using a high resolution three‐dimensional anisotropic tomographic model derived from seismic data of a French experiment “Horn of Africa” and existing broadband data. The joint inversion for seismic velocity and anisotropy of the upper 400 km of the mantle, and geochemical data reveals a complex interaction between mantle upwellings, and lithosphere. Two kinds of mantle upwellings can be distinguished: The first one, the Afar “plume” originates from deeper than 400 km and is characterized by enrichment in primordial 3He and 3He/4He ratios higher than those along mid‐ocean ridges (MOR). The second one, associated with other Cenozoic volcanic provinces (Darfur, Tibesti, Hoggar, Cameroon), with 3He/4He ratios similar to, or lower than MOR, is a consequence of shallower upwelling. The presumed asthenospheric convective instabilities are oriented in an east‐west direction, resulting from interaction between south‐north asthenospheric mantle flow, main plume head and topography on the base of lithosphere.

Late Cretaceous to Paleocene melilitic rocks of the Ohře/Eger Rift in northern Bohemia, Czech Republic: Insights into the initial stages of continental rifting

The volcanic rocks of the Ohře/Eger Rift (northern Bohemia, Czech Republic), the easternmost part of the Cenozoic Volcanic Province of western and central Europe, include rare occurrences of Late Cretaceous to Paleocene (68 to 59 Ma) ultramafic melilitic rocks in the Osečná Complex and associated Devil's Dyke swarm. These melilitic suites, related to the initial stage of rifting, occur in the outer parts of the rift zone. Magmatism during the main stage of the rifting is represented by a voluminous Eocene to Miocene (40 to 18 Ma) bimodal suite of basanites and phonolites which is present in the inner part of the Ohře Rift zone. The Osečná Complex is a lopolith-like subvolcanic intrusion, composed mainly of olivine melilitolite with rare pegmatoids, ijolites and glimmerites, accompanied by numerous cone-sheets and dykes of olivine micro-melilitolite and melilitic lamprophyre. The NNE–SSW trending Devil's Dyke swarm consists predominantly of melilite-bearing olivine nephelinite. The primitive melilitic rocks have a primary olivine + melilite + spinel ± clinopyroxene association and are characterized by low contents of SiO 2, Al 2O 3 and total alkalis but high CaO, MgO, Cr, Ni, CO 2 and strongly incompatible trace elements including light REE. High initial ɛ Nd values of + 3.2 to + 5.2 accompanied by variable 87Sr/ 86Sr ratios of ∼ 0.7033 to ∼ 0.7049 are interpreted as evidence for melting of a heterogeneous veined mantle. A portion of a depleted mantle source was overprinted by carbonate-rich fluids with enriched Sr isotopic composition. Mantle metasomatism was probably related to carbonatitic magmatism associated with incipient rifting of the Bohemian Massif lithosphere.

Mantle heterogeneity beneath the Cenozoic volcanic provinces of central Victoria inferred from trace-element and Sr, Nd, Pb and Hf isotope data

Volcanic rocks in central Victoria play a key role in unravelling magmatic relationships within an extensive zone of Late Mesozoic to Quaternary volcanism in southeastern Australia. In this study, new bulk-rock major, trace-element and Sr, Nd, Hf and Pb isotope data are presented for 20 samples of Late Cenozoic mafic volcanics from the central Victorian region. Mineral chemistry and bulk-rock analyses confirm that all samples can be treated as liquid compositions and that some were probably primary magmas. On the basis of incompatible trace-element and isotope ratios, processes such as magma mixing and crustal assimilation can be largely ruled out, and significant mantle-source heterogeneity beneath the area is proposed. If this heterogeneity extends to other regions of the post-10 Ma Victorian volcanics, the influence of the Mortlake Discontinuity and level of involvement from the lithospheric mantle in the genesis of these rocks, may need to be re-evaluated. Finally, it is argued that there is no clear evidence to suggest the New South Wales leucitite suite extends into Victoria; rather the Cosgrove leucitite flow represents part of the post-10 Ma Victorian volcanics.

Helium isotope signature of lithospheric mantle xenoliths from the Permo-Carboniferous magmatic province in Scotland — no evidence for a lower-mantle plume

Abstract Noble gas studies of well-characterized spinel-peridotite-facies lithospheric mantle xenoliths and garnet megacrysts from Scottish Permo-Carboniferous dykes, sills and vents demonstrate that the mantle beneath Scotland during the late Palaeozoic was more radiogenic than the source of mid-ocean ridge basalts (MORB). The samples were collected from the Northern Highland Terrane and the Midland Valley Terrane, which vary from Archaean-Proterozoic to Proterozoic-Palaeozoic in age. Helium isotope ratios of between 3 R a and 6 R a ( R a = atmospheric ratio) indicate that there has been time-integrated U-Th enrichment of the subcontinental mantle. This enriched mantle was preferentially melted following the transition from early Palaeozoic compression to late Palaeozoic extensional tectonics. Helium isotope ratios provide no clear evidence for the presence of undegassed plume-type mantle beneath this part of Scotland during the Permo-Carboniferous. The measured helium ratios do not discount the presence of a low-helium plume similar to those of the European Cenozoic volcanic province. A passive origin, however, is preferred for the Permo-Carboniferous magmatism due to the protracted activity, relatively small-extruded volumes of mafic magma and the low-helium isotope ratios measured.

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Continental intraplate basalts (15.42–0.16 Ma) from Abaga–Dalinuoer volcanic field (ADVF) in central Inner Mongolia of eastern China, as a part of Cenozoic volcanic province along eastern margin of the Eurasian continent, provide a good opportunity to explore potential links between deep subduction of the Pacific slab and continental intraplate volcanism. In this study, we report an integrated dataset of whole-rock K–Ar ages, major and trace elements and Sr–Nd–Pb isotopes, and olivine major and minor elements for the Abaga–Dalinuoer basalts (ADBs), and propose that mantle source lithology of the ADB magmas may consist of both pyroxenite and peridotite. The ADBs display low SiO2 (42.3–50.2 wt.%), high MgO (7.3–11.4 wt.%) and moderate K2O + Na2O (3.8–6.4 wt.%), and can be subdivided into basanites, alkali basalts and tholeiitic basalts that are all characterized by ocean island basalt (OIB)-like rare earth elements (REE) and enrichment in both large ion lithosphile elements (LILE) and high field strength elements (HFSE). Olivine phenocrysts have higher Ni and Fe/Mn and lower Mn, Ca and Ca/Fe relative to those from peridotite melts, but exhibit clearly lower Ni contents (< 2500 ppm) compared with expected Ni range (> 3000 ppm) for olivines crystallized from olivine-free pyroxenite melts. Estimated compositions of the ADB primary magmas, together with olivine compositions, suggest an iron-rich mantle source related with silica-deficient pyroxenite that is most likely derived from deeply subducted Pacific oceanic crust. Additionally, peridotite and recent subducted sediments are also required to account for high Ni and MgO in primary magmas together with their trace elements and Sr–Nd–Pb isotope systematics. We suggest that a mixed pyroxenite–peridotite source lithology can better match observed whole-rock and olivine signatures in the ADB, compared with either peridotite only or olivine-free pyroxenite only source lithology. In our model, pyroxenite melts would either react with or mechanically mix with peridotite, and the proportion of pyroxenite melts may range from 30% to 45% for mechanical mixing scenario. A continuous spectrum from tholeiitic to alkali melts revealed by melt-peridotite reaction experiment can explain formation of primary magmas of basanites, alkali basalts and tholeiitic basalts by increasing melting degree of a similar mantle source. Relatively higher 206Pb/204Pb of the ADB may suggest more significant role of recent (< 0.5 Ga) subducted Pacific oceanic materials, in contrast to other Cenozoic basalts in eastern China (e.g., Changbai basalts) that exhibit varying contributions from ancient (> 1.5 Ga) subducted continental sediments. We emphasize that coupled geochemical and geodynamic links (i.e., subduction polarity) between deeply subducted Pacific slab and continental intraplate volcanism in eastern China may exist, which directly support the involvement of deeply subducted Pacific materials in petrogenesis of the ADB. From the perspective of plate motion kinetics, decompression partial melting of upwelling fragmented Pacific slab (silica-deficient pyroxenite + recent subducted sediments) may be triggered by rollback of deeply subducted Pacific slab during Late Cenozoic times. Continental intraplate volcanism in the ADVF generally started with termination of opening of the Japan Sea, suggesting that deep subduction of the Pacific slab may have been an important geodynamic mechanism responsible for tectono-magmatic evolution of northeastern Asia. We suggest that the ADBs have the potential to shed light on genetic links between continental intraplate volcanism and deep subduction of the Pacific slab in geochemical and geodynamic processes.