Cement Specimens Research Articles

Mixed mode fracture properties of interface for composite MPC and cement concrete specimen with asymmetric semicircular bending beam

This paper investigates the interface fracture behavior of composite magnesium phosphate cement (MPC) and concrete asymmetric semicircular bending beam (ASCB) specimens under various loading conditions including pure mode I, mixed mode I&II, and pure mode II. Initially, finite element simulations are employed to compute and analyze the basic geometric characteristics of the ASCB specimens.. Subsequently, experimental tests are performed to determine the flexural strengths for different pre-crack lengths, and the critical stress intensity factors of ASCB specimens are obtained through testing. Then, parameters for the interface cohesive model are derived. Finally, the interface cohesive model for the composite MPC and concrete ASCB specimen is validated through numerical simulation. The present work show that a pure mode I opening crack represents the weakest form of the structure, and the flexural strength decreases with an increase in precrack length. The crack resistance at the repair interface is approximately 60% lower than the bearing capacity of pure mode II fractures. Intensity factor envelope analysis reveals that mixed mode I&II fractures should be avoided in composite structures experiencing complex stress states. The cohesive model effectively captures the interfacial bonding performance. When combined with the extended finite element method (XFEM), the cohesive model facilitates accurate simulation of the specimen’s interface fracture, demonstrating consistency with experimental results.

Nanocomposites Derived from Construction and Demolition Waste for Cement: X-ray Diffraction, Spectroscopic and Mechanical Investigations

In the production of cement, raw materials can be partially substituted by regenerable waste provided from glasses, construction and demolition waste in order to reduce the environmental problem and burden of landfills. In this study, limestone–silicate composites were synthesized using starting materials such as glass waste and lime, brick, autoclaved aerated concrete (ACC), mortar or plaster waste. The structure and mechanical properties of the nano-composite materials have been studied. The mean CaCO3 crystallite sizes are higher for composites containing ACC and brick than for doping with lime, mortar and plaster. Cement-based materials are formed by replacing 2.5% of the Portland cement with limestone–silicate composites. The results indicate new possibilities for introducing 2.5%of composites in cement paste because they promote the formation of the C-S-H network, which provides strength and long stability for the cement paste. The influence of varied types of mix composites in the expired cement on the initial cracking strain and stress, tensile strength and compressive strength were investigated. The compressive strength values of composite-expired cement specimens are situated between 11.8 and 15.7 MPa, respectively, which reflect an increase from 22.9 up to 63.54% over the compressive strength of expired cement matrix.

The influence and mechanism analysis of aluminum sulfate as an environmentally friendly early strength agent on the properties of cement-based materials

Environmentally friendly chemical admixtures are becoming important in the cement industry. The research objective of this paper is to use aluminum sulfate as an early-strengthening agent to achieve the goals of a large increase in early strength and a reduction in CO2 emissions. The experimental design was as follows: The macroscopic properties and microscopic characteristics of aluminum sulfate were experimentally investigated on five different replacement ratios of 0%, 1%, 2%, 3%, and 4% paste specimens of cement at different ages. The results show that (1) AS4 demonstrated a notable enhancement in early strength, while AS2 and AS3 contributed to increased late-stage strength. Over time, the Ultrasonic Pulse Velocity (UPV) of all samples exhibited a steady rise. Additionally, aluminum sulfate was found to reduce the electrical resistivity of the samples. (2) aluminum sulfate increased the rate of exothermic heat release of samples at induction and acceleration phases, advanced the accumulated heat was high in the samples with high aluminum sulfate content, and the accumulated heat was strongly correlated with the compressive strength. FT-IR and XRD results show that aluminum sulfate promoted the formation of AFt while depleting the CH content, and the TGA results show the content of bound water in the samples increased from Day 1 to Day 28, which had a positive effect on the compressive strength. UHR-SEM results show that increasing aluminum sulfate substitution results in the formation of a denser microstructure. (3) for all the various mixtures, AS2 has the lowest CO2 emissions per unit strength.

Analysis of Mechanical Properties of Fiber-Reinforced Soil Cement Based on Kaolin.

Adding fibers into cement to form fiber-reinforced soil cement material can effectively enhance its physical and mechanical properties. In order to investigate the effect of fiber type and dosage on the strength of fiber-reinforced soil cement, polypropylene fibers (PPFs), polyvinyl alcohol fibers (PVAFs), and glass fibers (GFs) were blended according to the mass fraction of the mixture of cement and dry soil (0.5%, 1%, 1.5%, and 2%). Unconfined compressive strength tests, split tensile strength tests, scanning electron microscopy (SEM) tests, and mercury intrusion porosimetry (MIP) pore structure analysis tests were conducted. The results indicated that the unconfined compressive strength of the three types of fiber-reinforced soil cement peaked at a fiber dosage of 0.5%, registering 26.72 MPa, 27.49 MPa, and 27.67 MPa, respectively. The split tensile strength of all three fiber-reinforced soil cement variants reached their maximum at a 1.5% fiber dosage, recording 2.29 MPa, 2.34 MPa, and 2.27 MPa, respectively. The predominant pore sizes in all three fiber-reinforced soil cement specimens ranged from 10 nm to 100 nm. Furthermore, analysis from the perspective of energy evolution revealed that a moderate fiber dosage can minimize energy loss. This paper demonstrates that the unconfined compressive strength test, split tensile strength test, scanning electron microscopy (SEM), and mercury intrusion porosimetry (MIP) pore structure analysis offer theoretical underpinnings for the utilization of fiber-reinforced soil cement in helical pile core stiffening and broader engineering applications.

Improving the bonding performance of new and old cement pastes by high-temperature treatment on the surface of old cement pastes

In concrete structure repair projects, patch repair is one of the most commonly used methods. However, the bonding interface is often the weakest part of the overall repaired structure, and its performance affects the safety of the entire structure. In this study, different groups of cement specimens with similar exposed surface were prepared by splitting the cement paste samples with water–cement ratio of 0.4 and 0.2 into two halves from the middle point. The exposed/split surfaces were then activated in an oven at 600 °C, 700 °C and 800 °C (heating time 30 min and holding time 5 min) respectively, and the new cement pastes were poured on the treated surface of the old cement paste samples after the treated samples were cooled down to room temperature. The interface bonding strengths of different groups of samples were tested through a three-point bending test, and the interface microstructure and composition were analyzed through micro indentation, scanning electron microscopy, and X-ray diffraction tests. Among them, the interface bonding effect was the best with treatment temperature of 800 °C with an increase of more than 80 %. With this activation method, the old base cement can undergo rehydration reaction with the water in newly covered cement paste, thereby improving the bonding performance of the interface. However, high temperature can also cause microcracks on the surface of the old cement block, and it is necessary to control the activation temperature to achieve the required performance improvement. Combining mechanical tests, interface microstructure tests, and mechanism analysis, this study proposed and verified a method to improve the bonding interface strength between new and old cement pastes by high-temperature treatment on the surface of the old cement paste. Engineering applications were also discussed and explored.

Improving freeze resistance of cement-based materials with modified graphite-paraffin composite low-temperature microencapsulated phase change materials

This study examines the influence of microencapsulated phase change materials (MPCM) on enhancing the freeze-thaw resistance of cementitious structures, overcoming the limitations commonly associated with traditional phase change materials (PCM), such as insufficient thermal conductivity and non-optimal phase change temperatures. The research focused on developing MPCM with improved thermal conductivity and lower phase transition points, utilizing a binary mixture of tetradecane and hexadecane as the core material, supplemented by modified graphite. The phase change performance and physicochemical stability of the prepared MPCM were thoroughly assessed. Cement specimens, incorporating different contents of MPCM, were then subjected to a series of tests under both room temperature and simulated freeze-thaw conditions. These tests included mechanical testing, temperature response experiments, and monitoring of internal damage. The findings identified the optimal MPCM formulation as a 9:1 mixture of tetradecane and hexadecane, with an addition of 2 % hydrophobically modified graphite, which exhibited a phase change temperature near 0 °C and a range exceeding 6.7 °C, along with stable physicochemical properties. When 3 % MPCM was included in cement specimens cured for 28 days under freeze-thaw conditions, a significant reduction in internal damage caused by freeze-thaw cycles was observed, leading to an increase in compressive strength by 0.12 % and in flexural strength by 11.77 %. Additionally, temperature tests confirmed the efficacy of MPCM in stabilizing internal temperature fluctuations within the cement specimens. The results of this study present a viable approach to enhance the durability of cement-based infrastructure in cold climates.

Color stability and marginal adaptation of ceramic veneers cemented using different composite resins.

The purpose of this study was to compare the color stability and marginal adaption of lithium disilicate veneers before and after thermocycling using various resin composite materials employed as cement. Laminate veneer preparation was done on an acrylic tooth according to standardized procedures. The veneer preparations were duplicated into twenty-one dies. The veneers were fabricated from lithium disilicate using the CEREC in Lab system. According to the cement type, the twenty-one die specimens were randomly divided into three equal groups: group I, with light cured adhesive resin cement (N.=7), group II, with flowable light cured composite, and group III, with preheated nano filled composite. The cemented specimens underwent 5000 thermocycling cycles. Color was assessed using a reflective spectrophotometer. The vertical marginal gap, following cementation and thermocycling, was measured using a digital microscope. One-way ANOVA followed by Tukey's post-hoc test was used to statistically assess the data. After thermocycling, there was no statistically significant difference in ΔE among cement type groups for color stability (P=0.369). However, the preheated composite showed the lowest ΔE mean values. Within adhesive resin cement and flowable composite groups, marginal gap means values recorded after thermocycling were significantly higher than those after cementation (P=0.013 and P<0.001, respectively). Although preheated composite cement showed the highest marginal discrepancy, it would be the best choice regarding color stability.

The Performance of Portland Cement Pastes (OPC) Incorporated with Ceramic Sanitary Ware Powder Waste (CSPW) at Ambient Temperature

The physical and mechanical performance of Portland cement pastes (OPC) incorporated waste ceramic sanitary ware powder waste (CSPW) at ambient temperature has been investigated. Cement mixes were prepared by replacing the cement with CSPW at proportions of 0, 4, 8, 12, 16 and 20 wt. %. The results showed that the water of consistency and setting times (initial and final) were increased with the gradual addition of CSP, whereas the water absorption and total porosity were decreased, while the bulk density slightly was enhanced but only up till 16 wt. % CSPW. The same trend was displayed with mechanical properties, where the flexural (FS) and compressive strengths (CS) of the cement specimens were also improved and enhanced till 16 wt. %, but then all were decreased with further addition of CSPW. The experimental results indicated that the CSPW has a potential to be successfully recycled in the OPC pastes as a partial replacement merely up to 16 wt. % which had a better performance than the blank at ambient temperature. The FT-IR spectra illustrated that the amount of CSHs was increased, while that of free lime content decreased. This was conformed by SEM microscopy. Moreover, the recovery of CSPW contributes to both reducing environmental pollution and CO2 emissions.

Application of SCMs and seawater to cement-bonded calcareous sand: Macro performance, micro mechanism, and strength prediction

Cement-bonded calcareous sand (C-BCS) demonstrates promising potential for marine island construction due to its exceptional mechanical properties. However, challenges such as freshwater scarcity and the erosive effects of seawater hinder the extensive utilization of C-BCS. To address this, this study comprehensively examines the feasibility of incorporating supplementary cementitious materials (SCMs) and seawater in C-BCS, focusing on macroscopic properties, microscopic mechanisms, and strength prediction. Macroscopic tests reveal that blast furnace slag and silica fume effectively enhance the hydration process and mechanical properties of C-BCS. Moreover, the cemented specimens developed in this study partially meet the strength standards for road pavement sub-base and airport runway upper-base applications. Microscopic analyses indicate that calcareous sand serves as a plentiful source of calcium, facilitating the formation of calcium aluminate silicate hydrate (C-A-S-H) and tobermorite when combined with Al2O3 and reactive SiO2 from slag and silica fume. This enhances the mechanical properties of the samples and their resistance against seawater erosion. Additionally, a back propagation (BP) neural network model accurately predicts the unconfined compressive strength of the cemented specimens. The findings of this study support the broader implementation of SCMs and seawater in practical island engineering projects involving C-BCS.

Deterioration of Cementitious Materials in Wastewater Treatment Plants’ Pumping Stations and Sand-Trap Structures

Wastewater treatment plants (WWTPs) are critical infrastructures for wastewater management, and their durability is crucial. Due to their excellent water tightness and strength, cementitious materials are used to build WWTPs. However, the performance of these materials is affected by aggressive environments. There are few in situ experiments in the literature regarding the deterioration of cementitious materials in WWTPs. This paper investigates their deterioration mechanisms in a sewage pumping station and a sand-trap structure of a WWTP. In situ experiment was conducted by exposing cement specimens in both locations for 1, 2, 3 and 7 months. The physical and morphological changes of the specimens were examined using stereo microscopy and scanning electron microscopy, whereas the mineralogical/solid phase changes were examined using X-ray diffraction. The results showed that the specimens from the pumping station formed colored surface products, which were confirmed to be secondary minerals (i.e., gypsum and ettringite), whereas there were no colored surface products in the sand-trap structure. The results demonstrated that cementitious materials subjected to wastewater vapors (in a pumping station) had higher deterioration effects than those subjected to wastewater liquid (in a sand-trap structure), suggesting that the wastewater vapors are more aggressive toward cementitious materials than wastewater liquids.

Physicochemical and mechanical properties of preheated composite resins for luting ceramic laminates.

This study analyzed and compared the physicochemical and mechanical properties of preheated resin composite with light-cured resin cement for luting indirect restorations. 210 specimens of resin cement/resin composite were prepared according to preheating treatment heated (Htd) or not (NHtd). Light-cured resin cement (Variolink Veneer, Ivoclar), and resin composite (Microhybrid-Z100, 3M; Nanohybrid-Empress direct, Ivoclar; and Bulk fill-Filtek One, 3M) were used (n = 10). Resin cement specimens were not preheated. The response variables were (n = 10): film thickness, microhardness, liquid sorption and solubility. Data were analyzed by 2-way ANOVA and Tukey HSD post-test (α = 0.05). Bulk fill NHtd resin had the highest film thickness values (p < 0.001). Microhybrid and nanohybrid Htd resins had the smallest thicknesses and did not differ from the cement (p > 0.05). The highest microhardness values were found for Bulk fill NHtd and Bulk fill Htd resins. The nanohybrid and microhybrid Htd resins showed the lowest microhardness values, with no difference in cement (p > 0.05). For liquid sorption, there was no significant difference between the groups (p = 0.1941). The microhybrid Htd resin showed higher solubility values than the other materials (p = 0.0023), but it did not differ statistically from resin cement (p > 0.05). Preheating composite resins reduced the film thickness. After heating, nanohybrid and Bulk fill resins retained stable microhardness, sorption, and solubility values.

Mechanical properties of cemented backfill under different unloading rates after cured at different temperatures

In the process of deep filling mining in coal mine, due to the influence of mining and other factors, the confining pressure on both sides of cemented backfill decreases. It is necessary to master the mechanical characteristics of cemented backfill under unloading conditions in different temperature environments to ensure the stability of cemented backfill. To simulate the unloading process of cemented backfill in the deep highland environment of coal mine, triaxial unloading confining pressure tests of cemented coal gangue- fly ash backfill at different unloading rates after curing at different temperatures (20 ℃, 35 ℃ and 50 ℃) were carried out by the Rock Triaxial Testing System, and the mechanical characteristics of cemented backfill unloading were systematically studied. The findings of the study show that, for the same unloading rate, the peak strength of cemented backfill specimen reduces initially before increasing with curing temperature rises. After curing at the same temperature, the peak strength of cemented backfill specimen varies exponentially with an increase in unloading rate. The deformation modulus and volume strain at different unloading rates satisfy an exponential function relationship, while the generalized Poisson's ratio and volume strain satisfy a quadratic function relationship. Under unloading conditions, there was no large fracture or fragmentation of cemented backfill, only cracks appeared on surface. At the same unloading rate, cemented backfill specimen cured at 35 ℃ and 50 ℃ exhibits significantly more shear cracks after failure compared to the material cured at 20 ℃. As the unloading rate increases, the proportion of shear cracks generated during unloading failure of cemented backfill specimen cured at 35 ℃ and 50 ℃ gradually increases. In addition, the theoretical curve of the four-stage cemented backfill unloading constitutive model established in sections is essentially compatible with experimental curve, confirming the theoretical model's reasonableness. The study's findings provide a theoretical basis for evaluating stability of cemented backfill after unloading in deep high temperature (35–50 ℃) environments.

Evaluation of saturation in cemented slags with P-wave velocities

The application of the circular economy concept to construction engineering and to transportation geotechnics, brings several challenges associated to the use of non-conventional artificial materials. Steel slags can replace natural raw materials, but a thorough mechanical characterisation is needed to assure an adequate behaviour and quality control parameters. The focus of this paper is a mixture of two types of steel slags (a reducing slag and an oxidizing slag) from electric arc furnace steel production. The mixture has cementing properties, mainly due to the reducing slag, being stable in water after compaction. Due to its high stiffness and reduced permeability, the evaluation of the degree of saturation of the mixture using the conventional Skempton parameter B is not very reliable. In this work, P wave velocity measurements in specimens with different cementation levels (given by amount of reducing slag and curing time) and soaked conditions (before and after submersion) were compared. In addition, the elastic shear stiffness evolution with time obtained by S wave velocity measurements demonstrated a clear increase in stiffness with curing time especially in soaked specimens. The aim of the paper is thus to discuss the advantage of P waves to identify full saturation in stiff specimens that harden with time and water. It was found that it is very difficult to evaluate the degree of saturation of a highly cemented specimen, either with the B value or with the P-wave velocities. However, the usual mechanical evaluation by triaxial compression tests is still valid provided that suction is low.

Quantitative Evaluation of Liquid Permeability in Cracked Oilwell Cement Sheaths

Summary Understanding the consequences of cracking in oilwell cement sheaths is crucial to evaluating the leakage scenarios that can lead to sustained casing pressure. However, the theoretical equations commonly used to estimate flows and permeabilities tend to overestimate actual flow rates through cracks, primarily due to the omission of key factors such as crack tortuosity, surface roughness, and self-healing processes. Therefore, experimental methods are required to quantify the influence of these factors and define “empirical reduction factors.” Because each material exhibits its own unique effects on flow behavior, empirical reduction factors must be determined for each specific material, including oilwell cement. This paper presents a comprehensive procedure for systematically measuring flows, determining permeabilities, and evaluating self-healing processes in deliberately cracked cement specimens with controlled crack widths. The procedure considers pressure gradients and crack widths relevant to oilwell conditions aiming to contribute to the development of more accurate models and simulations for cemented oil wells.

Alabama Field Project to Evaluate Variability in Soil–Cement Specimens Compacted with the Plastic Mold Device

The plastic mold compaction device (PM Device) was developed in Mississippi to compact cementitiously stabilized soil inside plastic molds to improve soil–cement quality by adding value during design and construction activities. The PM Device has been incorporated as an AASHTO provisional standard (AASHTO PP92-19) and, to date, prevailing activities have been Mississippi Department of Transportation projects and have included controlled laboratory evaluations and field projects. This paper goes beyond previous efforts, to document a field study in which the PM Device was successfully used on an Alabama Department of Transportation project to evaluate its effectiveness within another state’s construction specifications. The PM Device was capable of capturing quantifiable variation in mechanical properties over the duration of the construction project, as well as producing similar mechanical properties to cores taken from the compacted pavement surface. Additionally, molds described in AASHTO PP92-19 were compared with one another to evaluate their potential within the standard practice. AASHTO PP92-19 protocols were sufficient to produce viable, repeatable test specimens within another state department of transportation construction environment for quality control and quality assurance.

Statistical distribution of micro and macro pores in acrylic bone cement- effect of amount of antibiotic content

Aseptic loosening due to mechanical failure of bone cement is considered to be a leading cause of revision of joint replacement systems. Detailed quantified information on the number, size and distribution pattern of pores can help to obtain a deeper understanding of the bone cement's fatigue behavior. The objective of this study was to provide statistical descriptions for the pore distribution characteristics of laboratory bone cement specimens with different amounts of antibiotic contents. For four groups of bone cement (Palacos) specimens, containing 0.3, 0.6, 1.2 and 2.4 wt/wt% of telavancin antibiotic, seven samples per group were micro computed tomography scanned (38.97 μm voxel size). The images were first preprocessed in Mimics and then analyzed in Dragonfly, with the level of threshold being set such that single-pixel pores become visible. The normalized pore volume data of the specimens were then used to extract the logarithmic histograms of the pore densities for antibiotic groups, as well as their three-parameter Weibull probability density functions. Statistical comparison of the pore distribution data of the antibiotic groups using the Mann–Whitney non-parametric test revealed a significantly larger porosity (p < 0.05) in groups with larger added antibiotic contents (2.4 and 0.6 wt/wt% vs 0.3 wt/wt%). Further analysis revealed that this effect was associated with the significantly larger frequency of micropores of 0.1–0.5 mm diameter (p < 0.05) in groups with larger antibiotic content (2.4 wt/wt% vs and 0.6 and 0.3 wt/wt%), implying that the elution of the added antibiotic produces micropores in this diameter range mainly. Based on this observation and the fatigue test results in the literature, it was suggested that micropore clusters have a detrimental effect on the mechanical properties of bone cement and play a major role in initiating fatigue cracks in highly antibiotic added specimens.

Atmospheric plasma treatment: an alternative of HF etching in lithium disilicate glass-ceramic cementation.

Objectives: This study aimed to investigate whether the atmospheric pressure plasma jet (APPJ) could modify the surface of lithium disilicate glass ceramics (LDC) instead of hydrofluoric acid (HF) in LDC resin cementation. Methods: Two hundred and thirty-two LDC blocks were randomly divided into seven groups: Group 1 (16 specimens) was the blank control group (without HF or APPJ treatment); Group 2 (36 specimens) was etched by HF; Groups 3-7 (36 specimens each) were treated with APPJ, and the relative air humidity (RAH) of the discharge was 22.8%, 43.6%, 59.4%, 75.2%, and 94.0%, respectively. Three LDC blocks in each group were characterized via X-ray photoemission spectroscopy (XPS) analyses, 3 blocks via contact angle measurements, and other 10 blocks via surface roughness measurements. The residual LDC blocks in groups 2-7 were cemented to composite cylinders. Testing the cemented specimens' shear bond strength (SBS) before and after thermocycling (6,500 cycles of 5°C and 55°C) revealed fracture patterns. Data were analyzed by ANOVA (post hoc: Bonferroni) (α = 0.05). Results: After APPJ treatment, the water contact angle values of APPJ treated blocks dropped from 31.37° to 5.66°, while that of HF etched ones dropped to 18.33°. The O/C ratio increased after HF etching or APPJ treatment according to the calculated results, except for the APPJ-treated samples at a RAH of 22.8%. The surface roughness of LDC blocks showed no statistic difference before and after APPJ treatment, but experienced significant difference after HF etching. The O/Si and O/C ratios varied after HF etching or APPJ treatment. No significant difference in SBS values could be found among groups 2-7 before or after artificial aging (p > 0.05). All specimens showed mixed failure patterns. Conclusion: The APPJ treatment method reported in this study is a promising novel strategy for surface modification of the LDC. With acceptable bonding strength, it might be an alternative to HF in LDC-resin cementation.

Thermal behaviors of cement and mortar under microwave treatment and the influencing factors: An experimental study

Microwave-assisted breakage of cementitious materials has emerged as a promising green and low-carbon method for dismantling cementitious structures. To understand the mechanism of microwave-induced cracking in structures, it is essential to study the thermal behaviors of cement and mortar under microwave treatment. In this paper, the effects of mixture ratio, water content, and microwave power on the microwave heating characteristics of cement and mortar specimens were investigated through real-time temperature and mass monitoring. In particular, the influence of microwave power on the bursting effect of cement and mortar specimens was analysed, and the mechanism of specimen bursting was explained. The results show that moisture content, water-cement ratio, and microwave power significantly impact the heating rate and mass loss of cement and mortar during microwave treatment. Based on the heating rate, the heating process of cement and mortar under microwave treatment can be divided into three to four stages, depending on the moisture content. The primary reasons for variations in the heating rate are water evaporation and the decomposition of hydrolysis products. The thin-wall ball model based on steam pressure theory can explain the bursting of cement and mortar specimens. Our findings suggest that increasing microwave power and water content in mortar specimens can lead to microwave-induced cracking.

Hydration, Reactivity and Durability Performance of Low-Grade Calcined Clay-Silica Fume Hybrid Mortar

Low-grade calcined clay, due to its low cost, availability and low temperature calcination, has been gaining attention in recent times as a supplementary cementitious material (SCM) in the manufacture of revolutionary building materials to improve the fresh and hardened properties of concrete. Silica fume, on the other hand, has been used, over the years, to improve the performance of concrete due to its reduced porosity and improved transition zone quality. In spite of the individual contribution of these two pozzolans to the strength and durability of concrete, there is a knowledge gap in the properties of ternary blended mixes utilizing calcined clay and silica fume. In this study, the synergistic effect of calcined clay and silica fume on the fresh and hardened properties of cementitious mortar have been investigated. The two pozzolans were used to partially substitute Portland cement to form a ternary blended composite binder having, at a maximum, a replacement of 30% by weight and a varying content of calcined clay and silica fume. The influence of the binary and ternary blended mixes on hydration, pozzolanic reactivity and the mechanical and durability properties of mortar was studied. From the results, partial replacement of cement with 30% calcined clay and silica fume caused significant reductions in the portlandite content of the two hydrated pastes at all curing ages. Drying shrinkage was found to be less severe in the control mortar than the blended cement mixes. Compared to the blended cement specimens, the control suffered the most weight (13.3%) and strength (10%) losses, as indicated by the sulphate resistance test.

Study on the performance of vegetation concrete prepared based on different cements

In this paper, 16 ∼ 19 mm gap-graded aggregate and different cement were used to prepare vegetation concrete (VC). The effect laws of cement types (ordinary Portland cement, Portland slag cement, sulphoaluminate cement, aluminate cement) on the mechanical properties, water permeability, sound absorption and vegetation-growing performance of VC were analyzed. The results show that aluminate cement has the most significant effect on the mechanical properties of VC in the early stage (7d), Portland slag cement has an obvious improving effect on the mechanical properties of VC in the middle and late stages (14d, 28d), and its sound absorption performance, pH value and vegetation-growing performance, while ordinary Portland cement has the best effect on the water permeability of VC and the vegetation resistance. Thus, it is recommended to use Portland slag cement to prepare vegetation concrete. In addition, SEM, XRD and TG-DTG tests were conducted out on VC under different cement types. The analysis showed that Portland slag cement specimens were rich in hydration products and closely connected, with fewer pores and cracks, and the structural compactness was better. The intensity of Ca(OH)2 diffraction peak in the XRD pattern was significantly lower than that of ordinary Portland cement specimens. The mass loss rate in the range of 0 ∼ 400 °C in the TG curve was higher than that of ordinary Portland cement specimens, indicating that the compressive strength of Portland slag cement specimens was better than that of ordinary Portland cement specimens, which was consistent with the change law of VC macroscopic mechanical properties.