Cementitious Matrix Composites Research Articles

Study on the Correlation Between Mechanical Properties, Water Absorption, and Bulk Density of PVA Fiber-Reinforced Cement Matrix Composites

Fiber-reinforced cement matrix composites (CMCs) have gained significant attention due to their ability to enhance material properties for use in demanding environments. This study investigated the workability and mechanical properties of polyvinyl alcohol (PVA) fiber-reinforced CMCs, focusing on compressive strength, split tensile strength, and flexural strength. It also assessed water absorption capacity through immersive water absorption tests using cubes and capillary water absorption tests using cylinders, alongside bulk density measurements for both shapes. The results indicated that the dosage of PVA fibers significantly influences the workability of CMCs, while the water-to-binder ratio has a minimal effect. Increasing the dosage of PVA fibers in CMCs from 0.5 vol.% to 1 vol.% led to a decrease in several properties: compressive strength decreased by 13.38%, split tensile strength by 21.05%, flexural strength by 9.23%, bulk density of cube samples by 4.14%, and bulk density of cylindrical sample by 6.36%. Conversely, both immersive water absorption and capillary water absorption increased, rising by 10.87% and 77.71%, respectively. Compressive strength was found to increase with the bulk density of the cubes and to decrease with rising immersive water absorption. Similarly, split tensile strength increased with the bulk density of the cylinders and decreased as capillary water absorption increased. Strong correlations were observed among three key pairwise combinations: the bulk density of cubes and immersive water absorption (R2 = 94%), compressive strength and bulk density of cubes (R2 = 96%), and compressive strength and immersive water absorption (R2 = 92%). Furthermore, the analysis and comparison of carbon fiber-reinforced and PVA fiber-reinforced CMCs will provide important references for the field, especially in cases where material availability or cost varies.

Molecular dynamics simulation of nanocellulose and cement matrix composites

The interfacial properties of nanocellulose and cement matrix are the key factors affecting the mechanical properties of composite materials. However, it is challenging to study the interface combination through conventional experiments and microscopic characterization techniques. Molecular dynamics simulation (MD), as a nanoscale analytical method, can be used to calculate and analyze the strength, deformation, destruction and interfacial interaction of materials on the atomic scale. Since the existing methods of C-S-H modeling and fiber pull-out from the matrix in molecular dynamics simulations were not suitable for cellulose/C-S-H composite models. In this paper, a molecular dynamics simulation method for nanocellulose cement matrix composites was proposed. Based on the embedded composite model, the tensile stress-strain, interfacial interaction energy, hydrogen bond, and interface failure mode were studied when cellulose was pulled out of the matrix. The results showed that adding cellulose could improve the local ductility and tensile strength of cement matrix materials. The interfacial interaction energy between cellulose and C-S-H was approximately −1.09 J/m2, which was much higher than that between carbon nanotubes and C-S-H. Cellulose would adsorb hydrogen and oxygen atoms on H2O, OH− and silica tetrahedron in C-S-H. In the pull-out simulation of cellulose in C-S-H, C-S-H on the surface of cellulose would be destroyed and attached to the cellulose surface and moved along with it, indicating that cellulose could play a good bridging role in the matrix. The simulation results revealed the action mechanism of cellulose in cement matrix materials.

SnO wrap on SnS reinforced thermoelectric properties of CF/EG cement matrix composites

In this study, SnO wrap on SnS was prepared and incorporated into carbon fiber/expanded graphite (CF/EG) cementitious composites by the coating process. The effects of different SnO wrap on SnS coating ratios and contents on the microstructures of CF/EG cementitious composites were investigated and discussed, and the thermoelectric properties of SnO wrap on SnS CF/EG cementitious composites were systematically investigated in the temperature range of 35–70 °C. The results show that the coating ratio and content of SnO wrap on SnS have a significant effect on the thermoelectric properties of CF/EG cementitious composites. It is noteworthy that when the SnO wrap on SnS is 2:1, the thermoelectric properties of its cementitious composites are greatly improved. For example, when it is added at 1.0 wt%, the conductivity is 2.27 S/cm, the Seebeck coefficient is 41.90 µV/°C and the power factor is 0.38 µW·m−1K−2. The addition of SnO wrap on SnS to CF/EG cementitious materials generates a large number of interfaces, and the presence of high-density interfaces hinders the motion of carriers, which leads to the scattering of carriers at the interfaces and enhances the Seebeck effect in cementitious composites. Therefore, SnO wrap on SnS has great potential for thermoelectric applications.

Mechanical characteristics, microstructural evolution, and reinforcement mechanisms for a cement-matrix nanocomposite

The present paper is focused to understand the reinforcement mechanisms exerted by GO nanosheets to both strengthen and toughen cement-matrix composites since, despite intensive research, such mechanisms are still not completely clear. To such an aim, the mechanical characteristics (that is, mechanical strengths and fracture toughness) of a cement-matrix nanocomposite, with the 0.05 % of GO used as an additive, are experimentally investigated at different curing times. Since reinforcement mechanisms are closely related to cement hydration products, they are qualified and quantified by chemical, mineralogical and microstructural analyses performed at the above times of curing. The present investigation leads to the conclusion that the role of both CSH and AFt content is dominant in strengthen and toughen of cement matrix-nanocomposites with GO used as an additive.

Effect of ICCP on tensile performance of carbon fiber bundles in seawater sea-sand cementitious matrix

Impressed current cathodic protection (ICCP), carbon fabric reinforced cementitious matrix (CFRCM) composites, and piezoresistive effect have been widely studied in delaying steel bar corrosion, strengthening steel-reinforced concrete structures, and structural health monitoring, respectively. In this study, the effect mechanism of the ICCP procedure on the tensile performance degradation of CFRCM bundles with the two types of matrix (normal matrix (i.e., sand conforming to ISO standard) and seawater sea-sand matrix), as well as the tensile performance differences between them, were investigated through carbon fiber bundle tensile tests and CFRCM bundle tensile tests. The piezoresistive effects of CFRCM with the two types of matrix after the ICCP procedure and the effect of ICCP on the piezoresistive effect were analyzed. Prediction formulas for the tensile performance were established based on the different charge densities. Based on the dual functionality of carbon fiber strengthening and self-sensing, this study lays a foundation for the development of a triple-functional system of impressed current cathodic protection, structural strengthening, and structural health monitoring (ICCP-SS-SHM). The study indicates that seawater sea-sand positively influences the delay of CFRCM degradation through ICCP. This is advantageous in tackling the issue of scarce freshwater river sand resources.

Effect of ICCP on tensile performance and piezoresistive effect of CFRCM plates

Currently, extensive research has been conducted on carbon fabric−reinforced cementitious matrix (CFRCM) composites, impressed current cathodic protection (ICCP), and the piezoresistive effect in the field of strengthening of reinforced concrete (RC) structures, corrosion protection of steel reinforcement, and structural health monitoring, respectively. This study utilized two types of matrix materials: normal matrix (sand conforming to ISO standard) and seawater sea-sand matrix. The mechanism by which the ICCP procedure affects the degradation of tensile performance in CFRCM plates with these two types of matrix materials was investigated in the study. Additionally, the piezoresistive effects of CFRCM with the two types of matrix materials after the ICCP procedure were analyzed, and the impact of ICCP on the piezoresistive effect was also investigated. By observing the piezoresistive effect of each CFRCM segment, the sequence of crack propagation and an approximate crack location can be inferred. Finally, the tensile performance of CFRCM with charge density was investigated. Leveraging the dual functionality of carbon fiber reinforcement and sensing, this study lays the groundwork for the development of a triple-functional system encompassing impressed current cathodic protection, structural strengthening, and structural health monitoring (ICCP-SS-SHM). Seawater sea-sand has the potential to be used as an alternative to freshwater river sand, which is beneficial for addressing the shortage of freshwater river sand resources.

Fatigue and post-fatigue behavior of FRCM-concrete specimens under direct shear and bending conditions

The combined effect of cyclic loading and steel rebar corrosion can determine the premature deterioration of reinforced concrete (RC) structures subjected to dynamic and environmental actions. The use of fabric-reinforced cementitious matrix composites (FRCM) is a promising solution to extend the fatigue life of RC structures. Externally bonded FRCMs are applied to the tension side of structural members to reduce the rebar stress level, thus delaying fatigue crack nucleation and/or propagation. A key aspect for the design of FRCM strengthening of these structures is the matrix-fiber bond behavior under fatigue loading. In this paper, a critical review of currently available studies on the fatigue behavior of FRCM-strengthened RC beams is presented. Then, the results of 25 bond tests on PBO FRCM-concrete specimens are provided and discussed. These tests include both single-lap direct shear and modified beam tests performed in quasi-static and cyclic mode. The results obtained show that the cyclic load may induce progressive debonding at the matrix-fiber interface with rupture of fiber filaments. Modified beam tests are more affected by these phenomena than direct shear tests. The rupture of fiber filaments is confirmed by the results of post-fatigue tests that show capacities lower than those of corresponding quasi-static tests.

Restoration of two-span RC beams with severely corroded reinforcement using C-FRCM composites

The feasibility and viability of using carbon fabric-reinforced cementitious matrix (C-FRCM) composites for restoration of continuous reinforced concrete (RC) beams with severely corroded reinforcement were examined. Five large-scale dual-span RC beams were fabricated and tested. One beam was not corroded to serve as a control. Four beams were subjected to accelerated corrosion that corresponded to a tensile steel cross-sectional loss of 40% in either the sagging or the hogging region. Such a steel cross-sectional loss would cause a comparable reduction in the yield load of bare steel reinforcing bars. Two of the corroded beams were repaired with C-FRCM composites. An analytical model was formulated and utilized to design the number of C-FRCM layers required to fully restore the original load capacity. Experimental results verified the redistribution of moments between the sagging and hogging regions due to yielding of the tensile steel at critical sections. Both sagging and hogging sections contributed to the load-bearing capacity, and hence, the reduction in the load capacity caused by corrosion in one of the critical sections was smaller than the tension steel cross-sectional loss caused by corrosion. It was possible to predict the load capacity of the tested beams with reasonable accuracy considering the residual cross-sectional area of the corroded tension steel bars while keeping their yield strength and Young’s modulus unaltered in addition to implementing other conventional assumptions adopted by international codes and guidelines. As predicted analytically and verified experimentally, rehabilitation of corroded continuous beams with appropriate number of C-FRCM composite layers fully restored their original load capacity. Research findings would assist practitioners in conducting a proper analysis of continuous RC beams with corroded reinforcement before and after repair with C-FRCM composites.

Simplified Procedure to Determine the Cohesive Material Law of Fiber-Reinforced Cementitious Matrix (FRCM)-Substrate Joints.

Fiber-reinforced cementitious matrix (FRCM) composites have been largely used to strengthen existing concrete and masonry structures in the last decade. To design FRCM-strengthened members, the provisions of the Italian CNR-DT 215 (2018) or the American ACI 549.4R and 6R (2020) guidelines can be adopted. According to the former, the FRCM effective strain, i.e., the composite strain associated with the loss of composite action, can be obtained by combining the results of direct shear tests on FRCM-substrate joints and of tensile tests on the bare reinforcing textile. According to the latter, the effective strain can be obtained by testing FRCM coupons in tension, using the so-called clevis-grip test set-up. However, the complex bond behavior of the FRCM cannot be fully captured by considering only the effective strain. Thus, a cohesive approach has been used to describe the stress transfer between the composite and the substrate and cohesive material laws (CMLs) with different shapes have been proposed. The determination of the CML associated with a specific FRCM-substrate joint is fundamental to capture the behavior of the FRCM-strengthened member and should be determined based on the results of experimental bond tests. In this paper, a procedure previously proposed by the authors to calibrate the CML from the load response obtained by direct shear tests of FRCM-substrate joints is applied to different FRCM composites. Namely, carbon, AR glass, and PBO FRCMs are considered. The results obtained prove that the procedure allows to estimate the CML and to associate the idealized load response of a specific type of FRCM to the corresponding CML. The estimated CML can be used to determine the onset of debonding in FRCM-substrate joints, the crack number and spacing in FRCM coupons, and the locations where debonding occurs in FRCM-strengthened members.

FRCM Confinement of Masonry: Strain Model Assessment and New Proposals.

One of the main limitations to the use of fabric-reinforced cementitious matrix (FRCM) composites for the external confinement of masonry is the lack of accurate formulas for estimating the compressive strength and ultimate strain of confined members. With the aim of providing a contribution on the topic, the authors have been carrying out studies on the FRCM-confined masonry for some time and, in a recent study, they proposed some formulations for the prediction of compressive strength. In continuity to that work, an analytical study on the ultimate strain of FRCM-confined masonry is presented in this paper, and preliminary models were derived by considering a wide experimental database compiled from the technical literature. The accuracy of the found relationships was examined based on a comparison with the few formulas published in the literature or reported in international guidelines. To this purpose, it is worth highlighting that the current Italian Guidelines CNR-DT 215/2018 do not provide indications about the estimation of the ultimate strain of FRCM-confined masonry, and the study proposed here attempts to provide a contribution to the mentioned document.

Mechanical Properties of Cement Matrix Composites Reinforced with Polyoxymethylene Fibers of Different Lengths

Mechanical Properties of Cement Matrix Composites Reinforced with Polyoxymethylene Fibers of Different Lengths

Available measurement methods to evaluate the fiber and matrix bond performance of FRCM composites

Measuring the bond between Fabric-Reinforced Cementitious Matrix (FRCM) composites and the substrate onto which they are applied is crucial for assessing the performance of these materials when used for the strengthening of existing structures. Experimentally, this parameter has been investigated by conducting single/double lap shear tests. However, as the bond failure is usually reached at the fiber-matrix interface, it is hard to obtained reliable date of the local phenomena occurring at such location. This is caused by the impracticality of observing the behavior due to the presence of an exterior matrix layer. In this paper, a detailed review of methods used to measure the bond between the fibres and the matrix is presented. Methods studied include traditional instrumentation such as strain gauges, and more recently developed digital image correlation (DIC). In addition, due to the increase in use of new sensing technologies such as wavelength- or frequency-based fiber optic sensors (FOS), these techniques are also evaluated. The research presented in this paper emphasize the applicability of these techniques and offer a comprehensive analysis of their respective advantages and limitations, ultimately providing valuable insights into their utility for characterizing the bond behavior of FRCM composites.

Shear strengthening of RC beams with U-wrapped FRCM composites: assessment of current design guidelines

Fabric-reinforced cementitious matrix (FRCM) composites have been widely used in the past two decades as externally bonded (EB) reinforcement of existing concrete structures. They represent an effective solution for the flexural, shear, and torsional strengthening of reinforced concrete (RC) members. Shear strengthening with EB FRCM can be performed by either side bonding, U-wrapping, or full-wrapping the reinforcement around the cross-section of beams and columns. The FRCM can have a continuous or discontinuous layout, and the textile can be applied with different inclination angles with respect to the beam longitudinal axis. The contribution provided by the EB FRCM to the member shear strength is usually computed by an extension of the Mörsch truss model, which assumes the formation of a main diagonal shear crack. This approach is followed by both the Italian CNR-DT 215 (2018) and the American ACI 549.4R (2020) design guidelines, which provide similar formulations but rely on different hypotheses. In this paper, the accuracy of these formulations to determine the shear strength of U-wrapped FRCM-strengthened RC beams is assessed against a database of RC beams collected from the literature. Comparison between experimental results and analytical predictions allowed to identify the main features of the design models considered.

Experimental and numerical bond behavior of PBO FRCM tested using a pull-out set-up

Fabric-reinforced cementitious matrix (FRCM) composites have become increasingly popular in the field of externally bonded (EB) reinforcement of existing concrete and masonry structures. They are used as flexural, shear, and torsional strengthening of reinforced concrete (RC) members. They are comprised of high strength textiles embedded in an inorganic-based matrix. FRCM tensile mechanical properties are characterized by clamping-grip or clevis-grip tensile tests, whereas their bond behavior by indirect or single- and double-lap direct shear tests. The eccentricity between the applied load and the restraint in single-lap direct shear tests entails for the presence of normal stresses that can affect the bond stress-transfer mechanism. Furthermore, direct shear tests require relatively large and heavy specimens. To overcome these issues, a new pull-out test set-up was proposed in the literature to investigate the bond behavior of FRCM composites that fail at the textile-matrix interface. In this paper, nine pull-out tests are performed on PBO FRCM composites. Bonded lengths shorter and longer than the textile-matrix interface effective bond length are considered. Six specimens have a short bonded length (i.e., 150 mm), whereas three have a long bonded length (i.e., 450 mm). Applied stress – global slip curves of the specimens tested highlight the presence of friction at the textile-matrix interface. The results of the pull-out tests are compared with those of corresponding single-lap direct shear tests presented in a previous work with the same PBO FRCM composite and the same bonded length and width. The applied stress – global slip curves obtained from the two sets of test show good agreement. Finally, the pull-out test set-up is validated by means of a three-dimensional finite element model.

Bond behavior between carbon fabric reinforced cementitious matrix (FRCM) composites with added short fibers and concrete substrates

Fabric reinforced cementitious matrix (FRCM) composites show an innovative solution for strengthening existing concrete structural elements to solve the drawbacks of organic resins in fiber-reinforced polymers (FRP) system. However, the brittle fracture of the cementitious matrix significantly reduces the efficiency of the fabric. Hence, the incorporation of short fibers into the matrix is proposed to increase the fabric efficiency. For externally bonded FRCM composites to structural element surfaces, it is a crucial issue to investigate the bond behavior at the fabric-matrix and matrix-substrate interfaces, where the effect of short fibers is non-negligible and requires further investigation. In this study, a single-lap direct shear test was used to investigate the bond behavior between carbon FRCM composites with added short fibers and concrete substrates. 36 specimens were tested and discussed by considering the effects of bond length, volume content of short fibers, type of short fibers, and bond width. The experimental results were discussed in terms of failure mode, load-slip curve, and characteristic parameters. Subsequently, the contribution of weft yarns was studied and accounted for in the developed bond-slip model, which additionally takes into account the effects of the volume content of the short fibers, the type of short fibers, and the bond width.

Influence of severe thermal preconditioning on the bond between carbon FRCM and masonry substrate: Effect of textile pre-impregnation

Fabric-reinforced cementitious matrix (FRCM) composites often include polymer-impregnated bundles to improve the exploitation of the textile mechanical properties. However, organic components may degrade when exposed to elevated temperature. In this paper, the bond behavior of a carbon FRCM applied to a masonry substrate and exposed to a thermal preconditioning up to 300 °C for 250 min is investigated. Tensile tests on the textile and flexural and compression tests on the mortar matrix, as well as single-lap direct shear tests of FRCM-masonry joints with bare and impregnated textiles, are performed. Results show that the polymeric impregnation improves the mechanical properties of the FRCM even after thermal preconditioning.

Study on the physicochemical properties of Chinese PVA fibers: Toward low-cost cement-based composites

Engineered Cementitious Composites (ECC) reinforced by Japanese Polyvinyl Alcohol (PVA) fiber showed excellent tensile ductility, which attracted much attention in the field of civil engineering in recent years, but the application was still limited by cost. There were quite a few kinds of low-priced PVA fibers in China, with a tremendous difference in physical and chemical properties. In this paper, a variety of typical PVA fibers produced in different regions in China were compared with the products imported from Japan to analyze the performance differences, especially the dispersion and enhancement effect in fiber reinforced cement matrix composites. Combining with the physical and chemical characteristics of each fiber, the relationship between the characteristics of fibers and the properties of composites was summarized. The experimental results illustrated the strength and interface characteristics of PVA fibers were the dominating influencing factors to the bending and tensile properties of PVA-ECC, while hardly affected the compressive strength. Insufficient intrinsic strength of fibers significantly decreased bending resistance and tensile strength. Excessive oil agent treated PVA fibers performed lower interfacial reaction with the cement matrix, meanwhile original PVA fiber with high hydrophilicity was not conducive to the dispersion and bridging function. The appropriate interface treatment approach could guarantee the fibers to achieve the sliding pull out bridge connection, and also meet the high slip strengthening effect, leading to the multi-seam cracking and strain hardening characteristics of ECC material. This work provided the preparation of low-cost cement-based composites, guiding the selection of fiber raw materials in ECC.

Shear capacity prediction for FRCM-strengthened RC beams using Hybrid ReLU-Activated BPNN model

This study presents a robust Hybrid ReLU-Activated Backpropagation Neural Network (BPNN) model for predicting shear strength (VFRCM) in RC beams reinforced with Fiber-Reinforced Cementitious Matrix (FRCM) composites. The model demonstrates exceptional accuracy, boasting a coefficient of determination (R2) of 0.924 and a mean root mean squared error (RMSE) of 10.611 kN on the test set. Leveraging k-fold cross-validation, the model's performance is rigorously assessed across ten data splits, emphasizing its reliable predictive capabilities. Hyperparameter optimization, guided by Particle Swarm Optimization (PSO), reveals an optimal value of α = 0.5757, minimizing the Mean Squared Error (MSE) to 74.53 for the dataset. Feature importance analysis underscores the significant role of critical parameters in shear strength prediction, with the longitudinal reinforcement ratio (ρl) emerging as the most influential feature, contributing 37.55 % to the model's predictive power. Additionally, the effective beam depth (d) is identified as the second most influential feature, providing approximately 16 % to the accurate prediction of VFRCM in RC beams strengthened with FRCM composites.

Analysis of probable consequences of cement composite frost destruction

The article presents an analysis of variations in the internal resistance of standard and fiberreinforced cement composites under non-stationary low-temperature and humidity effects. Various aspects of the response kinetics of prismatic samples in the monotonous compression mode are considered. The sample set included control samples and those subjected to cyclic freezing and thawing according to their standard frost resistance. Test samples (100 × 100 × 400 mm) were made of conventional (B series) and fiber-reinforced (FB, polypropylene fibers df = 0.8 mm, lf = 40 mm, µf = 1.5 vol%) concrete with a component ratio of cement: sand: crushed stone: water = 1:1.42:3.57:0.55. The accepted base of T-W cycles corresponded to the standard concrete grade in terms of frost resistance, established in control tests (F200). Static tests of composites were preceded by low-temperature exposures according to an accelerated method for assessing frost resistance with a temperature decrease down to minus 35℃ and thawing in a 5% NaCl solution. Samples were automatically loaded (Instron 5989 test complex) according to a special program with a constant deformation rate of 5·10-5 mm/s and continuous recording of deformations. Significant differences were observed in the strength kinetics, magnitude and structure of deformations, along with a high sensitivity and quantitative informativeness of the significant parameters of the strength kinetic concept for solid bodies. The expediency of a differentiated approach to the selection of calculation models and criteria for the temperature and humidity transformations of cement-matrix composites, which takes operational requirements into account, is substantiated.

IMPACT OF HEAT TREATMENT METHOD AND MILLET POD TYPE ON REAL DENSITY AND POZZOLANIC ACTIVITY INDEX BY ASH RESISTANCE

Artificial pozzolans derived from agricultural by-products are generally obtained by heat treatment. The thermal treatment method used and the type of waste influence the quality of the final product. The aim of this study was to measure the actual density and pozzolanic activity index of millet pod ash produced in three different ways. Ash A is produced by direct calcination of the husks from which the millet seeds are removed (without the stalk). Ash B is obtained by burning and then calcining the millet husks. Ash C is produced by direct calcination of the millet straw (husks + stalks). The actual density was determined in accordance with standard NF EN 1097-6. The pozzolanic activity index by resistance was measured on the basis of the recommendations of American standard ASTM-C618. For the ashes A, B and C produced, we respectively obtained true densities of 2.256 g/cm3 2.150 g/cm3 and 2.033 g/cm3. The pozzolanic activity indices per strength obtained were 0.42, 0.23 and 0.70 respectively. These results showed that the ash produced from direct calcination of raw millet waste (straw) had the best reactivity and the lowest density. It is therefore well suited to the production of low-density cementitious matrix composites.