In order to improve the early properties of lithium slag (LS) blended binder, Mg/Al-LDH/polycarboxylate (PCE) nanocomposites as chemical admixture were adopted. In this research, effects of Mg/Al-LDH/PCE nanocomposites on the hydration behavior of Portland cement including LS powder (20 wt%) were evaluated. The rheological properties and compressive strengths were studied. And the micro-analysis, such as hydration heat, hydration products and micro-morphology were also analyzed to reveal the potential hydration mechanism of LS-cement binder in the function of LDH-PCE. Results showed that LDH-PCE was beneficial for improving the rheological and mechanical performances of the fresh binder. Adding 1 wt% LDH-PCE contributed to the highest compressive strength, leading to 14.66 %, 32.62 %, and 24.88 % enhancement at 3 d, 7 d, and 28 d, respectively. LDH-PCE acted as nucleation sites and promoted the hydration process of LS blended binder. With the addition of LDH-PCE, the second exothermic peak of hydration heat evolution and cumulative hydration heat elevated obviously. The amount of CH enhanced at the early stage (3 d) due to the enhanced hydration of cement clinker and decreased at a later time (28 d) because of enhanced pozzolanic reaction. Enhanced cement hydration and pozzolanic reaction of LS generated more hydration products in the matrix, resulting in denser microstructure as well as enhanced mechanical strength. The addition of LDH-PCE significantly improved the rheological properties of the LS blended binder, shortened the setting time, increased the compressive strength of the mortar, and promoted the hydration process.
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