Fullerene derivative 2 carrying pyridinium cation bound to sonicated calf thymus DNA in water. The binding ratio was 1 fullerene unit to 1 phosphate residue, giving the complex where DNA strand is seemingly coated with electron-conducting fullerenes. Cyclic voltammetry shows three-step redox couples in the complex, and the current peaks were broadened and shifted to positive side as compared to uncomplexed 2. Binding of 2 onto grooves of DNA double helix was suggested.