A scoping study was performed for chlorinating dross formed during uranium casting operations. The purpose is to minimize the losses of uranium to dross wastes. The dross is primarily a mixture of uranium metal and uranium oxide with a minor fraction of crucible and crucible coating materials. The reaction chemistries were performed in a carrier salt of LiCl-KCl eutectic at 500 °C. The addition of FeCl2 chlorinated the uranium metal to UCl3, by reducing the FeCl2 to iron metal. After the uranium metal was chlorinated, zirconium metal was added to the salt. The residual FeCl2 chlorinated the zirconium metal to ZrCl4, by reducing the FeCl2 to iron metal. In turn, the ZrCl4 chlorinated the uranium oxide to UCl3, by converting the ZrCl4 to zirconium oxide. The effectiveness of the chlorination reactions was qualitatively verified by cyclic voltammograms that indicated the presence or absence of FeCl2 and UCl3 in the salt.
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