Cassini Composite Infrared Spectrometer Research Articles

SEASONAL CHANGES IN TITAN'S POLAR TRACE GAS ABUNDANCE OBSERVED BY CASSINI

We use a six-year data set (2004-2010) of mid-infrared spectra measured by Cassini's Composite InfraRed Spectrometer to search for seasonal variations in Titan's atmospheric temperature and composition. During most of Cassini's mission Titan's northern hemisphere has been in winter, with an intense stratospheric polar vortex highly enriched in trace gases, and a single south-to-north circulation cell. Following northern spring equinox in mid-2009, dramatic changes in atmospheric temperature and composition were expected, but until now the temporal coverage of polar latitudes has been too sparse to discern trends. Here, we show that during equinox and post-equinox periods, abundances of trace gases at both poles have begun to increase. We propose that increases in north polar trace gases are due to a seasonal reduction in gas depletion by horizontal mixing across the vortex boundary. A simultaneous south polar abundance increase suggests that Titan is now entering, or is about to enter, a transitional circulation regime with two branches, rather than the single branch circulation pattern previously observed.

Infrared limb sounding of Titan with the Cassini Composite InfraRed Spectrometer: effects of the mid-IR detector spatial responses: errata

Infrared limb sounding of Titan with the Cassini Composite InfraRed Spectrometer: effects of the mid-IR detector spatial responses: errata

High spectral resolution infrared studies of Titan: Winds, temperature, and composition

The Cassini Huygens mission provides a unique opportunity to combine ground-based and spacecraft investigations to increase our understanding of chemical and dynamical processes in Titan’s atmosphere. Spectroscopic measurements from both vantage points enable retrieving global wind structure, temperature structure, and atmospheric composition. An updated analysis of Titan data obtained with the NASA Goddard Space Flight Center’s Infrared Heterodyne Spectrometer (IRHS) and Heterodyne Instrument for Planetary Wind and Composition (HIPWAC) prior to and during the Cassini Huygens mission is compared to retrievals from measurements with the Cassini Composite Infrared Spectrometer (CIRS). IRHS/HIPWAC results include the first direct stratospheric wind measurements on Titan, constraints on stratospheric temperature, and the study of atmospheric molecular composition. These results are compared to CIRS retrievals of wind and temperature profile from thermal mapping data and ethane abundance at 10–15° South latitude, near the equatorial region. IRHS/HIPWAC wind results are combined with other direct techniques, stellar occultation measurements, and CIRS results to explore seasonal variability over nearly one Titan year and to provide an empirical altitude profile of stratospheric winds, varying from ∼50 to 210 m/s prograde. The advantage of fully resolved line spectra in species abundance measurements is illustrated by comparing the possible effect on retrieved ethane abundance by blended spectral features of other molecular constituents, e.g., acetylene (C 2H 2), ethylene (C 2H 4), allene (C 3H 4), and propane (C 3H 8), which overlap the ν 9 band of ethane, and are not resolved at lower spectral resolution. IR heterodyne spectral resolution can discriminate weak spectral features that overlap the ν 9 band of ethane, enabling ethane lines alone to be used to retrieve abundance. Titan’s stratospheric mean ethane mole fraction (8.6±3 ppmv) retrieved from IRHS/HIPWAC emission line profiles (resolving power λ⧸Δ λ∼10 6) is compared to past values obtained from lower resolution spectra and from CIRS measurements (resolving power λ⧸Δ λ∼2×10 3) and more compatible recent analysis. Results illustrate how high spectral resolution ground-based studies complement the spectral and spatial coverage and resolution of moderate spectral resolution space-borne spectrometers.

A multilayer model for thermal infrared emission of Saturn’s rings II: Albedo, spins, and vertical mixing of ring particles inferred from Cassini CIRS

Since the Saturn orbit insertion of the Cassini spacecraft in mid-2004, the Cassini composite infrared spectrometer (CIRS) measured temperatures of Saturn’s main rings at various observational geometries. In the present study, we apply our new thermal model (Morishima, R., Salo, H., Ohtsuki, K. [2009]. Icarus 201, 634–654) for fitting to the early phase Cassini data (Spilker, L.J., and 11 colleagues [2006]. Planet. Space Sci. 54, 1167–1176). Our model is based on classical radiative transfer and takes into account the heat transport due to particle motion in the azimuthal and vertical directions. The model assumes a bimodal size distribution consisting of small fast rotators and large slow rotators. We estimated the bolometric Bond albedo, A V, the fraction of fast rotators in cross section, f fast, and the thermal inertia, Γ, by the data fitting at every radius from the inner C ring to the outer A ring. The albedo A V is 0.1–0.4, 0.5–0.7, 0.4, 0.5 for the C ring, the B ring, the Cassini division, and the A ring, respectively. The fraction f fast depends on the ratio of scale height of fast rotators to that of slow rotators, h r. When h r = 1, f fast is roughly half for the entire rings, except for the A ring, where f fast increases from 0.5 to 0.9 with increasing saturnocentric radius. When h r increases from 1 to 3, f fast decreases by 0.2–0.4 for the B and A rings while no change in f fast is seen for the optically thin C ring and Cassini division. The large f fast seen in the outer A ring probably indicates that a large number of small particles detach from large particles in high velocity collisions due to satellite perturbations or self-gravity wakes. The thermal inertia, Γ, is constrained from the efficiency of the vertical heat transport due to particle motion between the lit and unlit faces, and is coupled with the type of vertical motion. We found that in most regions, except for the mid B ring, sinusoidal vertical motion without bouncing is more reasonable than cycloidal motion assuming bouncing at the midplane, because the latter motion gives too large Γ as compared with previous estimations. For the mid B ring, where the optical depth is highest in Saturn’s rings, cycloidal vertical motion is more reasonable than sinusoidal vertical motion which gives too small Γ.

Seasonal change on Saturn from Cassini/CIRS observations, 2004–2009

Five years of thermal infrared spectra from the Cassini Composite Infrared Spectrometer (CIRS) are analyzed to determine the response of Saturn’s atmosphere to seasonal changes in insolation. Hemispheric mapping sequences at 15.0 cm −1 spectral resolution are used to retrieve the variation in the zonal mean temperatures in the stratosphere (0.5–5.0 mbar) and upper troposphere (75–800 mbar) between October 2004 (shortly after the summer solstice in the southern hemisphere) and July 2009 (shortly before the autumnal equinox). Saturn’s northern mid-latitudes show signs of dramatic warming in the stratosphere (by 6–10 K) as they emerge from ring-shadow into springtime conditions, whereas southern mid-latitudes show evidence for cooling (4–6 K). The 40-K asymmetry in stratospheric temperatures between northern and southern hemispheres (at 1 mbar) slowly decreased during the timespan of the observations. Tropospheric temperatures also show temporal variations but with a smaller range, consistent with the increasing radiative time constant of the atmospheric response with increasing pressure. The tropospheric response to the insolation changes shows the largest magnitude at the locations of the broad retrograde jets. Saturn’s warm south-polar stratospheric hood has cooled over the course of the mission, but remains present. Stratospheric temperatures are compared to a radiative climate model which accounts for the spatial distribution of the stratospheric coolants. The model successfully predicts the magnitude and morphology of the observed changes at most latitudes. However, the model fails at locations where strong dynamical perturbations dominate the temporal changes in the thermal field, such as the hot polar vortices and the equatorial semi-annual oscillation (Orton, G., and 27 colleagues [2008]. Nature 453, 196–198). Furthermore, observed temperatures in Saturn’s ring-shadowed regions are larger than predicted by all radiative-climate models to date due to the incomplete characterization of the dynamical response to the shadow. Finally, far-infrared CIRS spectra are used to demonstrate variability of the para-hydrogen distribution over the 5-year span of the dataset, which may be related to observed changes in Saturn’s tropospheric haze in the spring hemisphere.

Titan's prolific propane: The Cassini CIRS perspective

Although propane gas ( C 3 H 8 ) was first detected in the stratosphere of Titan by the Voyager IRIS infrared spectrometer in 1980, obtaining an accurate measurement of its abundance has proved difficult. All existing measurements have been made by modeling the ν 26 band at 748 cm - 1 : however, different analyzes over time have yielded quite different results, and it also suffers from confusion with the strong nearby ν 5 band of acetylene. In this paper we select large spectral averages of data from the Cassini Composite Infrared Spectrometer (CIRS) obtained in limb-viewing mode at low latitudes (30 ∘ S–30 ∘ N), greatly increasing the path length and hence signal-to-noise ratio for optically thin trace species such as propane. By modeling and subtracting the emissions of other gas species, we demonstrate that at least six infrared bands of propane are detected by CIRS, including two not previously identified in Titan spectra. Using a new linelist for the range 1300–1400 cm - 1 , along with an existing GEISA list, we retrieve propane abundances from two bands at 748 and 1376 cm - 1 . At 748 cm - 1 we retrieve 4.2 ± 0.5 × 10 - 7 ( 1 - σ error) at 2 mbar, in good agreement with previous studies, although lack of hotbands in the present spectral atlas remains a problem. We also determine 5.7 ± 0.8 × 10 - 7 at 2 mbar from the 1376 cm - 1 band — a value that is probably affected by systematic errors including continuum gradients due to haze and also an imperfect model of the ν 6 band of ethane. This study clearly shows for the first time the ubiquity of propane's emission bands across the thermal infrared spectrum of Titan, and points to an urgent need for further laboratory spectroscopy work, both to provide the line positions and intensities needed to model these bands, and also to further characterize haze spectral opacity. The present lack of accurate modeling capability for propane is an impediment not only for the measurement of propane itself, but also for the search for the emissions of new molecules in many spectral regions.

Infrared limb sounding of Titan with the Cassini Composite InfraRed Spectrometer: effects of the mid-IR detector spatial responses

The composite infrared spectrometer (CIRS) instrument on board the Cassini Saturn orbiter employs two 1x10 HgCdTe detector arrays for mid-infrared remote sensing of Titan's and Saturn's atmospheres. In this paper we show that the real detector spatial response functions, as measured in ground testing before launch, differ significantly from idealized "boxcar" responses. We further show that neglecting this true spatial response function when modeling CIRS spectra can have a significant effect on interpretation of the data, especially in limb-sounding mode, which is frequently used for Titan science. This result has implications not just for CIRS data analysis but for other similar instrumental applications.

Mapping potential vorticity dynamics on saturn: Zonal mean circulation from Cassini and Voyager data

Maps of Ertel potential vorticity on isentropic surfaces (IPV) and quasi-geostrophic potential vorticity (QGPV) are well established in dynamical meteorology as powerful sources of insight into dynamical processes involving ‘balanced’ flow (i.e. geostrophic or similar). Here we derive maps of zonal mean IPV and QGPV in Saturn's upper troposphere and lower stratosphere by making use of a combination of velocity measurements, derived from the combined tracking of cloud features in images from the Voyager and Cassini missions, and thermal measurements from the Cassini Composite Infrared Spectrometer (CIRS) instrument. IPV and QGPV are mapped and compared for the entire globe between latitudes 89 ∘ S – 82 ∘ N . As on Jupiter, profiles of zonally averaged PV show evidence for a step-like “stair-case” pattern suggestive of local PV homogenisation, separated by strong PV gradients in association with eastward jets. The northward gradient of PV (IPV or QGPV) is found to change sign in several places in each hemisphere, however, even when baroclinic contributions are taken into account. The stability criterion with respect to Arnol’d's second stability theorem may be violated near the peaks of westward jets. Visible, near-IR and thermal-IR Cassini observations have shown that these regions exhibit many prominent, large-scale eddies and waves, e.g. including ‘storm alley’. This suggests the possibility that at least some of these features originate from instabilities of the background zonal flow.

Dynamical implications of seasonal and spatial variations in Titan's stratospheric composition

Titan's diverse inventory of photochemically produced gases can be used as tracers to probe atmospheric circulation. Since the arrival of the Cassini-Huygens mission in July 2004 it has been possible to map the seasonal and spatial variations of these compounds in great detail. Here, we use 3.5 years of data measured by the Cassini Composite InfraRed Spectrometer instrument to determine spatial and seasonal composition trends, thus providing clues to underlying atmospheric motions. Titan's North Pole (currently in winter) displays enrichment of trace species, implying subsidence is occurring there. This is consistent with the descending branch of a single south-to-north stratospheric circulation cell and a polar vortex. Lack of enrichment in the south over most of the observed time period argues against the presence of any secondary circulation cell in the Southern Polar stratosphere. However, a residual cap of enriched gas was observed over the South Pole early in the mission, which has since completely dissipated. This cap was most probably due to residual build-up from southern winter. These observations provide new and important constraints for models of atmospheric photochemistry and circulation.

Endogenic heat from Enceladus' south polar fractures: New observations, and models of conductive surface heating

Linear features dubbed “tiger stripes” in the south polar region of Enceladus have anomalously high heat fluxes and are the apparent source of the observed plume. Several explanations for the observed activity have been proposed, including venting from a subsurface reservoir of liquid water, sublimation of surface ice, dissociation of clathrates, and shear heating. Thermal modeling presented in this work, coupled with observations from the Cassini Composite Infrared Spectrometer (CIRS) instrument, seeks to elucidate the underlying physical mechanism by constraining vent temperatures and thermal emission sources, using a model in which the observed thermal signature results primarily from conductive heating of the surface by warm subsurface fractures. The fractures feed surface vents, which may themselves contribute to the observed thermal emission. Model variables include vent temperature, presence of a surface insulating layer, vent width, time-variable heat input, and heat sources other than the central vent. Results indicate that CIRS spectra are best fitted with a model in which the surface is heated by narrow vents at temperatures as high as 223 K. Although equally good fits can be obtained for vent temperatures in the range of 130 to 155 K if the vents are wider (180 m and 22 m respectively) and dominate the emission spectrum, these models are probably less realistic because vents with these temperatures and widths cannot supply the observed H 2O vapor flux. The lack of emission angle dependence of the thermal emission when July 2005 and November 2006 CIRS observations are compared also argues against thermal emission being dominated by the vents themselves. Thus, results favor high-temperature models, possibly venting from a subsurface liquid water reservoir. However, a fracture filled with liquid water near the surface would produce significantly higher radiances than were detected unless masked by a thermally insulating surface layer. Models that best match the CIRS data are characterized by small fractions of the surface at high temperatures, which strengthens the case for the vents and/or their conductively-heated margins being the primary heat source. Models where the thermal emission is dominated by conductive heating of the surface from below by a laterally-extensive buried heat source cannot reproduce the observed spectrum. Models with a 10 cm thick upper insulating layer produce a poor match to the CIRS spectra, suggesting high thermal inertias near the tiger stripes. Finally, tiger stripe thermal emission measured by CIRS varied by less than 15% over the 16 month period from July 2005 to November 2006.

Isotopic Ratios in Titan's Atmosphere from Cassini CIRS Limb Sounding: HC 3 N in the North

This Letter reports the first detection of the three 13C isotopologues of HC3N on Titan, from Cassini Composite Infrared Spectrometer (CIRS) infrared spectra. The data are limb spectra taken at latitudes N54°-N69° in 2006 and 2007 when HC3N was enhanced in the north. Using a new line list for the ν5 bands of all isotopologues, we have modeled the isolated emission of H13CCCN at 658.7 cm−1 and both HC13CCN and HCC13CN at 663.0 cm−1, which are blended with the Q-branch of HC3N at 663.3 cm−1 at the resolution of CIRS (0.5 cm−1) and detectable as an increase in the intensity of the low-frequency wing. Using the resolved pair H13CCCN/HC3N we find 12C/13C = 79 ± 17, in line with other measurements on Titan from Cassini and Huygens.

Isotopic Ratios in Titan's Atmosphere from Cassini CIRS Limb Sounding: CO 2 at Low and Midlatitudes

This Letter reports on a search for infrared emissions of isotopologues of CO2 in the atmosphere of Titan using spectral data recorded by the Cassini Composite Infrared Spectrometer (CIRS). We have made a successful 6.5 σ detection of 13CO2 at a fraction CO2/13CO2 = 84 ± 17, consistent with measurements of 12C/13C in other species, and also the terrestrial value (89). We also find a probable 3.5 σ detection of C16O18O at a fraction CO2/C16O18O = 173 ± 55, slightly lower than the terrestrial value (253) and consistent with the twofold enhancement in 18O reported previously in CO, or with an intermediate value as suggested by chemistry. These isotopic ratios provide important constraints on models of the formation, evolution, and current processes in Titan's atmosphere.

The 12C/ 13C isotopic ratio in Titan hydrocarbons from Cassini/CIRS infrared spectra

We have analyzed infrared spectra of Titan recorded by the Cassini Composite Infrared Spectrometer (CIRS) to measure the isotopic ratio 12C/ 13C in each of three chemical species in Titan's stratosphere: CH 4, C 2H 2 and C 2H 6. This is the first measurement of 12C/ 13C in any C 2 molecule on Titan, and the first measurement of 12CH 4/ 13CH 4 (non-deuterated) on Titan by remote sensing. Our spectra cover five widely-spaced latitudes, 65° S to 71° N and we have searched for both latitude variability of 12C/ 13C within a given species, and also for differences between the 12C/ 13C in the three gases. For CH 4 alone, we find C 12 / C 13 = 76.6 ± 2.7 (1- σ), essentially in agreement with the 12CH 4/ 13CH 4 measured by the Huygens Gas Chromatograph/Mass Spectrometer instrument (GCMS) [Niemann, H.B., and 17 colleagues, 2005. Nature 438, 779–784]: 82.3 ± 1.0 , and also with measured values in H 13CN and 13CH 3D by CIRS at lower precision [Bézard, B., Nixon, C., Kleiner, I., Jennings, D., 2007. Icarus 191, 397–400; Vinatier, S., Bézard, B., Nixon, C., 2007. Icarus 191, 712–721]. For the C 2 species, we find C 12 / C 13 = 84.8 ± 3.2 in C 2H 2 and 89.8 ± 7.3 in C 2H 6, a possible trend of increasingly value with molecular mass, although these values are both compatible with the Huygens GCMS value to within error bars. There are no convincing trends in latitude. Combining all fifteen measurements, we obtain a value of C 12 / C 13 = 80.8 ± 2.0 , also compatible with GCMS. Therefore, the evidence is mounting that 12C/ 13C is some 8% lower on Titan than on the Earth (88.9, inorganic standard), and lower than typical for the outer planets ( 88 ± 7 [Sada, P.V., McCabe, G.H., Bjoraker, G.L., Jennings, D.E., Reuter, D.C., 1996. Astrophys. J. 472, 903–907]). There is no current model for this enrichment, and we discuss several mechanisms that may be at work.

Heat balance in Titan's atmosphere

The recent measurements of the vertical distribution and optical properties of haze aerosols as well as of the absorption coefficients for methane at long paths and cold temperatures by the Huygens entry probe of Titan permit the computation of the solar heating rate on Titan with greater certainty than heretofore. We use the haze model derived from the Descent Imager/Spectral Radiometer (DISR) instrument on the Huygens probe [Tomasko, M.G., Doose, L., Engel, S., Dafoe, L.E., West, R., Lemmon, M., Karkoschka, E., See, C., 2008a. A model of Titan's aerosols based on measurements made inside the atmosphere. Planet. Space Sci., this issue, doi:10.1016/j.pss.2007.11.019] to evaluate the variation in solar heating rate with altitude and solar zenith angle in Titan's atmosphere. We find the disk-averaged solar energy deposition profile to be in remarkably good agreement with earlier estimates using very different aerosol distributions and optical properties. We also evaluated the radiative cooling rate using measurements of the thermal emission spectrum by the Cassini Composite Infrared Spectrometer (CIRS) around the latitude of the Huygens site. The thermal flux was calculated as a function of altitude using temperature, gas, and haze profiles derived from Huygens and Cassini/CIRS data. We find that the cooling rate profile is in good agreement with the solar heating profile averaged over the planet if the haze structure is assumed the same at all latitudes. We also computed the solar energy deposition profile at the 10°S latitude of the probe-landing site averaged over one Titan day. We find that some 80% of the sunlight that strikes the top of the atmosphere at this latitude is absorbed in all, with 60% of the incident solar energy absorbed below 150 km, 40% below 80 km, and 11% at the surface at the time of the Huygens landing near the beginning of summer in the southern hemisphere. We compare the radiative cooling rate with the solar heating rate near the Huygens landing site averaging over all longitudes. At this location, we find that the solar heating rate exceeds the radiative cooling rate by a maximum of 0.5 K/Titan day near 120 km altitude and decreases strongly above and below this altitude. Since there is no evidence that the temperature structure at this latitude is changing, the general circulation must redistribute this heat to higher latitudes.

Infrared observations of Saturn's rings by Cassini CIRS : Phase angle and local time dependence

Since the Saturn orbit insertion (SOI) of the Cassini spacecraft, in July 2004, the Cassini Composite Infrared Spectrometer (CIRS) has obtained a large number of thermal infrared spectra of Saturn's rings. Over the two and a half years of observations to date, ring temperatures were retrieved for a large range of unique geometries, inaccessible from Earth. Understanding their dependencies with phase angle and local time is a clue to understanding the thermal properties and dynamics of Saturn's ring particles. Azimuthal scans of rings, which have been obtained by CIRS at constant radial distance from the planet, have been planned to measure ring temperature variations with local hour angle. Over 47 azimuthal scans for Saturn's main rings (A, B, C and Cassini Division) have been retrieved to date, on both lit and unlit sides, at different phase angles and spacecraft elevations. The first measurements of the transient thermal episode of eclipse cooling in the planetary shadow have also been obtained for all three rings. In this paper, we present an overview of all azimuthal scans obtained by the Cassini/CIRS instrument so far and the dependencies of the temperature and the filling factor with the phase angle and the local hour angle. The ring temperature varies with longitude as the input heating flux coming from Saturn and the Sun changes. The decrease in temperature with the increasing phase angle on both the lit and the unlit sides and for most of the local time also suggests the presence of slowly rotating particles. The crossing of the planet's shadow generates drastic azimuthal variations in temperature, up to 20 K in the C ring. The strong anisotropy of emission observed outside the shadow between low and high phase angles decreases when ring particles cross the shadow, suggesting that particles are almost isothermal in the shadow. This suggests a thermal inertia associated with a rotating rate of particles low enough to have a thermal contrast on their surface. The temperature in the B ring is less sensitive to the phase angle effect on the lit side, suggesting that particles are close enough to form a flat layer at a scale larger than the particle's radius. On the unlit side, particles in the B ring are less sensitive to the lack of solar input than in the C ring or in the A ring. Azimuthal variations of the filling factor in the A ring are also detected with changing ring local time. This effect might be created by the presence of gravitational instabilities (wakes).

Thermal observations of Saturn's main rings by Cassini CIRS: Phase, emission and solar elevation dependence

Two and a half years after Saturn orbit insertion (SOI) the Cassini composite infrared spectrometer (CIRS) has acquired an extensive set of thermal measurements (including physical temperature and filling factor) of Saturn's main rings for a number of different viewing geometries, most of which are not available from Earth. Thermal mapping of both the lit and unlit faces of the rings is being performed within a multidimensional observation space that includes solar phase angle, spacecraft elevation and solar elevation. Comprehensive thermal mapping is a key requirement for detailed modeling of ring thermal properties. To first order, the largest temperature changes on the lit face of the rings are driven by variations in phase angle while differences in temperature with changing spacecraft elevation are a secondary effect. Ring temperatures decrease with increasing phase angle suggesting a population of slowly rotating ring particles [Spilker, L.J., Pilorz, S.H., Wallis, B.D., Pearl, J.C., Cuzzi, J.N., Brooks, S.M., Altobelli, N., Edgington, S.G., Showalter, M., Michael Flasar, F., Ferrari, C., Leyrat, C. 2006. Cassini thermal observations of Saturn's main rings: implications for particle rotation and vertical mixing. Planet. Space Sci. 54, 1167–1176, doi: 10.1016/j.pss.2006.05.033]. Both lit A and B rings show that temperature decreases with decreasing rings solar elevation while temperature changes in the C ring and Cassini Division are more muted. Variations in the geometrical filling factor, β , are primarily driven by changes in spacecraft elevation. For the optically thinnest region of the C ring, β variations are found to be nearly exclusively determined by spacecraft elevation. Both a multilayer and a monolayer model provide an excellent fit to the data in this region. In both cases, a ring infrared emissivity > 0.9 is required, together with a random and homogeneous distribution of the particles. The interparticle shadowing function required for the monolayer model is very well constrained by our data and matches experimental measurements performed by Froidevaux [1981a. Saturn's rings: infrared brightness variation with solar elevation. Icarus 46, 4–17].

Global and temporal variations in hydrocarbons and nitriles in Titan's stratosphere for northern winter observed by Cassini/CIRS

Mid-infrared spectra measured by Cassini's Composite InfraRed Spectrometer (CIRS) between July 2004 and January 2007 ( L s = 293 ° – 328 ° ) have been used to determine stratospheric temperature and abundances of C 2H 2, C 3H 4, C 4H 2, HCN, and HC 3N. Over 65,000 nadir spectra with spectral resolutions of 0.5 and 2.5 cm −1 were used to probe spatial and temporal composition variations in Titan's stratosphere. Cassini's 180° orbital transfer in mid-2006 allowed low emission angle observations of the north polar region for the first time in the mission and allowed us to probe the full latitude range. We present the first measurements of composition variations within the polar vortex, which display increasing abundances right up to 90° N. The lack of a homogeneous abundance–latitude variation within the vortex indicates limited horizontal mixing and suggests that subsidence is greatest at the vortex core. Contrary to numerical model predictions and tropospheric cloud observations, we do not see any evidence for a secondary circulation cell near the south pole, which suggests a single Hadley-type circulation in the stratosphere at this epoch. This difference can be reconciled if the secondary cell is restricted to altitudes below 100 km, where there is no sensitivity in our data. Temporal variations in composition were observed in the south, with volatile species becoming less abundant as the season progressed. The observed variations are compared to numerical model predictions and observations from Voyager.

Characteristics of Titan's stratospheric aerosols and condensate clouds from Cassini CIRS far-infrared spectra

Four broad spectral features were identified in far-infrared limb spectra from the Cassini Composite Infrared Spectrometer (CIRS), two of which have not been identified before. The features are broader than the spectral resolution, which suggests that they are caused by particulates in Titan's stratosphere. We derive here the spectral properties and variations with altitude for these four features for six latitudes between 65° S and 85° N. Titan's main aerosol is called Haze 0 here. It is present at all wavenumbers in the far-infrared and is found to have a fractional scale height (i.e., the aerosol density scale height divided by the atmospheric density scale height) between 1.5 and 1.7 with a small increase in opacity in the north. A second feature around 140 cm −1 (Haze A) has similar spatial properties to Haze 0, but has a smaller fractional scale height of 1.2–1.3. Both Haze 0 and Haze A show an increase in retrieved abundance below 100 km. Two other features (Haze B around 220 cm −1 and Haze C around 190 cm −1) have a large maximum in their density profiles at 140 and 90 km, respectively. Haze B is much more abundant in the northern hemisphere compared to the southern hemisphere. Haze C also shows a large increase towards the north, but then disappears at 85° N.

The meridional phosphine distribution in Saturn's upper troposphere from Cassini/CIRS observations

The Cassini Composite Infrared Spectrometer (CIRS) has been used to derive the vertical and meridional variation of temperature and phosphine (PH 3) abundance in Saturn's upper troposphere. PH 3 has a significant effect on the measured radiances in the thermal infrared and between May 2004 and September 2005 CIRS recorded thousands of spectra in both the far (10–600 cm −1) and mid (600–1400 cm −1) infrared, at a variety of latitudes covering the southern hemisphere. Low spectral resolution (15 cm −1) data has been used to constrain the temperature structure of the troposphere between 100 and 500 mbar. The vertical distributions of phosphine and ammonia were retrieved from far-infrared spectra at the highest spectral resolution (0.5 cm −1), and lower resolution (2.5 cm −1) mid-infrared data were used to map the meridional variation in the abundance of phosphine in the 250–500 mbar range. Temperature variations at the 250 mbar level are shown to occur on the same scale as the prograde and retrograde jets in Saturn's atmosphere [Porco, C.C., and 34 colleagues, 2005. Science 307, 1243–1247]. The PH 3 abundance at 250 mbar is found to be enhanced at the equator when compared with mid-latitudes. At mid latitudes we see anti-correlation between temperature and PH 3 abundance at 250 mbar, phosphine being enhanced at 45° S and depleted at 25 and 55° S. The vertical distribution is markedly different polewards of 60–65° S, with depleted PH 3 at 500 mbar but a slower decline in abundance with altitude when compared with the mid-latitudes. This variation is similar to the variations of cloud and aerosol parameters observed in the visible and near infrared, and may indicate the subsidence of tropospheric air at polar latitudes, coupled with a diminished sunlight penetration depth reducing the rate of PH 3 photolysis in the polar region.

New upper limits for hydrogen halides on Saturn derived from Cassini-CIRS data

Far infrared spectra (10–600 cm −1) from Cassini's Composite InfraRed Spectrometer (CIRS) were used to determine improved upper limits of hydrogen halides HF, HCl, HBr, and HI in Saturn's atmosphere. Three observations, comprising a total of 3088 spectra, gave 3 σ upper limits on HF, HCl, HBr, and HI volume mole fractions of 8.0 × 10 −12 , 6.7 × 10 −11 , 1.3 × 10 −10 , and 1.4 × 10 −9 , respectively, at the 500 mbar pressure level. These upper limits confirm sub-solar abundances of halide species for HF, HCl, and HBr in Saturn's upper atmosphere—consistent with predictions from thermochemical models and influx of material from meteoroids. Our upper limit for HCl is 16 times lower than the tentative detection at 1.1 × 10 −9 reported by Weisstein and Serabyn [Weisstein, E.W., Serabyn, E., 1996. Icarus 123, 23–36]. These observations are not sensitive to the deep halide abundance, which is expected to be enriched relative to the solar composition.