Cassie State Research Articles

Wetting Transition from Wenzel to Cassie States: Thermodynamic Analysis

Superhydrophobicity is closely linked to the chemical composition and geometric characteristics of surface roughness. Building on our structural studies on water and air–water interfaces, this work aims to elucidate the mechanism underlying the wetting transition from the Wenzel to the Cassie state on a hydrophobic surface. In the Wenzel state, the grooves are filled with water, meaning that the surface roughness becomes embedded in the liquid. To evaluate the effects of surface roughness on water structure, a wetting parameter (WRoughness) is proposed, which is closely related to the geometric characteristics of roughness, such as pillar size, width, and height. During the wetting transition from Wenzel to Cassie states, the critical wetting parameter (WRoughness,c) may be expected, which corresponds to the critical pillar size (ac), width (wc), and height (hc). The Cassie state is expected when the WRoughness is less than WRoughness,c (<WRoughness,c), which can be achieved by altering the geometric characteristics of the roughness, such as increasing pillar size (>ac), decreasing width (<wc), or increasing height (>hc). Additionally, molecular dynamic (MD) simulations are conducted to demonstrate the effects of surface roughness on superhydrophobicity.

Stable Air Plastron Prolongs Biofluid Repellency of Submerged Superhydrophobic Surfaces.

Superhydrophobic surfaces find applications in numerous biomedical scenarios, requiring the repellence of biofluids and biomolecules. Plastron, the trapped air between a superhydrophobic surface and a wetting liquid, plays a pivotal role in biofluid repellency. A key challenge, however, is the often short-lived plastron stability in biofluids and the lack of knowledge surrounding it. Plastron stability refers to the duration for which a surface remains in the Cassie state before transitioning to the fully wetting Wenzel state. Here, a submersion test with real-time optical monitoring is used to determine the plastron lifetime of different superhydrophobic surfaces upon immersion in various biofluids. We find that biofluids of all types exhibit shorter plastron lifetimes compared to pure water, which is attributed to their lower surface tension and biomolecular adsorption through hydrophobic-hydrophobic interactions. Proteins and glucose are identified as the major contributors to plastron dissipation in fetal bovine serum-based biofluids. Plastron minimizes the solid-liquid interface, reducing biomolecular adsorption, making its stability crucial for biofluid repellence. Thus, the effects of surface texture, feature size, Cassie solid fraction, Wenzel dimensionless roughness, and surface chemistry on plastron stability are investigated. Our key findings indicate that prolonged plastron stability and thus enhanced biofluid repellency are achieved through a combination of larger plastron volumes, increased Wenzel roughness degrees, greater Cassie solid fractions, and smaller feature sizes. We demonstrate that with optimized parameters, our surface design can maintain plastron stability and sustain a consistent solid-liquid area fraction for over 120 h in complex biofluids containing high levels of protein and glucose, underscoring a robust design for long-term use in biomedical and antifouling applications. This research is essential for advancing the design of superhydrophobic surfaces that effectively resist biofouling in diverse medical and engineering settings.

Molecular Dynamics Simulation on Slippage Effect and Injection Capacity With Hydrophobic Nanoparticles Adsorption

ABSTRACTWith the continuous exploitation of global oil and gas resources, the focus of oilfield development has gradually shifted to low‐permeability and tight reservoirs. Nowadays the nanofluid has become one of the most important methods to enhance oil recovery in low‐permeability reservoir since the wettability and fluid flow characteristics can be changed as hydrophobic nanoparticles are adsorbed on the surface. In this study, we focus on the fluid slip characteristics feature of nanoparticles adsorbed with different adsorption degrees through molecular dynamics methods. Our results show that the adsorption of hydrophobic nanoparticles on the wall induces a velocity slip effect. The fluid flows in a Cassie state in the micro‐channel, with a significant increase in density, velocity, and slip length. In addition, the velocity in the mainstream area is significantly greater than that near the wall. The fluid flow rate within the pore channel is maximized and the most optimal adsorption degree is around 65.08%. Meanwhile, this study provides not only of great significance for the microscopic mechanism of pressure reduction and injection enhancement technology by nanoparticles adsorbed, but also an efficient method in enhance oil recovery in low‐permeability oil reservoirs.

Long range self-transport of liquid droplets driven by electric field and roughness gradient

It is well known that roughness and charge gradients could be used for droplet self-transport. The key issue is how to synergize the two effects. The uniform density charge can form linearly increasing charge gradient on a roughness gradient surface. Under this condition, the influence on the droplet self-transport under the synergy of these two effects was obtained by statics analysis, and the driving function was presented. An energy equation was constructed to study the conditions for crossing periodic boundaries, and the problem of distance limitation on periodic surfaces due to energy dissipation was solved by converting electric potential into droplet kinetic energy. A periodic roughness gradient surface with K = 0.07 was designed and prepared via 3D printing. Water droplets can be transported over long distances and the maximum velocity increases with charge density up to 46 mm/s. Finally, the effect of different structures on the maximum charge density in the Cassie state was investigated by simulation. The biomimetic structures exhibit great compressive stability, which can increase the surface charge density of droplets in the Cassie state by 3.6 times compared to pillar structures. It can be widely used in the fields of materials science and interface chemistry, etc.

Dropwise condensation on subcooled micropillar surfaces with 3D lattice Boltzmann method

In this investigation, an alternative geometric formula is proposed to address the force between fluid nodes and fluid ghost nodes, with the aid of which the contact angles can be varied in the range of 48.3°∼131.9°. This formula is applied to the three-dimensional double-distributed thermal lattice Boltzmann method being proved to be accurate and reliable by single droplet condensation. The effects brought by varying micropillar size on the kinetic properties of condensed droplets, including nucleation, growth, coalescence and jumping, are investigated in detail. The results show that the droplet wetting state tends to be the suspended Cassie state as the width and spacing of the micropillars are decreased, and the condensed droplets can merge and jump off the micropillar surface. In the meantime, the average droplet number increases, the average diameter and the diameter of dominant droplets decrease, thus reducing the condensate coverage. When the micropillar spacing is small, increasing the micropillar height results in the condensed droplet state being changed from Wenzel to Cassie state, and the percentage of small droplets also increases. Instead, when the micropillar spacing is large, by increasing micropillar height, droplets can nucleate in the middle of micropillars, and the percentage of large droplets is improved due to increased heat transfer area. In this study, the surface self-cleaning capability is strongest with the combination of dimensionless pillar height 0.4, spacing 0.1 and width 0.1, which reduces the condensate coverage by 66 % compared to its plain competitor.

Functionalized super-hydrophobic nanocomposite surface integrating with anti-icing and drag reduction properties

Anti-icing and drag reduction are two significant issues for aircraft, but functional surfaces integrating both properties are rarely reported. Here, we propose a functional super-hydrophobic nanocomposite surface with sharkskin-like groove structures, which achieves the combination of anti-icing and drag reduction properties. The nanocomposite surface was prepared by stripping polydimethylsiloxane doped with carbon nanotubes from a laser-prepared sharkskin-like structure mold and then spraying a layer of polytetrafluoroethylene hydrophobic coating. The microstructures and nanoparticles with low surface energy provide the surface with hydrophobicity and icephobicity, enabling droplet transitions between Cassie and Wenzel states during icing-melting process. Carbon nanotubes enhance the Joule heating performance when voltage is applied. Ice at interface melts into water film, significantly reducing adhesion and enabling efficient anti-icing. Under the influence of the bionic sharkskin riblet structure, the vortices are lifted and pinned above the riblet tips, which reduces the near-wall velocity gradient and total wall shear stress, ultimately leading to lower drag. In addition, the flexible surface undergoes adaptive deformation to more effectively conform to the fluid flow during motion. The riblet protrusions increase the contact area between the flexible surface and the fluid, thereby enabling the absorption of more turbulent energy and fluctuations, further reduces drag. This study presents a new method for manufacturing functional surfaces for practical anti-icing and drag reduction applications.

Effect of surface micro-texture morphology on the wettability of aluminum alloy on B4C surface

Abstract To enhance the wettability of AlSi10Mg on the B4C surface, a 2D laminar two-phase flow, phase-field coupled multi-field model is utilized to investigate the effect of surface micro-texture morphology on the wettability of AlSi10Mg on B4C surfaces and optimize the morphology of the micro-texture with the best improvement of the interfacial wetting effect. The results of the study show that compared to the square texture, the conical texture has a better effect on the improvement of the wettability of the interface. The best wettability of AlSi10Mg on the B4C surface was obtained at a 1:1 depth-to-width ratio of the conical texture, and the contact angle of the Al droplet is 47.9, which is improved by 21.22% compared to that of the smooth interface. The interfacial wetting state is transformed from the Wenzel state to the Cassie state with the increasing depth-to-width ratio of the textures, and the wettability of the interface deteriorates.

Time-resolved modeling of dropwise condensation patterns formed on a nanopillared substrate

Instantaneous condensation patterns formed over a vertical nanopillared copper surface are modeled by including drop level details including nucleation, growth, coalescence, droplet jumping and gravitational instability. The vapor phase is taken to be saturated and condensation is driven by a colder wall that imposes a given degree of subcooling. The mathematical model is setup in the form of a condensation cycle, starting from drop nucleation all the way to instability followed by fresh nucleation. In view of the condensing surface being pillared, a variety of droplet morphologies are possible, including Cassie, Wenzel, and partially-wetting that depend on the prevailing condensation conditions. The degree of subcooling is varied over 1 – 28 K, covering a wide range of condensation characteristics from Cassie jumping to Wenzel flooding with increasing temperature difference. Coalescence-based droplet jumping for Cassie and partially-wetting droplet configurations are incorporated as well. Gravitational instability of the largest drop leads to sweeping along the substrate followed by surface renewal and renucleation. With this overall approach, it is possible to explicitly determine the drop-size distribution as a function of time. The entire model is multiscale in space and time, making it a computationally demanding simulation. A domain decomposition framework is used and computations are carried out in a high-performance computing system with a parallel architecture employing message passing interface (MPI). The time-resolved model has been extensively tested against experimental data reported in the literature. The partially-wetting configuration for a subcooling of 8 K has a larger average droplet size and fewer jumping events generating similar heat fluxes as for Cassie droplets at a lower degree of subcooling (ΔT = 5 K) where the average droplet size is smaller and jumping events are frequent. In addition, the Cassie state yields an enhancement factor of around 2.5 relative to a flat surface while Wenzel droplets cause flooding and need subcooling levels as high as 24 K for similar heat flux values.

Hierarchical structure on tin bronze hydrostatic bearing surfaces to achieve ultra-high Cassie stability

The hierarchical structure represents a significant approach to enhance the Cassie stability on superhydrophobic hydrostatic bearing surfaces. However, the preparation of a robust hierarchical structure on tin bronze alloy remains unknown. In the present study, a hierarchical structure comprising micro-bulges and nanowires was fabricated on a tin bronze surface, exhibiting excellent superhydrophobicity (water contact angle, WCA = 163°). In contrast to the micro-bulge structure, the hierarchical structure surface exhibited a quasi-reversible trajectory after pressure, with the WCA recovered to 161°. For the same triple-phase contact line (TPCL), a higher Laplace pressure (3640 Pa) is required to destroy the Cassie state of the hierarchical structure. Droplets on the hierarchical structure can rapidly recover to a stable Cassie state after impact. It can be verified the hierarchical structure has higher Cassie stability to resist pressure, thermal exposure, and impact. The slip lengths of the hierarchical structure in water and VG5 lubricant are 18 μm and 27 μm, respectively. The hierarchical structure preparation is straightforward, and its application to hydrostatic bearings can enhance stability.

Lattice Boltzmann study of droplet dynamic behaviors impinging on textured surfaces under an external electric field

Textured surfaces contribute to enhancing the cooling effectiveness of electrostatic spray, while the droplet impacting dynamics on such substrates under the influence of electric field are crucial for cooling efficiency. This study utilized a multiphase lattice Boltzmann method combined with the leaky dielectric model to systematically examine the dynamics of droplet impingement on textured surfaces when exposed to electric field. The impact of Weber number, microstructural surface parameters, and electric field strength on droplet impact behavior was discussed in detail. Simulation outcomes reveal that, without the presence of an electric field, the impingement of droplets on textured surfaces results in three distinct deposition states: the Cassie state, partial penetration state, and Wenzel state, primarily contingent upon the surface solid fraction and the droplet impingement velocity. In the Cassie impact regime influenced by an applied electric field, the droplet spreading behaviors exhibit minimal sensitivity to the electric field, with surface tension and inertia primarily governing the spreading dynamics. Throughout the retraction stage, the droplet elongated the direction of the electric field as a result of electric field forces, and eventually, as the electric field strength grows, it bounces off the surface. In the Wenzel impact regime, as the strength of the electric field escalates, the droplet undergoes upward stretching and splits into satellite droplets during the retraction phase, attributed to the dynamic pressure and electrostatic pressure at the apex exceeding the capillary pressure and gravity. These findings could aid in advancing electrostatic spray cooling technology.

Understanding wetting behaviors on rough PTFE surfaces towards n-octane/water mixture separation by molecular dynamics simulation

The wetting behaviors of pure n-octane and water nanodroplets on rectangular pitted, grooved, and rectangular pillared polytetrafluoroethylene (PTFE) surfaces were examined by molecular dynamics simulation. The results showed that the three rough surfaces could achieve superlipophilicity and near superhydrophobicity by changing the rough morphology of surface. The n-octane droplets always presented the Wenzel state on the rough surfaces, and the water droplets were the Wenzel state, Transition state and Cassie state under different phase area fractions and/or roughness factors. Based on completely opposite wetting properties of the two droplets on the same surface, separation performances of mixture nanodroplets were further studied on the three rough PTFE surfaces. The results showed that the n-octane/water separation efficiency of pillared surface was above 98.4 %, significantly higher than those of pitted and grooved surfaces. The rough PTFE surface with special wettability enabled efficient separation of oil/water mixture. This work is expected to pave the way for the rational design and industrial application of oil/water separation materials.

Interfacial structure and properties of anodized 6061 Al alloy joints by ultrasonic-assisted hot dipping and soldering using a Sn–9Zn–2Al filler metal

Al alloy joints soldered with Sn-based filler metal are susceptible to corrosion and early failure when exposed to moisture, resulting in severe accidents and substantial economic losses. This study proposes a method to prevent galvanic corrosion by separating Al alloys and Sn-based filler metals with an insulating barrier layer of anodized aluminum oxide (AAO) composed of Al2O3. The successful joining of anodized aluminum alloy (AAA) with Sn–9Zn–2Al was achieved through ultrasonic-assisted hot dipping and soldering in air at 240 °C. Microstructural examination revealed strong bonding between the solder alloy and AAO, with the solder infiltrating the AAO nanotubes and a transition layer consisting of two sublayers at the interface: amorphous ZnO mixed with nanocrystals (ZnO and Al2O3) and amorphous Al2O3. The shear strength of the joints ranged from 31.8 to 32.8 MPa when subjected to ultrasonic hot dipping for 0.5–2.0 s, with no significant difference observed. Fracture initiation and propagation occur within the transition layer at the interface. The shear strength of joints subjected to dipping for more than 3.0 s decreased slightly to 27.9 MPa due to localized peeling off of AAO from the Al substrate. The formation of the interface involves the segregation of Al and Zn on the liquid filler metal surface, driven by differences in atomic activity. Due to the jet force from cavitation, an Al-rich liquid infiltrates the nanotube, resulting in the formation of Zn–O at the interface and Al–O both at the interface and within the nanotube. Throughout this process, the wetting model shifts from a Cassie state to a near-Wenzel state. Immersion tests of two types of joints, Al/SnZnAl/Al and AAA/SnZnAl/AAA, confirmed that galvanic corrosion of Sn/Al was completely inhibited by the latter. Consequently, AAA joints demonstrate excellent corrosion resistance, validating this approach as a promising solution to the Al/Sn galvanic corrosion issue.

Micro- and Nanoengineered Metal Additively Manufactured Surfaces for Enhanced Anti-Frosting Applications.

The greater geometrical design freedom offered by additive manufacturing (AM) as compared to the conventional manufacturing method has attracted increasing interest in AM to develop innovative and complex designs for enhanced performance. However, the difference in material composition and surface properties from conventional alloys has made surface micro-/nanostructuring of AM metals challenging. Frost accretion is a safety hazard in numerous engineering applications. To expand the application of AM, this study experimentally investigates the antifrosting performance of superhydrophobic and slippery lubricant-infused porous surfaces (SLIPSs) generated on AM alloy, AlSi10Mg. By strategically utilizing the subgrain structure in the metallography of the AM alloy, the functionalized superhydrophobic AM surface featuring hierarchical structures was shown to greatly reduce frost formation as compared to functionalized single-tier structured surfaces, hierarchical structures formed on conventional aluminum alloy surfaces, and SLIPSs. Optical observation of frost propagation demonstrated that the mechanism of frost delay is governed by the inhibition of spontaneous droplet freezing through exceptional Cassie state stability during condensation frosting. The Cassie stability results from the unique AM structure morphology, which creates a higher structural energy barrier to prevent condensate from infiltrating the cavities. This phenomenon also enables the formation of a high surface-to-droplet thermal resistance, which eliminates spontaneous droplet freezing down to a -15 °C surface temperature. Our work demonstrates a scalable structuring method for AM metals, which can result in delayed frost formation, and it also provides guidelines for the development of engineered surfaces requiring the antifrosting function for several industries.

Unconventional Dually-Mobile Superrepellent Surfaces.

The ability of water droplets to move freely on superrepellent surfaces is a crucial feature that enables effective liquid repellency. Common superrepellent surfaces allow free motion of droplets in the Cassie state, with the liquid resting on the surface textures. However, liquid impalement into the textures generally leads to a wetting transition to the Wenzel state and droplet immobilization on the surface, thereby destroying the liquid repellency. This study reports the creation of a novel type of superrepellent surface through rational structural control combined with liquid-like surface chemistry, which allows for the free movement of water droplets and effective repellency in both the Cassie and Wenzel states. Theoretical guidelines for designing such surfaces are provided, and experimental results are consistent with theoretical analysis. Furthermore, this work demonstrates the enhanced ice resistance of the dually-mobile superrepellent surfaces, along with their distinctive self-cleaning capability to eliminate internal contaminants. This study expands the understanding of superrepellency and offers new possibilities for the development of repellent surfaces with exceptional anti-wetting properties.

Long-Term Inhibiting Salt Crystallization on Photothermal Sheet by a Superhydrophobic CNT Composite Coating

Heterogeneous crystallization resulted in low conversion efficiency and short service life has become one of the important challenges of desalination. Here, a fluoro-modified CNT@epoxy composite coating is developed to durably inhibit salt crystallization of photothermal sheet even in highly concentrated salt water. Typically, it can have stable evaporation efficiency of [Formula: see text] without salt crystallization after continuously being operated for 40 cycles under one solar intensity in the 20[Formula: see text]wt.% NaCl solution. That is mainly due to the Cassie state superhydrophobicity that can large increase the heterogeneous nucleation barrier quite close to the homogeneous one in salt water. This study expects to solve the existing problems of complex structure and short service time of seawater desalination units.

Transition of Liquid Drops on Microstructured Hygrophobic Surfaces from the Impaled Wenzel State to the "Fakir" Cassie-Baxter State.

Low adhesion of liquids on solid surfaces can be achieved with protrusions that minimize the contact area between the liquid and the solid. The wetting state where an air cushion forms under the drop is known as the Cassie-Baxter state. Surfaces where liquids form macroscopic contact angles above 150° are called superhydrophobic and superhygrophobic, if we refer to water or any liquid, respectively. The Cassie state is desirable for applications, but it is usually unstable compared to the Wenzel state, where the drop is in direct contact with the rough surface. The Cassie-to-Wenzel transition can be triggered by an increase in pressure and vibrations, but the inverse Wenzel-to-Cassie is much more difficult to observe. Here, we examine under what conditions the Wenzel-to-Cassie transition is triggered when the microscopic contact angle changes abruptly. For this, we applied a lubricant of low surface tension around drops that were in the Wenzel state on microstructured surfaces. The increase of the microscopic contact angle lifted the drop from the rough surface, when the pillar height and spacing are large and small, respectively. Numerical calculations for the drop-lubricant interface showed that the surface geometry requirements for the Wenzel-to-Cassie transition are stricter than the ones for the stability of the Cassie state. A surface geometry where the Cassie state is more stable than the Wenzel for a given Laplace pressure of the drop may not always allow the Wenzel-to-Cassie transition to take place. Therefore, the stability of the Cassie state is a necessary but insufficient condition for the inverse transition.

Exploiting intermediate wetting on superhydrophobic surfaces for efficient icing prevention

HypothesisSuperhydrophobic surfaces can effectively prevent the freezing of supercooled droplets in technological systems. Droplets on superhydrophobic surfaces commonly not only wet the top asperities (Cassie State), but also partially penetrate into microstructure due to surface properties, environment, and droplet impact occurring in real-world applications. Implications on ice nucleation can be expected and are little explored. It remains elusive how anti-icing surfaces can be designed to exploit intermediate wetting phenomena. ExperimentsWe utilized engineered micro-/nanostructures, specifically micropillars, to modulate the wetting fraction in the microstructure. The behavior of intermediate wetting with supercooling and resulting implications on ice nucleation delay when potential nucleation sites are formed in the microcavities were investigated using experimental, theoretical, and simulation components. FindingsThe temperature-dependent wetting fraction in the microstructure increased at supercooled temperatures, partly activated by condensation in the microcavities. At −10/−20 °C, a critical wetting fraction led to maximum ice nucleation delays, with experimental results consistent with theoretical predictions. This critical wetting fraction minimized the effective contact area solid-to-liquid along the partially wetted microstructure. The study establishes physical relations between ice nucleation delays, geometrical surface parameters and wettability properties in the intermediate wetting regime, providing guidance for the design of ice resistant microstructured surfaces.

Lotus leaf inspired hierarchical micro-nano structure on NdYbZr2O7 ceramic pellet with enhanced volcanic ash repellence

Volcanic ash dispersed in the air adheres to thermal barrier coatings (TBCs) on the hot section components of gas turbines, posing a severe threat to aviation safety. Here, we report a novel strategy inspired by lotus leaf for mitigating the molten volcanic ash adhesion and corrosion. A hierarchical micro-nano structure composed of arrayed micro-conoids and numerous nanoparticles were constructed on the surface of NdYbZr2O7 ceramic pellet by ultrafast laser direct writing technology, whose morphology could be changed by optimizing the processing parameters. The laser-ablated pellet exhibits larger contact angle of molten volcanic ash than the original one, revealing an enhanced resistance repelling volcanic ash. This phenomenon is primarily attributed to the air trapped in the micro-grooves, together with these nanoparticles. Note that the evolution of viscous force and capillary force with time accelerates the transition of molten volcanic ash from the Cassie state to the Wenzel state and reduces its contact angle. Also, this structure effectively inhibits the infiltration of molten volcanic ash by rapidly developing a reaction layer. These findings are an important step toward the design and development of next-generation silicate ash-repellent TBCs.

Molecular dynamics simulation study on the wetting characteristics of carbon dioxide droplets on smooth and rough surfaces

A thorough investigation of the wetting behavior of carbon dioxide (CO2) is crucial for enhancing carbon capture efficiency and improving carbon storage and sequestration processes. This work investigates the wetting characteristics of CO2 droplets on smooth and rough Cu-like surfaces using molecular dynamics simulations. The results indicate that an increase in surface energy causes a linear decrease in the contact angle of CO2 droplets on smooth surfaces. An increase in temperature enhances the wetting tendency of the smooth surface toward CO2 droplets. On CO2-phobic surfaces, CO2 droplets tend to detach from the surface, causing the contact angle to increase. On neutral surfaces, CO2 droplets generally maintain wettability, with contact angles remaining almost unchanged. On CO2-philic surfaces, CO2 droplets rapidly wet and spread to form liquid film layers, causing the contact angle to decrease rapidly. In addition, constructing rough surfaces is beneficial for enhancing the surface CO2-phobic property, but the wettability of CO2 droplets varies slightly on different rough surfaces (cylindrical pillars, square pillars, and grooves), the fluctuation of contact angles of CO2 droplets on the grooved surface is relatively small. For square pillared surfaces, in contrast to smooth surfaces, as the surface energy increases, the CO2-phobic property of CO2-phobic surfaces is enhanced, and neutral surfaces can be transformed into CO2-phobic surfaces, with the CO2-philic property of CO2-philic surfaces enhanced. For CO2-phobic square pillared surfaces (α = 0.08), the wetting morphology and wetting modes of CO2 droplets on the square pillared surface are jointly influenced by both the pillar height and the interpillar spacing. When the interpillar spacing is constant, there exists a critical pillar height that can induce the transition of the wetting mode of CO2 droplets from Wenzel to Cassie state.

Enhancing carbon capture: Exploring droplet wetting and gas condensation of carbon dioxide on nanostructured surfaces

The investigation of carbon dioxide (CO2) condensation on heat exchange surfaces is essential to the advancement of carbon capture, utilization, and storage (CCUS) technology. Molecular dynamics simulations are employed to explore the wetting and condensation behavior of CO2 on nanostructured surfaces. The results indicate that the contact angle of CO2 droplets on nanostructured surfaces is greater than that on smooth surfaces. Increasing the pillar height (h) or solid fraction (f) induces the transition of CO2 droplets from the Wenzel to Cassie state, resulting in an increased contact angle. Nanostructured surfaces significantly enhance the nucleation rate, with molecules initially nucleating at the bottom of the pillars. A higher h or f accelerates the nucleation rate during the condensation. Droplets in the Wenzel state exhibit higher heat transfer efficiency than those in the Cassie state. Additionally, the formation of Cassie-state CO2 droplets undergoes a dewetting transition, altering the heat conduction mode. The dewetting behavior of CO2 droplets favors their detachment from the surface, potentially reducing the initial heat resistance. Therefore, appropriately increasing h and f can promote nucleation and droplet growth, enhancing dewetting transition and mass transfer performance. These simulation results hold great importance for inspiring the design of future CO2-phobic surfaces and guiding CO2 condensation production.