Carboxymethyl Cellulose Fibers Research Articles

Natural helical carboxymethyl cellulose fibers-based actuator for smart controller applications.

Water-responsive polymers have received great attention in the field of smart actuators due to their mechanical response to humidity without energy consumption. Natural polymers-based actuators are competitive because of their green, sustainable, and biocompatible characteristics. In this paper, we report a natural twisting carboxymethyl cellulose (CMC) fiber-based actuator (TCFA) with remarkable performance under water and moist stimulation. The water-responsive CMC fibers were prepared using wet spinning and twisting. Owing to the helical structure, good water absorption, and swelling performance, the CMC fiber exhibits excellent rotational motion with a rotation speed of 4615 rpm and recovery speed of 1538.4 rpm under water stimulation. In addition, the actuator revolutions remained almost constant after more than 254 cycles, thus demonstrating the excellent cyclic stability of this untwisting recovery process. Moreover, the CMC fiber shows application in a smart rainy curtain, smart crane, and concentration detection for alcohol solution. We offer an easy and scalable method to obtain a CMC fiber-based actuator with low cost, sustainability as well as excellent driving performance. Our work inspires a new idea in the design of cellulose-derived actuators and their application in future intelligent systems.

Eco-friendly sustainable adsorption dyeing of MOF-modified carboxymethyl cellulose fiber fabric using acid dyes

Eco-friendly sustainable adsorption dyeing of MOF-modified carboxymethyl cellulose fiber fabric using acid dyes

Analysis of Enhanced Wound Closure Potential of ADSC-Derived Secretome Compared to Aquacel Extra in Diabetic Rats

Background: Diabetes Mellitus (DM) can lead to serious complications, such as Diabetic Foot Ulcers (DFUs). Currently, Aquacel Extra is one of the standard therapies for DFUs, but its efficacy has some limitations that may be overcome by alternative treatments, such as the secretome derived from Adipose-Derived Stem Cells (ADSCs). ADSC secretome has shown promising results in promoting wound healing by enhancing cell proliferation, collagen synthesis, and migration of fibroblasts. Aims: This study aims to compare the effect of the adipose-derived stem cell (ADSC) secretome to Aquacel Extra, a hydrofiber dressing containing gel-forming agents, on wound healing in a diabetic rat model. Aquacel Extra has sodium carboxymethylcellulose fibers, which contribute to its unique properties. Objective: The objective of this study is to compare the wound healing outcome of ADSC secretome and Aquacel Extra in streptozotocin-induced diabetic rats. Methods: Sprague Dawley rats received a single intravenous administration of streptozotocin to induce diabetes mellitus (DM). A full-thickness excisional circular wound was created at the dorsum aspect of the rats two weeks after diabetic induction. Rats were randomly divided into two groups: the Aquacel Extra group, which received the hydrofiber dressing Aquacel Extra containing gel-forming agents, and the secretome group, which received the ADSC secretome on days 0, 3, and 7. The gross examination was performed on days 0, 3, 7, and 14. On day 14, the rats were euthanized, and full-thickness skin biopsies of the wounds were taken for histological and immunohistochemical analysis. Results: The secretome group demonstrated accelerated cutaneous wound healing compared to the Aquacel Extra group, as indicated by faster wound closure (p < 0.05). Hematoxylin and eosin staining revealed a thicker epidermal layer in the secretome group than in the Aquacel Extra group (p < 0.05). The mean histological score of the secretome group was higher at 10 ± 1.73 compared to the score of 8.33 ± 1.52 in the Aquacel Extra group, indicating a more mature tissue architecture. Immunohistochemical analysis showed lower expression of α-smooth muscle actin (α-sma) in the secretome group than in the Aquacel Extra group, which correlated with reduced collagen secretion and deposition in the secretome group, as indicated by Masson’s trichrome staining. Conclusion: The ADSC secretome accelerated the healing of diabetic wounds compared to Aquacel Extra. However, as this study is preliminary, future studies should be conducted similar to this study with a larger sample and wound size. In addition, the optimal dosage of ADSC secretome and the components of the secretome that promoted wound healing should be determined to fully elucidate the clinical potential of ADSC secretome.

Synthesis of MIL-88(Fe) coordinated to carboxymethyl cellulose fibers nanocomposite for dispersive solid phase microextraction of acetanilide herbicides from cereal and agricultural soil samples

In this study, MIL-88(Fe) coordinated to carboxymethyl cellulose fibers was successfully synthesized, characterized, and utilized as a nanocomposite for the dispersive solid phase microextraction of butachlor and acetochlor. These analytes served as representative analytes for acetanilide herbicides (AHs) present in real samples. Effective parameters on the extraction efficiency were investigated to maximize the analytical performance of the developed method. Under optimized conditions, which encompassed sorbent amount of 12 mg, solution pH of 7.0, 4.0 min of the vortex time, 3.0 min of the extraction time, chloroform as desorption agent and no salt addition, the developed method exhibited remarkable figures of merit, such as high linearity (R2> 0.99), low limits of detection of 0.90 ng mL−1, substantial preconcentration factors (between 213 and 228), relative recoveries in the range of 90.8% to 109%, and good repeatability with relative standard deviations equal or below 7.2%. After validation, the developed method was applied to detect AHs in various cereal and agricultural soil samples.

Morphological and Thermal Analysis of Poly(L-lactic acid)/ Carboxymethyl Cellulose Bio-composites

Poly (L-lactic acid) (PLLA) and carboxymethyl cellulose (CMC) are derived from renewable resources and both have excellent properties such as biocompatibility and biodegradability. Applications of PLLA are restricted for some of its inadequate physical properties such as low glass transition temperature, relatively low melting point, high crystallization temperature, slow crystallization rate, and poor heat stability. This study aims to prepare and characterize a renewable bio-composite with more adequate properties for applications by solution casting of different PLLA, and CMC ratios. CMC was prepared from microcrystalline cellulose (MCC) of mustard stalks (agricultural wastes) and the yield was about 78%. The samples were analyzed via Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetric (DSC), wide-angle X-ray diffraction (WAXRD), and scanning electron microscopy (SEM) for spectroscopic and thermal properties characterization. The interaction between carboxylate groups of CMC surfaces and the terminal hydroxyl, terminal carboxyl, and carbonyl groups of PLLA through hydrogen bonds caused the shift and broadening of the band of FTIR spectra. The decomposition temperature of CMC was increased and formed excellent bio composites with PLLA. Composite crystallinity varied with the percentages of the CMC. The fibrous form of CMCs is present in the SEM micrograph indicating cellulose's fibrous structure was not affected by carboxymethylation. In composites, the surfaces of CMC fibers are layered and different from the reported results of SEM micrographs of PLLA/MCC composites. PLLA/CMC performs better in thermal properties but its mechanical characteristics cannot be determined owing to a limitation where the composite was too brittle and not able to undergo tensile testing.

Effects of carboxymethyl cellulose fiber formations with chitosan incorporation via coating and mixing processes

To date, the utilization of carboxymethyl cellulose (CMC) fibers are only restricted to weak mechanical application such as wound dressing. Physically, CMC has a weak mechanical strength due to the high hydrophilicity trait. However, this flaw was saved by the extensive number of reactive functional groups, allowing this macromolecule to form linkages with chitosan to ensure its versatility. This work successfully fabricated CMC-chitosan fiber via dissolution, crosslinking, dry-jet wet-spinning extrusion, and coagulation processes. Chitosan was constituted with CMC fiber in two approaches, coating, and inclusion at various concentrations. Morphologically, chitosan incorporation has triggered agglomerations and roughness toward CMC fibers (CMCF). Chemically, the interaction between CMC and chitosan was proved through FTIR analysis at peaks 1245 cm−1 (ECH covalent crosslinking), while 3340 cm−1 and 1586 cm−1 were due to ionic and hydrogen bonding. The result from analysis showed that at higher chitosan concentrations, the chitosan-included CMC fiber (CMCF-I) and chitosan-coated CMC fiber (CMFC) were mechanically enhanced (up to 86.77 and 82.72 MPa), thermally more stable (33 % residual mass), and less hydrophilic compared to the plain CMCF. The properties of CMC-chitosan fibers have opened up vast possible applications, especially as a reinforcement in a watery medium such as a hydrogel.

Effectively reinforcing rolled reconstituted tobacco with carboxymethylated cellulose fibers

Effectively reinforcing rolled reconstituted tobacco with carboxymethylated cellulose fibers

In situ growth of Cu(BDC) on microscale Cu‐based carboxymethylcellulose fibers: A new strategy for constructing efficient catalysts for A3‐coupling reactions

Based on the coordination properties of carboxylates in carboxymethylcellulose (CMC) and metal ions, we have prepared microscale Cu‐based carboxymethylcellulose fibers (Cu(II)/CMC) by extruding the CMC‐Na solution into a Cu(II) ions coagulation bath. We found that the as‐obtained microscale Cu(II)/CMC fibers are well suitable for the in situ growth of the copper terephthalate (Cu(BDC)) MOFs directly from the coordinated Cu(II) sites enriched on the surface of fibers (Cu(BDC)@Cu(II)/CMC) in the terephthalic acid solution. The composition and structure of Cu(BDC)@Cu(II)/CMC composite fibers were verified using various FTIR, XRD, SEM, EDX, elemental mapping, XPS, TGA, and BET tools. The characterized data revealed that well‐defined Cu(BDC) particles were distributed uniformly on the surface of the microscale Cu‐based fibers. The resulting Cu(BDC)@Cu(II)/CMC fibers were used as an effective and retrievable heterogeneous catalyst for the aldehyde‐alkyne‐amine (A3) coupling reactions. The superior catalytic activity is attributed to the excellent dispersion and stability of the Cu(BDC) MOFs crystallites containing the numerous active Cu(II) sites on the microscale fibers. In addition, the microscale fibrous catalyst can be conveniently retrieved with tweezers after each cycle and reused at least six times without a significant drop in its activity.

Semitransparent films from low-substituted carboxymethylated cellulose fibers

Semitransparent films from low-substituted carboxymethylated cellulose fibers

Necrotizing Soft Tissue Infection of the Forearms in a Patient Using Intravenous Heroin: Case Report of Advanced Wound Management Improving Dressing Tolerance and Expediting Skin Graft

BACKGROUND: Necrotizing soft tissue infection (NSTI) is rare and characterized by rapid onset and spread of inflammation and necrosis. The infection starts within the fascia but can rapidly progress to include musculature, subcutaneous fat, and overlying skin. Its presentation is considered a surgical emergency. Persons who use intravenous or subcutaneous opioids are at higher risk of NSTIs. PURPOSE: The purpose of this case report is to describe the positive clinical outcome after consulting with wound specialists and using a dressing regimen to expedite more rapid wound healing, shortened time to skin graft, and improved pain tolerance in a patient with a history of intravenous and subcutaneous heroin use. CASE REPORT: The patient presented with an NSTI that required extensive debridement of the bilateral upper extremities. The acute surgical wound service was consulted. A dressing regimen consisting of hypochlorous acid–preserved wound cleansing, followed by carboxymethylcellulose fiber with 1.2% ionic silver covered by hydrocellular foam to promote a moist healing environment, was used to facilitate granulation. RESULTS: Healthy granulation tissue was noted 6 days after debridement. The improved rate of granulation and the patient’s tolerance to dressing changes secondary to decreased pain from these dressings significantly expedited the time to graft and wound healing. The patient underwent split-thickness skin grafting 10 days after debridement. There was 100% uptake of the grafts on postgraft day 8. CONCLUSION: The favorable clinical outcome suggests that early consultation with wound specialists and implementation of the dressing regimen were effective in this patient regarding improved pain control and healing. However, because the patient left against medical advice on hospital day 20, the clinical course could not be followed beyond the first few postoperative weeks.

Carboxymethyl Cellulose (CMC) Optical Fibers for Environment Sensing and Short-Range Optical Signal Transmission.

Optical fibers are a key component in modern photonics, where conventionally used polymer materials are derived from fossil-based resources, causing heavy greenhouse emissions and raising sustainability concerns. As a potential alternative, fibers derived from cellulose-based materials offer renewability, biocompatibility, and biodegradability. In the present work, we studied the potential of carboxymethyl cellulose (CMC) to prepare optical fibers with a core-only architecture. Wet-spun CMC hydrogel filaments were cross-linked using aluminum ions to fabricate optical fibers. The transmission spectra of fibers suggest that the light transmission window for cladding-free CMC fibers was in the range of 550–1350 nm, wherein the attenuation coefficient for CMC fibers was measured to be 1.6 dB·cm–1 at 637 nm. CMC optical fibers were successfully applied in touch sensing and respiratory rate monitoring. Finally, as a proof-of-concept, we demonstrate high-speed (150 Mbit/s) short-distance signal transmission using CMC fibers (at 1310 nm) in both air and water media. Our results establish the potential of carboxymethyl cellulose-based biocompatible optical fibers for highly demanding advanced sensor applications, such as in the biomedical domain.

Conductive graphene coated carboxymethyl cellulose hybrid fibers with polymeric ionic liquids as intermediate

In this study, a kind of polymeric ionic liquid (PIL) called PIL-Cl was synthesized and modified to obtain conductive graphene coated carboxymethyl cellulose hybrid fibers. Carboxymethyl cellulose (CMC) was formed into fibers by wet spinning assisted with PILCl. Co-precipitation test of CMC and PIL-Cl demonstrated that PIL-Cl could precipitate with CMC through strong electrostatic interaction and molar ratio of CMC and PIL-Cl (calculated in repeating units) would affect the formation of precipitation. Secondly, modified PIL-Cl named PIL-Ac was used as an intermediate connecting CMC fiber and graphene to fabricate conductive CMC/PIL/graphene fibers. A series of tests were performed on CMC/PIL/graphene fibers, including Raman spectroscopy, scanning electron microscopy and conductivity test. The results showed that PIL-Cl could help form CMC fiber, and PIL-Ac could functionalize it and make it conductive.

Effectiveness of Semiocclusive Sodium Carboxymethyl Cellulose Fibers and Hydrocolloid Dressings for Irritant Peristomal Dermatitis: A Case Series.

The most common complication in individuals with ostomies is irritant contact dermatitis from the acidic stoma effluent coming into contact with the peristomal skin. Although protective powders are widely used for the treatment of peristomal skin, there is little scientific evidence to justify their use. The combined use of sodium carboxymethylcellulose cellulose fibers (SCCFs) together with a hydrocolloid dressing for fixation is an effective alternative in the management of these wounds. Here, the authors report a case series of three patients presenting at a stoma therapy clinic with peristomal skin lesions because of severe irritant contact dermatitis. Patients were men aged between 70 and 81 years, had been diagnosed with colon cancer (n = 2) or bladder cancer (n = 1), and had undergone a colostomy (n = 1), ileostomy (n = 1), or Bricker-type ureteroileostomy (n = 1). A semiocclusive care protocol was applied in a moist environment using SCCF and an extrathin hydrocolloid adhesive dressing, and the collection device was secured using adhesive resin and an ostomy belt. The combined use of SCCF and hydrocolloid dressings provided beneficial results to treat the dermatitis, with reduced discomfort after 7 days and lesions healing within 4 weeks.

A green, reusable and remarkable catalyst for selective aerobic oxidation of alcohols: Construction of Cu(BDC) on the surface of carboxymethyl cellulose fiber

Removing or reducing the amount of metal used in catalytic methods is one of the most important concerns of today's activists in the field of green chemistry. In the present paper, copper terephthalate metal-organic framework (MOF) is chemically attached to carboxymethyl cellulose fiber via an in-situ synthesizing method. The synthesized novel hybrid material (Cu(BDC)/CMC) was applied as an efficient, reusable, and environmentally benign heterogeneous catalyst for the aerobic oxidation of alcohols to the corresponding aldehydes and ketones with good yields under mild conditions. FT-IR, XRD, TGA, SEM, EDS, and TEM techniques confirmed successful construction of catalyst. Obtained results revealed that primary aromatic alcohols are easily converted to aromatic aldehydes in high yields (from 70 to 94 %) with the zero-order kinetics model without additional oxidation to carboxylic acids compared to secondary aromatic alcohols (yields: from 6 to 22). The outstanding advantages of the synthesized catalyst are a non‐hazardous catalyst, desired yields, good selectivity, operational simplicity, mild reaction conditions, and reusability. On the other hand, this catalytic system overcomes essential defects of copper terephthalate MOFs as a catalyst, such as poisoning, deactivation, and non-reusability nature.

Ultrasound-assisted synthesis of MIL-88(Fe) coordinated to carboxymethyl cellulose fibers: A safe carrier for highly sustained release of tetracycline

For stopping long-time harmful bacterial infection, designing a drug carrier with a highly prolonged release profile is a promising approach that is of interest to different biomedical areas. The subject of this work is to synthesis a novel carrier system through coordination of MIL-88(Fe) to carboxymethyl cellulose (CMC) for enhancing interaction between drug and carrier. We established an ultrasound-assisted synthetic method for in situ synthesis of MIL-88(Fe) in the presence of CMC resulting in CMC/MIL-88(Fe) composite. The CMC/MIL-88(Fe) was loaded with a high amount of Tetracycline (TC) by immersion of carrier to the TC aqueous solution. The release profile in the simulated physiological conditions, pH 7.4, revealed a low initial burst release followed by a sustained and prolonged release over 384 h. The in vitro cytotoxicity of CMC/MIL-88(Fe) against Human skin fibroblast (HFF-1) cells was calculated by MTT assay and showed a good cytocompatibility. The antibacterial activity was found for TC-loaded CMC/MIL-88(Fe) toward both E. coli and S. aureus with MIC 64 mg·ml−1.

Cellulose fibers-reinforced self-expanding porous composite with multiple hemostatic efficacy and shape adaptability for uncontrollable massive hemorrhage treatment

Uncontrollable hemorrhage leads to high mortality and thus effective bleeding control becomes increasingly important in the military field and civilian trauma arena. However, current hemostats not only present limitation when treating major bleeding, but also have various side effects. Here we report a self-expanding porous composites (CMCP) based on novel carboxymethyl cellulose (CMC) fibers and acetalized polyvinyl alcohol (PVA) for lethal hemorrhage control. The CMC fibers with uniform fibrous structure, high liquid absorption and procoagulant ability, are evenly interspersed inside the composite matrix. The obtained composites possess unique fiber-porous network, excellent absorption capacity, fast liquid-triggered self-expanding ability and robust fatigue resistance, and their physicochemical performance can be fine-tuned through varying the CMC content. In vitro tests show that the porous composite exhibits strong blood clotting ability, high adhesion to blood cells and protein, and the ability to activate platelet and the coagulation system. In vivo hemostatic evaluation further confirms that the CMCP presents high hemostatic efficacy and multiple hemostatic effects in swine femoral artery major hemorrhage model. Additionally, the CMCP will not fall off from the injury site, and is also easy to surgically remove from the wound cavity after the hemostasis. Importantly, results of CT tomography and 3D reconstruction indicate that CMCP can achieve shape adaptation to the surrounding tissues and the wound cavities with different depths and shapes, to accelerate hemostasis while protecting wound tissue and preventing infection.

Preparation and Characterization of Mustard Stalks Derived Carboxymethyl Cellulose and Poly(L-Lactic Acid) Biocomposites

The influences of poly ( L- lactic acid) (PLLA) and carboxymethyl cellulose (CMC) derived from mustard stalks content on the morphological and thermal properties of PLLA/CMC biocomposites were investigated. The yield of CMC from microcrystalline cellulose (MCC) of mustard stalks was about 78%. Biocomposites were prepared using the solution casting method, varying PLLA, and CMC ratio. Prepared samples were characterized using Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetric, X-ray diffraction, and scanning electron microscopy. The decomposition temperature of CMC was increased and formed excellent biocomposites with PLLA. Composite crystallinity was varied with the percentages of the CMC. The CMC fibers coated with a layer of PLLA suggested that CMC and PLLA have good compatibility.

Self-supporting three-dimensional carboxymethyl cellulose conductive sponges used as electrodes for lithium-ion batteries

In this study, two kinds of self-supporting three-dimensional (3D) carboxymethyl cellulose (CMC) conductive sponges were fabricated and used as electrodes for lithium-ion batteries (LIBs). One was used nano-silicon graphite (Si–graphite) and the other was used nano-ferriferous oxide (Fe–graphite) as active materials. The fabrication and microstructures of two kinds of self-supporting 3D CMC conductive sponges were investigated via scanning electron microscopy and their electrochemical performances were tested when they are used as electrodes. The results show that the hybrid particles are deposited on fibrous CMC layers to form conductive sponges during the freeze-drying. Combined with those of half-battery experiments, two kinds of self-supporting 3D CMC conductive sponges used as electrodes exhibit good electrochemical performances. Moreover, most of the active materials remain encased in the CMC fiber after recycling. These novel Si–graphite and Fe–graphite CMC conductive sponged electrodes can maintain reversible capacities of 1350 and 345.8 mAh/g after 200 and 1000 charge–discharge cycles, respectively, indicating that continuous fibrous CMC conductive networks can provide novel insight into electrode materials for LIBs with enhanced electrochemical performance.

Thermostable Cellulases from the Yeast Trichosporon sp.

Objectives Identification of cellulolytic microorganisms is of great interest to the hydrolysis of cellulosic biomass. This study focuses on the identification of cellulolytic yeasts and the optimization of cellulase activities produced by the best performing isolate. Results 30 cellulolytic yeast isolates were selected. Enzymes produced by an isolate from the Trichosporon genus showed the property to hydrolyze different substrates: carboxymethyl cellulose (CMC), cellulose fiber, and filter paper (FP). The optimum measured temperature was 55°C for CMCase and 60°C for FPase. The optimal pH was 5 for CMCase and 4 to 6 for FPase. The effect of the substrates concentration showed that the best activities were obtained at 100 mg/mL CMC or FP. The highest activities were 0.52 for the CMCase and 0.56 for the cellulase fiber at 10 min incubation, 0.44 IU/mL at 15 min incubation, and 24 h FPase preincubation. Conclusion Cellulases produced by the studied yeast are capable of hydrolyzing soluble and insoluble substrates at elevated temperatures and at a wide pH range. They are considerable interest in the production of fermentable sugars from lignocellulosic substrates.

Fabrication of carboxymethylated cellulose fibers supporting Ag NPs@MOF‐199s nanocatalysts for catalytic reduction of 4‐nitrophenol

In this work, we prepared high‐performance and recyclable nanocatalysts that consist of small and well‐dispersed silver nanoparticles (Ag NPs) immobilized onto Cu‐ based metal–organic framework (MOF‐199 s) supported by carboxymethylated cellulose fibers (CCFs). The as‐prepared green nanohybrid catalysts, namely Ag NPs@ MOF‐199 s/CCFs, were characterized using SEM, TEM, XRD and FT‐IR techniques. The catalytic performances showed that Ag NPs@ MOF‐199 s/CCFs catalysts exhibited a very high catalytic efficiency towards the reduction of 4‐nitrophenol to 4‐aminophenol. The enhanced catalytic performances are attributed to the improved dispersity, small particles of Ag NPs stabilized by the MOF‐199 s, and the porous catalyst structures. The introduction of cellulose fiber further facilitates the reuse and sustainability of the nanohybrid catalysts, showing a stable and high reusability (more than 91% of catalytic activity) even after five runs.