Efficient Carbon Research Articles

Pyrolysis fuel oil-derived hollow carbon nanocages as high-stability anode materials for potassium ion storage

The use of graphite to make anode materials for potassium-ion batteries (KIBs) results in diminished electrochemical performance, largely due to significant interlayer expansion caused by potassation/depotassiation. To address this limitation, novel hollow carbon nanocages (HCNCs) are prepared from pyrolysis fuel oil (PFO), a cost-effective byproduct. The HCNCs heat-treated at 1500 °C has a graphitic structure with high porosities and numerous closed pores and exhibits a notable potassium-ion storage capacity of 307.2 mAh/g at a current density of 50 mA g−1. Moreover, structurally stable HCNCs withstand the substantial volume expansion associated with potassium-ion intercalation. The stability of the material is attributed to a hybrid adsorption/insertion mechanism, which results from synergistic interplay between the unique morphologies of the HCNCs and the developed carbon layers. This configuration delivers a specific capacity of 131.6 mAh/g and 98.9 % capacity retention over 1000 cycles at a high current density of 2000 mA g−1. Consequently, these proposed HCNCs present a significant advance in developing efficient carbon materials for KIBs, and addressing the critical challenges of graphite such as unstable cycling stability.

Estimating the energy return on investment of forestry biomass: Impacts of feedstock, production techniques and post‐processing

AbstractThe Energy Return On Investment (EROI) is a recognised indicator for assessing the relevance of an energy project in terms of net energy delivered to society. For woody biomass divergences remain on the right methodology to assess the EROI leading to large variations in the published estimates. This article presents an in‐depth discussion about the EROI of woody biomass in three different forms: woodchips, pellets and liquid fuels. The conceptualisation of EROI is further developed to reach a consistent definition for biomass post‐processed fuels. It considers, on top of the external energy investments, the grey energy associated with the energy used to enrich the fuel. With the proposed methodology, all woodchips have an EROI of the same order of magnitude, between 20 and 37, depending on forestry types, operations and machineries. For secondary residues, the first estimate is 170 if, as co‐products, no energy investment is allocated to the forestry operations and transport. On the basis of a mass allocation for forestry operations and transport, the EROI for secondary residues becomes of the same order of magnitude as that for wood chips. Woodchips can be further post‐processed into pellets or liquid fuels. Pellets have an EROI of 4–7 if the heat is externally supplied and 8–23 if internally supplied (self‐consumption of part of the raw material). Liquid fuels derived from primary wood and residues through gasification and Fischer‐Tropsch synthesis have an EROI between 4 and 16. Fuel enhancement with hydrogen (Power & Biomass to Liquids) impacts negatively the EROI due to the low EROI of hydrogen produced from renewable electricity. However, these fuels offer other advantages such as improved carbon efficiency. A correct estimate of EROI for forestry biomass, as proposed in this work, is a necessary dimension in assessing the suitability of a project.

Direct carbonation of porous materials produced from self-hardened paper mill fly ash

A high-Ca fly ash generated from a paper mill using a fluidized bed boiler was used as the potential medium to sequester CO2 via the direct carbonation process. In this study, the fly ash samples were exposed to accelerated carbonation to produce hardened pastes. The influence of the porosity controlled by the amount of foam in the matrix for maximizing CO2 sequestration was determined. The effect of porosity on carbonation was evident. The samples prepared with 40 % foam and a water-to-fly ash ratio of 0.79 recorded porosities of 56.1 % (carbonated) and 66.8 % (naturally carbonated (NC)) with the lowest mechanical strength of 2.1 and 1.1 MPa, respectively. These naturally carbonated (NC) samples have been cured naturally without using high CO2 pressure. Meanwhile, the samples prepared with 10 % foam and a water-to-fly ash ratio of 0.5 recorded porosities of 41.1 % (carbonated) and 52.9 % (NC) with the highest strength at 10.2 and 4.6 MPa, respectively. The highest carbonation efficiency determined by thermogravimetric analysis was obtained from the carbonated samples with 40 % foam. Scanning electron microscopy–energy-dispersive spectroscopy depicted the areas with high Al/Si content but low Ca–O content (dark areas) and carbonated areas with high Ca–O content (bright areas). Mercury intrusion porosimetry was used to determine the pore size distribution, whereby the samples were dominated by large capillary pores, resulting in their high porosity in this study.

The Current Status and Future Prospects of Carbon Capture, Carbon Transportation, And Carbon Utilization Technologies in Chinese Coal-Fired Power Plants Within the Context of Dual Carbon Goals

Carbon dioxide capture, utilization, and storage (CCUS) constitute vital measures for achieving net emissions reduction in China. Against the backdrop of the “dual carbon” initiative in China, this paper meticulously examines and analyzes the key technological principles, merits and demerits, and bottlenecks associated with CCUS carbon capture in the country’s thermal power plants at the current stage. It combines the prevailing industrial application status and the future development trajectory of pertinent technologies with considerations of industrial economic benefits and business models. Building upon this analysis, the paper summarizes the application status of CCUS technology in China’s thermal power plant industry and presents future prospects. On the technological front, the three capture methods grapple with the challenge of high costs. Therefore, there is a need to intensify efforts in developing low-cost and efficient carbon capture materials, as well as researching and practically applying low-cost oxygen generation technology. Economically, CCUS technology currently faces high costs, low returns, and certain commercial barriers, placing China in a demonstrative business model stage. To overcome these challenges and realize the economic benefits of CCUS technology, government incentives and technological innovation are imperative. These measures aim to reduce the overall cost of CCUS technology, stimulate the scale development, and foster commercialization, ultimately contributing to the achievement of China’s carbon emission reduction targets.

Facile one-pot green synthesis of Aloe vera mediated silver nanoparticles and their catalytic efficiency towards organic transformations

A facile approach for the synthesis of Aloe vera mediated silver nano-particles (AgNPs) has been carried out via chemical route. The developed Aloe vera mediated AgNPs were characterized by using various techniques such as SEM, FT-IR etc. Additionally, catalytic applications of this interesting nanomaterial were utilized for the synthesis of 4-phenylthiazole- 2-amine and its derivatives. After completion of catalytic reactions, Aloe vera mediated AgNPs were easily recycled without any significant loss in catalytic activity. The robust features of the current approach involve an outstanding catalytic performance, ease of catalyst retrievability, easy work up procedure, and large substrate tolerance. Besides this, the green chemistry metrics for the products formed such as E-factor (Environment Factor), PMI (Process Mass Intensity), RME (Reaction Mass Efficiency), Atom Economy (AE) and carbon efficiency (CE) were in associated with high efficiency and selectivity which further confirms the effectiveness of this approach. This work highlights the significance of using economic and eco-friendly approach for synthesizing thiazole derivatives in good to excellent yields via Aloe vera mediated AgNPs under waste free conditions.

Cooperative management can mitigate trade-offs between livestock production and ecological functions to promote grassland sustainability

An increase in the population in pastoral regions and an improvement in living standards have increased livestock production; however, this has led, at least in part, to global grassland degradation. Consequently, the optimal pathway to mitigate trade-offs between livestock production and ecological functions of grassland is the key to achieve sustainable development in pastoral regions. Transformative adaptation is the recommended and feasible approach. However, most studies are not designed to determine which grassland management system addresses transformative adaptation and, therefore, do not provide options that can resolve the trade-offs. To fill this gap, we compared three grassland management systems, namely single, joint and cooperative. The grassland health index (GHI), data envelopment analysis (DEA), life cycle assessment (LCA), TOPSIS model and the multi-objective optimization model were employed to assess the productive and ecological benefits of the three systems. Cooperative management had the greatest comprehensive benefits when considering ecological functions, livestock production, carbon efficiency utilization and grassland area utilization efficiency, and had the greatest potential to achieve a balance between livestock production and ecological functions in the future.

Investigating the influence of oxygen doping in modulating product distribution for electrocatalytic CO2 reduction reaction

Efficient carbon recycling hinges on a comprehensive understanding of the mechanics behind electrocatalytic carbon dioxide reduction reactions (ECO2RR). Here, we have engineered, in-situ growth of CuO featured on O-doped gCN (COG) and ex-situ growth of CuO on bare gCN (CG) respectively, functioned as platforms fordisengaging the fundamental of ECO2RR. The COG holds substantial capacity compared to CG for efficient conversion of CO2 into hydrocarbons and initiated the C2 product pathway with enlarged faradaic efficiency (FE). The experimental results indicate that the COG enhanced the product conversion of CH3OH (FE = 61.5% ± 0.5), C2H5OH (FE = 24.7% ± 0.5), and HCOO– (FE = 6.1% ± 0.5) at −1.1 V Vs RHE. Meanwhile, the CG exhibited the maximum conversion of CO2 into CH3OH (FE = 56.4% ± 0.5) at the same potential range. For the CG, the partial current density of CH3OH (JCH3OH) is −1.8 mA cm−2, whereas COG exhibited −4.9 mA cm−2. Interestingly, in this ECO2RR, the study of oxygen doping demonstrated that feasible CO2 conversion, due to its affinity towards CO2 and high donor density.

Facile Preparation of Stable NiII‐ and CoII‐tetraaminophthalocyanine Electropolymers for Highly Efficient Heterogeneous Carbon Dioxide Reduction

This study focused on preparation of stable polymer films of NiII‐ and CoII‐tetraaminophthalocyanines, p‐NiTAPc and p‐CoTAPc, respectively, for highly efficient heterogeneous electrochemical carbon dioxide (CO2) reduction in a flow electrolysis cell. Major development represented in this work was fabrication of p‐NiTAPc and p‐CoTAPc films via electropolymerization of their corresponding monomers on carbon‐based substrates without using binder or conducting additive materials to obtain efficient gas diffusion electrodes (GDEs) for scalable, productive and selective CO2‐to‐CO conversion. The target polymers were characterized by UV‐visible spectrophotometry, attenuated total reflection‐Fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersive X‐ray spectroscopy and cyclic voltammetry. According to controlled potential electrolysis and gas chromatography, p‐NiTAPc‐catalyzed CO2 reduction at –0.99V vs. reversible hydrogen electrode (RHE) gave 953 mL of CO in a period of 16 hours with current density and Faradaic efficiency (FE) of 109±1 mA·cm‐2 and 99±2%, respectively. A p‐CoTAPc‐modified GDE exhibited superior catalytic performance to the case of p‐NiTAPc in terms of catalyst stability and CO productivity by performing the continuous CO2 reduction at the potential of –1.10 V vs. RHE for up to 41 hours and affording almost 3 times higher amount of CO with the current density of 161±5 mA/cm2 and 95±2% FE.

Sulfonated Chitosan Gel Membrane with Confined Amine Carriers for Stable and Efficient Carbon Dioxide Capture.

Capturing carbon dioxide (CO2) from flue gases is a crucial step towards reducing CO2 emissions. Among the various carbon capture methods, facilitated transport membranes (FTMs) have emerged as a promising technology for CO2 capture owing to their high efficiency and low energy consumption in separating CO2. However, FTMs still face the challenge of losing mobile carriers due to weak interaction between the carriers and membrane matrix. Herein, we report a sulfonated chitosan (SCS) gel membrane with confined amine carriers for effective CO2 capture. In this structure, diethylenetriamine (DETA) as a CO2-mobile carrier is confined within the SCS gel membrane via electrostatic forces, which can react reversibly with CO2 and thus greatly facilitate its transport. The SCS ion gel membrane allows for the fast diffusion of amine carriers within it while blocking the diffusion of nonreactive gases, like N2. Thus, the prepared membrane exhibits exceptional CO2 separation capabilities when tested under simulated flue gas conditions with CO2 permeance of 1155 GPU and an ultra-high CO2/N2 selectivity of above 550. Moreover, the membrane retains a stable separation performance during the 170 h continuous test. The excellent CO2 separation performance demonstrates the high potential of gel membranes for CO2 capture from flue gas.

Structure and composition of rehabilitated mangrove in Lubuk Kertang Village, North Sumatra, Indonesia

Mangroves are generally distributed in tidal zones along tropical and subtropical coasts and are known as woody halophytes. Mangroves are one of the most productive and efficient long-term natural carbon sinks. Deforestation and mangrove degradation produced substantial carbon emissions that account for the majority and salt marshes emissions. Mangroves play an important role in protecting against storms and sea level rise, preventing coastline erosion, regulating coastal water quality, providing habitat for commercial interests. This study was conducted to measure the diversity, structure and composition of forests in the rehabilitation of abandoned pond mangrove forests in Lubuk Kertang Village, West Brandan District, Langkat Regency, North Sumatra. The method used was to conduct a census in a 1.6 ha restoration forest by measuring the overall diameter, height and species found. Fourteen species were found, namely Aegiceras corniculatum, Avicennia marina, Acrostichum aureum, Bruguiera gymnorrhiza, Ceriops tags, Exoecaria agallocha, Finlaysonia maritimea, Nypa fruticans Rhizophora apiculata, Rhizophora mucronata, Rhizophora stylosa, Sonneratia alba, Scyphiphora hydrophyllacea, Sesuvium portulacastrum.

Study on geothermal energy self-recycling extraction and ScCO2 storage in the horizontal well annuli with fracture network system

With the extensive exploitation of fossil fuels, a substantial number of production and injection wells have been or are on the verge of being abandoned. However, many of these wells present viable opportunities for geothermal energy extraction, as they are situated in geothermal reservoirs with favourable temperatures. In alignment with carbon neutrality policies, supercritical CO2 (ScCO2) has emerged as the preferred working fluid for geothermal extraction, facilitating subsequent storage. This study has developed three transient models to characterize the heat and mass transfer processes of ScCO2 circulating within a horizontal wellbore and the reservoir's fracture network. Finite element method and Comsol Multiphysics 6.1 software are employed to solve these models. Results show that ScCO2 efficiently flows from the annuli into the hydraulic fracture network and then circulates back through the annuli completing a self-recycling heat extraction process. The findings reveal several key insights: (a) Lower injection mass flow rates and flow rates lead to more efficient extraction of thermal energy within horizontal wellbores. (b) Low-temperature ScCO2 enhance thermal energy recovery. (c) The larger the coverage area of the fracture network, the more effective the heat extraction. (d) The efficiency of heat extraction and ScCO2 storage in the horizontal well-fracture network self-circulation system is 3 to 5 times and 6 to 7 times higher than that of the horizontal well self-recycling and injection-production systems. (e) Periodic thermal extraction proves to be more efficient than continuous methods. (f) The cumulative heat production of the vertical dual well injection-production system is the highest, reaching 2.45 × 1011 kJ. But it's still lower than the self-circulating system. The heat extraction effect of the diagonal dual well injection-production system is the lowest, which is 1.83 × 1011 kJ. (g) Three developed transient models facilitate efficient heat extraction and ScCO2 storage reservoir screening and evaluation. In conclusion, the self-recycling system has achieved efficient heat extraction and carbon dioxide storage, providing a theoretical basis for future energy conversion and management.

Bacillus Subtilis-Derived Carbon Nanorods as Efficient ORR Electrocatalysts

Developing high-performance anion-exchange membrane fuel cells requires stable and highly active oxygen reduction (ORR) catalysts. To fabricate cheap and efficient porous carbon materials for ORR, heteroatom-doped carbon nanorods were synthesized by pyrolyzing Bacillus subtilis. The obtained carbon material maintained the uniformly distributed nanorods as original Bacillus subtilis and had inherent doped heteroatom. The obtained BS-2.0 had the highest specific surface area (209.04 m2 g−1) and the maximum ID/IG (1.0372). Its starting potential (0.93 V vs RHE) and semi-wave potential (0.81 V vs RHE) were close to 20% commercial Pt/C, and its ultimate current density was 3.98 mA cm−2@1600 rpm. Meanwhile, the stability of cycling potentiates polarization, and methanol tolerance of BS-2.0 were all greater than 20% commercial Pt/C. It was the inherent heteroatom, well-distributed nanorods, abundant pore distribution, and large surface area that contributed to its excellent electrochemical performance.

The impact of herbaceous plants on biodiversity and stability of pine plantations in Western Polissia

In the field of ecology, more and more attention is paid to the analysis of the interaction of herbaceous plants with the structure of ecosystems, including forests. The aim of the study was to determine the impact of herbaceous plants on the biodiversity and stability of pine plantations in Western Polissia of Ukraine. To achieve this goal, in 2010-2023, the State Enterprise “Research Farm “Horodetske” assessed the diversity of herbaceous plant species, measured their number and cover, evaluated soil physical properties and biometric parameters of pine trees, and assessed how changes in the pine plantation ecosystem caused by herbaceous plants can affect carbon sequestration and oxygen productivity. The study found that herbaceous species among pine plantations in Western Polissia perform important ecological functions that contribute to the conservation and restoration of ecosystems. The presence of these plants enriches the soil with organic matter and helps maintain the structural and functional stability of ecosystems. The study showed that herbaceous plants contribute to the restoration of pine plantations by providing protection and support for young trees, and have a positive impact on their biometric parameters, increasing the total phytomass. Herbaceous plants also improve soil physical properties, such as pH, humus content, aggregate water resistance and water permeability, which can contribute to soil structural stability and the health of pine stands. In addition, the presence of herbaceous plants contributes to more efficient carbon sequestration and oxygen production, which is important for the balance of the air environment in the ecosystem. The results obtained are of great importance for environmental management and conservation of natural resources in the Western Polissia region, as they provide scientific basis for developing strategies for the conservation and restoration of forest ecosystems, taking into account the role of herbaceous plants in their functioning

Salted Dried Bamboo Shoots-Derived Mesoporous Carbon Inherently Doped with SiC and Nitrogen for Capacitive Deionization.

Dried bamboo shoots (DBS) are a natural resource with inherent silica content, which can serve as sacrificial templates for the formation of mesoporous carbon but also promote the generation of silicon carbide (SiC). Building on this, we introduced mesoporous and graphitic carbon/SiC (SiC/BSC) as the CDI electrode for copper ion (Cu2+) removal. Mesoporous carbon electrodes facilitate faster ion transport, diffusion, and electron-transfer pathways. Furthermore, SiC accelerates electron transfer and promotes faradic redox reactions during the charge and discharge processes. Consequently, the synergistic effect of SiC/BSC mesoporous carbon material leads to a promising electrode for Cu2+ capacitive deionization. Leveraging these unique properties, the SiC/BSC electrode material exhibits an outstanding CDI performance of 381.5 mg/g at 1.8 V. This study offers a strategy for the preparation of efficient mesoporous carbon materials as CDI electrodes, specifically tailored for the deionization of Cu2+ ions.

Energy Efficient Carbon Capture through Electrochemical pH Swing Regeneration of Amine Solution.

Carbon capture is widely acknowledged as a promising strategy for achieving negative emissions. Electrochemical carbon capture technologies are considered a viable alternative to conventional temperature swing processes. Among these, employing the hydrogen oxidation and hydrogen evolution reactions as a redox couple, along with an ion exchange membrane, offers an effective means of establishing a pH swing for desorbing CO2 and regenerating the alkaline solvent. However, the practical scalability of this approach is impeded by challenges such as high energy demands resulting from a high pH differential between anodic and cathodic environments and operation with solutions with a low conductivity, required to obtain an acceptable current yield. To address these limitations, this study introduces an innovative anion exchange membrane (AEM)-based electrochemical process for solvent regeneration. Our research demonstrates the advantageous utilization of amines as chemical buffers. Selecting an amine solution with a favorable pKa (∼7 to 10) helps in maintaining bicarbonate as the predominant carbon species within the system, thereby ensuring a high current yield (>80%) across various operational conditions (current, load ratio, and solution concentration). Furthermore, our analysis indicates that the use of amine solutions effectively reduces the overpotential of the hydrogen evolution reaction due to a lower local pH. This results in a minimum energy requirement of 63 kJ/mol at a current density of 20 A/m2 to regenerate the solution (MDEA) while maintaining high (>99%) product (CO2) purity.

Onboard pre-combustion carbon capture with combined-cycle gas turbine power plant architectures for LNG-fuelled ship propulsion

This paper investigates the concept of pre-combustion carbon capture (Pre-CCS) with a combined cycle gas turbine (CCGT) propulsion system to achieve energy efficient carbon capture onboard a Liquid Natural Gas fuelled vessel. A basic CCGT model with energy efficiency of 51.6 % when using LNG as fuel was integrated with a Pre-CCS system composed of a steam methane reformer, water–gas shift reactors, pressure swing adsorption (SMR-PSA), and liquid CO2 storage. Various waste heat utilisation schemes integrated with the CCGT-reformer were modelled in Aspen HYSYS. The modelling of the waste heat recovery networks as energy streams integrating between various processes and unit of operations has facilitated a closed-loop simulation of various systems. It was concluded that a proper utilisation of the high-grade heat from the gas turbine (GT) exhaust and from the reformer is crucial to improve the overall energy efficiency and carbon capture rate, exemplified by a scheme where the heating needs for the SMR and the cooling needs from the water–gas-shift reactors are fully integrated. When optimised, the integrated system had an overall energy efficiency of 41.5 % and 43.2 % (i.e. an efficiency loss of 10.2–10.5 percentage points from the base CCGT system) accompanied with specific GHG emission reduction of 51.2 % and 52.3 % for operation of the GT at a turbine entry temperature of 1700 K and 1850 K, respectively. Intermediate levels of reforming, where the GT uses a mix of LNG and reformate gases, were also simulated, showing an almost linear evolution from the 100 % LNG feed to the GT to the 100 % reformate case. Such a strategy could be used for gradual evolution to meet the required CO2 reduction timeline. It was determined that the 100 % reformate case provides the highest CO2 capture rate. Estimates of other emissions from the GT assuming typical combustor residence times for the whole range of fuel blends were also carried out, showing that the overall greenhouse gas emission is dominated by CO2, given that the GT emits negligible N2O and unburnt methane. Some capital cost estimates were also made to determine the unit price of hydrogen fuel produced onboard, suggesting that the CAPEX was not prohibitive. These findings support the pre-combustion CCS − CCGT integrated system as a promising long-term decarbonisation and propulsion strategy to comply with emissions regulations, displaying good performance in terms of cost, energy consumption, and CO2 reduction. The scalability and adaptability of the proposed system for existing and new-built ships across the decarbonisation timeline is also discussed.

Accelerated carbonation of incineration fly ash (IFA) and its impact on inhibiting heavy metals leaching and removal of soluble salts

This study analysed the composition and leaching results for 12 IFA samples from a local incineration plant by XRF and leaching tests based on BS EN12457-1:2002. XRF results show that the main elements are Ca, Cl and S in all IFA samples. Leaching test results shows a high leachability of Na, Cl, Br, Pb, Zn and Cu. The accelerated carbonation with (NH4)2CO3 was attempted to inhibit heavy metals leaching and remove soluble salts. The effect of (NH4)2CO3 concentration on carbonation efficiency and inhibition of heavy metal leaching was systematically investigated. TGA and ICP-MS were used to determine carbonation capacity and heavy metal leaching, respectively. TGA results show the maximum carbonation capacity is achieved in one hour with 10 wt% (NH4)2CO3 and 76% carbonation occurs -in the first 10 min. Leaching test results reveal that Cu and Pb are efficiently immobilised when the concentration of (NH4)2CO3 is as low as 2 wt% with a s/l ratio of 1:5 within 1 hr. Increasing the concentration of (NH4)2CO3 to 4 wt%, the leaching rate of Zn is also below NEA RVs (National Environment Agency of Singapore). Carbonation is also effective to immobilise Cd and Ni, but not for Cr since it exists as CrO42- and cannot be carbonated. XRF results from a larger scale reaction confirm the significant removal of soluble salts, and lower leachability (except SO42-) is substantiated by leaching tests. By integrating the processes of CO2 capture with ammonia and accelerated carbonation, our work contributes to CO2 sequestration and IFA detoxification.

From waste corn straw to graphitic porous carbon: A trade-off between specific surface area and graphitization degree for efficient peroxydisulfate activation

Electron transfer pathways have been verified as overriding regimes when peroxydisulfate (PDS) was activated by porous carbon. The incorporation of graphitic structure into carbon matrix was favorable to the rapid electron transfer, but excessive graphitization would deteriorate the specific surface area (SSA), weakening the catalytic performance. The reasonable trade-off between SSA and graphitization degree was necessary and challenging for the preparation of efficient carbon based PS-activators. Herein, a series of graphitic porous carbon with discrepant SSA and graphitic structure were fabricated. The incorporation of graphitization tracks into ultra-thin edges on porous carbon film was verified by multifarious structural characterization. After trade-off, the optimum catalyst exhibited superior catalytic performance with degradation rate constant (kobs) exceeding that of ungraphitized precursor by up to 16.0 times. Mechanistic investigations substantiated that the sufficient SSA of catalyst provided favorable conditions for its affinity towards PDS and sulfadiazine (SDZ), resulting in the formation of PDS* complexes and SDZ adsorption, while the appropriate graphitization degree ensured the reinforced electron transfer rate, which collectively accelerated SDZ oxidation through electron-transfer pathway. The multivariate linear regression model linking kobs to SSA and graphitization degree was established providing basis to construct efficient catalysts for PDS activation.

Carbon emissions changes of animal husbandry in China: Trends, attributions, and solutions: A spatial shift-share analysis

China is a major livestock producer confronting the dual challenges of rising demand for animal-based food consumption and decreasing carbon emissions. To effectively address these issues, it is crucial to understand the trends of carbon emissions from animal husbandry and the competitive advantages of carbon emission reduction in different regions. This study uses panel data from 31 provinces from 2004 to 2020 to investigate the contributing factors to carbon emissions and explore ways to reduce carbon intensity in animal husbandry. The analysis employs spatial shift-share analysis and the spatial Durbin model. Our findings indicate that life-cycle carbon emissions associated with animal husbandry in China decreased from 572.411 Mt CO2eq to 520.413 Mt CO2eq over time, with an average annual decline of 0.568 %. The annual contribution of output value and internal industry-mix adjustment to carbon emission growth is 22.639 MT CO2eq and 6.226 MT CO2eq, respectively. On the other hand, the annual contribution of carbon efficiency improvement to carbon emission reduction is much higher, at 36.316 MT CO2eq. However, there is significant regional heterogeneity in the spatial decomposition of the carbon efficiency change component. The Northeastern region, Northwest and along the Great Wall demonstrate neighborhood advantages in enhancing carbon efficiency. In contrast, the South China and Southwest regions rely more on local carbon efficiency advantages to reduce the carbon intensity of animal husbandry. Furthermore, the carbon intensity in local and neighboring areas can be reduced through environmental regulations and industrial agglomeration. While technical progress significantly negatively impacts carbon intensity in neighboring regions, it does not contribute to reducing the carbon intensity of local animal husbandry. The findings provide valuable insights for local governments, aiding them in recognizing the pros and cons of carbon reduction in animal husbandry and strengthening regional cooperation in emission reduction management.

Well-being and entertainment carbon efficiency: A study of spatial externality in geographic psycholinguistics in response to economic policy uncertainty

This study investigates the impact of well-being on carbon efficiency in the entertainment market from the perspective of geographic psycholinguistics. To analyze this impact, we employ quantile regression based on the method of moments and spatial econometric models that incorporate economic policy uncertainty. The results highlight the substantial impact of well-being on energy conservation and carbon emission reduction. On one hand, our findings indicate that well-being significantly reduces carbon emissions and exhibits a spatial externality effect. Furthermore, well-being indirectly contributes to carbon reduction by alleviating the adverse consequences of economic policy uncertainty. The rationale behind this relies on psycholinguistic expressions of well-being, which play a crucial role in enhancing the quality of life and serving as psychological foundations for individuals to adopt environmentally conscious actions and low-carbon lifestyles. This exploration is of great significance for understanding the synergistic growth of well-being and the development of the green economy.