Carbonate Veins Research Articles

Geology, alteration, age, and origin of iron oxide–apatite deposits in Upper Eocene quartz monzonite, Zanjan district, NW Iran

Iron oxide–apatite deposits are present in Upper Eocene pyroxene-quartz monzonitic rocks of the Zanjan district, northwestern Iran. Mineralization occurred in five stages: (1) deposition of disseminated magnetite and apatite in the host rock; (2) mineralization of massive and banded magnetite ores in veins and stockwork associated with minor brecciation and calcic alteration of host rocks; (3) deposition of sulfide ores together with potassic alteration; (4) formation of quartz and carbonate veins and sericite, chlorite, epidote, silica, carbonate, and tourmaline alteration; and (5) supergene alteration and weathering. U–Pb dating of monazite inclusions in the apatite indicates an age of 39.99 ± 0.24 Ma, which is nearly coeval with the time of emplacement of the host quartz monzonite, supporting the genetic connection. Fluid inclusions in the apatite have homogenization temperatures of about 300 °C and oxygen isotopic compositions of the magnetite support precipitation from magmatic fluids. Late-stage quartz resulted from the introduction of a cooler, less saline, and isotopically depleted fluid. The iron oxide–apatite deposits in the Tarom area of the Zanjan district are typical of a magmatic–hydrothermal origin and are similar to the Kiruna-type deposits with respect to mineral assemblages, fabric and structure of the iron ores, occurrence of the ore bodies, and wall rock alteration.

Colombian-style emerald mineralization in the northern Canadian Cordillera: integration into a regional Paleozoic fluid flow regime

Emerald in the Mackenzie Mountains is hosted in extensional quartz–carbonate veins cutting organic-poor Neoproterozoic sandstones and siltstones within the hanging wall of a thrust fault that emplaced these strata above Paleozoic rocks. Isotopic compositions of water extracted from emerald are typical of evolved sedimentary sulphate brines. Fluid inclusion studies indicate two saline fluid populations: a CO2–N2-bearing, high-salinity brine (20.4–25.8 wt.% NaCl equivalent), and a gas-free, saline brine (7.6–15.3 wt.% NaCl equivalent). Both populations display evidence of post-entrapment volume changes. δ18OVSMOW (VSMOW, Vienna standard mean ocean water) values for emerald, quartz, and dolomite yield averages of 17.3‰ (±0.9), 19.6‰ (±1.5), and 18.1‰ (±1.0), respectively. Dolomite δ13CVPDB (VPDB, Vienna Pee Dee belemnite) averages –6.8‰ (±1.0). Two pyrite samples returned δ34SCDT (CDT, Cañon Diablo troilite) values of 5.1‰ and 11.2‰. Triply concordant mineral equilibration temperatures determined from mineral pair δ18OVSMOW equilibration (quartz–emerald, quartz–dolomite, emerald–dolomite) range from 380 to 415 °C. Depth calculations based on mineral pair isotope equilibration and typical geothermal gradient indicate vein formation at 6–11 km depth. A Re–Os isochron age of 345 ± 20 Ma from pyrite indicates that mineralization was contemporaneous with estimated ages of some northern Cordilleran Zn–Pb occurrences. Emerald mineralization resulted from inorganic thermochemical sulphate reduction via the circulation of warm basinal brines through siliciclastic, carbonate, and evaporitic rocks. These brines were driven along deep basement structures and reactivated normal faults during the development of a trans-tensional back-arc basin during the late Devonian to middle Mississippian. The Mountain River emerald occurrence thus represents a variant of the Colombian-type emerald deposit model requiring thermochemical sulphate reduction.

High-temperature carbonate minerals in the Stillwater Complex, Montana, USA

High-temperature carbonate minerals have been observed in association with sulfide minerals below the platiniferous Johns-Manville (J-M) reef of the Stillwater Complex in a stratigraphic section that has been previously shown to be characterized by unusually Cl-rich apatite. The carbonate assemblage consists of dolomite with exsolved calcite in contact with sulfide minerals: chalcopyrite and pyrrhotite in the Peridotite Zone; and pyrrhotite with pentlandite, pyrite and chalcopyrite in Gabbronorite Zone I of the Lower Banded Series. A reaction rim surrounds the carbonate–sulfide assemblages, showing an alteration of the host orthopyroxene to a more calcium-enriched, Fe-depleted pyroxene. The calcite–dolomite geothermometer yields a minimum formation temperature as high as 950 °C for the unmixed assemblages. Iron and manganese concentrations exceed the range seen in carbonatite and mantle xenolith carbonates and are distinctly different from the nearly pure end-member carbonates associated with greenschist-grade (and lower) assemblages (e.g., carbonate veins in serpentinite) that occur locally throughout the complex. The association of high-temperature carbonates with sulfides beneath the J-M reef supports the hydromagmatic theory which involves a late-stage chloride–carbonate fluid percolating upwards, dissolving PGE and sulfides and redepositing them at a higher stratigraphic level. Characterization of the processes which form strategically important metal deposits, such as the J-M reef of the Stillwater Complex and the analogous Merensky reef of the Bushveld Complex in South Africa, could potentially lead to better exploration models and, more broadly, a deeper understanding of the cooling and compositional evolution of large bodies of ultramafic and mafic magma and of carbonatites, on both a local and a regional scale.

Greenstone-hosted lode-gold mineralization at Dungash mine, Eastern Desert, Egypt

The auriferous quartz±carbonate veins at Dungash mine, central Eastern Desert of Egypt, are confined to ∼E-trending dilation zones within variably foliated/sheared metavolcanic/volcaniclastic rocks. The vein morphology and internal structures demonstrate formation concurrent with a dextral shear system. The latter is attributed to flexural displacement of folded, heterogeneous rock blocks through transpression increment, late in the Neoproterozoic deformation history of the area. Geochemistry of the host metavolcanic/metavolcaniclastic rocks from the mine area suggests derivation from a low-K, calc-alkaline magma in a subduction-related, volcanic arc setting. In addition, chemistry of disseminated Cr-spinels further constrain on the back-arc basin setting and low-grade metamorphism, typical of gold-hosting greenstone belts elsewhere.Mineralogy of the mineralized veins includes an early assemblage of arsenopyrite–As–pyrite–gersdorffite±pyrrhotite, a transitional pyrite–Sb–arsenopyrite±gersdorffite assemblage, and a late tetrahedrite–chalcopyrite–sphalerite–galena–gold assemblage. Based on arsenopyrite and chlorite geothermometers, formation of gold-sulfide mineralization occurred between ∼365 and 280°C. LA-ICP–MS measurements indicate the presence of refractory Au in arsenian pyrite (up to 53ppm) and Sb-bearing arsenopyrite (up to 974ppm). Abundant free-milling gold associated with the late sulfide assemblage may have been mobilized and re-distributed by circulating, lower temperature ore fluids in the waning stages of the hydrothermal system.Based on the isotopic values of vein quartz and carbonate, the calculated average δ18OH2O values of the ore fluids are 5.0±1.4‰ SMOW for quartz, and 3.3±1.4‰ for vein carbonate. The measured carbonate δ13C values correspond to ore fluids with δ13CCO2=−6.7±0.7‰ PDB. These results suggest a mainly metamorphic source for ore fluids, in good agreement with the vein morphology, textures and hydrothermal alteration. The calculated δ34SH2S values for early, transitional, and late sulfide assemblages define three distinct ranges (∼1.5–3.6‰), (∼0.4–1.0‰), and (−3.7‰ to −1.9‰), respectively. The systematic evolution towards lighter δ34S values may be attributed to recrystallization, or to ore fluid buffering under variable physicochemical conditions.The shear zone-related setting, mineralogy and isotopic characteristics of gold mineralization in Dungash mine are comparable with other orogenic gold deposits in the region (e.g., Barramiya deposit), which may suggest a regional setting controlling gold metallogeny of the region. This setting should guide future exploration programs in the central Eastern Desert province.

Hydrothermal alteration related to a deep mantle source controlled by a Cambrian intracontinental strike-slip fault: Evidence for the Meruoca felsic intrusion associated with the Transbraziliano Lineament, Northeastern Brazil

One of the most prominent geological structures in Borborema Province, northeast Brazil, is the Transbraziliano Lineament that crosscuts most of the South American Platform and was active at least until the Devonian. This continental structure is responsible for the formation of rift and pull-apart basins in Northeastern Brazil, most of which filled with volcanic and continental sedimentary rocks (Parente et al., 2004). In the region of Sobral, Ceará State, this same continental structure controlled the intrusion of the Meruoca pluton and the formation of the Jaibaras Basin, which is bounded by strike-slip shear zones. Hydrothermal alterations seem to have been pervasive in Meruoca, as indicated by disturbances in both the Rb–Sr and U–Pb systems (Sial et al., 1981; Fetter, 1999) and by the large dispersion of anisotropic magnetic susceptibility (AMS) (Archanjo et al., 2009).In this paper, we address the origin of the hydrothermal fluids that affected the borders of the Meruoca batholith and their relationship with the activity of the Transbraziliano Lineament. These fluids were responsible for carbonate veins and Fe–Cu mineral concentrations that are commonly found associated with hydrothermally altered breccias. The carbon and oxygen isotope composition of these carbonate veins suggest that they may be related to CO2-bearing mantle-derived fluids that were channelized by the Transbraziliano Lineament. Based on oxygen isotopes, we argue that Fe–Cu concentrations may have formed in isotope equilibrium with the rhyolitic rocks at temperatures between 500 and 560 °C. This scenario points to magmatism as the main process in the formation of these rocks.We also report a K–Ar age of 530 ± 12 Ma for muscovite associated with the last ductile event that affected the Sobral-Pedro II Shear Zone and a U–Pb age of 540.8 ± 5.1 Ma for the Meruoca pluton. We further suggest that this granite is a late-kinematic intrusion that is most likely associated with the Parapuí volcanic rocks of the Jaibaras basin (535.6 ± 8.5 Ma, Garcia et al., 2010).

Gold-bearing ferroselite (FeSe2) from Trogtal, Harz, Germany, and significance of its Co/Ni ratio

Ferroselite from Trogtal, the type locality of the cobalt selenide trogtalite, in the Harz Mountains, Germany, forms a trogtalite–ferroselite assemblage in pockets of massive clausthalite in which specular hematite is dispersed. The pockets occur in hematite-impregnated carbonate veins, emplaced in a reddened greywacke of Lower Carboniferous age. Ferroselite contains ~0.2–5.0 ppm Au; trogtalite has even higher Au contents. Ferroselite has Co/Ni ratios mostly above unity. These characteristics likely reflect oxidizing brines with Co/Ni > 1, such as those involved in the formation of sediment-hosted copper deposits.

The polar sulfur cycle in the Werenskioldbreen, Spitsbergen: Possible implications for understanding the deposition of sulfate minerals in the North Polar Region of Mars

In this study we investigated the polar cycling of sulfur (S) associated with the Werenskioldbreen glacier in Spitsbergen (Svalbard). Sulfide-derived S comprised 0.02–0.42wt% of the fine-grained fraction of proglacial sediments. These sediments originated from glacial erosion of Precambrian sulfide-rich quartz and carbonate veins. In summer 2008, the δ34S of dissolved SO4 in glacier melt waters (+9‰ to +17‰) was consistent with SO4 generation from oxidation of primary sulfide minerals in the bedrock (+9‰ to +16‰). The calculated monthly SO4 load was ∼6881kg/month/km2 in the main glacier stream. Subsequent evaporation and freezing of glacial waters lead to precipitation, accumulation, and temporary storage of sulfate salt efflorescences in the proglacial zone. These salts are presumably ephemeral, as they dissolve during annual snow/glacial melt events.Hydrated sulfates such as gypsum are also important constituents of the low-elevation areas around the polar ice cap of Planum Boreum on Mars. The origin of this gypsum on Mars might be better understood by using the investigated polar S cycle in Spitsbergen as a foundation. Assuming a trace sulfide content in the basaltic bedrock on Mars, the weathering of sulfides within the fine, porous texture of the ancient aeolian strata (basal unit) underlying Planum Boreum could have created elevated SO4 fluxes (and gypsum precipitation) during episodic thawing/melting events in the past. Limited water activity and prevailing dry conditions on the surface of Mars are the likely factors that accounted for the larger accumulation and preservation of polar gypsum on the surface and its broad aeolian distribution around Planum Boreum. This suggestion is also supported by an experiment showing that gypsum sand can be transported, under dry conditions, over great distances (∼2000km) without a significant loss of mass.

Dawsonite and Other Carbonate Veins in the Cretaceous Izumi Group, SW Japan: A Natural Support for Fracture Self-Sealing in Mudstone Caprock in CGS?

Dawsonite-bearing carbonate veins are abundant in a compact mudstone layer of the lower part of the Izumi Group, SW Japan. The mode of occurrence of the veins probably indicates fracturing and mineral sealing associated with upwelling of CO2-rich fluid evolved in the reservoir beneath. The carbonate veins studied here can be a natural support to fracturing and healing of mudstone caprock in the CO2 geological storage.

Calcium carbonate veins in ocean crust record a threefold increase of seawater Mg/Ca in the past 30 million years

Chemical (Sr, Mg) and isotopic (δ18O, 87Sr/86Sr) compositions of calcium carbonate veins (CCV) in the oceanic basement were determined to reconstruct changes in Sr/Ca and Mg/Ca of seawater in the Cenozoic. We examined CCV from 10 basement drill sites in the Atlantic and Pacific, ranging in age between 165 and 2.3Ma. Six of these sites are from cold ridge flanks in basement <46Ma, which provide direct information about seawater composition. CCV of these young sites were dated, using the Sr isotopic evolution of seawater. For the other sites, temperature-corrections were applied to correct for seawater–basement exchange processes. The combined data show that a period of constant/low Sr/Ca (4.46–6.22mmol/mol) and Mg/Ca (1.12–2.03mol/mol) between 165 and 30Ma was followed by a steady increase in Mg/Ca ratios by a factor of three to modern ocean composition. Mg/Ca–Sr/Ca relations suggest that variations in hydrothermal fluxes and riverine input are likely causes driving the seawater compositional changes. However, additional forcing may be involved in explaining the timing and magnitude of changes. A plausible scenario is intensified carbonate production due to increased alkalinity input to the oceans from silicate weathering, which in turn is a result of subduction-zone recycling of CO2 from pelagic carbonate formed after the Cretaceous slow-down in ocean crust production rate.

Carbon Mineralization: From Natural Analogues to Engineered Systems

Carbon mineralization sequesters CO2 by reaction of alkaline earth metal bearing silicate and hydroxide minerals with CO2 to form stable carbonate minerals. Seifritz (1990) proposed harnessing this natural process as a method for sequestration of anthropogenic CO2. It was first studied in detail as an industrial process by Lackner et al. (1995), which is often referred to as “mineral carbonation.” Much of this early research aimed to capitalize on the globally abundant natural deposits of ultramafic and mafic rocks, which are rich in alkaline earth metals, in addition to the long-term stability of the resultant carbonate minerals (Lackner et al. 1995). More recently, other process routes have been investigated that rely on feedstocks other than naturally occurring minerals (e.g., industrial wastes) as a source of cations for carbonate precipitation. Therefore, we use the more general term “carbon mineralization” to refer to any process that sequesters CO2 as a solid carbonate phase. The main advantages of carbon mineralization as a CO2 storage method are that the reactions are thermodynamically favored, the carbonation processes can be readily controlled and manipulated, and the resulting product is benign and stable over geological time. We begin this review with an overview of the fundamental processes that are relevant to carbon mineralization, which provides a basic framework in which to understand CO2 sequestration strategies based on carbon mineralization. We next discuss natural analogues to engineered systems, focusing on (1) exhumed hydrothermal systems in peridotite that have formed listvenite (magnesite + quartz) and soapstone and (2) shallow subsurface peridotite weathering processes and related alkaline springs that form carbonate veins, surficial travertine deposits, and hydromagnesite–magnesite playas. The propensity to form carbonate minerals in these ultramafic terranes reflects the thermodynamic instability of Mg-silicate minerals in the presence of CO2. …

REE geochemistry of auriferous quartz carbonate veins of Neoarchean Ajjanahalli gold deposit, Chitradurga schist belt, Dharwar Craton, India

REE composition of the carbonates of the auriferous quartz carbonate veins (QCVs) of the Neoarchean Ajjanahalli gold deposit, Chitradurga schist belt, Dharwar Craton, is characterized by U-shaped chondrite normalized REE patterns with both LREE and HREE enrichment and a distinct positive Eu anomaly. As positive Eu anomaly is associated with low oxygen fugacity, we propose that the auriferous fluids responsible for gold mineralization at Ajjanahalli could be from an oxygen depleted fluid. The observed positive Eu anomaly is interpreted to suggest the derivation of the auriferous fluids from a mantle reservoir. The location of Ajjanahalli gold deposit in a crustal scale shear zone is consistent with this interpretation.

Solute transport across basement/cover interfaces by buoyancy-driven thermohaline convection: Implications for the formation of unconformity-related uranium deposits

Previous studies have suggested that buoyancy-driven convection could only have developed in thick sandstone aquifers within Proterozoic intracratonic sedimentary basins that host unconformity-related uranium deposits. On the other hand, oxygen and hydrogen isotopic and fluid inclusion studies of quartz and carbonate veins have shown that basinal brines have interacted with basement rocks and basement-derived fluids pervasively. Finite element modeling was conducted to investigate the potential mechanisms driving fluid interaction across a basement/cover unconformity. We firstly constructed a simplified conceptual model by integrating the known features shared by the Athabasca, Thelon and Kombolgie basins and their Phanerozoic counterparts. Based on this conceptual model, various numerical scenarios were designed to examine buoyancy-driven (heat and solute transport are coupled) fluid flow patterns and the corresponding solute transport. The results show that thermohaline convection may have penetrated into the basement for up to 1 to 2 km below the unconformity, when typical hydrological parameters for these Proterozoic hydrogeological units were used. Fluid flow velocities in the sandstone sequence were several orders of magnitude larger than those in the basement. If a uranium source (a pore fluid with 500 mg/l uranium) was assumed to be located in the center of the basin below the unconformity, uranium was able to gradually spread into the sandstone aquifer through thermohaline convection without considering any contribution from fluid-rock interaction. The uranium concentration of basinal fluids above the uranium source approached 15 and 24 mg/l after 1 and 5 m.y. of modeling time, respectively. If the uranium source was initially located at the center of the aquifer, a uranium plume developed and percolated down to 2 km below the unconformity at 5 m.y. The location of the uranium source also affects the solute transport efficiency. A uranium source located around the sloping basal unconformity, either in the basin fill or basement, close to the basin margin, led to a wider uranium plume than if it was located near the center of the basin. Given appropriate hydrological conditions, thermohaline convection could have caused widespread interaction of basinal brines with basement rocks or basement-derived fluids in Proterozoic basins where unconformity-related uranium deposits have developed, and that enough uranium could have been leached from the uranium-rich basement to form large, high-grade unconformity-related uranium deposits.

CORDYLITE-(La), A NEW MINERAL SPECIES IN FENITE FROM THE BIRAYA Fe-REE DEPOSIT, IRKUTSK, RUSSIA

Cordylite-(La), (Na,Ca)2Ba2(La3Sr)∑4(CO3)8F2, is a new mineral species (IMA2010–058) from the Biraya Fe–REE deposit, Irkutsk district, Russia. It occurs in direct association with barite, biraite-(Ce), niobium-rich chevkinite-(Ce), fergusonite-(Nd), ancylite-(Ce) and ancylite-(La), daqingshanite-(Ce) and daqingshanite-(La), bastnasite-(Ce), hydroxylbastnasite-(Ce), carbocernaite, monazite-(Ce), talc, humite, thorite, pyrite, and pyrrhotite in carbonate veins composed of aragonite, strontianite, calcite, dolomite, and cordylite-(Ce). Cordylite-(La) forms as colorless, honey-yellow, or pinkish yellow, irregularly-shaped, tabular, or short-prismatic hexagonal crystals up to about 3 mm across. The only forms observed are {1010} and {0001} and crystals have perfect cleavage on {0001}. Crystals have a greasy to vitreous luster, a brittle tenacity, a conchoidal to uneven fracture, and a hardness of 4 on the Mohs scale. Crystals are uniaxial (−), ɛ = 1.573–1.574, and ω = 1.749–1.751. The empirical formula for two different crystals gave: (Na1.24Ca0.78)∑2.02Ba2.10[(La1.54Ce1.31Nd0.17Pr0.04)∑3.06Sr0.89]∑3.95(C1.01O3)8(F1.78OH0.05)∑1.83 and(Na1.23Ca0.79)∑2.02Ba1.98[(La1.43Ce1.33Nd0.25Pr0.10)∑3.11Sr0.94]∑4.05(C1.01O3)8(F1.51OH0.38)∑1.89. The crystal structure, solved on the same two crystals ( R 1 = 0.0246 and 0.0205) gave the unit cell parameters in P 63/ mcc: a = 5.1182(5) and c = 23.1785(16) A and V = 525.84(16) A3 and a = 5.1196(3) and c = 23.1784(16) A and V = 525.13(5) A3 with Z = 1, and confirms that the mineral is isostructural with cordylite-(Ce). We also discuss new heterovalent substitution mechanisms found in the cordylite group minerals and the effect they have during the formation of crystals.

Geology and fluid evolution of the Wangfeng orogenic-type gold deposit, Western Tian Shan, China

The Wangfeng gold deposit is located in Western Tian Shan and the central section of the Central Asian Orogenic Belt (CAOB). The deposit is mainly hosted in Precambrian metamorphic rocks and Caledonian granites and is structurally controlled by the Shenglidaban ductile shear zone. The gold orebodies consist of gold-bearing quartz veins and altered mylonite. The mineralization can be divided into three stages: quartz–pyrite veins in the early stage, sulfide–quartz veins in the middle stage, and quartz–carbonate veins or veinlets in the late stage. Ore minerals and native gold mainly formed in the middle stage. Four types of fluid inclusions were identified based on petrography and laser Raman spectroscopy: CO2–H2O inclusions (C-type), pure CO2 inclusions (PC-type), NaCl–H2O inclusions (W-type), and daughter mineral-bearing inclusions (S-type). The early-stage quartz contains only primary CO2–H2O fluid inclusions with salinities of 1.62 to 8.03wt.% NaCl equivalent, bulk densities of 0.73 to 0.89g/cm3, and homogenization temperatures of 256°C–390°C. Vapor bubbles are composed of CO2. The middle-stage quartz contains all four types of fluid inclusions, of which the CO2–H2O and NaCl–H2O types yield homogenization temperatures of 210°C–340°C and 230°C–300°C, respectively. The CO2–H2O fluid inclusions have salinities of 0.83 to 9.59wt.% NaCl equivalent and bulk densities of 0.77 to 0.95g/cm3, with vapor bubbles composed of CO2, CH4, and N2. Fluid inclusions in the late-stage quartz are NaCl–H2O solution with low salinities (0.35–3.87wt.% NaCl equivalent) and low homogenization temperatures (122°C–214°C). The coexistence of inclusions of these four types in middle-stage quartz suggests that fluid boiling occurred in the middle-stage mineralization. Trapping pressures estimated from CO2–H2O inclusions are 110–300MPa and 90–250MPa for the early and middle stages, respectively, suggesting that gold mineralization mainly occurred at depths of about 10km. In general, the Wangfeng gold deposit originated from a metamorphic fluid system characterized by low salinity, low density, and enrichment of CO2. Depressurized fluid boiling caused gold precipitation. Given the regional geology, ore geology, fluid-inclusion features, and ore-forming age, the Wangfeng gold deposit can be classified as a hypozonal orogenic gold deposit.

Oxygen isotope and fluid inclusion study of the Sorkhe-Dizaj iron oxide-apatite deposit, NW Iran

The Sorkhe-Dizaj orebody is located 32 km southeast of Zanjan within the Tarom subzone of the Alborz-Azarbaijan structural zone. It is hosted mainly in quartz monzonite-monzodiorite and, to a lesser extent, in volcanoclastic rocks. Mineralization occurs in the form of stockwork and veins, comprising predominantly magnetite and actinolite, with minor pyrite and chalcopyrite. Two generations of magnetite and apatite are inferred: the first as disseminations in the host rock and the second mainly as an alteration product of actinolite, secondary K-feldspar, silica, sericite, chlorite and epidote. Fluid inclusion studies were carried out on second-generation apatite, and late-stage quartz to understand the geochemical evolution of the ore-bearing fluids. Fluid inclusions are of three types, i.e. primary, secondary, and pseudo-secondary. These inclusions are liquid or vapour single-phase, two-phase rich in liquid or vapour, and three-phase. Homogenization temperatures of second-generation apatite are inferred to be between 209°C and 520°C (mostly between 290°C and 320°C), indicating salinities of 9.08–21.61 wt.% NaCl equiv. At 342°C, the δ18O values range from 9‰ to 11.32‰ for the second-generation magnetite associated with coeval apatite. Fluid inclusions in the late-stage quartz veins are inferred to have homogenized between 186°C and 263°C, with δ18O values ranging between 2.5‰ and 7.4‰ at 220°C. Oxygen isotopes in the late-stage carbonate veins have values of 3.28–6.14‰ at 100°C. These data in the late-stage veins imply introduction of a cooler, less saline, isotopically depleted fluid, probably meteoric water. Field observations, mineral parageneses, and fluid inclusion + oxygen isotope data suggest that the magnetite-apatite veins formed from a predominantly magmatic-derived fluid. Introduction of cooler meteoric water in the final stage of mineralization reduced δ18O values, facilitating precipitation of sulphides, quartz, and carbonate veins.

Geological and thermochronological studies of the Dashui gold deposit, West Qinling Orogen, Central China

The Dashui gold deposit is a structurally controlled, Carlin-type gold deposit hosted by recrystallised limestone in the West Qinling Orogen of Central China. The major, structurally late east-trending Dashui Fault forms the hanging wall to the gold mineralisation at the Dashui mine and defines the contact between Middle Triassic limestone and a steeply dipping overlying succession of Middle Triassic argillaceous limestone, dolomite, and sandstone. Multiple carbonate veins and large-scale supergene enrichment, represented by hematite, goethite, limonite and jarosite, characterise the deposit. Detailed geochronological investigation using zircon SHRIMP U-Pb dating reveals that volcanic rocks closely associated with the Dashui gold deposit were synchronous with the Ge’erkuohe Granite and pre-date mineralisation. The igneous dyke sample from the hanging wall has the same U-Pb zircon age as the footwall, ca. 213 Ma. (U-Th)/He thermochronology on dykes in the hanging wall and footwall of the Dashui Fault yields identical (U-Th)/He zircon ages of ca. 210 Ma but distinct (U-Th)/He apatite ages of ca. 136 and 211 Ma, respectively. Therefore, the hanging wall and footwall are interpreted as having distinct post-mineralisation exhumation histories. Reverse fault movement exhumed the hanging wall ~2 to 4 km since the Late Triassic with the main component of faulting taking place between the Late Triassic and Early Cretaceous. These relationships suggest a Late Triassic to Early Cretaceous age for the primary gold mineralisation at the Dashui gold deposit, with the corollary that any ‘missing portion’ of the deposit, previously hypothesised to exist in the hanging wall of the Dashui Fault, has been eroded away. The mineralisation in the footwall may have been supergene enriched soon after the primary mineralisation was emplaced, because it has been located at shallow depth since the Late Triassic. Semi-quantitative results obtained in this study also constrain the maximum depth of formation of the Dashui gold at no more than 2 km.

Geological and geochemical constraints on genesis of the Liziyuan gold-dominated polymetal deposit, western Qinling orogen, central China

The Liziyuan gold deposit, located on the northern margin of the western Qinling orogen (WQO), consists of five mineralized sites hosted by metavolcanic rocks, and one hosted by the Tianzishan monzogranite. Orebodies mainly occur as lenticular veins along NW-striking dextral ductile strike–slip shear zones. Major wall rock alteration includes silicification, pyritization, and carbonation, progressively increasing in intensity towards the orebodies. Ore minerals are dominated by pyrite, galena, and chalcopyrite; the major gangue minerals are quartz and calcite. Native gold is present chiefly as separate phases in sulphide and quartz microfractures. We recognize four stages of mineralization: (I) pyrite-quartz, (II) native gold-chalcopyrite-pyrite-quartz, (III) pyrite-freibergite-galena-quartz-carbonate, and (IV) carbonate stages. Fluid inclusion petrography and microthermometric results suggest that three types of primary fluid inclusions (carbonic, CO2–H2O, and aqueous) are present in the deposit. Microthermometric data and Laser Raman analyses indicate that the ores were deposited from moderate temperature (240–280°C), low salinity (0.5–9.1 wt.% NaCl equiv.) H2O–NaCl–CO2–(CH4) fluids. The common coexistence of aqueous, CO2–H2O, and carbonic inclusions indicates the trapping of heterogeneous immiscible fluids. Trace elements in mineralized quartz and carbonate veins suggest that the ore-forming fluids were mainly produced by prograde metamorphism of the upper crust. The calculated and δD values are 1.8–3.8‰ and –77‰ to –75‰, respectively, for quartz from stage II and –8.5‰ to –6.6‰ and –72‰ to –71‰ for calcite from stage III, implying that the ore-forming fluids were metamorphic in origin and evolved by late-stage mixing with meteoric water. Pyrite and galena have δ34S values of 3.9–8.5‰ with a pronounced mode at 5–8‰. Such relatively homogeneous sulphur isotopic compositions are consistent with orogenic gold deposits throughout the world, indicating that the sulphur was mainly sourced from reduced metamorphic fluids. The Liziyuan gold deposit can be grouped with other orogenic gold deposits that have similar characteristics. Geological observations and available isotopic ages suggest that the Liziyuan lode mineralization was related to the Indosinian orogenesis of the Qinling belt. Triassic continental collision caused crustal thickening, dextral ductile shearing, and greenschist facies metamorphism throughout the orogen. Due to the intensive deformation and metamorphism, crustal rocks released copious fluids that evidently mobilized and extracted ore elements along their flow pathways. The ductile shear zone in the Liziyuan mining area provided regions of low mean stress and high permeability, and thus appeared to be preferential channels for precipitation of the ore-forming fluids. As highly charged fluids migrated into the high permeability shear zones, rapid changes in physicochemical conditions resulted in sulphide precipitation and gold mineralization.

Silver-rich telluride mineralization at Mount Charlotte and Au–Ag zonation in the giant Golden Mile deposit, Kalgoorlie, Western Australia

The gold deposits at Kalgoorlie in the 2.7-Ga Eastern Goldfields Province of the Yilgarn Craton, Western Australia, occur adjacent to the D2 Golden Mile Fault over a strike of 8 km within a district-scale zone marked by porphyry dykes and chloritic alteration. The late Golden Pike Fault separates the older (D2) shear zone system of the Golden Mile (1,500 t Au) in the southeast from the younger (D4) quartz vein stockworks at Mt Charlotte (126 t Au) in the northwest. Both deposits occur in the Golden Mile Dolerite sill and display inner sericite–ankerite alteration and early-stage gold–pyrite mineralization replacing the wall rocks. Late-stage tellurides account for 20 % of the total gold in the first, but for 30 g/t Au) is characterized by Au/Ag = 2.54 and As/Sb = 2.6–30, the latter ratio caused by arsenical pyrite. Golden Mile-type D2 lodes occur northwest of the Golden Pike Fault, but the Hidden Secret orebody, the only telluride bonanza mined (10,815 t at 44 g/t Au), was unusually rich in silver (Au/Ag = 0.12–0.35) due to abundant hessite. We describe another array of silver-rich D2 shear zones which are part of the Golden Mile Fault exposed on the Mt Charlotte mine 22 level. They are filled with crack-seal and pinch-and-swell quartz–carbonate veins and are surrounded by early-stage pyrite + pyrrhotite disseminated in a sericite–ankerite zone more than 6 m wide. Gold grade (0.5–0.8 g/t) varies little across the zone, but Au/Ag (0.37–2.40) and As/Sb (1.54–13.9) increase away from the veins. Late-stage telluride mineralization (23 g/t Au) sampled in one vein has a much lower Au/Ag (0.13) and As/Sb (0.48) and comprises scheelite, pyrite, native gold (830–854 fine), hessite, and minor pyrrhotite, altaite, bournonite, and boulangerite. Assuming 250–300 °C, gold–hessite compositions indicate a fluid log f Te2 of −11.5 to −10, values well below the stability of calaverite. The absence of calaverite and the dominance of hessite in the D2 lodes of the Mt Charlotte area point to a kilometer-scale mineral and Au/Ag zonation along the Golden Mile master fault, which is attributed to a lateral decrease in peak tellurium fugacity of the late-stage hydrothermal fluid. The As/Sb ratio may be similarly zoned to lower values at the periphery. The D4 gold–quartz veins constituting the Mt Charlotte orebodies represent a younger hydrothermal system, which did not contribute to metal zonation in the older one.

Complex deposits in the Lo Gam structure, northeastern Vietnam: mineralogy, geochemistry, and formation conditions

The Pb–Zn deposits in the Lo Gam structure, northeastern Vietnam, account for>80% of all the Pb and Zn resources of Vietnam. All the deposits make up four isolated ore districts (Thai Nguyen, Cho Don, Cho Dien, Na Son), which can be combined in one metallogenic zone extending for >100 km from southeast to northwest. The Pb–Zn deposits in all the ore districts show some similarity to stratiform (Mississippi-type) deposits: confinement to Devonian carbonate sediments; localization at the intersection of faults of different orientations; vein and stockwork (pocket-vein-disseminated) morphology of the mineralized zones; evidence for hydrothermal-metasomatic formation (carbonate-rock marbleization, quartz–carbonate veins, etc.); and low and moderate mineralization temperatures (<250 °C). On the other hand, some differences from stratiform deposits are observed: widespread occurrence of Permo-Triassic igneous rocks in the above ore districts; absent tabular orebodies, which are typical of stratiform deposits; large set of trace elements (In, Bi, Sb, Au, Ag, Cu, Cd) not typical of stratiform deposits; and an endogenic primary source, as evidenced by the isotope composition of sulfur (δS34= 2.68‰), which is close to meteoritic, and the set of trace elements, which are mainly of deep genesis. All this indicates that the above Pb–Zn deposits within the carbonate units are low-and moderate-temperature hydrothermal-metasomatic products associated with active magmatism which took place in this region in the Permo-Triassic.The differences in the mineral composition of the deposits, as well as in the trace-element set and contents at different deposits, clearly indicate an intricate ore formation process and the relation of the deposits with magmatism of different compositions. The simple mineral composition and the limited set of trace elements (Cd, Ag, Sb, As) at the Lang Hich deposit are closer to the characteristics of stratiform deposits. Also, manifestations of magmatism are almost absent here. On the contrary, unusually high (ppm) In (75.8), Sn (307.5), Cu (1080), Ag (157.7), Bi (99), and As (13,650) contents were observed at the deposits of the Cho Don and Cho Dien districts, with widespread granitoid magmatism in the Phia Bioc complex. Rare-earth mineralization (orthite) and high Mo, Re, and Rb contents at the deposits of the Na Son district are probably due to the widespread occurrence of stratified alkaline volcanics and their subvolcanic analogs, which belong to the Pla Ma complex (ξγPZ2 pm).

Coexisting serpentine and quartz from carbonate-bearing serpentinized peridotite in the Samail Ophiolite, Oman

Tectonically exposed mantle peridotite in the Oman Ophiolite is variably serpentinized and carbonated. Networks of young carbonate veins are prevalent in highly serpentinized peridotite, particularly near low-temperature alkaline springs emanating from the peridotite. An unusual feature in some samples is the coexistence of serpentine and quartz, which is not commonly observed in serpentinites. This assemblage is unstable with respect to serpentine + talc or talc + quartz under most conditions. Serpentine in the carbonated serpentinites in this study is more iron rich than in most serpentinites reported in previous studies, and samples with co-existing quartz contain the most iron-rich serpentines. Calculations of thermodynamic equilibria in the MgO–SiO2–H2O–CO2 system suggest that serpentine + quartz may be a stable assemblage at low temperatures (e.g., <~15–50 °C) and is stabilized to higher temperatures by preferential cation substitutions in serpentine over talc. Based on these calculations, serpentine + quartz assemblages could result from serpentinization at near-surface temperatures. Clumped isotope thermometry of carbonate veins yields temperatures within error of the observed temperatures in Oman groundwater for all samples analyzed, while the δ18O of water calculated to be in equilibrium with carbonate precipitated at those temperatures is within error of the observed isotopic composition of Oman groundwater for the majority of samples analyzed. As groundwater geochemistry suggests that carbonate precipitation and serpentinization occur concomitantly, this indicates that both hydration and carbonation of peridotite are able to produce extensive alteration at the relatively low temperatures of the near-surface weathering environment.