Carbonate Deposits Research Articles

The possible actiniarian sea anemone burrow Bergaueria hemispherica from the Pliensbachian (Lower Jurassic) of the Lusitanian Basin (Central Portugal)

Abstract The shallow marine carbonate deposits of the S. Miguel Formation in the Lusitanian Basin reveal erosional events exposing stiff substrates with abundant Bergaueria hemispherica . The ichnoassociation represented by B. hemispherica , Thalassinoides suevicus , Spongeliomorpha isp., Asterosoma ludwigae and Rhizocorallium commune is dated from lowermost Pliensbachian by the association with ammonites from the jamesoni Biozone, brevispina Subzone. The unlined forms of B. hemispherica include peripheral and bottom burrow concentrations of shell debris, annular-like structures in the burrow margin and paired burrows-to-linear clusters that are comparable with the penetrative burrowing mechanism, anchoring and feeding behaviours of sea anemones. From the ethological point of view, and comparing with modern behaviours of burrowing anemones, the B. hemispherica from the Lusitanian Basin may represent temporary burrowing and relocation of actiniarian anemones. Their comparison with either thenarian or athenarian actiniarians may evidence a preferred surficial feeding strategy on the organic-rich muddy sediments they burrowed.

Reef Complexes of the Late Ordovician–Early Silurian Altai Basin: Classification, Structure, Paleobiota, and Paleogeography

Abstract —The paper presents data on the classification, structure, and biota of reef complexes from the Late Ordovician–early Silurian Altai Basin. The early Paleozoic history of the Altai Basin included the early–middle Katian, late Katian, early Hirnantian, late Telychian, and middle–late Sheinwoodian events of large-scale reef formation which produced framework reefs, mud mounds, and coral meadows. The early Paleozoic reefs of the area formed at rates of 40 to ~12 cm per thousand years. The late Telychian reef system, which formed in 0.51–1.0 Myr, occupied the largest area of the basin. The lateral extent of reef systems in the Late Ordovician–early Silurian basin of Altai depended more on the rates of vertical and lateral growth, as well as on the previous sea bottom topography and clastic inputs, than on the duration of reef formation. Carbonate deposition in the Altai basins of that time can be simulated with a general model implying formation of distal barrier reefs.

Sediment geochemistry of the section Tagay-1 at Olkhon Island (Lake Baikal, Eastern Siberia): a contribution to palaeoenvironmental interpretations

The Miocene Tagay section in the north-western part of Olkhon Island, Lake Baikal, provides a unique window into past life in northern Asia. To aid palaeoenvironmental reconstructions, we carried out whole-rock geochemical analyses of 17 sedimentary layers of this section. The aim of this geochemical approach is to examine the element variations as a response to climate change during formation of the Tagay section deposits with a focus on the hydrological regime of the catchment and in-lake processes. Our results establish that temperature and climate conditions during the formation of sediments of section Tagay-1 were fairly stable, no abrupt climatic changes occurred. The palaeoclimate was temperate, however, it had a cyclic nature: wet and semiarid epochs of different intensity and duration alternated. The basal part of the sediment sequence is dominated by terrigeneous material, mainly by surface runoff, so the sedimentation was fed by erosion products of the weathering crust. During sedimentation of this lower part (layers 17–9), the palaeo-lake level and salinity stayed practically unchanged. The drawdown of the palaeo-lake and increasing salinity started in the higher middle part (layer 8), and reached the minimum water level and maximum salinity in layers 7–6. Sediments of the layers 8–6 accumulated in an arid climate. After deposition of layer 5, the water level began to rise, and during formation of layer 3 it fell again. The highest sedimentation rate was in layers 12–5, these are also the layers with the highest enrichment of biogenic elements (layers 12, 7–5) and where carbonate deposition took place. The observed changes in element behaviour are related to hydrological changes in the catchment (precipitation), lake level status, and evaporation, and are ultimately driven by climate.

Paleoenvironmental analyses of coralline red algal assemblages in Lower Miocene carbonate deposits of Central Iran

ABSTRACT This work is based on coralline red algal flora-dominated Lower Miocene carbonates of the Qom Formation from Central Iran Basin. Five assemblages, including corallinoid, lithophylloid, mastophoroid, melobesioid and sporolithoid corresponding to 11 genera of geniculate and non-geniculate, were identified. Also, growth forms and taphonomic characteristics of coralline-algal grains were assessed. The arborescent, layered to foliose lamellae, fruticose, lumpy, warty and encrusting growth forms of studied taxa are observed and five taphonomic traits belonging to both mechanical [abrasion, disarticulation, fragmentation] and biological [encrustation, bioerosion] processes were recognised. The relative abundance of assemblages, growth forms, and taphonomy of red algae visualised at thin-section scale were calculated. Our quantitative analysis highlights mechanical (abrasion > fragmentation) and biological (bioerosion> encrustation) processes. Moreover, layered to foliose and fruticose abundance peaks reveal higher than others. This kind of algal distribution in the examined region indicates that the Qom Formation was deposited on a marine carbonate shelf, which is a deepening depositional system in tropical and subtropical zone. This approach expresses more abundance of red algal assemblages on the deep part of inner and proximal to distal middle shelf settings along with a regime of moderately high towards low hydrodynamic energy and mesophotic – oligophotic conditions.

RADIOCARBON DATING OF URBAN SECONDARY CARBONATE DEPOSITS: SITE EFFECT AND IMPLICATION FOR CHRONOLOGY: CASE STUDY OF PARIS AND VERSAILLES PALACE FOUNTAINS

ABSTRACTIn urban environments, diachronic evolution of water quality can be reconstructed using geochemical analysis of urban secondary carbonate deposits (USCDs), from urban underground structures, similar to speleothems from natural caves. The use of the radiocarbon bomb peak to build their precise chronology was recently tested in two Paris-area urban sites (France). In this study, new samples from contrasted environments in the Paris region were sampled in order to test the sites’ effects on the radiocarbon signal recorded: under wood, under a fountain, in underground aqueducts, in the south and north of Paris. We compared the post-bomb atmospheric radiocarbon record with the one measured at the top of USCDs, and estimated the dead carbon proportion (DCP), between 0 and 40%. USCDs fed by water with a rapid transfer through thin soil (Versailles fountain) had the lowest DCP (14C very close to atmospheric one). Highest DCP were found for USCD from deep underground quarry under urban wood, and intermediate ones for USCDs fed by the waters of perched aquifers. These data support the use of radiocarbon as chronometer for USCDs in contrasted urban contexts, and show that it can be used to determine carbon transport and sources, an important parameter for pollution reconstruction.

The upper Hauterivian–Barremian (Lower Cretaceous) Arrifes section (Algarve Basin, Southern Portugal): A palynostratigraphic and palaeoenvironmental approach

Integrated sedimentological, palynological, and palynofacies analyses of the Arrifes section in the central Algarve Basin (southern Portugal) provided new information on the age and environments of this Lower Cretaceous sequence. The sedimentary succession at the Arrifes section consists of fossiliferous interbedded limestones, marly limestones, and marls, dated as latest Hauterivian to late Barremian age (Lower Cretaceous) based on key dinoflagellate taxa. During this interval, the Arrifes area records climatic shifts and, multiple sea-level fluctuations; overall deposition was in shallow subtidal to intertidal settings, with deposition of carbonate and marly sediments. During the latest Hauterivian to earliest Barremian interval, an evident sea-level fall culminated in the subaerial exposure of the local carbonate ramp with increased influx of clastic sediments. However, during the Barremian, both sedimentological and palynological analyses suggest an overall deepening of the water depth towards the top of the section. These overall increase in the water column are confirmed by oscillation of terrestrial/marine palynomorph groups and supported by dinosaur track levels at the top of the succession; the latter indicate that sedimentation occurred in intertidal to subtidal environments. Finally, an attempt was made to correlate the Arrifes section with other sections from the Algarve Basin, as well as with broader region. These new data suggest a setting in the Tethyan basin influenced during the latest Hauterivian to the end of the Barremian. These new data allow local correlations and new palynological ages and paleoenvironmental interpretations for the Lower Cretaceous succession of the Algarve Basin.

No evidence for expansion of global ocean euxinia during the base Stairsian mass extinction event (Tremadocian, Early Ordovician)

A Tremadocian (Early Ordovician, base Stairsian North American Stage) mass extinction event is recorded globally in rocks from several ancient continents and is accompanied by a globally correlated positive carbon isotope excursion (CIE; the largest during the Early Ordovician). In this study, elemental concentrations and uranium isotope compositions (δ238U) were measured for carbonate samples from three sections (along a proximal-to-distal transect: Ibex area, Shingle Pass, Meiklejohn Peak, respectively) in the Great Basin to test the role of ocean anoxia/euxinia on the base Stairsian mass extinction event. Dysoxic/suboxic to oxic water columns and non-sulfidic porewaters are inferred for these sections based on multiple local redox proxies (e.g., Mo/Al, U/Al, Mo and U concentrations, Mo/U ratios).Carbonate δ238U data exhibit different δ238U trends in the three sections. The proximal Ibex area exhibits a small negative δ238U excursion (a magnitude of 0.2–0.3‰) and the Shingle Pass section has one sample with unusually low δ238U, in both cases within the middle of the CIE. Samples with the lowest δ238U in each section also have the highest Mn/Sr ratios, suggesting diagenetic alteration associated with adsorption of isotopically light U onto Mn oxides, followed by dissolution of Mn oxides by reducing porewaters and capture of the isotopically light U by sediments. The distal Shingle Pass and Meiklejohn Peak sections better preserve global ocean signals and the limited δ238U variations in these sections imply no significant changes in global seawater δ238U and thus no significant changes in the extent of global ocean euxinia. Given the non-sulfidic porewaters inferred for these carbonates, we apply a sediment–seawater δ238U offset of 0–0.27‰ (the 0.27 ± 0.14‰ isotopic offset observed for modern Bahamas carbonates with sulfidic porewaters is used as a maximum constraint) to the average carbonate δ238U from the two distal sections (−0.48 ± 0.09‰) to derive a coeval seawater δ238U of between −0.75 ± 0.09‰ and −0.48 ± 0.09‰. A three-sink U isotope mass balance model suggests 0.2–15.8% global euxinic seafloor area existed during deposition of these Tremadocian carbonates. Our study implies that a small biotic crisis during a small CIE was not associated with an expansion of global ocean euxinia, in contrast to major Phanerozoic mass extinctions that were commonly associated with significant expansion of ocean euxinia during large carbon perturbations (e.g., the Late Devonian). In addition, we propose that the post-SPICE Cambrian and Early Ordovician oceans were characterized by limited changes in ocean euxinia and only a few episodes of expanded ocean suboxia-anoxia during carbon perturbations. The “biomere” events within this period, including the base Stairsian event, were probably related to these episodes of expanded suboxic-anoxic oceans and/or other ecological stresses.

Geological Structure Features of Carbonate Formations and Their Impact on the Efficiency of Developing Hydrocarbon Deposits

The development of deposits with a complex geological structures is often accompanied by a set of problems associated with optimal decision making. The efficiency of the entire development system depends on the completeness and the quality of the analysis of reservoir parameters. This paper presents methodological approaches for the study of carbonate deposits, and the development of further steps to increase the efficiency of reserve recovery. The secondary transformation of reservoir rocks, resulting in channels of increased conductivity, cracks, and caverns, plays a special role in the nature of the recovery of hydrocarbon reserves from such deposits. Secondary cavernosity leads to violations of the linear laws of fluid filtration in a porous medium, and complicates the field performance prediction based on geological and hydrodynamic modeling. The studied geological structure was detailed using the example of carbonate deposits composed of oil and water- saturated formations, taking into account the results of core studies and the interpretation of geophysical well studies. Furthermore, the parameters of production wells made it possible to confirm that the oil saturated and underlying water saturated formations have hydrodynamic connectivity due to the presence of vertical micro cracks. At the same time, the thickness of the bridge between the reservoirs directly affects the initial water cutting of well production, and further growth dynamics of the water ratio are associated with the structural factors determining the initial oil content of the reservoir. The combination of the obtained dependencies and the distribution model of the reservoir properties along the area made it possible to build a complex map reflecting the predicted development efficiency in certain areas. The integration of the results of various field studies on the injection well stock established that a significant part of the water flows was injected into the water saturated formation, which reduces the efficiency of formation pressure maintenance in the target formation. As a result, in order to reduce the low efficiency injection volume, switching to a more rigid waterflooding system, in terms of the ratio of production and injection wells, is proposed with a further decrease in the injection pressure inside the wells.

Sedimentary model of the Ediacaran Doushantuo cap carbonates from the southeastern margin of the Yangtze Block: Evidence from carbon and oxygen isotopes and elemental geochemistry

Cap carbonate of the early Ediacaran period represents an abrupt climate shift from severe Marinoan glaciation to a post‐glacial warm environment. Some consensuses on the distinctive negative excursion of δ13Ccarb and the origin of its unique sedimentary structures have been reached over the past decades, but certain aspects such as the distribution and redox conditions of cap carbonate still remain controversial. To resolve these issues, we collected detailed samples of the Doushantuo cap carbonate from the Ganlong‐Fanyang section and the Poutoushang reservoir section in the Danzhai County, southeast Guizhou Province, respectively. We conducted carbon and oxygen isotope analysis and trace element analysis in this study. The Ganlong‐Fanyang section was possibly situated in a submarine highland because of its higher carbon isotope than that of the Potoushang section according to the carbon isotopic gradient. Negative carbon isotope excursions at the basal Doushantuo cap carbonate from the two sections correlate well with those from other equivalent cap carbonates and were corresponding to the first one (SN1 or EN1) of the carbon isotopic curve during the Ediacaran period, implying a remarkable global event after the post‐Marinoan glaciation. Geochemical features of trace elements and rare earth elements support an overall oxygen‐rich condition with syn‐depositional or pene‐contemporaneous hydrothermal activities and methane seeps during the deposition of cap carbonate. We reconstruct a new sedimentary model that the Doushantuo cap carbonates were mainly precipitated in relatively shallow‐ to deep‐water shelf environments without disturbance by abundant terrestrial materials, which may be on isolated platforms over the early developed grabens in a deep‐water basinal condition, rather than within the entire oceanic basin.

Episodic ventilation of euxinic bottom waters triggers the formation of black shale-hosted Mn carbonate deposits

Many manganese (Mn) carbonate deposits over geologic history are often closely associated with black shales. However, the mechanism(s) by which the Mn entered the sediments remains controversial because on one hand oxygenated waters are required for primary Mn(IV) oxide formation but on the other hand black shales generally form under reducing conditions. China hosts some of the world’s largest black shale-hosted Mn deposits, for example, the Carboniferous Ortokarnash and Malkantu Mn deposits in the Malkansu region, offering a good opportunity to revisit the genesis of black shale-hosted Mn carbonate deposits. Here, we present the first coupled, systematic paleoredox and hydrographic reconstruction of those deposits with the aim of elucidating the redox-state of the depositional basin at the time of their initial deposition. The Mn ore beds in this region are hosted within laminated, organic-rich mudstones (i.e., black shales) reflective of a relatively deep-water depositional environment. The Mn ores are comprised of the Mn(II) carbonate minerals (rhodochrosite and Ca-rhodochrosite), with minor alabandite, pyrite, and monazite. Multiple independent lines of evidence, including positive shale-normalized Ce anomalies (average 3.0), negative δ13CVPDB values (average −11.55 ‰), and negative δ98MoNIST+0.25 values (average −1.07 ‰), indicate that the Mn(II) carbonate ores were formed during diagenesis via the coupled oxidation of organic matter and reduction of Mn(IV) oxides originally deposited from an oxygenated water column. However, in apparent contradiction, highly reactive iron to total iron (FeHR/FeT; average 0.66) and pyrite iron to highly reactive iron (FePy/FeHR; average 0.71) ratios, combined with a high abundance of small framboidal pyrites (mean diameter ∼5 μm) with narrow size ranges (standard deviations <2 μm), suggest that the associated black shales were deposited in euxinic (H2S-bearing) bottom waters. Euxinia resulted from sluggish water mass circulation, with sedimentary Mo/TOC ratios indicating a relatively strong hydrologic restriction. During this stage, dissolved Mn(II) would have accumulated in euxinic waters but not become permanently fixed into sediments, as indicated by higher degrees of enrichment for Mo over U and lower Mo isotope values than coeval seawater recorded in the black shales. These reveal an active Mn(IV) oxide shuttle across a redox-stratified water column. Combined, the Mn ore intervals document sharp benthic oxygenation of euxinic bottom waters, a process that might be induced by the periodic incursions of oxic seawater associated with eustatic sea level rises. This model is supported by the Mo isotopic characteristics of the Mn carbonate ores, which indicate original Mn oxide precipitation from an overlying water with Mo isotopic composition close to coeval open seawater (minimum δ98MoNIST+0.25 of 1.9 ‰). In contrast to the generalized “bathtub ring” model envisaging that the black shale-hosted Mn deposits were formed at shallow basin margins, our results highlight that they were more likely formed by in-situ ventilation of anoxic (especially euxinic) deep waters of basin center settings. In this regard, we suggest that the ventilation model better explains the close association of Mn carbonate ores with black shales, and has profound implications for understanding the paleoredox framework of otherwise Mn-rich black shale successions.

Biostratigraphy and paleoenvironmental significance of Paleogene foraminiferal assemblages from Dashte Zari area in High Zagros, West Iran

The Paleogene carbonate deposits of Pabdeh and Jahrum formations are widespread from the northwest (Dashte Zari area) to the southwest of the Shahrekord region in the High Zagros Mountains of Iran and record the lateral and upward transition from open marine into the shallow water environment. The Pabdeh Formation shows a succession of open marine pelagic and hemipelagic limestone, argillaceous limestone, and argillaceous chert. It consists of planktonic wackestone, pellet-planktonic wackestone, mudstone with planktonic foraminifera, and radiolarian siliceous wackestone, which accumulated within the Zagros Foreland Basin. The planktonic foraminifers are assigned to the Late Paleocene–Late Eocene and correspond to subtropical and tropical Zones P4b–E15. The Jahrum Formation is represented by bioclast-bearing limestone and calcarenite. It consists of benthic foraminiferal wackestone, benthic foraminiferal-red algal packstone, and bioclast-intraclast packstone deposited in a shallow platform environment. The Jahrum Formation is inter-fingered in the upper part of the Pabdeh Formation and finally overlies it conformably during the Bartonian–Priabonian. Shallowing and off-lap relationships record basin shrinking, while repeated inter-fingering signals moderate tectonic subsidence. Both formations are disconformably covered by the Late Oligocene–Miocene Asmari Formation. Keywords: biostratigraphy, Pabdeh Formation, Zagros, Paleogene, Iran.

Sedimentology and Diagenesis of the Early–Middle Eocene Carbonate Deposits of the Ceno-Tethys Ocean

An integrated study based on field observation, petrography, and scanning electron microscopy (SEM) on the Early–Middle Eocene carbonate rocks has been carried out, which were deposited in the Ceno-Tethys Ocean. The study area of the Yadgaar Section lies on the eastern margin of the Upper Indus Basin, Pakistan. The Early–Middle Eocene Margalla Hill Limestone and Chorgali Formation act as reservoir rocks in other parts of the basin and are also present in the Yadgaar Section. The lack of comprehensive study in this area makes these reservoir rocks highly attractive for sedimentological evaluations and future exploration of hydrocarbons. The Early–Middle Eocene carbonate rocks are divided into nine microfacies: dolomicritic foraminiferal mudstone–wackestone microfacies (EMI); green algae dominated, mixed foraminiferal wackestone–packstone microfacies (EMII); ostracod, green algae and gypsum dominating mudstone–wackestone microfacies (EMIII); algae and mixed foraminiferal wackestone–packstone microfacies (EMIV); Nummulites dominating mudstone–wackestone microfacies (EMV); algal limestone mudstone microfacies (EMVI); Assilina bed wackestone–packstone microfacies (EMVII); micritized larger benthic foraminiferal wackestone–packstone microfacies (EMVIII); and algal limestone, mudstone microfacies (EMIX). The transgressive-regressive environment in the Ceno-Tethys Ocean leads to the deposition of these microfacies in the platform interior, open marine platform, platform edge, platform margin reef, toe of the slope apron, arid–humid platform interior, platform edge, open marine platform interior, and restricted marine platform interior, respectively. Initial post-depositional diagenetic stages are identified from the base to the top of the strata by their respective cement types, i.e., the base–lower middle part of the strata demonstrates an eogenetic sub-stage with the appearance of drusy cement, the middle section indicates a mesogenetic sub-stage by the appearance of blocky cement, while the top portion again reveals an eogenetic sub-stage of diagenesis by the presence of drusy and blocky types of cement. The ascending–descending hierarchy of cement generations is directly proportional to the grade of diagenesis from the base to the top of the carbonate strata. Variable diagenetic effects on the various microfacies also increase the secondary porosity range and enhance the reservoir characteristics of the Formations. The presence of foraminifera microfossils determined that these carbonate formations date from the Early–Middle Eocene.

Properties of Mortar Containing Recycled Fine Aggregate Modified by Microbial Mineralization

Microbial-induced mineralization deposition was used to improve the quality of the recycled fine aggregate (RFA) in this paper. In order to obtain a better improvement effect, the microbial mineralization conditions were first optimized. The effect of the pH value, temperature, bacterial concentration and calcium ion concentration on the mineralization ability of bacteria were investigated. The optimal microbial mineralization conditions were selected for the treatment of RFA and the microbial mineralization modification effect of RFA was evaluated based on the water absorption and crushing index. In addition, the natural fine aggregate (NFA), unmodified RFA and modified RFA were made into ordinary mortar, recycled mortar and modified recycled mortar, respectively. The workability, mechanical properties and chloride ion penetration resistance of mortars was investigated. Meanwhile, the precipitations formed by microbial mineralization were characterized using a scanning electron microscope (SEM) with an energy dispersive spectrometer (EDS) and X-ray diffraction (XRD). The pore structure of mortars was analyzed using the mercury intrusion porosimeter (MIP). The results showed that the bioprecipitations were mainly calcite calcium carbonate and the quality of the RFA was improved by microbial-induced calcium carbonate deposition. The water absorption and crushing index of the modified RFA decreased by 25.7% and 4.2%, respectively. Compared with the crushing index, the water absorption of the RFA was improved more obviously. The workability, mechanical performance, chloride ion penetration resistance and pore structure of the modified recycled mortar was improved. Compared with the recycled mortar, the fluidity of the modified recycled mortar was 7.3% higher, the compressive strength of 28 d was 7.0% higher and the 6 h electric flux was 18.8% lower. The porosity of the ordinary mortar, recycled mortar and modified recycled mortar was 16.49%, 20.83% and 20.27%, respectively. The strengthening of the modified recycled mortar performance may be attributed to the improvement of the mortar microstructure due to the enhancement of the RFA quality after the biotreatment.

Microbial carbonate rocks: composition, structures, textures, mechanisms and environments of formation. Emergence of the doctrine of microbial formations and their forms. Article 1

Introduction. Concepts describing bacterial effects on mineral formation and, first of all, on the formation of carbonate deposits, started to appear late in the 19th century both in Russia and globally. The precipitation of materials was demonstrated to take place directly at the sedimentation stage and continue in the formed precipitate during diagenetic processes. Research in this direction has recently intensified. Rocks and their constituent parts formed as a result of bacterial activity have been referred to as “biosedimentary structures” or “microbiolites”.Aim. The paper presents the results of generalization and systematization of accumulated research data on the abovementioned forms.Materials and methods. In addition to literature materials, carbonate rocks of various ages – from the Vendian and Lower Cambrian of the Siberian platform to the Crimea Neogene and sediments of contemporary oceans – were examined using macro- and microscopic (mainly) methods of studying and describing specific objects. Article 1 considers the main morphological types of such carbonate formations, both in the form of individual structural components of sedimentary rocks and rocks themselves with peculiar structural characteristics.Results. Two main morphological groups of carbonate microbiolites were identified and characterized. The first group represents individual and independent forms of carbonate material, both of calcite, highly magnesian-dolomite and even pure magnesite composition. This type includes mineralized precipitates of bacterial forms represented by coccolites, tubules, filaments, as well as by plate and sheet structures – mineralized glycocalyx traces. In addition, this group features isolated carbonate objects, familiar to lithologists, including oolites, oncolites, microclusters of pelitomorphic carbonate materials, thrombolites and, apparently, such specific formations as tubiphytes, etc. The second group includes laminated forms of stromatolites with their specific internal structure, as well as mineralized microbial films and mats with a complex structure, etc.Conclusions. In the overwhelming majority of cases, microbiolites are formed at the sedimentation stage, and their morphology and type are determined by specific paleogeographic and paleoclimatic conditions.

CO2 buildup drove global warming, the Marinoan deglaciation, and the genesis of the Ediacaran cap carbonates

What caused ocean/climate changes that drove Marinoan deglaciation, and the subsequent genesis of Ediacaran cap carbonates remains unclear. To address this issue, we examined the Hg records in Ediacaran cap carbonates from shelf to slope depositional settings in exposures from South China. These cap carbonates show higher total Hg (THg) concentrations (4.9 to 405 ppb), most of which are comparable to that observed in carbonates deposited during non-LIPs periods. The lack of THg/TOC anomalies in these cap carbonates suggests that background volcanic activity, rather than a short-term large igneous province event, drove the Marinoan deglaciation. The cap carbonates show positive Δ199Hg values (0.18 to 0.34 ‰) in slope settings and slightly negative to slightly positive Δ199Hg values (−0.16 to 0.11 ‰) in shelf settings, suggesting a binary mixing of seawater- and terrestrial-derived Hg in early Ediacaran Ocean. We infer that the accumulation of greenhouse gases, due to ongoing volcanic emissions of CO2 and enhanced release of gas hydrates, triggered global warming. This warming led to melting of sea ice cover, enhanced terrestrial inputs of alkalis (e.g., K+, Na+, Ca2+, Mg2+), and large-scale dissolution of atmospheric CO2 into seawater, driving widespread deposition of Ediacaran cap carbonates.

Identification of water–rock interaction of surface thermal water in Songwe medium temperature geothermal area, Tanzania

The Songwe geothermal prospect is situated in western Tanzania in the Rukwa Rift of the western branch of the East African Rift System. Thermal springs discharge along NW–SE oriented fracture zones in two separate areas: in the main Songwe graben (Iyola, Main springs, Rambo and Kaguri) and eastern Songwe graben (Ikumbi). Lithologies forming and filling the Songwe graben are metamorphic gneiss and shist as basement rocks, overlain by the Karoo sandstones, and Red sandstones, both silt- and sandstones with a carbonatic matrix. In some areas of the graben, volcanic rocks intruded these formations forming basalt outflows. The discharge temperatures of springs are between 37 and 85 °C with Na-HCO3 type fluids. Carbonate deposits surround most of the springs. Using previous geophysical, geological studies and historical fluid geochemical data and mineral data, the Songwe geothermal system interpretation was updated, including new reservoir fluid temperature, fluid flow pathway and water–rock interaction models. The classical geothermometers of K-Mg and Na-K-Ca (Mg correction) were used to predict the reservoir fluid temperature and show that fluid emerging in the Songwe area reaches temperatures between 125 and 148 °C. Reservoir fluid characteristics are reconstructed based on the geothermometer calculation and a PHREEQC model in which the deep fluid reacts with certain lithologies. Minerals precipitating at the surface and reservoir depth were used to calibrate the models. The models run at surface temperature were calibrated with minerals precipitating around the springs and suggest that Songwe thermal fluids interact with Red sandstone only, while Ikumbi spring water is the only spring that interacts with all lithologies (simplified referred to as: metamorphic rocks, Karoo and Red sandstone). The model run at reservoir temperature indicates that rising water is also in contact with Karoo sandstones and Ikumbi spring water composition is again influenced by the contact with all lithologies in the graben. Our conceptual model summarizes all data showing the meteoric origin of the fluids, the travel through the basement, rising along the Mbeya fault and the main reaction with sandstones through a lateral travel towards the hot springs. The proposed models reinforce the idea that carbonate dissolution from the sandstone layers is the most common water–rock interaction. Our model is supported by carbonate deposition observed in all springs, dominated by HCO3 and Na.

Effect of in situ deposition of calcium carbonate in cotton fiber on its mechanical properties

AbstractIn this study, in order to improve mechanical properties of cotton fabrics, nano‐micro sized calcium carbonate (CaCO3) was deposited in situ on cotton fabrics. The mechanical properties, surface morphology, crystalline index, infrared spectrum, thermal property, and wettability of the deposited fabrics were measured and discussed. The results showed that the breaking strength of cotton fabric increased by about 10% after in situ deposition of nano‐micro calcium carbonate. After ultrasonic washing, the strength of cotton fabric deposited CaCO3 was still increased by about 10%. The crystallinity of the cotton fabric deposited with calcium carbonate increased from 76% to 84%. The hydrogen bond between cellulose molecules and calcium carbonate was confirmed by infrared spectroscopy. The hydrophilicity and thermal properties of cotton fabric were not significantly influenced by calcium carbonate deposition. This provides a new idea for improving the mechanical properties of cotton fabric.

Holocene Lacustrine Abiotic Aragonitic Ooids from the Western Qaidam Basin, Qinghai-Tibetan Plateau

Carbonate ooids are a significant component of shallow water carbonate deposits in the present and geologic past, yet their origin and formation mechanism have been the subject of continuing debate. This study focuses on the well-preserved Holocene aragonitic ooids collected from the west Qaidam Basin, Qinghai-Tibetan Plateau (QTP). The mineralogical and chemical compositions, and stable (δ13C and δ18O), and radiocarbon isotopes of the ooids were analyzed to investigate their formation and develop a depositional model. The ooids formed approximately 5377±61 cal BP, and their cortices were composed of microcrystalline aragonite, with most nuclei being quartz grains. Stable carbon and oxygen isotopes indicate that authigenic aragonite precipitation is driven by evaporation and associated degassing of CO2 under turbulence conditions in a shallow alkaline lakes. Furthermore, eletron microscopy showed no presence of microfossils in ooid cortices or other evidence of microbial activity. Therefore, we propose that aragonite precipitation during ooid formation is most likely induced abiotically by increasing alkalinity due to evapoconcentration of lake waters based on an absence of an efficient carbonate-inducing metabolic pathway. New observations and detailed analyses of aragonitic ooid samples in the Qaidam Basin provide an improved understanding of the origin and formation processes of carbonate ooid in modern environment and the geologic past.

Hyperalkaline seepage water and the accompanying carbonate deposits from the grouted foundation rock of a rock-fill dam

The inspection gallery of a dam is leached by reservoir water that has infiltrated through the rock-fill dam body from the high-pressure water area upstream (leakage), and groundwater seeping through the foundation bed which has been injected with ordinary Portland cement (OPC) grout. Seepage waters with a pH greater than 12 are characterized by the major components of Ca(OH)2 and alkali hydroxides, lower Mg2+ concentration and higher K+/Na+ molar ratio than those for river and spring waters and groundwater near the dam site, and the extensive carbonate deposits precipitated from the waters. During a low discharge period, NaOH was the major component because Ca2+ was removed as carbonate deposits. Based on the stable isotope ratios of hydrogen and oxygen in the water, which reflect the altitude effect, it was inferred that the seepage waters are supplied from the shallow groundwater near the dam site and that the leakage is a mixture of the seepage water and reservoir water. Alkali hydroxides and Ca(OH)2 cement porewaters formed during the early stages of hydration of OPC are still present in the cement mass after 46 years, and that the OPC still remains partially unhydrated. These highly alkaline porewaters have seeped through gaps of the concrete joint surfaces to discharge into the inspection gallery. The Ca(OH)2 concentration in the seepage was below the portlandite saturation, therefore, the grout-derived solutes are considered to have been diluted as they diffused into the shallow groundwater before being discharged with the groundwater seeping into the gallery due to the hydraulic head difference and mixed with the groundwater. Ca(OH)2 in the seepage reacted with atmospheric CO2 in the inspection gallery, and the carbon stable isotope ratio of the carbonate deposits produced in this way was unusually low, about −25‰ VPDB, due to the large disequilibrium isotope fractionation during the direct reaction of CO2 with OH− in the solution. In addition to the change in its discharge, the hyperalkaline seepage and the resulting carbonate deposits with unusually low δ13C values can be measures of the durability of the grout-treated foundation rock of the rock-fill dam, because the decrease in pH in the future is related to the instability of the grout hydration products by carbonation.

On the effect of simulated contamination of chlorides and sulfates on steel rebar corrosion: Electrochemical behavior and surface analysis

To understand the effect of sulfate ions on the chloride-induced corrosion of reinforced concrete, this study focuses on the electrochemical behavior and surface analysis of standarded carbon steel that was exposed to simulated pore solutions, with different combinations of high and low chloride and sulfate concentrations. Linear scanning voltammetry and electrochemical impedance spectroscopy were used to monitor the corrosion reaction. Steel surface was characterized by X-ray photoelectron spectroscopy and field emission scanning electron microscopy. Results indicate that the presence of sulfate affects the electrochemical behavior of steel corrosion at a low and high chloride concentration, where the capability of the corrosion protective layer was influenced by the increase of the sulfate and chloride content. Calcium carbonate deposits were observed at the surface of corroded samples, where higher precipitation of calcium carbonate crystals on carbon steel surface is associated with higher rates of localized corrosion.