Carbon Steel Research Articles

Performance materials with variations of tractor drive wheel fin angle and low-cost manufacturing analysis

Nowadays, the demand for workers in the agriculture industry has decreased and there is a need for rising mechanization in the agriculture process. The agriculture process that requires mechanization is cultivating. The rice cultivator has to be as light as possible, so requires a lighter material but is also strong enough. The correlation between the rice transplanter tool and the wheels is closely related to soil conditions. The selection of wheel materials is considered based on the characteristics of the planting area. In addition, another influence variable is the angle of the fin in the rice transplanter wheel. Material of rice transplanter wheel has been established, these are 1023 carbon steel sheet, AISI 1020 steel cold rolled, AISI 316 stainless steel. The angle of the fin was varied, these are 30, 35, and 40, this fin will give an effect on the traction result of rice transplanter wheel movement. The combination of lightweight material and the appropriate fin angle of the rice transplanter wheel has the best traction result. As a result of this research, the suitable material for the rice transplanter wheel was carbon steel and the fin’s angle was 30. This research involved a comparison and analysis of material strength under various fin angles. The evaluation of stress criteria was conducted using design values to determine the most reliable final product design. The paper contributes by illustrating how to represent the final decision on the combination of design and materials, incorporating a cost index assessment.

Investigation of a pyridazinone derivative as a corrosion inhibitor for carbon steel in acidic conditions using experimental and theoretical methods

The anti-corrosive properties of the newly synthesized compound pyridazinone, especially 2-(3-(4-fluorophenyl)-2-oxopropyl)-4-(3-nitrobenzyl)-6-phenylpyridazin-3(2H)-one (FOPP), on carbon steel in a 1M hydrochloric acid solution were thoroughly investigated. We used multiple techniques, including potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), surface morphology analysis, contact angle measurements, UV-visible spectrometry, and quantum chemical calculations. The maximum corrosion inhibition efficiency of FOPP was found to be 96.3% at 10-3 M concentration and 303K temperature. PDP studies showed that FOPP acts as a mixed-type inhibitor with anodic predominance. The hydrophobicity of the surface of the metal studied showed considerable improvement by the FOPP coating using the contact angle technique. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDX) were used to confirm the results obtained using the contact angle technique. The two methods of theoretical chemistry, namely density functional analysis (DFT) and molecular dynamics simulation, were used to gain a better understanding of the interactions between the inhibitor and the surface of the metal studied and the ability of this inhibitor to adhere to the surface of the iron and form a protective film.

Monitoring atmospheric corrosion under multi-droplet conditions by electrical resistance sensor measurement

This paper presents a novel approach to investigate atmospheric corrosion kinetics of carbon steel under multi-droplet conditions. A homemade climate chamber has been developed to accurately control and monitor environmental conditions, including temperature (T) and relative humidity (RH), during exposure. Carbon steel corrosion kinetics are monitored with a custom-designed Electrical Resistance (ER) sensor pair. Savitzky-Golay (S-G) based filtering technique has been used for the corrosion signal processing. In parallel, top-view droplet temporal evolution has been recorded by microscopic imaging and analyzed for both droplet size distribution and the solid-liquid contact angle. The droplet size distribution can typically be described with a power-law form curve. The curve shows a decrease in height and a concurrent expansion in width with progressive drying. The introduction of NaCl into the electrolyte and surface roughness variations have also been identified to substantially influence the carbon steel corrosion rate. A strong correlation between the corrosion rate derived from the ER monitoring method and the RH can be observed. This correlation is further analyzed to incorporate the impact of droplet-based electrolyte conditions. This study offers valuable insights into the development of mechanistic and kinetic prediction models for atmospheric corrosion.

Monitoring atmospheric corrosion under multi-droplet conditions by electrical resistance sensor measurement

This paper presents a novel approach to investigate atmospheric corrosion kinetics of carbon steel under multi-droplet conditions. A homemade climate chamber has been developed to accurately control and monitor environmental conditions, including temperature (T) and relative humidity (RH), during exposure. Carbon steel corrosion kinetics are monitored with a custom-designed Electrical Resistance (ER) sensor pair. Savitzky-Golay (S-G) based filtering technique has been used for the corrosion signal processing. In parallel, top-view droplet temporal evolution has been recorded by microscopic imaging and analyzed for both droplet size distribution and the solid-liquid contact angle. The droplet size distribution can typically be described with a power-law form curve. The curve shows a decrease in height and a concurrent expansion in width with progressive drying. The introduction of NaCl into the electrolyte and surface roughness variations have also been identified to substantially influence the carbon steel corrosion rate. A strong correlation between the corrosion rate derived from the ER monitoring method and the RH can be observed. Additionally, this correlation can be further expanded to droplet-based electrolyte conditions. This study offers valuable insights into the development of mechanistic and kinetic prediction models for atmospheric corrosion.

Investigating the effects of partitioning temperature fluctuations on the mechanical properties of ASTM A36 carbon steel using Q-P-T heat treatment: an experimental study

In the continuum of time and technological advancement, the use of metals, specifically carbon steel, has significantly increased as primary materials in various operational and industrial domains, including tool fabrication and automotive components. To meet the evolving demands of industries, precise heat treatment processes have been developed to enhance the metallic properties. This study specifically focused on the application of the Quenching-Partitioning-Tempering (Q-P-T) method to ASTM A36 steel. The study investigated different partitioning temperatures, namely 300℃, 350℃, and 400℃, with 15-minute intervals. A comprehensive set of mechanical tests, including hardness, tensile, and microstructural analyses, were conducted to assess the response of the material to the treatment. The results reveal significant findings: a partitioning temperature of 300℃ yields the highest hardness value of 164 Vickers Hardness Number (VHN). Furthermore, the tensile tests demonstrate that a partitioning temperature of 300℃ is optimal, achieving a maximum stress value of 515.73 MPa. Conversely, a partitioning temperature of 400℃ exhibits the highest strain value at 21.08% and the highest elastic modulus value at 11.47 GPa. Microstructural evaluations highlighted the presence of pearlite and ferrite phases, with the partitioning temperature of 300°C displaying the highest proportion of pearlite phase at 38.5%. This meticulous investigation expands our understanding of metallurgy and underscores the intricate relationship between partitioning temperatures and the mechanical properties of ASTM A36 steel. It provides valuable insights for material design and application methodologies and facilitates advancements in industrial practices

Inhibition of carbon steel corrosion caused by Pseudomonas aeruginosa biofilms using the eco-friendly ε-Polylysine antimicrobial peptide

This study evaluated the effect of the ε-Polylysine (E-PL) antimicrobial peptide on the corrosion behavior of P. aeruginosa attached to carbon steel surfaces. The results showed that E-PL exhibited good antibacterial and antibiofilm activity, further effectively inhibited the corrosion behavior of P. aeruginosa by biofilm thickness, surface morphology, corrosion product, EIS and molecular biology method. In addition, the transcriptome and qPCR data showed that E-PL significantly downregulated the expression of key genes in flagella, quorum sensing, biofilm formation, and phenazines for resisting microbiologically influenced corrosion. This study has theoretical significance for evaluating the corrosion of marine equipment.

Effect of Corrosion Media on Biofilm Detachment and the Corrosion Mechanism of Serratia marcescens on Carbon Steel in River Water

Effect of Corrosion Media on Biofilm Detachment and the Corrosion Mechanism of Serratia marcescens on Carbon Steel in River Water

Effect of plating time on surface morphology and corrosion behavior of electroless Ni-P coating in simulated concrete pore solution

As a protective coating, electroless Ni-P (ENP) coating with various deposit times was fabricated on the carbon steel. The morphology, microstructure, and composition of the ENP coating were investigated via SEM, AFM and XRD. The anti-corrosion capability and protective mechanism of the coating exposed to chloride-contaminated simulated concrete pore solution (CL-SCPS) were evaluated by OCP, potentiodynamic polarization, EIS, and Mott-Schottky analysis. As deposit duration increased, the Ni and P content percentage and compactness of ENP coating increased, but “trenches” appeared. The corrosion behavior of ENP coating was closely related to the thickness and surface morphology. That is to say, the coating with the thin layer and defects could represent low corrosion resistance. Moreover, passivation would occur on the ENP coating in an alkaline environment. The performance of the passive film was also related to the thickness and morphology of the coating. The oxidation products could partially repair the surface “trenches”. The ENP coating with an 80-min deposit duration had the highest corrosion resistance in the short immersion stage. Coating with a 60-min deposit duration represented optimal corrosion resistance and desirable electrochemical stability in the long-term service in aggressive media.

Damage and failure mechanisms of hybrid carbon fiber and steel fiber reinforced polymer composites

Fiber-reinforced plastics (FRPs) are widely used due to their superior properties but often suffer from brittle failure and poor structural integrity under impact loads. Metal fiber hybrids (MFH) offer a solution, but understanding their structure–property relationships remains challenging. This research provides a comprehensive mechanical characterization of a stainless steel-carbon fiber hybrid (SCFRP) embedded in epoxy resin, with a particular focus on the failure mechanisms and their influences. Therefore, the mechanical properties of the material, as well as the propagation and damage of the fracture, are investigated. In addition, three main failure mechanisms are identified and analyzed. The failure mode of a SCFRP laminate can be influenced by its composition, architecture, and specimen size and result from a combination of the blast effect of the brittle failing carbon fibers, the magnitude of the associated damage, and the movement of the fracture gap formation initiated by the carbon fiber failure.

Vanillin‐Based Photocurable Anticorrosion Coatings Reinforced with Nanoclays

AbstractThis study investigates the chemical–physical properties and anticorrosion effectiveness of UV‐cured coatings produced using epoxidized vanillin (DGEVA) as biobased precursor, then reinforced by the addition of nanoclay. After optimizing the UV‐curing parameters of three different formulations by Fourier transform infrared spectroscopy (FTIR), the thermo‐mechanical properties of the coatings are assessed by differential scanning calorimetric analysis (DSC), dynamic thermal mechanical analysis (DTMA), and pencil hardness. The coatings are applied on mild steel substrates and then their barrier properties are investigated by electrochemical impedance spectroscopy measurements, immersing the samples in 3.5 wt% NaCl aerated solutions. The results show the good corrosion protective effectiveness of the biobased coatings. The nanoclay addition has a beneficial effect, as it hinders the diffusion of the aggressive ions from the electrolyte solution to the metal substrate. The reported findings demonstrate the possibility of using biobased precursors and UV‐curing technology to reduce the environmental impact of the coating industry.

Electroactive additives into polyurethanes for high corrosion resistance coatings for mild steel

Electroactive additives into polyurethanes for high corrosion resistance coatings for mild steel

Reinforcing steels in low-carbon mortars subjected to chloride attack and natural carbonation: Contradictory trends in passivation ability and corrosion resistance

After a 7-year exposure to simulated marine environments with chloride attack and natural carbonation, the passivation ability and corrosion resistance of carbon steel and 2304 duplex stainless steel in two types of low-carbon mortars, designed with alkali-activated slag and Bayer red mud, were investigated, which were compared with those observed in ordinary Portland cement (OPC) mortar. Although a reduced passivation ability was confirmed for steels in the low-carbon mortars, an improved corrosion resistance was highlighted after long-term exposure. Accordingly, the underlying mechanisms for the detrimental impacts and beneficial effects on the corrosion resistance of steels provided by these low-carbon mortars were discussed in terms of pore solution chemistry, pore structure as well as electrical resistivity, which will shed new lights on the design of novel cementitious materials with low carbon footprint and high corrosion protection.

Application of voltammetry as a technique to monitor cathodic protection performance of steel in simulated soil solution

Cathodic protection (CP) in combination with organic coating is applied as a secondary technique to mitigate corrosion of buried steel in an effort to prolong the lifespan of the buried steel pipeline. This study was aimed at developing and applying an adequate technique for monitoring the electrochemical behaviour of buried steel in the presence of CP. A modified voltammetry procedure was applied on carbon steel immersed in simulated soil solution for four days under open circuit potential (OCP) before applying CP for further ten days. Electrochemical impedance spectroscopy (EIS) was also applied at various time intervals to investigate the electrochemistry at the steel/solution interface. The voltammetry experiments revealed that the corrosion rate peaked at 680 µm/yr after three days of being subjected to OCP and then decreased to 411 µm/yr on day four as a result of a passive layer development on the steel surface. The corrosion rate was reduced from 411 µm/yr to 8 µm/yr as result of CP application before fluctuating between 21 and 40 µm/yr. The examination of steel surface via x-ray diffraction revealed the presence of calcareous deposit which resulted due to the application of cathodic protection.

Enhancing Adhesion and Durability: A Biomimetic Approach with Dopamine-Modified Lignin-polydimethylsiloxane Coatings

Corrosion causes significant challenges in industrial settings, leading to economic losses and safety concerns. Previously, we developed a lignin-polydimethylsiloxane (lignin-PDMS) coating that exhibited high corrosion resistance. However, the adhesion of the developed lignin-PDMS coating to carbon steel was limited, affecting its overall performance. To address this, we incorporated dopamine (DOPA), known for its strong adhesive properties, as a pre-treatment before applying the coating. It was found that the adhesion and corrosion resistance of lignin-PDMS coated steel could be improved by adjusting the pH value of the DOPA solution. The steel treated with pH 4.5 DOPA solution showed two times higher adhesion strength to the coating than non-treated steel. After the DOPA treatment, the coating can maintain high barrier property for at least 3 months in 1M NaCl solution, which is even better than commercial gelcoat, demonstrating super corrosion protection. Quartz Crystal Microbalance with Dissipation (QCM-D) and X-ray Photoelectron Spectroscopy (XPS) analyses confirmed the DOPA deposition on the steel surface. Our findings show that the DOPA-lignin-PDMS system is an environmentally friendly and efficient solution for enhancing the durability of steels in corrosive environments.

The alloyed cementite (Fe-Ni-Cr)3C: local environment, atomic magnetic moments, and magnetization from DFT calculation

The alloying element added to carbon steel to enhance its properties also penetrates Fe3C cementite particles, altering their properties and influencing the steel product through them. This is why the impact of alloying elements on cementite has been extensively studied. Ni and Cr exhibit opposing behavior in cementite, so cementite doped with Ni and Cr is investigated using DFT calculations. The data obtained for total energy, lattice, magnetization, local magnetic moments at metal atoms, and their nearest environment are compared to experimental magnetic data for Ni and Cr-alloyed cementite. The relationship between Fe atom magnetic moments and their nearest environment is discussed in comparison between Cr and Ni doping. Decrease in magnetization with Ni and Cr content is attributed to 1) replacement of a larger Fe magnetic moment (mFe=1.9-2.0 μB) with a smaller or even negative moment (mNi=0.2-0.5 μB, mCr=-0.3 – -1.0 μB); 2) a decrease in the average Fe moment with the number of Cr atoms in the nearest environment; and 3) a strong dependence of the Curie temperature on Cr content in Cr-doped cementite.

Enhancing adhesion and durability: A biomimetic approach with dopamine-modified lignin-polydimethylsiloxane coatings

Corrosion causes significant challenges in industrial settings, leading to economic losses and safety concerns. Previously, we developed a lignin-polydimethylsiloxane (lignin-PDMS) coating that exhibited high corrosion resistance. However, the adhesion of the developed lignin-PDMS coating to carbon steel was limited, affecting its overall performance. To address this, we incorporated dopamine (DOPA), known for its strong adhesive properties, as a pre-treatment before applying the coating. It was found that the adhesion and corrosion resistance of lignin-PDMS coated steel could be improved by adjusting the pH value of the DOPA solution. The steel treated with pH 4.5 DOPA solution showed two times higher adhesion strength to the coating than non-treated steel. After the DOPA treatment, the coating can maintain high barrier property for at least 3 months in 1 M NaCl solution, which is even better than commercial gelcoat, demonstrating super corrosion protection. Quartz Crystal Microbalance with Dissipation (QCM-D) and X-ray Photoelectron Spectroscopy (XPS) analyses confirmed the DOPA deposition on the steel surface. Our findings show that the DOPA-lignin-PDMS system is an environmentally friendly and efficient solution for enhancing the durability of steels in corrosive environments.

Analysis and optimization design of internal pressure resistance of flexible composite pipe

Flexible composite pipes have the advantages of light weight, corrosion resistance, scale resistance, and low cost compared to carbon steel pipes, and have attracted much attention in the application of onshore oil and gas gathering and transportation systems. Understanding the relationship between the pressure-bearing mechanical properties of composite pipes and their structural characteristics is crucial for guiding their process application. To investigate the mechanical behavior of flexible composite pipes under internal pressure loads, discrete and combined finite element models were established to analyze the stress-strain characteristics of flexible composite pipes. The bursting strength was predicted, and the influence of winding angle and number of reinforcement layers on the pressure-bearing capacity of flexible composite pipes was revealed. The applicability of the two models in the analysis of internal pressure resistance of flexible composite pipes was evaluated using whole pipe strain testing and instantaneous hydrostatic burst experiments. The results showed that the reinforcement layer is the main pressure-bearing layer of flexible composite pipes, and the innermost reinforcement layer bears the highest pressure. The pressure-bearing capacity of flexible composite pipes significantly increases when the winding angle is greater than 53°, and the increase in pressure-bearing capacity slows down when the number of reinforcement layers exceeds 3. Under the combination model, the strain and bursting strength of flexible composite pipes were closer to the experimental results. The study clearly defines the stress-strain characteristics of flexible composite pipes under internal pressure load and the impact of process parameters, providing a basis for the optimization design of single well oil transmission pipelines in Xinjiang oilfield.

Analysis of a film-forming amine response in impedance spectra

In this study, a detailed analysis of the dielectric response of a film-forming amine (1,3 N-oleyl propanediamine (OLDA)) in impedance spectra is presented, addressing both "bulk" OLDA and adsorbed OLDA layer on a carbon steel surface. The dielectric response of the “bulk” OLDA in the absence of electrolyte over an extensive temperature range (-150°C to 50°C) was explored by broadband dielectric spectroscopy (BDS). Subsequently, the response of the OLDA adsorbed layer on the steel surface was analysed by electrochemical impedance spectroscopy (EIS), for various immersion times (2 - 100 min) and temperatures (25 - 75°C) in an aqueous NaCl solution.Impedance spectra (BDS and EIS), interpreted through the complex conductivity formalism, showed a resistive behaviour in the mid-frequency range and a capacitive behaviour at higher frequencies. The high frequency capacitive response in EIS spectra was shown to contain contributions from the OLDA layer and from the electrochemical double layer, as well. The temperature dependency of the OLDA conductivity was found to be similar to the temperature dependency of the electrolyte resistance, suggesting that the electrolyte (water and ions) crossed the OLDA layer to reach the steel surface. The presence of gauche defects in the OLDA alkyl chain, revealed by polarization modulation infrared reflection absorption spectroscopy (PM-IRRAS) analyses, may be a contributing factor to the disorder in the adsorbed layer, facilitating electrolyte infiltration.

Optimization of tool wear and surface roughness in ST-37 steel turning process with varying tool angles and machining parameters

The process of cutting low carbon steel (ST-37) typically utilizes High-Speed Steel (HSS) tools owing to their high hardness, affordability, and ease of shaping tool geometry. In machining, tool geometry plays a crucial role in the material cutting process and determines the quality of the final product, particularly surface roughness. The objective of this research is to achieve optimal surface roughness by varying the tool geometry and nose radius. This study employed an experimental approach using ST-37 and HSS tools. The variations in tool geometry include side rake angles of 12°, 15°, and 18°; side cutting edge angles of 85°, 80°, and 75°; and nose radii of 0 mm, 0.4 mm, and 0.8 mm. The machining parameters applied consist of a cutting depth of 1 mm and 2 mm, spindle rotation speeds of 185 rpm, 425 rpm, and 624 rpm, and a feed rate of 0.05 mm/rev, 0.075 mm/rev, and 0.1 mm/rev. Tool wear measurements were captured using a USB camera, whereas the surface roughness was assessed using a surface roughness tester. The impact of the tool geometry on the surface roughness was analyzed using the Taguchi-Grey Relational Analysis (Taguchi-GRA) and ANOVA methods. The optimal combination for ST-37 lathe machining with a sharpening tool is: A1 (cutting depth 1 mm), B1 (cutting speed 17.42 m/min), C3 (feed 0.05 mm/rev), D1 (corner radius 0 mm), E3 (side rake angle γ 18°), and F3 (side cutting edge angle γ 75°). According to the Analysis of Variance (ANOVA), three factors—cutting speed, tool tip angle, and chip angle—should be considered to achieve minimal tool wear and desirable surface roughness during machining

A novel flaw detection approach in carbon steel pipes through ultrasonic guided waves and optimized transformer neural networks

A novel flaw detection approach in carbon steel pipes through ultrasonic guided waves and optimized transformer neural networks