Carbon Steel Research Articles

Comparative study on productivity of double slope solar still using different wick and energy storage materials

The aim of the proposed study is to evaluate the efficiency of Double Slope Solar Still (DSS) using different wick and energy storage materials. In the study, wick materials such as jute, cotton and sponge were used in combination with energy storage materials such as mild steel, cast iron and copper. The experiments were conducted using DSS with different combinations of wick and energy storage materials to determine the efficient performance combination. The results show that sponge and copper have higher efficiency with wicks and energy storage materials. The results show that the maximum amount of water produced in a single day was 3147 ml when the DSS system was used with a combination of sponge and copper materials. This range shows an increase of 17.47 % and 12.44 % over the DSS with jute and copper and the DSS with the combination of cotton and copper respectively. The DSS showed the highest average energy efficiency when used in conjunction with a combination of sponge and copper, namely 51 % of the average efficiency. This corresponds to an increase of 18.60 % and 10.86 % compared to the combination of DSS with jute and copper and the combination of DSS with cotton and copper respectively. The best evaporation heat transfer coefficient of 345 W/m2K was determined for the combination of DSS with sponge and copper. Average exergy efficiency is also maximum of 3.076 % for the DSS with sponge and copper materials, which is higher than other investigated combinations. The proposed system has an energy payback period of 1.26 years, an energy production factor of 0.78, a life cycle efficiency of 6.9 % and a cost of $0.031 per litre of water produced in the environmental economic analysis.

Effect of drill gash rake angle on drillability in plain carbon and low alloy steels

In this study, the effects of the gash rake angle (γa), which is an important component of the drill geometry, on the thrust force and drilling torque occurring in the drilling of ordinary carbon steels (AISI 4140 and Ck 45) were examined through experimental and FEM-supported numerical simulation studies on surface roughness, tool surface roughness, wear and diameter deviation values were investigated experimentally. In the experiments, 6.8 mm diameter solid cementite carbide, coated and internal cooling channel drills with +10°, 0°, −10° gash rake angle were used. Three different feed rates and cutting speed levels were selected as cutting parameters. Determination of material-specific gash rake angle and cutting parameters for different materials was carried out by Taguchi-assisted variance analysis of experimental data. In experimental studies, the gash rake angle was 65.9% effective on the thrust force for AISI 4140 tempered steel, while it was the second effective parameter with 29.22% for Ck 45 manufacturing steel. While the feed rate is the more effective parameter in the drilling moments that occur when drilling different materials, it has been observed that γa also has a significant effect. It has been determined that chisel edge wear, main cutting edge wear and crater wear occur in the drill when drilling AISI 4140 tempered steel and Ck 45 manufacturing steel. The data obtained from the finite element-assisted chip removal analyses support the experimental results and provide guiding results in the selection of material-specific gash rake angle.

Machining Data Selection by Using a Fuzzy Logic Model

The fuzzy model has been developed for machining parameter selection. The correlation between the hardness of the work-piece and cutting velocity is not exact, but a proper relationship can be established by using a developed model. The fuzzy model was applied to machining data for carbon steel (wrought) that are collected from the ASM handbook, and a proper relationship between handbook data and predicted data by the fuzzy application was obtained. The model was developed by considering input hardness and output speed. A linear fuzzy equation has been proposed to represent the machining data with good correlation. The aim of the present work is to develop a fuzzy logic model to enable the computerization process of machining data that is available in the machining data handbook. As a result, a fuzzy logic-based expert system for machining data selection can be created.

Decomposition products of oxygen scavengers and their effect on corrosion of steam generator materials – I. Diethyl-hydroxylamine and carbohydrazide

Hydrazine used as oxygen scavenger in the secondary circuit of pressurized water reactors is hazardous to the environment and potentially carcinogenic, thus, suitable replacement chemicals for it are actively sought. In the present paper, decomposition products of two potential replacements – carbohydrazide and diethyl-hydroxylamine – are analyzed, and their effect on secondary water chemistry and corrosion of the main steam generator materials – carbon steel 22 K, stainless steel 0X18H10T and Alloy 690 – is studied by in-situ electrochemical techniques complemented by ex-situ analyses of the formed oxides by spectroscopic and microscopic methods. Quantitative interpretation of the electrochemical impedance data with the Mixed-Conduction Model allowed for the estimation of oxidation and corrosion release rates depending on scavenger formulation, alloy type and temperature. Conclusions on the extent of interaction of decomposition products with construction materials are drawn based on the experimental and calculational results.

Corrosion performance and mechanism of clay-lignin biocomposite: Effective bio based coating with strong adhesion character for extended carbon steel protection

The development of sustainable and eco-friendly anticorrosion coating for metal substrates is a pivotal advancement in various engineering fields. Hence, the novel sepiolite-lignin (SP-L) and bentonite-lignin (BN-L) biocomposites were successfully introduced in an alkyd resin 5.0 wt% and applied on carbon steel (CS), to prepare the alkyd SP-L (A/SP-L) and BN-L (A/BN-L) coatings. Particle size and zeta potential measurements were conducted to determine the average particle size and assess the stability of the reinforcing pigments. The corrosion performance of A/SP-L and A/BN-L coatings revealed higher protection with an impedance modulus of about 5.18 × 105 Ω.cm² and 7.86 × 105 Ω.cm², respectively, after 6weeks of immersion in 3 % NaCl solution, measured by electrochemical impedance spectroscopy (EIS), which were extremely higher than the reference alkyd (RA) 1.13 × 103 Ω.cm². The adhesion of the three coated samples before and after immersion was assessed using pull-off test, while their hydrophobicity and impermeability were evaluated using saline corrosion and water absorption tests. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were utilized to examine the corrosion mechanism. The results demonstrated an excellent coating quality and interfacial adhesion against corrosion.

Millettia aboensis leaves extract as eco-friendly corrosion inhibitor for mild steel in acidizing solution: From experimental to molecular level prediction

The development of environmentally friendly corrosion inhibitors is becoming more popular since conventional inhibitors are poisonous and non-biodegradable. The anti-corrosive effectiveness of Millettia aboensis leaves extract (MALE) has been assessed in this study using several methods, such as electrochemical measurements, X-ray Photoelectron spectroscopy and scanning electron microscopy on mild steel in acidic solution. Gas chromatography-mass spectrometry (GC-MS) analysis was combined with qualitative and quantitative phytochemical analysis to identify the phytochemicals linked to the activity of the Millettia aboensis extracts and identified key phytoconstituents such as Hexanedioic acid, Phenol derivatives, Octadecanoic acid, and Linolenic acid, which play significant roles in the extract's inhibitory performance. The results showed that the inhibition efficiency (IE%) improved to 88.6 % with the addition of inhibitor concentration from 0.1 g/L to 3.0 g/L and that the corrosion rate drastically reduced from 56.91 mpy to 16.09 mpy. Furthermore, at a greater concentration (3.0 g/L), the Rct values rose from 61.42 Ω cm2 to 176.3 Ω cm2 thus, indicating that the inhibitor molecules were forming a protective film over the metallic surface. Scanning Electron Microscopy (SEM) provided visual evidence of surface morphology, revealing a smoother surface in the presence of the inhibitor, indicative of the protective film formed by the adsorption of organic molecules onto the steel surface. Theoretical calculations using the ωB97XD functional and def2svp basis set further supported the experimental findings, showing that the protonated form of C21H36O4 exhibited the highest interaction energy, correlating with its superior inhibition efficiency on the metal surface.

Microbial corrosion inhibition of mild steel by Bacillus thuringiensis

Microbial corrosion inhibition of mild steel by Bacillus thuringiensis

Evaluation of entropy-coupled multi-criteria decision-making methods for enhancing machinability

Optimizing machining parameters is crucial, enhancing machinability while maintaining high product quality standards. This study bridges a critical research gap by evaluating and comparing five Taguchi-based Multi-Criteria Decision Making (MCDM) techniques—Combined Compromised Solution (CoCoSo), Grey Relational Analysis (GRA), Multi-Objective Optimization Ratio Analysis (MOORA), Technique for Order Preference by Similarity to Ideal Solution (TOPSIS), and Complex Proportional Assessment (COPRAS)—coupled with the Entropy method to optimize machining parameters for enhancing machinability in turning medium carbon steel. The focus is on feed rate and cutting speed under dry and Minimum Quantity Lubrication (MQL) environments considering six critical machining responses: material removal rate, surface roughness, main cutting force, cutting temperature, cutting ratio, and tool life.The results reveal that MQL consistently improves machining performance, with COPRAS, TOPSIS, MOORA, and GRA converging on an optimal setting favoring an MQL environment, a 0.14 mm/rev feed rate, and a cutting speed of 137 m/min, whereas CoCoSo suggests a different optimal parameter setting. CoCoSo and GRA demonstrate the highest reliability, evidenced by minimal discrepancies between predicted and experimental results, with absolute percentage errors of 0.647 % and 0.659 %, respectively. The COPRAS method also shows strong predictive accuracy with a 5.573 % error, outperforming MOORA and TOPSIS. Spearman's rank correlation analysis reveals a high agreement between COPRAS, MOORA, and TOPSIS, with COPRAS emerging as a potential replacement for the latter in similar decision-making scenarios. SEM and EDX analyses confirm that MQL conditions reduce tool wear, enhance surface quality, and extend tool life compared to dry machining. This research provides insights into effective parameter optimization strategies for improving machinability and underscores the benefits of adopting MQL for sustainable manufacturing processes.

Biopolyurethane coatings with silica-titania microspheres (MICROSCAFS®) as functional filler for corrosion protection

In this work, we studied a biopolyurethane (BioPU) coating derived from a bio-based polyol and isocyanate for the protection of carbon steel against corrosion. The direct utilization of polyols obtained from raw biomass represents a novelty in polyurethane coatings production. The protective properties of these coatings were enhanced by incorporating unique silica-titania (ST) MICROSCAFS®, which are microspheres exhibiting interconnected macro- and mesoporosity. They were loaded with tannic acid (TA), an eco-friendly corrosion inhibitor. Confirmation of TA loading into the ST carriers (therefore called ST\\TA) was achieved through Attenuated total reflectance - Fourier-transform infrared spectroscopy (ATR-FTIR) and Thermogravimetric (TG) analyses. TG analysis revealed that ST\\TA particles contain approximately 34 wt% TA, and their average particle diameter is approximately 25 ± 5 μm, observed by SEM. The TGA shows slightly improved thermal resistance of the coatings modified with the filler MICROSCAFS®. Furthermore, it was observed that the fillers strengthened the coating hardness without negatively affecting the adhesion strength. Electrochemical Impedance Spectroscopy (EIS) results demonstrated that all modified coatings exhibited very good to excellent resistance in mild corrosive environments. The coatings maintained a high impedance modulus (|Z|) at low frequencies and phase angle values close to −90° across a wide frequency range, over an immersion period of 80 days in a 0.05 M NaCl solution. After 80 days of immersion, the best coating, BPU-ST\\TA, displayed |Z| of 3 × 1010 Ω cm2. Scanning Vibrating Electrode Technique (SVET) analysis revealed the inhibitory behaviour of TA. For the BPU-ST\\TA sample, inhibition of both anodic and cathodic activities was clearly visible, with a significant reduction of the current densities starting at 1 h and up to at least 24 h of immersion. In summary, the BioPU coatings modified with tannic acid-loaded MICROSCAFS® exhibit improved barrier properties and notable corrosion inhibition capacity in mild corrosive environments.

An experimental investigation of abrasive jet machining parameters for optimized surface finish of mild steel components

Abrasive jet machining is one of the unconventional machining processes that are initiated for alternations of surface characteristics of ductile materials, like mild steel, due to the entrainment of high-velocity abrasive particles. The present experimental investigation deals with the major process parameters of the AJM process, namely air pressure, standoff distance, and time of machining, on the average surface roughness (Ra) of mild steel specimens. Experiments were conducted on the self-developed AJM setup using aluminum oxide abrasive particles of an average size of 50 µm. The pressure of air is changed in three levels, 6, 7, and 8 bars. The standoff distance is taken as 2 mm constant for all the cases. The surface roughness was measured at machining times of 20, 40, and 45 seconds. The presence of the increase of air pressure from 6 to 8 bars applied for all the machining time showed an increasing influence on roughness, although always significant in Ra. For 8 bars of pressure and 45 s of machining, the minimum resulted in 1.39 µm, compared with 3.47-4.02 µm. The rate of decrease in surface roughness is sharp with increasing machining time from 20 to 40 seconds but marginal beyond that. An optimal machining time of 40–45 seconds was identified to obtain a minimum Ra. Capability of AJM as an effective technique to enhance the surface finish of mild steel components, and practical insight of this study is very useful toward optimization of process parameters for attaining the targeted surface quality. The results obtained may assist in expanding the industrial application of AJM toward the finishing of ductile materials in various manufacturing fields.

Synthesis of new binary trimethoxyphenylfuran pyrimidinones as proficient and sustainable corrosion inhibitors for carbon steel in acidic medium: experimental, surface morphology analysis, and theoretical studies

In this study, synthesis and assessment of the corrosion inhibition of four new binary heterocyclic pyrimidinones on CS in 1.0 M hydrochloric acid solutions at various temperatures (30–50 °C) were investigated. The synthesized molecules were designed and synthesized through Suzuki coupling reaction, the products were identified as 5-((5-(3,4,5-trimethoxyphenyl)furan-2-yl)methylene)pyrimidine-2,4,6(1H,3H,5H)-trione (HM-1221), 2-thioxo-5-((5-(3,4,5-trimethoxyphenyl)furan-2-yl)methylene)dihydropyrimidine-4,6(1H,5H)-dione (HM-1222), 1,3-diethyl-2-thioxo-5-((5-(3,4,5-trimethoxyphenyl)furan-2-yl)methylene)dihydropyrimidine-4,6(1H,5H)-dione (HM-1223) and 1,3-dimethyl-5-((5-(3,4,5-trimethoxyphenyl)furan-2-yl)methylene)pyrimidine-2,4,6(1H,3H,5H)-trione (HM-1224). The experiments include weight loss measurements (WL), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PDP). From the measurements, it can be shown that the inhibition efficiency (η) of these organic derivatives increases with increasing the doses of inhibitors. The highest η recorded from EIS technique were 89.3%, 90.0%, 92.9% and 89.7% at a concentration of 11 × 10−6 M and 298 K for HM-1221, HM-1222, HM-1223, and HM-1224, respectively. The adsorption of the considered derivatives fit to the Langmuir adsorption isotherm. Since the ΔGoads values were found to be between − 20.1 and − 26.1 kJ mol−1, the analyzed isotherm plots demonstrated that the adsorption process for these derivatives on CS surface is a mixed-type inhibitors. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), atomic force microscope (AFM) and Fourier- transform infrared spectroscopy (FTIR) were utilized to study the surface morphology, whereby, quantum chemical analysis can support the mechanism of inhibition. DFT data and experimental findings were found in consistent agreement.Graphical

The effect of cold forming residual stresses in local fatigue approaches: A numerical perspective

Thin-walled structures generally rely on cold-formed mild steel profiles. Due to cold forming, a significant formation of residual stresses impacts their overall fatigue behaviour. In this work, a state-of-the-art framework for fatigue life prediction is proposed and applied to both roll-formed and press-braked full-scale profiles. In summary, the profile’s manufacturing process is numerically simulated to obtain a representative residual stress field. These results are then used as the initial state during a subsequent structural and fatigue analysis. A clear detrimental residual stress effect is verified. Importantly, however, is to note that prediction accuracy increases significantly when these effects are considered.

Study on Initial Corrosion Behavior of Arc-thermally Spray Zn, Zn–Al, and Al–Mg Coatings Exposed in Atmospheric Environment for One-Year

AbstractThis paper presents the results of a study comparing the initial corrosion characteristics of thermal spray coatings on Zn, Zn-Al, and Al–Mg thermal spray coatings after one year atmospheric exposure tests at two atmospheric environment sites. The thermal spray coatings were obtained by electroric arc spraying of various metals onto a carbon steel substrate. Atmospheric exposure tests were also conducted for outdoor accelerated exposure tests in which test specimens were applied with artificial seawater. The corrosion properties of these spray coatings were evaluated by surface analysis, film thickness measurements, cross-sectional analysis and anodic/cathodic polarization measurement. After one year of atmospheric exposure testing, white, granular corrosion products were observed on the surface of the Zn and Zn-Al thermal spray coatings, while no significant changes were observed in the Al–Mg thermal spray coating. Similar results were obtained for the surfaces of test specimens in atmospheric exposure tests with artificial seawater. The thickness of the thermal spray coating increased for the Zn thermal spray coating, while no significant change was observed for the other thermal spray coatings. Thus, differences in corrosion behavior were observed due to the composition of the thermal spray coatings. The initial corrosion behavior of the thermal spray coatings was also investigated based on the results of coating morphology and cross-sectional elemental distribution of the coatings.

Exploration of modified β-cyclodextrin compounds as enhanced eco-friendly and easily accessible corrosion inhibitors for carbon steel in hydrochloric acid

β-CD was esterified independently with two distinct ionic liquids to evaluate their potential as corrosion inhibitors for carbon steel in a 1.0 M HCl solution. Experimental and computational methods were used to assess the inhibitors’ efficiency regarding temperature and concentration effects and to elucidate the adsorption mechanism. Both inhibitors acted as barriers, with a maximum inhibition efficiency of about 94 % at 200 ppm. There was a direct relationship between the inhibitor's concentration and their efficiency, while increasing the temperature reduced the inhibitors’ effectiveness. The thermodynamic and kinetic parameters were evaluated and studied. DFT calculation revealed the electronic structure and reactivity of the inhibitors. Molecular dynamic simulation provided insight into the optimal configuration and binding energies of inhibitors on the Fe (110) surface.

Imidazole derivative for corrosion protection: A comprehensive theoretical and experimental study on mild steel in acidic environments

The inhibition efficiency derivative imidazole, 2-mercapto-5,5-diphenyl-3,5-dihydro-4 H-imidazol-4-one (AM0), against corrosion in a hydrochloric acid (HCl) environment was studied. The research focused on the compound's ability to adsorb onto mild steel surfaces. Various experimental techniques, including potentiodynamic polarization (PDP), electrochemical frequency modulation (EFM), and impedance spectroscopy (EIS), were employed to analyze the inhibitory effects. Results showed that the effectiveness of AM0 increased with concentration, reaching an inhibitory efficiency of 95.1 %. Polarization studies revealed that the inhibitor displayed mixed-type behavior. The adsorption process was modeled using the Langmuir adsorption model. Surface characterization techniques such as scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDS), and X-ray photoelectron spectroscopy (XPS) were utilized to examine the inhibited corrosion surfaces. Theoretical calculations based on density functional theory (DFT) and density functional tight binding (DFTB) suggested that inhibitors with electron-accepting capabilities exhibited strong interactions with the iron surface, shedding light on specific bond formations that contribute to the stability and interaction dynamics at the molecular interface. This study provides valuable information on the corrosion inhibition potential of the new imidazole compound, offering important pointers for the development of effective corrosion inhibitors in acidic environments.

Investigating the Corrosion Inhibition Performance of a Novel Coconut Oil-Based Poly(urethane-urea) Hybrid Coating on Carbon Steel in 3.5% NaCl Solution

Polyurethane has been used for years as an anti-corrosion coating due to its intrinsic hydrophobic properties. However, its hydrophobicity is not enough to inhibit the permeation of corrosive agents; thus, incorporating it with polyurea would further enhance its hydrophobic properties. In this study, coconut oil, a saturated, low molecular weight vegetable oil, was employed as an eco-friendly precursor for synthesizing a novel poly(urethane-urea)- based hybrid coating. The synthesis process involved the utilization of a coconut oil-based polyol blend, triethanolamine (TEA) as an amine source, and hexamethylene diisocyanate (HDI). The resulting hybrid coating on carbon steel demonstrated remarkable anticorrosion performance in a 3.5 wt. % NaCl solution, owing to the intrinsic hydrophobic characteristics of coconut oil and polyurea. Significant corrosion rate reduction was observed with increasing amine content, accompanied by an enhancement in mechanical properties. Notably, an amine loading of 4% consistently exhibited superior corrosion resistance and mechanical performance in the hybrid coating. Chemical structural analysis revealed a hydrogen-bonding network in polyurea coatings, reducing porosity, enhancing barrier properties, and improving mechanical characteristics, highlighting its potential for sustainable corrosion protection.

Improvement of the tribological and high‐temperature oxidation behavior of mild steel by alumina coating

Improvement of the tribological and high‐temperature oxidation behavior of mild steel by alumina coating

Microscopic characteristics and properties of co-based coating by pulse current-assisted laser cladding on high carbon steel

Laser cladding has the advantages of a short processing cycle and good processing quality, and has been extensively researched in the field of rail property enhancement. The current study focuses mostly on enhancing the mechanical properties of rails by altering the laser process parameters and using complicated materials. However, the enhancement of mechanical properties such as corrosion and friction resistance by laser cladding is limited. As an effective metallurgical processing method, pulse current can be used to control the microstructure and improve the mechanical properties by altering the solidification process of the metal. In this paper, the effects of pulse current parameters (pulse current frequency, current peak, and duty cycle) on microscopic characteristics, such as microstructure number of pores, and microhardness, as well as mechanical properties, such as wear and corrosion resistance, of stellite-6 coatings created by pulse current-assisted laser cladding (PC-ALC), on the U71Mn substrate were investigated. The results showed that the electromagnetic action of the current refined the grains and reduced the number of pores in the PC-ALC coating. The degree of grain fineness increased, then decreased, as the current intensity increased. When compared with the microhardness without pulse current, the average hardness of the HAZ and coating rose by 49.7 % and 167 %, respectively. The results showed a positive link between corrosion resistance and current frequency, but a negative correlation between corrosion resistance and current peak. The corrosion resistance was improved by increasing the current duty cycle from 25 % to 50 %. The wear resistance of coatings was positively related to microhardness, and the coating reached the wear stabilization stage with a friction loss of about 0.5 %. The tests indicated that PC-ALC coatings had good corrosion and friction resistance for rail repair, extending their service life.

Fluid depth-dependent biofilm characteristics and their influence on sulfate-reducing bacteria-induced corrosion of carbon steel

This study investigates the response of biofilm characteristics to variations in fluid depth and their influence on the corrosion behavior of carbon steel (C1020) under low-flow fluid conditions, utilizing Desulfovibrio vulgaris. The experiments were conducted in an anaerobic chamber at 30 °C, utilizing modified Baar's medium as the testing medium. The findings reveal that fluid depth significantly impacts biofilm-corrosion product composite formation, with deeper depths promoting thicker and more heterogeneous biofilm-corrosion product layer compared to shallower depths, where a thinner and more uniform biofilm-corrosion product layer is observed. Moreover, the characteristics of initially attached biofilms was verified as the primary factor affecting subsequent corrosion behavior during prolonged exposure. Corrosion analysis reveals that greater fluid depth leads to increased weight loss (91 ± 13.2 mg/cm2) and deeper pit depths (540 ± 69 μm), surpassing those observed in shallower test media (21 ± 2.3 mg/cm2 and 105 ± 17 μm) after 28 days of exposure. The corrosion products within the biofilm were predominantly FeS and Fe3(PO4)2·8H2O. A direct relationship was observed between the thickness of this biofilm-corrosion product layer and the progression of pit depth, suggesting a strong correlation between carbon steel corrosion and biofilm development in limited fluid depths (e.g., 5–15 mm). Furthermore, a significant association between the deepest pits (average) and the number of sessile cells within the biofilm underscores the pivotal role of sessile cell numbers in carbon steel corrosion.

Fatigue Behaviour of High-Performance Green Epoxy Biocomposite Laminates Reinforced by Optimized Long Sisal Fibers.

In recent decades, in order to replace traditional synthetic polymer composites, engineering research has focused on the development of new alternatives such as green biocomposites constituted by an eco-sustainable matrix reinforced by natural fibers. Such innovative biocomposites are divided into two different typologies: random short fiber biocomposites characterized by low mechanical strength, used for non-structural applications such as covering panels, etc., and high-performance biocomposites reinforced by long fibers that can be used for semi-structural and structural applications by replacing traditional materials such as metal (carbon steel and aluminum) or synthetic composites such as fiberglass. The present research work focuses on the high-performance biocomposites reinforced by optimized sisal fibers. In detail, in order to contribute to the extension of their application under fatigue loading, a systematic experimental fatigue test campaign has been accomplished by considering four different lay-up configurations (unidirectional, cross-ply, angle-ply and quasi-isotropic) with volume fraction Vf = 70%. The results analysis found that such laminates exhibit good fatigue performance, with fatigue ratios close to 0.5 for unidirectional and angle-ply (±7.5°) laminates. However, by passing from isotropic to unidirectional lay-up, the fatigue strength increases significantly by about four times; higher increases are revealed in terms of fatigue life. In terms of damage, it has been observed that, thanks to the high quality of the proposed laminates, in any case, the fatigue failure involves the fiber failure, although secondary debonding and delamination can occur, especially in orthotropic and cross-ply lay-up. The comparison with classical synthetic composites and other similar biocomposite has shown that in terms of fatigue ratio, the examined biocomposites exhibit performance comparable with the biocomposites reinforced by the more expensive flax and with common fiberglass. Finally, appropriate models, that can be advantageously used at the design stage, have also been proposed to predict the fatigue behavior of the laminates analyzed.