Carbon Production Research Articles

Basics and new opportunities for chemical re-alkalisation of carbonated concrete, including alkali-activated binders

Steel corrosion is one of the main factors limiting the durability of existing reinforced concrete components. Based on the corrosive circumstances, different prevention and repair methods can be applied. In the case of carbonation-initiated corrosion, chemical re-alkalisation (CRA) is one of the standard measures to counteract alteration processes in the concrete that lead to reinforcement corrosion. The current state of research on the CRA of carbonated concrete and the various materials that have been investigated in terms of their applicability for this repair measure are summarised. The review summarises current research results in the field of carbonated concrete and the proven pozzolanic reactivity of the carbonation products in contact with portlandite, which suggests an inhibitory effect on CRA, although this has not yet been investigated. There are also initial attempts that deviate from the application of classic Portland cement as a repair material, but their applicability in practice must be questioned. The use of alternative binders and the associated different compositions of pore solutions and varying alkalinity of these binders (e.g. composite cements with a high substitution rate or alkali-activated binders), have not yet been investigated for repair processes such as CRA, although the chemical composition of binders is of the greatest importance for successful application of the repair measure.

Pastures as natural climate solutions: A socioecological study of tree carbon and beef production trade-offs

Sustainable management strategies that facilitate the incorporation of trees into cattle pastures are widely recognized as emerging natural climate solutions. However, their potential to dually improve ecological functioning and human livelihoods has yet to be evaluated across regions on local scales, utilizing both ecological and sociological data. Further, the relationship between landowner participation in conservation management programs (CMPS) and their management priorities (i.e. production vs sustainability) also remains unclear. Therefore, the aims of this study were to evaluate the accuracy of past global-scale remote estimations of aboveground biomass and derived tree carbon density (MgC ha−1) within pasturelands at the local scale in both temperate and tropical regions. We also sought to analyze how participation in CMPs related to the perceptions of stakeholders toward the ecological health of their system. We compared findings between farms in temperate (n = 26) and tropical (n = 16) ecosystems. We found that discrepancies exist between previous remote studies and current field estimations of tree carbon in the farms, and these differences were not regionally uniform. In contrast, stakeholders enrolled in CMPs had a higher value of trees in both regions. CMPs participants also had lower annual stocking rates than those that practiced conventional management but no differences in woody species diversity (H’) or tree carbon (MgC ha−1). We demonstrate the urgent need for local-scale studies to accurately estimate tree carbon in mosaic pasture systems and the importance of conservation management in shifting the priorities of landowners, which could eventually lead to more sustainable systems.

Carbon footprint of tobacco production in China through Life-cycle-assessment: Regional compositions, spatiotemporal changes and driving factors

The global contribution of cigarette production to greenhouse gas emissions is substantial, with tobacco agricultural production being a major source. Based on statistical data, this research employs a Life-Cycle Assessment (LCA) method to comprehensively evaluate China’s flue-cured tobacco production carbon footprint (CF) from 2004 to 2020, detailing its components, spatiotemporal dynamics, and driving factors. The study reveals that the average CF per hectare for China’s tobacco production (CFr) amounted to 12576.46 kg CO2eq·ha−1. Regionally, the CFr was 10799.55 kg CO2eq·ha−1 in Northern China, 14517.00 kg CO2eq·ha−1 in Southeastern China, 11788.82 kg CO2eq·ha−1 in the lower Yellow/Huai River region, 13138.70 kg CO2eq·ha−1 in the mid-Yangtze River and 12415.56 kg CO2eq·ha−1 in Southwestern China. Over the study period, Southwest China’s CFr exhibited an upward trend with an annual growth rate of 121.81 kg CO2eq·ha−1. At the micro-level, coal use contributes more than 60 % of carbon emissions, followed by curing power consumption. On a macro scale, economic activities significantly elevated the CF, whereas factors like carbon emission intensity, production efficiencies, and structural shifts contributed to its reduction. This research indicates that employing clean energy in curing barns, reducing agricultural film usage, and enhancing fertilizer utilization rates represent effective strategies for achieving low-carbon tobacco production. The results of this study have certain reference value for the policy formulation of low-carbon tobacco production and sustainable agriculture in China.

Design of the Particle Size and Morphology of Hard Carbon Anode Materials for Sodium-Ion Batteries Through Hydrothermal Carbonization

With sodium-ion batteries (SIBs) finding widespread application, the demand grows for hard carbon, the most popular anode material for SIBs. Hydrothermal carbonization facilitates the production of hard carbon with desired characteristics from various sources. Despite the considerable volume of literature addressing this subject, there is a notable absence of investigations elucidating the relationship between synthesis conditions and the electrochemical characteristics of the product. Here we study systematically the influence of hydrothermal carbonization parameters on hard carbon characteristics and emphasize the potential of hard carbon as an anode material for SIBs. The initial Coulombic efficiency (ICE) is significantly affected by the particle size of the glucose-derived hard carbon, which, in turn, depends on glucose concentration in the initial solution, pH, and stirring regime. By optimizing the hydrothermal carbonization parameters, the ICE up to 91% and a good reversible capacity of ∼300 mAh g−1 in a half cell are achieved. Full cells with Na3(VO)2(PO4)2F cathode material demonstrate ICE of about 80% and reversible capacity of up to 100 mAh g−1 cath. Considering the effective performance of pouch-cell SIB prototypes based on Na3(VO)2(PO4)2F and hard carbon, hydrothermal carbonization of glucose yields hard carbon with the necessary characteristics required for its successful application in SIBs.

Simultaneous optimization of activation conditions of alperujo (two-phase olive mill waste) using a desirability function: Production of porous carbons for adsorption and energy storage

Valorization of agro-industrial waste is considered an essential step towards a circular economy. The potential reuse of these byproducts in practical applications requires feasibility assessments and optimization of variables in order to be profitable. In the present study, an abundant and problematic residue from the olive oil industry, “alperujo” (two-phase olive mill waste), was used as precursor material for activated carbons. A simultaneous optimization methodology was applied to maximize two response variables: energy storage capacity and lead (Pb) removal efficiency. The simultaneous optimum conditions were 3.66 g of KOH per g of carbonized residue and a temperature of 650 °C for 120 min. The result was a microporous activated carbon with an energy storage capacity of 252 F/g and a lead removal from aqueous solutions of 68.8 %. These values are comparable with those offered by commercial activated carbons, evidencing that porous materials obtained from alperujo using unique activating conditions for both applications present a remarkable performance. The novelty of the present study lies in the application of a useful statistical methodology for simultaneous optimization through the “desirability function”, resulting in a reduction in cost and time. Our results have demonstrated that it is possible to generate activated carbons with the highest performance for two different applications using the same combination of activation variables.

Mild modification of sponge-like carbon: Ammonia post-treatment for enhanced CO2 adsorption and suitability for supercapacitors

During the synthesis of carbon-based CO2 adsorbents and supercapacitors, the introduction of nitrogen atoms into the carbon matrix has been identified as a means to enhance their performance. Nevertheless, the intricate effects of nitrogen doping on material properties pose a significant challenge in developing efficient methodologies. In this investigation, porous carbons resembling sponges were fabricated utilizing macadamia nut shells as a precursor and a dual salt comprising K2C2O4-KCl as an activating agent. Subsequent modification of the materials through ammonia post-treatment facilitated the production of nitrogen-doped porous carbon. The alterations in surface characteristics and pore morphology after ammonia treatment were meticulously examined to unravel the underlying mechanism of this modification process. The samples under scrutiny showcased remarkable CO2 adsorption capacities, peaking at 6.97 mmol/g at 0 °C and 4.65 mmol/g at 25 °C. Employing mathematical models to probe the influence of pore structure and surface properties on CO2 adsorption efficacy proved to be fruitful. A linear correlation was established to depict CO2 adsorption behavior, underscoring the joint impact of ultramicropore volume and nitrogen content on the adsorption process. Notably, the material exhibited a specific capacitance of 290.4F/g at a current density of 0.5 A/g within a three-electrode configuration, demonstrating commendable rate capability and cyclic stability. The pivotal findings from this inquiry emphasize that ammonia post-treatment represents a gentle modification strategy exerting minimal influence on the pore architecture, thereby efficaciously enhancing both CO2 adsorption and electrochemical performance.

Spatio‐temporal visualization of soil dissolved organic carbon production and mobilization in a high‐elevation Andean catchment

Spatio‐temporal visualization of soil dissolved organic carbon production and mobilization in a high‐elevation Andean catchment

Enhancing the adsorption capacity of organic and inorganic pollutants onto impregnated olive stone derived activated carbon

This study presents a sustainable approach to activated carbon production from olive stones in comparison to commercial ones, using various activating agents such as H3PO4, KOH, and ZnCl2, for enhancing the adsorption properties and versatile adsorption capability to remove a range of pollutants including copper ion, methylene blue, and 2,4-Dichlorophenoxyacetic acid from aqueous solutions. The performances of activated carbons across varying conditions such as pollutant concentrations, temperatures, pH levels, and adsorbent amounts were tested. Increased initial pollutant concentrations correlated with higher adsorption capacities. Maximum adsorption capacities were achieved at pH levels of 5, 10, and 2 for Cu, MB, and 2,4-D, respectively. For KOSAC, Cu removal rose from 27 % to 52 %, for ZOSAC, MB removal increased from 39 % to 65 %, and for ZOSAC, 2,4-D removal surged from 33 % to 99 % at varying adsorbent amounts. Model validation was carried out utilizing the kinetic models (PFO, PSO) and isotherm models (Langmuir, Redlich-Peterson). The PFO kinetic model and Langmuir isotherm model proved more suitability for Cu adsorption, whereas PFO and PSO kinetic models, along with Redlich-Peterson isotherm models, were more prominent for MB and 2,4-D adsorption. Thermodynamic analysis revealed that the adsorption of Cu and 2,4-D was exothermic, while MB adsorption was endothermic. By optimization of experimental conditions, the maximum adsorption capacities were attained at 30.34 °C and 297.65 mg L−1 for KOSAC-Cu, 48.62 °C and 269.37 mg L−1 for ZOSAC-MB, and 30.31 °C and 299.02 mg L−1 for ZOSAC-2,4-D sorption. This research highlights ZOSAC's potential as a cost-effective, eco-friendly solution for water treatment, contributing to environmental sustainability and economical feasibility.

The role of Vorasurf 504 surfactant in the production of large mesoporous carbon using solvent-free method and its application in the removal of emergent contaminants

This work reports using the solvent-free method for the first time in the literature using the surfactant Vorasurf504 (V504) to produce mesoporous carbons (MC). In addition to V504, resorcinol was used as a carbon source, and terephthalaldehyde as a cross-linking agent. Three materials were produced with different proportions of resorcinol: V504, 1:1 (R1V), 1:2 (R2V), and 1:3 (R3V). V504 enabled the production of large mesoporous carbon, mainly for the materials with higher proportions of surfactant. The average pore diameters of the materials varied between 5 and 29 nm, and the mesopore volumes were on the order of 0.922 cm3 g−1. The three produced materials were applied to remove emerging contaminants (EC) with different structural dimensions: paracetamol (PA), atrazine (AT), tenofovir (TF), and ceftriaxone (CF). During the contact test, R2V and R3V showed removals above 90 % for all EC. However, due to its limited mesoporosity, the R1V material had its removal capacity reduced for contaminants of larger structural dimensions. Through kinetic and isotherm studies for systems involving paracetamol and ceftriaxone, it was proven that, in fact, not only the specific surface area but also the pore size and pore volume influence adsorption. As a result of this study, large mesoporous carbon could be produced using a surfactant that has not previously been investigated for the solvent-free method. Furthermore, the materials produced can be used as effective adsorbents for emerging contaminants of various structural dimensions.

Optimizing the leaf-to-bunch ratio in ‘Mazafati’ date trees by considering source-sink limitation and physiological-molecular responses

The balance between carbon production and consumption is regulated by source and sink, which can limit plant performance. When there is an imbalance between source and sink, the plant's performance is affected. Thus, source and sink are interdependent. We conducted a two-year study (220–221) to investigate how different leaf-to–bunch ratios (LBR) (7–12) affect source–sink balance and yield in ’Mazafati’ date trees. We also determined the optimal number of bunches per tree as the main carbon sinks competing with other organs. Trehalose is a non-reducing sugar that protects cellular structure and function under stress. We found that 9–10 LBR-trees had no biotic stress due to carbon deficiency or excess, as indicated by minimal expression of the trehalose-6-phosphate synthase (TPS) gene and synthesis of trehalose. This alleviated source-sink limitation and resulted in the highest yield, bunch weight, fruit weight and flavor, water use efficiency, and reduced abscised fruit. Hormones gibberellic acid (GA3) and abscisic acid (ABA), gene expression of sucrose phosphate synthase 1 (SPS1), enzyme activities of sucrose phosphate synthase (SPS) and sucrose synthase (SuSy) related to sucrose synthesis, reducing and non-reducing sugars, and starch increased with increasing LBR in date palm fruit. Based on our findings, we concluded that a LBR of 9–10 optimizes fruit quality in date palm.

Prospective Life Cycle Assessment Prospective (LCA) of Activated Carbon Production, Derived from Banana Peel Waste for Methylene Blue Removal

Prospective Life Cycle Assessment Prospective (LCA) of Activated Carbon Production, Derived from Banana Peel Waste for Methylene Blue Removal

A novel method for MSWI fly ash resource based on calcium component regulation and CO2 mineralization

While accelerated carbonation has been widely studied for the disposal of municipal solid waste incineration (MSWI) fly ash, there has been limited consideration for high-value applications of carbonization products and environmental risks. High-performance CaCO3 ceramics and cement pastes were produced in a low-carbon and sustainable manner by combining calcium extraction, CaCO3 crystal transformation, and cold sintering to reduce the environmental risks associated with heavy metals in MSWI fly ash. The mechanisms of CaCO3 crystal transformation, dissolution-reprecipitation, stabilization of heavy metals (HMs), and hydration of acid-leached solids were explored. Experiments and density functional theory results show that calcite has a stabilizing impact on divalent HMs (Ba, Cd, Ni, Pb, and Zn) (Ei < 0). According to the principles of thermodynamics and crystallography, temperature, pH, and reaction time affected the gradual transition of Vaterite to calcite. The optimal reaction conditions were 10 % ammonia water and 10 min reaction time. Vaterite in CaCO3 ceramics demonstrated outstanding mechanical properties (compressive strength > 265 MPa) based on pressure solution creep. The potential risk of acid-leached solids in alkaline environments was low (The overall pollution toxicity index is only 15). Calcium sulfate (>50 %) in acid-leached solid reacted with aluminate to form ettringite. Strongly alkaline cement pastes with high compressive strengths (>40 MPa) generated from acid-leached cementitious materials posed a low risk of HMs leaching. Throughout the disposal process, HMs leaching concentration in leachate and reaction solution fulfilled Class III groundwater criteria (GB/T 14848–2017). This approach offers environmental benefits and demonstrates broad applicability across diverse alkaline solid waste types.

Innovative MOS-based fiber cement boards: Effect of kraft pulp mills waste and curing by accelerated carbonation

The increasing global waste generated by industrial activities poses significant environmental challenges. Eco-waste management emerges as an economically viable solution for converting, valorizing, and repurposing these byproducts, aligning with circular economy principles, and aiming to reduce greenhouse gas emissions. Construction, known for its unsustainability due to high energy consumption, non-renewable resource utilization, waste generation, and greenhouse gas emissions, particularly from cement production, has led to the exploration of alternative materials. Magnesium oxide (MgO)-based cement, an alternative to Ordinary Portland Cement (OPC), has gained attention, leveraging Brazil's prominence as a major magnesite producer. This study explores the valorization of waste from kraft pulp mills of the paper industry, specifically lime sludge (LS) and lime slaker grits (grits), to produce magnesium oxysulfate (MOS)-based fiber cement boards. The effect of accelerated carbonation on cementitious composites produced with formulations containing grits and LS was investigated. Replacing 25% of the limestone with grits showed no noticeable differences in the properties of the boards, and MOR values close to 11.17 MPa were obtained. However, the physical-mechanical performance showed a decrease with the use of LS and higher concentrations of grits, associated with Na2SO4.XH2O formation in the system and ITZ structure formed around the aggregated particle, respectively. Carbonation in a saturated atmosphere led to the carbonation of the 5–1–7 phase, which was related to the decrease in mechanical strength of the boards after the curing process. The thermal decomposition of the Hydrated Magnesium Carbonates (HMCs) formed during accelerated carbonation corroborated with the changes in the physical properties of the composites, demonstrating that the carbonation products are formed within the voids and pores of the material and contribute to the reduction in water absorption of the boards.

Produce low-CO2 silica fume hybrid high-strength concrete using dry ice (solid CO2) as a CO2-utilized admixture

Concerns about high-strength concrete (HSC) have increasingly grown in tandem with the building industry's rapid development. However, the high CO2 emissions, high hydration heat, and high autogenous shrinkage of HSCs considered key issues that limit their wide application. In this study, various proportions of dry ice (solid CO2) were added to concrete to optimize HSC. The test results indicated that adding solid CO2 decreased the hydration heat and autogenous shrinkage and increased the mechanical properties and surface electrical resistivity of HSC. This is primarily attributed to the physical and chemical effects of solid CO2 in HSC curing. At 28 d of curing, the sample containing 3 wt% solid CO2 exhibited the most significant optimization effect. This is attributed to the fact that, at lower solid CO2 content (3%), the production of carbonation products compensates for the loss of strength caused by the reduction of hydration products. In addition, the addition of solid CO2 caused a decrease in the initial temperature, which delayed the hydration reaction and reduced the autogenous shrinkage. Adding solid CO2 led to an increase in acidity and promoted the formation of AFt, further reducing the autogenous shrinkage. And the more solid CO2 added, the greater the reduction in CO2 emissions for the mixture. Therefore, adding solid CO2 can play a role in optimizing the performance and promoting the sustainability of HSC and can contribute to the objectives of low CO2 emissions, low hydration heat, and low autogenous shrinkage of HSC.

Distributed electrified heating for efficient hydrogen production

This study introduces a distributed electrified heating approach that is able to innovate chemical engineering involving endothermic reactions. It enables rapid and uniform heating of gaseous reactants, facilitating efficient conversion and high product selectivity at specific equilibrium. Demonstrated in catalyst-free CH4 pyrolysis, this approach achieves stable production of H2 (530 g h−1 L reactor−1) and carbon nanotube/fibers through 100% conversion of high-throughput CH4 at 1150 °C, surpassing the results obtained from many complex metal catalysts and high-temperature technologies. Additionally, in catalytic CH4 dry reforming, the distributed electrified heating using metallic monolith with unmodified Ni/MgO catalyst washcoat showcased excellent CH4 and CO2 conversion rates, and syngas production capacity. This innovative heating approach eliminates the need for elongated reactor tubes and external furnaces, promising an energy-concentrated and ultra-compact reactor design significantly smaller than traditional industrial systems, marking a significant advance towards more sustainable and efficient chemical engineering society.

Blended Nephelium lappaceum and Durio zibethinus wastes for activated carbon production via microwave-ZnCl2 activation: optimization for methylene blue dye removal

Herein, this work targets to employ the blended fruit wastes including rambutan (Nephelium lappaceum) peel and durian (Durio zibethinus) seed as a promising precursor to produce activated carbon (RPDSAC). The generation of RPDSAC was accomplished through a rapid and practical procedure (microwave-ZnCl2 activation). To evaluate the adsorptive capabilities of RPDSAC, its efficacy in eliminating methylene blue (MB), a simulated cationic dye, was measured. The Box–Behnken design (BBD) was utilized to optimize the crucial adsorption parameters, namely A: RPDSAC dose (0.02–01 g/100 mL), B: pH (4–10), and C: time (2–6 min). The BBD design determined that the highest level of MB removal (79.4%) was achieved with the condition dosage of RPDSAC at 0.1 g/100 mL, contact time (6 min), and pH (10). The adsorption isotherm data is consistent with the Freundlich concept, and the pseudo-second-order versions adequately describe the kinetic data. The monolayer adsorption capacity (qmax ) of RPDSAC reached 120.4 mg/g at 25 °C. Various adsorption mechanisms are involved in the adsorption of MB dye onto the surface of RPDSAC, including π–π stacking, H-bonding, pore filling, and electrostatic forces. This study exhibits the potential of the RPDSAC as an adsorbent for removal of toxic cationic dye (MB) from contaminated wastewater.

Integrated and Automated: Liquid Metal‐based System for Full Cycle CO2‐to‐Carbon Conversion

AbstractThe urgency for carbon neutrality is driving the need for cost‐effective Carbon Capture and Conversion (iCCC) technology, but the lack of a unified platform for capture, release, and the subsequent in situ catalytic conversion has hindered its widespread adoption. To address this gap, it have showcased the feasibility of achieving an energetically balanced design intertwining CO2 capture and in situ conversion through a continuous gas‐to‐solid reaction process on the customized liquid metal‐based reaction system. The system exhibits a remarkable carbon production capability, achieving a peak yield of 550.57 µmolC mmol CO2‐−1 accompanied by 100% carbon conversion rate. The vertically bottom‐up spiral reactor design introduces significant mass transfer enhancements, resulting in a higher conversion yield rate of 8658.3 µmol h−1 (323.24 µmolC mmolCO2‐−1) while requiring an energy input of only 30.79 GJ t−1 CO2 in a 1.508×10−3 m3 unit. The solid carbon produced in the continuous setup also holds the potential for high‐end application value, such as being a high‐performance material for wave adsorption or acting as an efficient photocatalyst. This research insights are poised to chart new pathway into refining the design strategy for CO2 solidification processes, particularly the seamless melding of carbon capture and in situ conversion.

Environmental characterization of ferrochromium production waste (refined slag) and its carbonization product

This paper presents the results of research on the method of utilization of self-disintegrating slags of refined ferrochrome production by autoclave carbonization in carbon dioxide environment. The work has a complex character, including earlier laboratory studies of the slag carbonization process under different conditions, as well as studies of chemical and mineralogical composition of initial waste slags taken from the slag dump and samples of bricks subjected to carbonization. The composition of slags and obtained products was investigated by XRD, DTA, DTG and XRF analyses, which showed that the main phases of the studied samples are dicalcium silicate, montichelite, periclase, magnesiochromite, calcite. Thermal analytical studies showed that magnesium carbonate is present only in the samples of artificially carbonized material. Also, the process of carbonate formation in the thickness of bricks during forced carbonization was investigated. As a result, it was obtained that with increasing CO2 pressure, the amount of bound carbon in the products increases proportionally in all layers. It was determined that the amount of CO2 absorbed during carbonization can reach 20 % of the mass of the initial slag. Stale slag can be used simultaneously as a carbon dioxide absorber and as a building product.

Towards low-cost and sustainable activated carbon production: Influence of microwave activation time on yield and CO2 uptake of PET-derived adsorbents

Microwave (MW) heating is proposed as a method to transform polyethylene terephthalate (PET) into porous adsorbents. The yield, textural properties, and CO2 uptake of the PET-derived adsorbents irradiated at different durations (3 – 35 min) at 400 °C were assessed. MW activation time influenced both the physical properties and CO2 uptake capacities of the resulting adsorbents. The yield decreased with activation time, but the surface area, total pore volume, micropore volume, and CO2 uptake capacities all increased with MW activation time before declining. The optimal sample (produced with 5 min of MW activation time) showed improved textural properties as well as higher equilibrium and dynamic CO2 uptakes than the commercial activated carbon used as reference. This adsorbent also possesses good selectivity for CO2 in the binary 10:90%vol/vol CO2: N2 mixture. Additionally, an excellent recyclability over 20 cycles, (Regeneration Efficiency > 97%) was observed, and the CO2 adsorption kinetics best fits Lagergren’s pseudo-second-order model. This study has shown that a low activation temperature (400 °C), a short MW activation time (5 min), and a low amount of chemical agent (KOH, 0.72 M) could produce CO2 adsorbents from a cheap and abundant material (PET-waste) with better CO2 uptake to that of a commercial activated carbon.

Activated carbon assisted cobalt catalyst for hydrogen production: synthesis and characterization

In this work, a cobalt catalyst supported by activated carbon was used to produce hydrogen through the hydrolysis of sodium borohydride (NaBH4). First, hydrochar was produced from MDF powder by hydrothermal pretreatment. Then, ideal parameters (activator percentage, activation time, baking time, and temperature) for activated carbon production were determined. The best conditions for the synthesis of activated carbon were found to be a 70% activator rate, 24 hours of activation time, 45 minutes of baking time, and 700 ⁰C temperature, according to iodine number measurements. The iodine number was measured as 929 mg/g under optimum conditions. Activated carbon (as a support) produced under optimum conditions was combined with the cobalt catalyst. DT/TGA, FT-IR, SEM, and EDX analyses were used to evaluate the catalyst's structure. Supporting material ratio, NaOH concentration, catalyst amount, and NaBH4 concentration are the variables studied in catalyst synthesis. The trials led to the identification of the optimal catalyst parameters as being 70% support material, 5% NaOH, 40 mg catalyst, and 2% NaBH4 concentration. The hydrogen production rate with the catalyst synthesized in these conditions was determined as 8592.8 ml/g.min. As a result of the hydrolysis reactions carried out at different temperatures, it was determined that the reaction was n. order and the reaction activation energy was 31.19 kJ/mol. Even after the sixth use, 100% efficiency was attained when the catalyst activity was tested repeatedly.