Percentage Of Carbon Research Articles

Characterization of Heavy Metal and Physico-chemical Profiling of Sewage Water Soil in Jaipur District, Rajasthan, India

Jaipur is the capital state of Rajasthan. During the year 2021, District Jaipur of 3 blocks (Chomu, Sanganer, and Shahpura) in 9 villages [Keshav Nagar (V1), Morija (V2), Nindola (V3), Goner (V4), Shrikishanpura (V5), Durgapura (V6), Shivpuri (V7), Manoharpur (V8), Nwalpura (V9)] were selected for estimation of physico-chemical properties and Heavy metal contamination in severage channels. A total of 9 samples were collected from 9 villages sewerage channels. This study aimed to analyze the physico-chemical properties of agricultural soil and irrigation water in three blocks of Jaipur, Rajasthan. The findings revealed significant variations in the physico-chemical properties of the agricultural soil and water in Chomu, Sanganer, and Shahpura. Standard methods were employed to assess the physico-chemical characteristics of soil samples contaminated with sewerage effluents in these regions, which exhibited considerable diversity. The pH levels of the soil samples were predominantly slightly acidic and alkaline ranging from 6.22 to 7.31. Electrical conductivity values varied between 0.41 to 0.62 mmhos/cm. The percentages of organic matter and organic carbon in the soil samples ranged from 0.17% to 0.25% and 0.29% to 0.43%, respectively. Additionally, the analysis included heavy metals such as zinc (Zn), manganese (Mn), iron (Fe), and copper (Cu). The soil samples were found to contain elevated levels of heavy metals, surpassing the permissible limits. The discharge of sewerage effluent into the environment, primarily originating from the textile industry, house, etc. constitutes are major source of pollution that can adversely impact the local flora and fauna. Therefore, it is imperative to implement effluent treatment measures before their release into the environment.

Functionalization methods for ZnO nanoparticles with citric acid and their effect on the antimicrobial activity

The functionalization of ZnO nanoparticles has proven to be an effective alternative to avoid agglomeration and improve their physic-chemical properties. In this work, we studied the functionalization of ZnO nanoparticles using citric acid (CA) through two methods: in situ functionalization and sonochemical functionalization to compare the effects on the physicochemical and antimicrobial properties of functionalized commercial ZnO nanoparticles with those synthesized and functionalized at the same time. Both methods are considered environmentally friendly (green chemistry) since the use of chemical toxic agents was avoided and the reaction medium was water. The in situ method demonstrated the ability of CA to act as a reducing and stabilizing agent. Fourier transform infrared spectroscopy (FTIR) and RAMAN spectroscopy analyses confirmed the functionality of ZnO nanoparticles, through the formation of the COO−/ZnO complex. The wurtzite-type hexagonal crystalline structure of the ZnO nanoparticles was confirmed by X-ray diffraction (XRD). The thermogravimetric analysis (TGA) analysis showed that in situ functionalization was more favored than sonochemical functionalization since 46.66 % and 27.22 % of the organic ligand were obtained on the surface of the nanoparticles, respectively. X-ray photoelectron spectroscopy (XPS) results revealed the chemical and electronic state of the zinc which was 2+ and atomic percentages of carbon of 40.64 % and 38.35 %, as well as atomic percentages of oxygen of 38.67 and 36.78 % for ZnO-AC and ZnO-AC-R1 nanoparticles, respectively. The evaluation of the antibacterial efficiency of the nanoparticles functionalized by both methods demonstrated that they possess a superior antimicrobial activity when compared with non-fuctionalized nanoparticles. The ZnO nanoparticles synthesized and functionalized via in situ showed an efficiency of 99.99 % starting concentrations of 200 ppm.

Physio-chemical Characterisation of Dumped Solid Waste

Landfilling is the most common practice used for the disposal of solid waste since it is the cheapest method of municipal solid waste management. The present study aims to determine the physical and chemical characteristics of dumped solid waste collected directly from Okhla landfill site (New Delhi, India) which has been declared as exhausted in 2018. These waste samples have been collected having ages beyond 20 years. Further, several laboratory tests were performed on the samples to investigate parameters namely physical composition, moisture content, density, optimum moisture content, pH, electrical conductivity, percentages of carbon (C), nitrogen (N), hydrogen (H), sulphur (S) and C/N ratio. The physical composition of samples was found to be substantially heterogenous. The mean values for moisture content and optimum moisture content were observed as 10.03% and 22.27% respectively. Moreover, the mean of density, pH and electrical conductivity were obtained as 1323.88 kg/m3, 6.44 and 3.06 mho/cm respectively. On the other hand, the elemental parameters C, H, N, S mean percentages were evaluated as 5.98%, 0.73%, 0.27% and 0.71%. Consequently, C/N ratio was evaluated as 23.46 for the samples. These results have also been compared with the MSW characteristics of Asian countries.

Evaluation of Two Ecosystem Services Provided by a Pistia stratiotes Population on the Pacific Coast of South America.

One of the most fascinating wetlands on Peru's central coast is the Santa Rosa wetland (Chancay, Lima), an ecosystem threatened by anthropogenic activities. Some of these impacts have led to the uncontrolled growth of Pistia stratiotes, an invasive aquatic plant. This study sought to quantify the regulation and provisioning of ecosystem services provided by P. stratiotes using carbon storage and the provision of biomass as indicators. To this end, the biomasses of 50 plots measuring 0.0625 m2 were weighed and georeferenced and the percentages of dry biomass (%DB) and total organic carbon in the biomass (%C) were quantified. The biomass and its coordinates were entered into ArcGIS and a Kriging interpolation technique was applied to determine the total amount of biomass (B). It was found that P. stratiotes stored 3942.57 tCO2 and that 2132.41 tons of biomass could be obtained for fodder. The total carbon stored by this aquatic plant represented 28.46% of the total carbon sequestered in the wetland ecosystem by vascular plants, suggesting that its contribution to the carbon cycle is significant. This is the first study to estimate the biomass of a floating aquatic plant population in a coastal Peruvian wetland and is a pioneering study addressing the in situ carbon estimation of Peruvian floating aquatic plants. The results and methods proposed in this research will serve in the evaluation of the potential of ecosystem services among similar populations of floating aquatic species. In addition, the data presented can be used to establish plans for the management and use of this biomass in the production of soil fertilizers and cattle forage.

Mineral and Organic Fertilizers' Effect on the Growth of Young Argane Trees (Argania spinosa L.) and Soil Properties under Vulnerable Conditions.

Argania spinosa (L.) Skeels is an endemic species to Morocco that has multiple uses. It plays multiple important roles in terms of its botanical, ecological, and economic properties. However, the domestication of this species will open up considerable economic opportunities for Morocco. Here, for the first time, we assessed the effect of different doses of compost and NPK fertilizers on the vegetative growth parameters, biochemical and antioxidant potential of the Argania spinosa plant, and soil properties. Over a two-year period (2022-2023), eight different treatments were applied across two experimental sites. These treatments included the following: T0 (Control), T1 (F1-80.50.70 g NPK/plant), T2 (F1-125.75.100 g NPK/plant), T3 (F2-160.100.140 g NPK/plant), T4 (F2-250.150.200 g NPK/plant), T5 (F1-2.5 kg/plant compost), T6 (F1-5 kg/plant compost), T7 (F2-5 kg/plant compost), and T8 (F2-10 kg/plant compost), with F1 and F2 being the frequencies of application. We compared several doses of fertilizers with no fertilization as a control. The results showed a significant influence of the compost and NPK fertilizer on the vegetative growth parameters. For the Tamjlojt site, the first year is important because treatments T3 and T4 significantly increased height by 71.94 ± 21.15% and 74.31 ± 12.31%, respectively. For the circumference, the results showed a significant improvement by the treatments T4 and T3, and T1 demonstrated the highest gain. For the collar diameter, all treatments showed a significant difference. The most notable difference was observed with treatments T3 and T7 with 115.63 ± 33.88% and 101.09 ± 20.84%, respectively. For the Rasmouka site, the second year was the most important. The treatments with the most important height increase were T7 and T8, with a value of 43.14 ± 10.06% and 36.44 ± 9.95%; the same was observed for collar diameter as a significant increase was found in T8 and T7 with a value of 55.05 ± 15.7% and 54.08 ± 9.64%. For the circumference parameter, the treatments that increased significantly this parameter were T8 and T7 with a value of 53.36 ± 15.11% and 50.34 ± 11.29% in 2023. In addition, the highest content of carbohydrates was recorded for the treatment T3 with a value of 148.89 ± 8.11 (mg EG/g). For phenolic determination, the highest value was 2532 ± 457.13 (µg GAE/mL), shown for treatment T1. For flavonoids, the treatments that showed a significant effect were T1 and T6 with a value of 2261.98 ± 184.61 and 1237.70 ± 95.65 (µg QE/mL), respectively. For the impact on soil properties, the electrical conductivity, at the Tamjlojt site, treatment T1 showed a significant increase to 1139.00 ± 241.30 (ms/cm), while at the Rasmouka site, treatment T8 showed a significant increase to 303.33 ± 9.33 (ms/cm). Concerning organic carbon, all treatments resulted in increased percentages of this parameter in the soil. For the Tamjlojt site, the T7 treatment had a significant positive effect on this parameter with a value of 0.87 ± 0.12%. For the Rasmouka site, the T3 treatment increased the percentage of organic carbon with a value of 1.17 ± 0.07%. In addition, the organic matter content showed an improvement with a value of 2.02 ± 0.12%. As there are no previous studies in Argania spinosa fertilization, this study greatly contributes to our understanding of the benefits of using different fertilizers at different doses, in particular T8 and T7 as organic fertilizers and T3, T4 as chemical ones, on argan growth, the biochemical and antioxidant properties of leaves, and its soil properties.

Effect of Different Levels of NPK, Biochar and Azotobacter on Physico-chemical Properties of Soil on Cowpea (Vigna unguiculata)

In light of this, the following goals are present in the experiment "Effect of Different Levels of NPK and Biochar, Azotobacter on Physico-chemical Properties of Soil and Yield Attributes of Cowpea to calculate the impact of various NPK, Biochar, and Azotobacter dosages on the physical-chemical characteristics of soil. An excavated soil sample from the experimental site revealed that the land topography ranged from nearly level to sloped by 1% to 6%, with soil area falling into the Inceptisol order. The soil texture was sandy loam, with sand percentages of 62.65%, silt percentages of 21.09, and clay percentages of 16.26. The pH of soil was 6.89, and its electrical conductivity (EC) was non-saline (0.42 ds m-1). Organic carbon content was low to medium, available nitrogen was low to medium (280.78 kg ha-1), available phosphorus was 17.34 kg ha-1, and available potassium was 168.16 kg ha-1. Two factors with three levels of @NPK 0, 50, and 100% ha-1, three levels of @Biochar 0, 50, and 100% ha-1, and a randomized block design were used in the statistical analysis. During field testing, nine different treatments were used; the best outcomes were significant. The results indicate that the physical and chemical parameters of the soil, including the cumulative mean values for bulk density (1.39 and 1.41 mg m-3), particle density (2.46 and 2.47 mg m-3), and soil pH (6.89 and 6.91), attained their maximum in T1 (Absolute control) at depths of 0-15 cm and 15-30 cm, respectively. Additionally, the percentage pore space was found to be 48.22% and 47.39%, and the water holding capacity was found to be 44.14% and 45.34%), electrical conductivity (EC) was measured at 0.49 ds m-1 and 0.52 ds m-1, the percentage of organic carbon was determined to be 0.40%), and the available nitrogen was found to be (299.78 kg ha-1 and 295.76 kg ha-1, available phosphorus was (23.78 kg ha-1 and 21.98 kg ha-1), and the available potassium was (179.25 kg ha-1 and 176.56 kg ha-1).

Naphthenic Acid Corrosion Mitigation: The Role of Niobium in Low-Carbon Steel.

Naphthenic acid corrosion is a well-recognized factor contributing to corrosion in the construction of offshore industry pipelines. To mitigate the corrosive effects, minor quantities of alloying elements are introduced into the steel. This research specifically explores the corrosion effects arising from immersing low-carbon steel, specifically A333 Grade 6, in a naphthenic acid solution. Various weight percentages of niobium were incorporated, and the resulting properties were observed. It was noted that the addition of 2% niobium in low-carbon steel exhibited the least mass loss and a lower corrosion rate after a 12 h immersion in naphthenic acid. Microstructural analysis using scanning electron microscopy (SEM) revealed small white particles, indicating the presence of oil sediment residue, along with corrosion pits. Following the addition of 2% niobium, the occurrence of corrosion pits markedly decreased, and only minor voids were observed. Additionally, the chemical composition analysis using energy-dispersive X-Ray analysis (EDX) showed that the black spot exhibited the highest percentage of carbon, resembling high corrosion attack. Meanwhile, the whitish regions with low carbon content indicated the lowest corrosion attack. The results demonstrated that the addition of 2% niobium yielded optimal properties for justifying corrosion effects. Therefore, low-carbon steel with a 2% niobium addition can be regarded as a superior corrosion-resistant material for offshore platform pipeline applications.

Role of oil droplet size on dynamic pore wetting of active carbon and particle-bubble interaction: New inspiration for enhancing the porous mineral floatability

The dynamic pore wetting plays a vital role in the flotation separation process of porous mineral particles, such as low-rank coal, fly ash and chrysocolla, etc. This paper investigated the dynamic pore wetting behavior of active carbon particles in the water-oil emulsion by 1H low-field nuclear magnetic resonance (1H LF-NMR). The influence of oil droplet size on pore wetting process was revealed. The change in the surface properties of particles before and after wetting was analyzed by contact angle and FTIR measurements. The particle-bubble attachment process in the emulsion and pure water was compared. The total pore wetting percentage of active carbon had a first-order kinetic relationship with the wetting time. The emulsion was beneficial to decrease the pore wetting percentage of particles compared with water. And the pore wetting percentage decreased with the decrease of oil droplet size in emulsion. The pores were easily filled by the oil droplet with small size and the hydrophobicity of sample surface was improved, which prevented the subsequent pore wetting by water. As a result, the detachment force of particle-bubble was increased with the help of micro-oil droplets. This work attempts to provide a new inspiration for the study of porous mineral flotation.

Comparison of Carbon Storage in Forested and Non-Forested Soils in Tropical Wetlands of Caimanera, Colombia, and Llano, Mexico

Mangrove forests are considered to be the most productive ecosystems on the planet due to the multiple ecosystem services they offer, both environmental economic, and social; however, their area in recent years has been decreasing due to anthropogenic activities such as urbanization and deforestation. These activities alter the normal cycle of carbon stored in sediments, which is considered their main function to counteract climate change. Therefore, the objective of this research was to compare the carbon storage capacity and coverage in forested and non-forested sites of two tropical wetlands located in Colombia (the Caimanera) and Mexico (the Llano). Methodologically, we began by identifying the coverages and determining the area in the wetlands with Sentinel-2A satellite images and a supervised classification; subsequently, soil cores were extracted in all the coverages to a depth of 70 cm and the apparent density (AD), the percentage of organic carbon (OC), and the density of carbon in the soil were determined. For analysis of the variables, a trend graph was constructed between carbon density and depth with descriptive statistics, using one-way ANOVA to establish which coverage and wetland were the most significant concerning carbon storage. The results of the supervised classification showed that Rhizophora mangle and Avicennia germinans are the dominant species, also finding deforested areas in both wetlands. The one-way ANOVA statistical test indicated that the Caimanera, with the percentage of organic carbon (18.4 ± 1.19%), is 1.57 times greater than of the Llano mangrove swamp with (11.7 ± 0.748 MgC/ha). Through the trend graph, it was observed that the carbon density of the forested area of the Caimanera ranged from 120 to 140 MgC/ha, which is higher than in the deforested areas of the same wetland between 40 and 60 MgC/ha, and the homologous areas of the Llano wetland. The results suggest that deforested areas are sources of greenhouse gas emissions because they contain less carbon than forested areas. Therefore, it is concluded that the Caimanera and the Llano wetlands have the same mangrove species and that the average organic carbon stored in their soil is below the average of other mangrove forest soils in the American continent; it is recommended that the findings of this work be considered for the carbon balances by continent and the characterization of mangrove species according to their carbon storage capacity.

Biosynthesis of polyhydroxybutyrate from methane and carbon dioxide using type II methanotrophs

Methane (CH4) and carbon dioxide (CO2) are the dominant greenhouse gases (GHGs) that are increasing at an alarming rate. Methanotrophs have emerged as potential CH4 and CO2 biorefineries. This study demonstrated the synchronous incorporation of CH4 and CO2 into polyhydroxybutyrate (PHB) for the first time using 13C-labeling experiments in methanotrophs. By supplying substantial amounts of CO2, PHB content was enhanced in all investigated type II methanotrophic strains by 140 %, 146 %, and 162 %. The highest content of PHB from CH4 and CO2 in flask-scale cultivation reached 38 % dry cell weight in Methylocystis sp. MJC1, in which carbon percentage in PHB from CO2 was 45 %. Flux balance analysis predicted the critical roles of crotonyl-CoA carboxylase/reductase and phosphoenolpyruvate carboxylase in CO2 recycling. This study provided proof of the conversion of GHGs into a valuable and practical product using methanotrophic bacteria, contributing to addressing GHG emissions.

Hydrothermal liquefaction of composite household waste to biocrude: the effect of liquefaction solvents on product yield and quality.

The hydrothermal liquefaction (HTL) of composite household waste (CHW) was investigated at different temperatures in the range of 240-360 °C, residence times in the range of 30-90 min, and co-solvent ratios of 2-8 ml/g, by utilising ethanol, glycerol, and produced aqueous phase as liquefaction solvents. Maximum biocrude yield of 46.19% was obtained at 340 °C and 75 min, with aqueous phase recirculation ratio (RR) of 5 ml/g. The chemical solvents such as glycerol and ethanol yielded a biocrude percentage of 45.18% and 42.16% at a ratio of 6 ml/g and 8 ml/g, respectively, for 340 °C and 75 min. The usage of co-solvents as hydrothermal medium increased the biocrude yield by 35.30% and decreased the formation of solid residue and gaseous products by 19.82% and 18.74% respectively. Also, the solid residue and biocrude obtained from co-solvent HTL possessed higher carbon and hydrogen content, thus having a H/C ratio and HHV that is 1.01 and 1.23 times higher than that of water as hydrothermal medium. Among the co-solvents, HTL with aqueous phase recirculation resulted in higher carbon and energy recovery percentages of 9.36% and 9.78% for solid residue and 52.09% and 56.75% for biocrude respectively. Further qualitatively, co-solvent HTL in the presence of obtained aqueous phase yielded 33.43% higher fraction of hydrocarbons than the pure water HTL and 7.70-17.01% higher hydrocarbons when compared with ethanol and glycerol HTL respectively. Nitrogen containing compounds, such as phenols and furfurals, for biocrudes obtained from all HTL processes, were found to be present in the range of 8.30-14.40%.

Efficacy of plasma treatment for surface cleansing and osseointegration of sandblasted and acid-etched titanium implants.

This study was conducted to evaluate the effects of plasma treatment of sandblasted and acid-etched (SLA) titanium implants on surface cleansing and osseointegration in a beagle model. For morphological analysis and XPS analysis, scanning electron microscope and x-ray photoelectron spectroscopy were used to analyze the surface topography and chemical compositions of implant before and after plasma treatment. For this animal experiment, twelve SLA titanium implants were divided into two groups: a control group (untreated implants) and a plasma group (implants treated with plasma). Each group was randomly located in the mandibular bone of the beagle dog (n = 6). After 8 weeks, the beagle dogs were sacrificed, and volumetric analysis and histometric analysis were performed within the region of interest. In morphological analysis, plasma treatment did not alter the implant surface topography or cause any physical damage. In XPS analysis, the atomic percentage of carbon at the inspection point before the plasma treatment was 34.09%. After the plasma treatment, it was reduced to 18.74%, indicating a 45% reduction in carbon. In volumetric analysis and histometric analysis, the plasma group exhibited relatively higher mean values for new bone volume (NBV), bone to implant contact (BIC), and inter-thread bone density (ITBD) compared to the control group. However, there was no significant difference between the two groups (P > .05). Within the limits of this study, plasma treatment effectively eliminated hydrocarbons without changing the implant surface.

SYNTHESIS AND CHARACTERIZATION OF ACTIVATED CARBON PREPARED FROM RICE HUSK BY PHYSICS-CHEMICAL ACTIVATION

Activated carbon is an amorphous carbon material predominantly composed of free carbon atoms with high adsorption capacity. The amorphous structure in activated carbon affects its adsorption capacity; the higher the percentage of amorphous carbon, the greater the adsorption capacity of the activated carbon. Activated carbon can be obtained from rice husk waste containing 30-40% C in cellulose, hemicellulose, and lignin. Therefore, this study was conducted to observe activated carbon's phases, morphology, elemental composition, and particle size. Activated carbon was synthesized using a physics-chemical activation method, which began with washing the rice husk samples, followed by air drying, carbonizing into charcoal, and grinding it finely. The rice husk charcoal powder was then physically activated at a temperature of 500℃. The physically activated product was then chemically activated using 6M HCl with a charcoal-to-activator ratio of 1:10 (m/V), stirred at 250 rpm for 1 hour, and then allowed to settle for 24 hours. It was then washed and dried to produce activated carbon powder. XRD test results showed diffraction peaks at 2θ = 22.23° without sharp or pointed peaks, indicating that the activated carbon has an amorphous structure. SEM test results showed the morphology of rice husk-activated carbon with spherical particle shapes and a particle size distribution of 20-70 nm. EDX test results showed that the rice husk activated carbon is predominantly composed of C, O, and Si with respective percentages of 54.31%, 40.04%, and 2.49%.

Modeling of Effectiveness of N3-Substituted Amidrazone Derivatives as Potential Agents against Gram-Positive Bacteria.

Prediction of the antibacterial activity of new chemical compounds is an important task, due to the growing problem of bacterial drug resistance. Generalized linear models (GLMs) were created using 85 amidrazone derivatives based on the results of antimicrobial activity tests, determined as the minimum inhibitory concentration (MIC) against Gram-positive bacteria: Staphylococcus aureus, Enterococcus faecalis, Micrococcus luteus, Nocardia corallina, and Mycobacterium smegmatis. For the analysis of compounds characterized by experimentally measured MIC values, we included physicochemical properties (e.g., molecular weight, number of hydrogen donors and acceptors, topological polar surface area, compound percentages of carbon, nitrogen, and oxygen, melting points, and lipophilicity) as potential predictors. The presence of R1 and R2 substituents, as well as interactions between melting temperature and R1 or R2 substituents, were also considered. The set of potential predictors also included possible biological effects (e.g., antibacterial, antituberculotic) of tested compounds calculated with the PASS (Prediction of Activity Spectra for Substances) program. Using GLMs with least absolute shrinkage and selection (LASSO), least-angle regression, and stepwise selection, statistically significant models with the optimal value of the adjusted determination coefficient and of seven fit criteria were chosen, e.g., Akaike's information criterion. The most often selected variables were as follows: molecular weight, PASS_antieczematic, PASS_anti-inflam, squared melting temperature, PASS_antitumor, and experimental lipophilicity. Additionally, relevant to the bacterial strain, the interactions between melting temperature and R1 or R2 substituents were selected, indicating that the relationship between MIC and melting temperature depends on the type of R1 or R2 substituent.

Mathematical modelling for predicting performance and emissions of a diesel engine fuelled with palm kernel biodiesel–diesel-diethyl carbonate fuel blends

The search for environmentally friendly and sustainable alternatives to conventional diesel fuels has prompted investigations into blends of biodiesel and oxygenated additives like diethyl carbonate. This study focuses on developing mathematical models to predict the performance and emissions of a single-cylinder diesel engine running on palm kernel biodiesel blended with varying proportions of diethyl carbonate. Response Surface Methodology with a general factorial design was employed to create mathematical models for brake thermal efficiency, brake-specific fuel consumption, hydrocarbon, carbon monoxide, and oxides of nitrogen emissions. The two input variables were engine load (five levels) and diethyl carbonate percentage in the fuel blend (five levels). Second-order models were developed, and model fit was evaluated using analysis of variance (ANOVA) at 95% confidence. The developed RSM models showed excellent fit with high R-squared values close to unity, satisfying the model adequacy criteria. ANOVA revealed the models to be statistically significant predictors of the response variables based on load and diethyl carbonate percentage. The optimum operating condition for best performance and emissions balance was found to be 71% load and 10% diethyl carbonate inclusion. The study emphasises the importance of alternative fuels in mitigating environmental pollution and reducing dependence on fossil fuels.

The selective cytotoxicity effect of biosynthesized zinc oxide nanoparticles using honey

This work aims to produce biosynthesized zinc oxide nanoparticles using honey (Ho-ZnO-NPs). First, the process of characterization was completed using different techniques, including the color changing to light brown, Zeta-potential that shows a sharp peak at − 5.08 mV, Energy Dispersive X-ray (EDX), which represents the high percentage of Zinc (57.36 %), oxygen (35.03 %) and carbon (7.62 %), Transmission and Scanning Electron Microscopy (TEM and SEM) and X-ray Diffraction (XRD) analysis that illustrate the spherical and hexagonal structure. Then, the cytotoxicity activity was studied using an MTT assay on three cancer cell lines (MCF-7, HepG2, and A431) and an HSF normal cell line. Furthermore, the prepared nanoparticles Ho-ZnO-NPs show that the different IC50 are 118.1, 49.5, and 751.7 µg/mL for MCF-7, HepG2, and A431, respectively. In addition, IC50 is 1.47 mg/mL for HSF. In conclusion, the study reveals that the biosynthesized Ho-ZnO-NPs have higher anticancer activity against HepG2, plus their safety against normal skin cells.

Anthropic Importance of the “Bretscher State” in DT Fusion

The term “Bretscher state” may not be as familiar as “Hoyle state,” but its anthropic importance cannot be overstated. In Big Bang nucleosynthesis, the deuterium-tritium (DT) fusion reaction 3H ( d , n ) 4 He, enhanced by the 3/2+ resonance due to the Bretscher state, is responsible for ∼ 99 % of primordial 4He. While this fact has been known for decades, it has not been widely appreciated, and we recently proposed that its significance be commemorated by naming the 3/2+ state after Egon Bretscher, its discoverer. The importance of the resonant nature of the DT fusion reaction has been amplified by recent activities related to the production and use of terrestrial fusion including recent, net gain shots at the National Ignition Facility. Here, we aim to highlight the anthropic importance of the 4He-producing DT reaction that plays such a prominent role in models of nucleosynthetic processes occurring in the early universe. This primordial helium serves as a source for the subsequent creation of ≥ 25 % of the carbon, 12C and other heavier elements that comprise a substantial fraction of the human body. Further studies are required to determine a better characterization of the amount of 12C than this lower limit of 25%. Some scenarios of core stellar nucleosynthetic yield of 12C suggest that even higher percentages of carbon from primordial helium are possible.

Organic matter decomposition in mountain peatlands: effects of substrate quality and peatland degradation

Abstract Background and Aims Peatlands occupy only 3% of Earth’s terrestrial lands but store about one-third of global soil carbon. However, these large carbon stocks are currently under threat due to peatland degradation, where altered hydrological balance could enhance peat oxidation; thus releasing large amounts of CO2 into the atmosphere. We investigated the interactive effects of substrate quality, peat depth and peatland degradation on the decomposition rate of organic matter in peatlands by way of a field incubation experiment. Methods We incubated high-quality fresh peat and a lower-quality degraded peat substrate at three different depths (5, 15, and 30 cm) in two (intact and degraded) mountain peatlands for 18 months. Our results indicated that there is a significant interactive effect of substrate quality, peat depth, and peatland type on the peat decomposition rate. Results The fresh peat showed significantly higher decomposition rates than the degraded peat substrate, likely due to the high percentage of bioavailable carbon in the fresh moss substrate. In the degraded peatland, fresh peat at 30 cm showed no mass loss during the incubation period, likely due to the high-water table creating anaerobic conditions. The fresh peat incubated in the intact peatland showed a higher decomposition rate than the same substrate incubated in the degraded peatland due to the comparatively lower water table in the intact peatland. Conclusions Our findings indicate that the quality of the substrate being decomposed and the depth of the water table act as the main factors affecting the decomposition rate in mountain peatlands.

Preparation and characterization of stationary phase gradients on C8 liquid chromatography columns

Continuous C8 stationary phase gradients are created on commercial Waters Symmetry Shield RP8 columns by strategically cleaving the C8 moieties in a time-dependent fashion. The method relies on the controlled infusion of a trifluoroacetic acid/water/acetonitrile solution through the column to cleave the organic functionality (e.g., C8) from the siloxane framework. The bond cleavage solution is reactive enough to cleave the functional groups, even with polar groups embedded within the stationary phase to protect the silica. Both the longitudinal and radial heterogeneity were evaluated by extruding the silica powder into polyethylene tubing and evaluating the percent carbon content in the different sections using thermogravimetric analysis (TGA). TGA analysis shows the presence of a stationary phase gradient in the longitudinal direction but not in the radial direction. Two different gradient profiles were formed with good reproducibility by modifying the infusion method: one exhibited an ‘S’-shaped gradient while the other exhibited a steep exponential-like gradient. The gradients were characterized chromatographically using test mixtures, and the results showed varied retention characteristics and an enhanced ability to resolve nicotine analytes.

Biodiesel production and selected fuel qualities from prospective non-edible oils: Hevea brasiliensis, Madhuca longifolia, Azadirachta indica, and Gossypium hirsutum

ABSTRACT Biodiesel predominantly originates from edible oil. Exploring non-edible oil resources is crucial to biodiesel manufacturing’s commercial viability and food security. This study examines four non-edible seed oils Hevea brasiliensis, Madhuca longifolia, Azadirachta indica, and Gossypium hirsutum as biofuel feedstocks. This study optimized reaction parameters to improve base-catalyzed transesterification, oil extraction and biodiesel synthesis. The produced esters were identified by nuclear magnetic resonance, Fourier transform infrared, and gas chromatography mass spectrometry. Elements composition was determined using inductively coupled plasma-optical emission spectrometry and elemental analyzer. The biofuel’s physicochemical properties met American Society for Testing and Materials and European standards. The maximum amount of crude oil was seen in Hevea brasiliensis using the soxhlet extraction process, ranging from 52-63%. This was followed by Madhuca longifolia 38-55%, Azadirachta indica 24-33%, and Gossypium hirsutum with 19-27%. The density of the plant sources exhibited a range of 0.88-0.90 g/cm3 @ 15 °C, while the kinematic viscosity showed a range of 3.2-4.1 mm2/s. The elemental composition of biodiesel, expressed as percentages of carbon, hydrogen, nitrogen, and oxygen, varied between the ranges of 70.52-76.30, 11.25-14.02, 1.18-2.75, and 9.11-13%, respectively. Since they may be grown in infertile and unproductive settings, these non-consumable seeds are cost-effective for renewable energy. They also help solve the energy situation by boosting biodiesel production..