Carbon Network Research Articles

Synergistically enhanced photocatalytic properties of Co3O4-G/GO nanocomposites: unravelling their interactions and charge-transfer dynamics using XAS.

Metal oxide composites with graphene/graphene oxide have increasingly gained popularity in enhancing the photocatalytic degradation of several existing harmful dyes. Moreover, identifying the role of carbon networks and their interactions in composite formation would assist in the design and development of photocatalysts. In the present study, we investigated the role of carbon networks in improving photocatalytic properties. Electronic structure analysis of cobalt oxide-graphene (C2)/graphene oxide (C3) nanocomposites using XAS suggested possible charge transfer from cobalt oxide nanoparticles to the carbon network during composite formation. The photocatalytic degradation of C3 towards phenol dye (1×10-3M) was >50% and improved the degradation rate with k = 0.231 h-1.In the quest to understand the mechanism unfolding on its surface, in situ XAS under UV-visible irradiation was performed, which shed light on delayed excitonic recombination in the synthesized nanocomposites. This enabled hydroxy radicals (˙OH) to play a preeminent role in the cleavage of the phenol ring and its intermediaries. Based on these observations, a detailed mechanism for charge transfer occurring during nanocomposite formation and the mechanism involved in the enhanced photocatalytic activity of the nanocomposite photocatalyst towards phenol degradation under the influence of UV-visible irradiation are discussed.

Self-Supporting Hierarchical Carbon Network Loaded with NiW Nanoparticles for Efficient Hydrogen Evolution.

Water splitting technology can convert renewable energies such as solar and wind into hydrogen energy, which is key to achieving a low-carbon hydrogen economy cycle. However, Pt-based catalysts for hydrogen evolution reaction (HER) are too expensive, thus it needs to develop efficient non-noble metal catalysts as alternatives. Herein, Ni-BDC-loaded carbon cloth (CC) is co-pyrolyzed with urea to obtain a composite structure of carbon nanotubes (CNT) and porous carbon (PC) embedded with W-doped Ni nanoparticles on CC, resulting in NiW-CNT/PC/CC. Benefiting from the synergistic effect between Ni and W, the high conductivity of CNT, and the high mass transfer rate of PC, NiW-CNT/PC/CC exhibits excellent HER activity in KOH, which only requires a low overpotential of 45mV to drive a current density of 10mAcm-2 with stability exceeding 40 h. Simulation calculations confirm that the W doping in metal Ni can optimize its electronic structure by lowering the d-band center and weakening hydrogen adsorption, thus reducing its HER barrier.

Mixed Eucalyptus plantations enhance soil organic carbon accumulation and chemical stability through soil microbial community and multifunctionality

Forest conversion can impact soil organic carbon (SOC) fixation and ecosystem functions. The newly proposed “evenness of SOC chemical components” index can indicate the permanence of stored SOC during environmental disturbances. However, how the mixing of tree species impacts SOC accumulation and persistence and changes in soil microbial communities and multifunctionality remain unknown. Thus, we conducted a field experiment (11 years) of monospecific Eucalyptus urophylla × E. grandis plantation for evaluating the influences of the mixed planting of a non-nitrogen (N)-fixing tree, Castanopsis hystrix, and an N-fixing tree, Dalbergia odorifera, on SOC accumulation and chemical stability. Compared with pure plantations, mixed Eucalyptus plantations (particularly those mixed with D. odorifera) exhibited significantly increased SOC concentrations by 28.60–33.71 % and increased SOC chemical component evenness by 3.96–4.67 % (P < 0.05). We also found that the concentrations and chemical component evenness of SOC were strongly linked with litter quality, soil N, phosphorus and their availability, multifunctionality, microbial activity, carbon use efficiency (CUE), biomass, diversity, and network complexity. Furthermore, tree species mixing increased litter quality, soil nutrient availability, microbial biomass, activity, diversity, CUE, and network complexity. Soil microbial anabolism, community characteristics and multifunctionality influenced the SOC concentrations and SOC chemical components evenness. Specifically, microbial diversity enhanced the concentrations and chemical component evenness of SOC by increasing network complexity and soil multifunctionality. These findings revealed differential responses and mechanistic controls of SOC accumulation and chemical stability in different Eucalyptus planting patterns. Overall, mixed plantations, particularly those in which N-fixing species were introduced, effectively improved SOC accumulation and stabilization by positively altering soil quality and microbial properties, potentially representing a sustainable forestry management strategy to improve soil C benefits and multifunctionality in forest ecosystems.

Exploring New Carbon Allotropes and Nanographenes on Surfaces

The quest for planar sp2-hybridized carbon allotropes other than graphene has stimulated substantial research efforts because of their predicted unique mechanical, electronic, and transport properties. However, the syntheses of these nonbenzenoid networks remain challenging due to the lack of reliable protocols for generating nonhexagonal rings. We have developed various on-surface synthesis strategies by which straight polymer chains are linked to form the nonbenzenoid carbon networks. In this way, we synthesized biphenylene network, a new carbon allotrope with 4-6-8-membered rings, which is metallic already at very small dimensions. Similarly, we generated phagraphene nanoribbons, which are based on 5-6-7-membered rings.Acenes are another interesting class of carbon materials that have fascinated chemists and physicists due to their potential for use in organic electronic applications. We show the synthesis of tridecacene (13ac) and pentadecacene (15ac), the longest acenes known to date, via multistep single-molecule manipulation of suitable precursor molecules on Au(111). We find antiferromagnetic open-shell ground state electron configurations for both acenes. 15ac shows a low-bias spin-excitation feature, indicating a singlet-triplet gap of around 124 meV. Investigation of 15ac complexes with up to 6 gold atoms suggest considerable multiradical contributions to the electronic ground state of 15ac.Altering the electronic and magnetic properties of carbon-based nanomaterials can also be achieved by doping with heteroatoms. We present an access to a variety of nitrogen-containing 0D and 1D carbon nanostructures including planar and curved cycloarenes with different cavities as well as N-doped graphene nanoribbons.

(Invited) Controlled Charged Management in SWNTs

Gaining control of the doping level of SWNTs at the single particle level opens up new possibilities for their applications. Electrochemical gating allows fine tuning of the desired position of the Fermi level but can be implemented on ensembles of tubes. Filling the tubes with charge-transfer molecules, on the other side, allows doping at the single nanotube level but lacks fine control over the amount of charges transferred. Here we report our approach based on covalently attached ad-hoc synthesized charge-transfer compounds. This approach does not perturb the pi-conjugation of the carbon network, preserving their optoelectronic properties. By controlling the number of groups attached onto the SWNTs, we can set the amount of charges transferred into them, spanning from p-doping to n-doping in a straightforward way.

Fabrication of Micro‐Mesopores on Spiral Carbon Nanocoils and Simultaneous Doping with Oxygen to Expand Microwave Absorption Bandwidth

AbstractThe exceptional benefits of structural defects and doped atoms in carbon network regarding electromagnetic properties inspire the design of advanced carbon‐based microwave absorption (MA) materials. However, excessive structural defects decline the physical properties of materials, especially their conductivity. Therefore, it is a great challenge to balance structural defects and doped atoms to optimize conductive behavior for carbon‐based MA materials. The spiral carbon nanocoil (CNC), with coexisting amorphous and polycrystalline carbon structures and moderate conductivity, has significant MA properties but lacks pores and doped atoms. Herein, the amorphous carbon parts with relatively weak C─C bond energies are preferentially oxidized at 500 °C in air atmosphere to create pores and combine O atoms in the bodies of CNCs. Furthermore, the mechanism prioritizing the formation of O doping over defects is discovered. Benefiting from the synergistic interplay of structural defects and O dopants, the O‐enriched porous CNCs demonstrate enhanced conduction and polarization losses than the pure CNCs, realizing a wide effective absorption bandwidth of 7.3 GHz at a filling ratio of only 3 wt.%. Theoretical calculations further support these experimental results. The combination of structural defects and doped atoms may serve as an effective pathway for unlocking tunable dielectric properties of carbon‐based materials.

High-throughput arousing interconnected interfaces for excellent sodium storage chemistry

Heterostructures endow electrochemical hybrids with promising energy storage properties owing to synergistic effects and interfacial interaction. However, developing a facile but effective approach to maximize interface effects is crucial but challenging. Herein, a bimetallic sulfide/carbon heterostructure is realized in a confined carbon network via a high-throughput template-assisted strategy to induce highly active and stable electrode architecture. The designed heterostructures not only yield abundant interconnected Co9S8/MoS2/N-doped carbon (Co9S8/MoS2/NC) heterojunctions with continuous channels for ion/electron transfer but maintain excellent conversion reversibility. Serving as anode for sodium storage, the Co9S8/MoS2/NC framework displayed excellent sodium storage properties (reversible capacity of 480 mAh/g after 100 cycles at 0.2 A/g and 286.2 mAh/g after 500 cycles at 2 A/g). Given this, this study can guide future design protocols for interface engineering by forming dynamic channels of conversion reaction kinetics for potential applications in high-performance electrodes.

Polyvinylpyrrolidone-assisted sol–gel synthesis of efficient Li2TiSiO5/C composite anodes for Li-Ion batteries

This study presents the process of developing an effective anode material for lithium-ion batteries (LIBs) by usage of Li2TiSiO5 coated with a thin layer of carbon (LTSO/C). The material was prepared through a sol–gel method, where varying amounts of polyvinylpyrrolidone (PVP) were used as a carbon source during the synthesis process. The physicochemical analysis of the LTSO/C samples indicates that as the amount of PVP used during sol–gel synthesis increases, the particle diameter of LTSO decreases. Furthermore, the analysis shows that a thin amorphous carbon layer is deposited on the LTSO surfaces, along with additional carbon networks between the LTSO particles. Based on the electrochemical analysis conducted to optimize the amount of PVP during synthesis, the resulting LTSO/C composite electrode synthesized with 1 g of PVP exhibits a specific capacity of 274.5 mAh·g−1 at 0.1C after 150 cycles, which is quite close to the theoretical capacity. In addition, this LTSO/C electrode demonstrates exceptional electrochemical performance when operated at high rates, surpassing a discharge capacity of 170 mAh g−1 up to 2C. Therefore, the LTSO/C is an excellent choice for high-performance anode material in LIBs.

Hierarchically decorated ZnO/CoOx nanoparticles on carbon fabric for high energy–density and flexible supercapacitors

Exploring the electrochemical performance of metal/metal oxide nanoparticle composites is vital for enhancing the charge storage capability of supercapacitors. Herein, electrodes coated with ZnO/CoOx are fabricated by soaking cotton fabric seeded with 2-methylimidiazole in an ethylene glycol–based solution containing Zn and Co salts. The use of cotton fabric can reduce textile industrial waste while achieving high capacitance and sustainable energy for wearable electronics. In addition, the three-dimensional network of conductive flexible carbon derived from cotton fabric facilitates rapid ion transport kinetics at interlayers. The concentrations of Zn and Co salts are varied to produce ZnO/CoOx samples and determine the optimal salt ratio for superior electrochemical performance. The optimal sample exhibits a capacitance of 1.95 F cm−2 at 5 mA cm−2 and an energy density of 725 μWh·cm−2 over a wide potential window of 1.6 V. The long-term stability test results of the symmetric cells indicate 94 % capacitance retention after 12,000 charge–discharge cycles, emphasizing the advantages of mixed metallic oxides with cellulose-derived carbon fabric for supercapacitor electrodes. This study offers valuable insights into the fabrication of high-performance, flexible, and binder-free supercapacitor electrodes as a scalable alternative for practical applications.

Synthesis of trimetallic oxide/nitrogen-doped carbon composite using ZIF-guided combustion pyrolysis for efficient bifunctional oxygen catalysis in zinc–air batteries

Multi-element catalysts coupled with heterogeneous atom-doped carbons have significant potential for bifunctional oxygen catalysis owing to multiple active sites and tunable electronic structures. However, their synthesis routes involve multi-step procedures, limiting efficient screening of optimal designs considering electrocatalytic performance. Herein, we present a single-step strategy for synthesizing Co/Ni/Fe trimetallic oxide (TO) catalysts within nitrogen-doped carbon (NC) networks via combustion pyrolysis of ZIF-67 metal–organic framework/NiO/Fe2O3 precursors. The ultrafast melting-recrystallization induced by a rapid heating-cooling duration (∼1.5 s) lead to uniformly mixing metal elements, enabling abundant oxygen vacancies/strong chemical bonds within the porous structure, and optimizing the energy barrier for bifunctional catalysis, while decreasing interfacial resistances. The optimized TO-NC catalyst exhibits excellent overpotential of 0.88 V, and provides outstanding power density (125 mW cm−2) and stability (>200h) to a liquid zinc–air battery, outperforming those with a Pt/C + Ir/C catalyst. This research establishes scalable yet tunable thermochemical fabrication of multi-element/carbon-based catalysts.

Ferrocene-Modified Polyacrylonitrile-Containing Block Copolymers as Preceramic Materials.

In the pursuit of fabricating functional ceramic nanostructures, the design of preceramic functional polymers has garnered significant interest. With their easily adaptable chemical composition, molecular structure, and processing versatility, these polymers hold immense potential in this field. Our study succeeded in focusing on synthesizing ferrocene-containing block copolymers (BCPs) based on polyacrylonitrile (PAN). The synthesis is accomplished via different poly(acrylonitrile-block-methacrylate)s via atom transfer radical polymerization (ATRP) and activators regenerated by electron transfer ATRP (ARGET ATRP) for the PAN macroinitiators. The molecular weights of the BCPs range from 44 to 82 kDa with dispersities between 1.19 and 1.5 as determined by SEC measurements. The volume fraction of the PMMA block ranges from 0.16 to 0.75 as determined by NMR. The post-modification of the BCPs using 3-ferrocenyl propylamine has led to the creation of redox-responsive preceramic polymers. The thermal stabilization of the polymer film has resulted in stabilized morphologies based on the oxidative PAN chemistry. The final pyrolysis of the sacrificial block segment and conversion of the metallopolymer has led to the formation of a porous carbon network with an iron oxide functionalized surface, investigated by scanning electron microscopy (SEM), energy dispersive X-ray mapping (EDX), and powder X-ray diffraction (PXRD). These findings could have significant implications in various applications, demonstrating the practical value of our research in convenient ceramic material design.

Analogous Chelation to Boost Utilization of Sb in Sb Nanoparticles and N-doped Carbon Composites for Enhancing Potassium Storage.

Antimony (Sb) is an attractive anode material for potassium-ion batteries (PIBs), but it suffers from aggregation during the charging-discharging process, thus causing embedded active sites and collapsed structure. The analogous chelation refers to the reaction in which the central nanoparticle is linked to the matrix through multiple coordination bonds to form a stable composite. This strategy can inhibit aggregation and maintain the nanosized structure of Sb, thus activating the utilization of Sb active sites and structural stability. Given the special position of nitrogen (N) in the periodic table of elements and the strong bond energy of Sb-N, the N element can serve as an intermediate to connect Sb nanoparticles and an intrinsic N-doped carbon network via strong Sb-N-C/Sb-N═C covalent bonds using analogous chelation. Herein, a hybrid material of Sb@CTF-NC is fabricated via analogous chelation. The Sb atoms exposed on the surface of Sb nanoparticles are used to chelate with the N-doped carbon for high-performance PIBs. The mechanism underwent ex situ characterizations. The calculation of density functional theory reveals that the increase of adsorption energy and reduction of the K+ diffusion barrier accelerate the electrochemical reaction kinetics.

NiCo2V2O8@NC Spheres with Mesoporous Yolk- Bilayer Hierarchical Structure for Enhanced Lithium Storage.

Metal vanadates as negative electrode materials for lithium-ion batteries have attracted widespread attention, attributed to their substantial capacity, broad availability, and exceptional safety. In this study, NiCo2V2O8@NC microspheres featuring a yolk-double shell structure were successfully synthesized via ion exchange reactions and surface deposition techniques, employing metal glycerolate as a template. Owing to the bimetallic cobalt-nickel synergistic effect and the N-doped carbon network, this configuration not only optimizes the pore structure but also enhances conductivity, thereby augmenting the stability of the overall structure. The unique yolk-double shell design significantly enhances the utilization of active components and reduces the ion transport distance, thereby achieving high capacity. Thanks to the synergistic effects of this bimetallic and intricate structure, the material demonstrates exceptional capacity and cycle stability in lithium storage. The initial discharge capacity possesses 1522 mAh g-1 at a current density of 0.2 A g-1, with the reversible capacity still maintained at 1197 mAh g-1 after 100 cycles. In addition, at a high current density of 0.5 A g-1, the initial discharge capacity is 1487 mAh g-1, with a reversible capacity of 747 mAh g-1 maintained after 500 cycles. This study offers a perspective and methodology for the design and fabrication of complex porous double shell nanostructures.

Water at the nanoscale: From filling or dewetting hydrophobic pores and carbon nanotubes to "sliding" on graphene.

In this work, we study the effect of nanoconfinement on the hydration properties of model hydrophobic pores and carbon nanotubes, determining their wetting propensity and the conditions for geometrically induced dehydration. By employing a recently introduced water structural index, we aim at two main goals: (1) to accurately quantify the local hydrophobicity and predict the drying transitions in such systems, and (2) to provide a molecular rationalization of the wetting process. In this sense, we will further discuss the number and strength of the interactions required by the water molecules to promote wetting. In the case of graphene-like surfaces, an explanation for their unexpectedly significant hydrophilicity will also be provided. On the one hand, the structural index will show that the net attraction to the dense carbon network that a water molecule experiences through several simultaneous weak interactions is sufficient to give rise to hydrophilic behavior. On the other hand, we will show that an additional effect is also at play: the hydrating water molecule is retained on the surface by a smooth exchange of such simultaneous weak interactions, as if "sliding" on graphene.

P-band regulation guides the free-standing porous carbon electrode for efficient Na-CO2 batteries

The Na-CO2 batteries with low-cost resources and high energy density have attracted huge attention in Mars and deep ocean exploration, but the slow CO2 reduction reaction (CO2RR) and CO2 evolution reaction (CO2ER) kinetics severely limit their practical application. Developing free-standing cathodes and understanding the relationship between the catalyst's active center and activity are essential to address long-standing challenges. This manuscript explores the promising metal-free porous carbon as a catalyst. The porous carbon network vertically grows on the surface of free-standing carbon paper to maximum exposure to the active site and optimization of electron/electrolyte transfer. Moreover, the active center of the carbon catalyst is optimized by introducing nitrogen or sulfur hetero-atom to regulate the p-band center, which steers the orbital hybridization and accelerates CO2RR and CO2ER kinetics The p-band optimized free-standing porous carbon electrode shows outstanding cycling of 1000 h with a small voltage gap of 1.04 V and a large energy efficiency of 71.2 % at 10 uA cm−2. This study provides a new strategy for designing and fabricating p-band guided free-standing electrodes aiming at high-performance and wearable Na-CO2 batteries.

Fe3O4 Nanoparticles Embedded into Pyridinic-N-Rich Carbon Nanohoneycomb with Strong dx2-Pz Orbital Hybridization for High-Performance Electromagnetic Wave Absorption.

Carbon-based magnetic nanocomposites as promising lightweight electromagnetic wave (EMW) absorbents are expected to address critical issues caused by electromagnetic pollution. Herein, Fe3O4 nanoparticles embedded into a 3D N-rich porous carbon nanohoneycomb (Fe3O4@NC) were developed via the pyrolysis of an in-situ-polymerized compound of m-phenylenediamine initiated by FeCl2 in the presence of NaCl crystals as templates. Results demonstrate that Fe3O4@NC features highly dispersed Fe3O4 nanoparticles into an ultrahigh specific pyridinic-N doping carbon matrix, resulting in excellent impedance matching characteristics and electromagnetic wave absorbing capability with the biggest effective absorption bandwidth (EAB) of up to 7.1 GHz and the minimum reflective loss (RLmin) of up to -65.5 dB in the thin thickness of 2.5 and 2.3 mm, respectively, which also outperforms the majority of carbon-based absorbers reported. Meanwhile, its high absorption performance is further demonstrated by an ethylene propylene diene monomer wave absorbing patch filled with 8.0 wt % Fe3O4@NC, which can completely shield a 5G signal in a mobile phone. In addition, theory calculation reveals that there is a strongest dx2-Pz orbital hybridization interaction between Fe3O4 clusters and pyridinic-N dopants in the carbon network, compared with other kinds of N dopants, which can not only generate more dipoles of carbon networks but also increase net magnetic moments of Fe3O4, thereby leading to a coupling effect of efficient dielectric and magnetic losses. This work provides new insights into the precise design and synthesis of carbon-based magnetic composites with specific interface interactions and morphological effects for high-efficiency EMW absorption materials.

Taming the anchor and conversion of polyselenides with a self-reinforcing host in lithium–selenium batteries

Energy-dense lithium–selenium (Li–Se) batteries have attracted increasing attention, while their practical application is still hindered, highly relating to the volume expansion and shuttle of Li polyselenides (LiPSes). Herein, a concurrent anchoring/converting strategy is proposed to restrain the dissolution and realize the rapid conversion of LiPSes. A prototypical regulator comprises of polar catalysts embedded in the interconnected porous muti-walled carbon network (i.e., CoSnO3 nanocubes/CNTs), which promises fast electron/ion transportation and inhibits volumetric effect. Moreover, CoSnO3 as redox accelerator enables the stretched Se−Se bonds to decrease the LiPSes bidirectional conversion barrier, achieving accelerated reaction kinetics. Consequently, the self-reinforcing optimized cathode exhibits superior initial capacity of 730 mAh/g, greatly enlarged capacity after 200 cycles (increase by ∼ 32 % than that of the cell with CNTs), and superior rate capacity (153 mAh/g at 2C). This work uncovers the roles of electronic/ionic conductivity and adsorption/catalysis in Li–Se batteries, providing a guidance for taming the utilization and kinetics of cathode from material perspectives.

Atomically dispersed Co/Mn immobilized on O, N dual doped hollow carbon spheres as sulfur host for lithium sulfur batteries

The regulation of the chemical coordination environment in the electrocatalyst can effectively suppress the shuttle effect of sulfur species in lithium-sulfur batteries. However, the mechanism of the atomically dispersed dual metal atom with the coordination of various heteroatoms used as the sulfur cathode catalyst and trapper remains unknown. This study introduces, for the first time, atomically dispersed Co and Mn in-situ immobilized on O, N dual-doped hollow carbon spheres (SACoMn/C-(N, O)) as sulfur host. Experiments combined with density functional theory calculations reveal that the synergy between Co-(N, O) and Mn-(N, O) sites enhances the nucleation/deposition and decomposition capabilities of Li2S. This enhancement is attributed to the anchoring-coupling-conversion behavior of sulfur species on the SACoMn/C-(N, O) surface, which effectively restrains the shuttle effect and facilitates the conversion kinetics. Moreover, the cooperation of dual metal atoms with O, N non-metal atoms embedded in the carbon network structure accelerates electric transport and ion diffusion kinetics. The cathode demonstrates a high initial specific capacity of 890 mAh·g−1 at 1 C and show exceptional long-term cycling durability, with a low capacity degradation of 0.037 % per cycle after 1700 cycles. This research may offer novel insights into the design of dual metal atom-decorated, functionalized carbon materials to improve the conversion reaction in sulfur cathodes.

Molecular Descriptors Of Certain Class Of Carbon Nanocone Networks Through Quotient Graph Approach

Nanoparticles have potential applications in a wide range of fields, including electronics, medicine and material research, because of their remarkable and exceptional attributes. Carbon nanocones are planar carbon networks with mostly hexagonal faces and a few non-hexagonal faces (mostly pentagons) in the core. Two types of nanocone configurations are possible: symmetric and asymmetric, depending on where the pentagons are positioned within the structure. In addition to being a good substitute for carbon nanotubes, carbon nanocones have made an identity for themselves in a number of fields, including biosensing, electrochemical sensing, biofuel cells, supercapacitors, gas storage devices, and biomedical applications. Their astonishing chemical and physical attributes have made them well-known and widely accepted in the fields of condensed matter physics, chemistry, material science, and nanotechnology. Mathematical and chemical breakthroughs were made possible by the concept of modeling a chemical structure as a chemical graph and quantitatively analyzing the related graph using molecular descriptors. Molecular descriptors are useful in many areas of chemistry, biology, computer science, and other sciences because they allow for the analysis of chemical structures without the need for experiments. In this work, the quotient graph approach is used to establish the distance based descriptors of symmetrically configured two-pentagonal and three-pentagonal carbon nanocones.

Achieving High-Performance Na3V2(PO4)2F3 Cathode Material through a Bifunctional N-Doped Carbon Network.

Na3V2(PO4)2F3 (NVPF) is emerging as a popular cathode for sodium-ion batteries owing to its stable structure, high operating voltage, and large energy density. However, its practical application is hindered by its low conductivity. In addition, due to the loss of fluorine during synthesis, Na3V2(PO4)3 (NVP) impurity is often easily generated, resulting in a decrease in actual operating voltage. Herein, a bifunctional carbon network composed of an N-doped carbon layer and carbon bridge is constructed around NVPF particles. Through pyrolysis of polydopamine (PDA), the NVPF particles are covered in situ by an N-doped carbon layer, and the carbon bridge generated by polytetrafluoroethylene (PTFE) is also coated with N-doped carbon. Besides, PTFE also serves as a fluorine supplement to ensure that pure NVPF is obtained. As a result, the bifunctional N-doped carbon network-modified NVPF delivers a high reversible capacity (125.7 mA h g-1 at 0.2 C) and appreciable cycle stability (92.7% at 1 C over 300 cycles, and 89.8% at 10 C over 1500 cycles). When assembled into a full cell with a commercial hard carbon anode, it displays a discharge median voltage of up to 3.62 V at 0.2 C. Furthermore, it achieves a high energy density of 373.7 W h kg-1 at a power density of 461.2 W kg-1, with an excellent specific energy retention of 78.2% after 200 cycles. Therefore, this modification method is expected to be extended to other fluorine-containing materials with poor electrical conductivity.