Marine Carbonate Sediments Research Articles

The Albian – Cenomanian boundary on the southern Tethyan margin: Abu Gharadig Basin, Northern Western Desert, Egypt

Lithostratigraphy and biostratigraphy sometimes provide contradictory interpretations, especially when trying to establish a chrono-lithological boundary between two reservoir formations from different paleoenvironments. One of these contradictions is the definition of the boundary between the Kharita and Bahariya formations and the Albian and Cenomanian Stages in the Abu Gharadig Basin of the Western Desert, Egypt. an integrated approach has been applied to this problem using borehole image logs, palynology, and conventional wireline logs. authors also calibrate the stratigraphic sections with global chronostratigraphic charts, using nannoplankton, planktonic foraminifera, and dinoflagellates to construct a better understanding of this basin. The abundances of pollen, spores, and dinoflagellates in the interpreted reservoir intervals suggest that hydrocarbons trapped in the Albian-Cenomanian reservoirs are composed of type II/III kerogen. The interpreted intervals are subdivided into seven depositional cycles: one in the Kharita Formation, five in the Bahariya Formation, and one in the Abu Roash Formation. The interpreted environments are, from bottom to top: I) fluvio-deltaic distributary channels, II) and III) intertidal to subtidal deposits, IV) offshore bar deposits, V) intertidal to subtidal deposits, VI) shoreface deposits, and VII) shallow marine carbonate deposits. Diagnostic palynomorphs reflect climatic change from arid to humid conditions and also enable changes in salinity to be determined.Much of the published work in the southern Tethyan margin, particularly in the Western Desert, is either related to stratigraphy, palynology, or reservoir evaluation with a focus on a narrow field. Tectonostratigraphic studies and analyses of petroleum system elements have often been very regional in nature. The work presented here is of an intermediate scale linking regional frameworks with local details to provide comprehensive information about the Albian-Cenomanian succession in the Northern Western Desert. The focus has been the Abu Gharadig basin but this integrated approach has implications for other basins in North Africa. A specific example is the similarity of Western Desert and Libyan Sirt basin Albian-Cenomanian key palynomorphs which would facilitate a similar integrated chrono-lithologic intepretation.

Threshold of motion of coral reef sediment under currents in flume experiments

AbstractThis study experimentally documented the thresholds of critical motion for tropical shallow marine carbonate sediments by conducting a total of 225 laboratory experiments that included the analysis of nine median sediment diameters and five water depths. A shape factor, Sf, which quantifies the shape of a single particle, was evaluated during the investigation. Both the critical Shields parameter and the incipient mean velocity were used to represent the critical thresholds of motion. The thresholds of motion for coral reef sediment were then compared with the results from quartz sand. The experimental results show that the critical threshold of motion is smaller for coral reef sediment than for quartz sand of the same median sieve diameter due to differences in particle shape in spite of the coral reef sediment being of higher density. For diameters higher than 1.425 mm, the critical Shields parameters and incipient mean velocities tend to have similar values to quartz sand. The differences between the two increased significantly for median sieve diameters <1.075 mm. Based on the experimental data, Shields curve bands and equations for the incipient mean velocity for sediments of differing shape factors were obtained for tropical shallow marine carbonate sediments as well as marine carbonate grains.

Syndepositional Uptake of Uranium, Molybdenum and Vanadium into Modern Bahamian Carbonate Sediments during Early Diagenesis

Syndepositional diagenesis is a complicating factor when interpreting geochemical proxies in carbonate sedimentary environments. Previous studies have suggested that carbonate deposits may preserve the geochemical and isotopic signatures of seawater that can be used for paleo-redox reconstructions. However, more work is necessary to understand how these trace metals are preserved. The present study examines shallow marine carbonate sediments from the Bahamas to better understand diagenetic effects on trace metal uptake and sequestration. Analysis of diagenetic effects and trace metal uptake follows a multi-method approach, combining sequential extraction, stable isotope analyses, and rare earth elemental analysis. Stable isotopes track bacterial sulfate reduction, denitrification, and organic matter source and provide insight into thresholds and processes for the authigenic trace metal uptake. Importantly, exchangeable phases exhibit authigenic accumulation of molybdenum, uranium and vanadium, and intensified bacterial sulfate reduction is evidenced by most depleted sulfur isotope signatures. In addition, rare earth element values are very indicative proxies that suggest altered primary seawater trace element in carbonates (no cerium or lanthanum anomaly, moderate heavy rare earth element enrichment, decreased y/ho ratios and positive correlations between aluminum, manganese, and iron). Taken together, these results allow the development of a framework to better understand how to apply sedimentary geochemistry of carbonate rocks to paleo-environments as this study shows significant authigenic accumulation of redox-sensitive trace metals by exchangeable phases.

Influence of polyborate ions on the fractionation of B isotopes during calcite deposition

Boron (B) isotopes are widely used in studies of water–rock interaction and earth surface processes. The δ11B is a potentially attractive proxy of seawater pH, as the relative abundance of the two primary aqueous B species in seawater (boric acid, H3BO3 and borate, B(OH4)−) is strongly pH-dependent. In the process of marine carbonate deposition, the fractionation of the B isotope is controlled by the proportion of H3BO3 and B(OH4)− in seawater. In addition to H3BO3 and B(OH4)−, there are polyborates (e.g., B3O3(OH)4−, B4O5(OH)42−, and B5O6(OH)4−) in salt-lake brine, and their impacts on B isotope fractionation are still unclear. Notable, significant differences are observed in the degrees of fractionation of B isotope during the deposition of carbonates in marine and salt-lake; nonetheless, studies on the internal reasons for this significant difference between the marine and salt-lake environments are scarce, limiting the application of B isotope in salt lakes. In this study, a series of calcite sedimentary experiments in mother liquor with different BO compounds was conducted at a constant pH of 8.20 (±0.05). The results indicate the incorporation of H3BO3 through polyborates into calcite during the precipitation of calcite, thus reducing the B isotope fractionation degree between the mother liquor and calcite. This study provides an experimental basis for explaining the differences in B isotope fractionation between marine and terrestrial environments and the inversion of paleo-salinity using the B isotope of sedimentary carbonate.

Temporal variation of mineralization rates and its influence on carbon storage over the last 50 years in Bohai Bay, China

Recorded information on marine sediments is affected by mineralization. In this study, we collected sediment samples from Bohai Bay, where human interference is typically high. Overall, the CO2 fluxes in the columnar sediments decreased with increasing depth. The change in constants revealed a “C-curve” in which the mineralization rate first decreased significantly (i.e., from the 2020s to the 1980s) and subsequently increased slowly (i.e., from the 1980s to 1965). This may be explained by the fact that sediments from the 1980s–2020s were markedly influenced by the sedimentation rate, whereas sediments from the 1960s–1980s were predominantly influenced by microbial action. The loss of organic carbon due to mineralization accounted for approximately 15–20 % of the initial total organic carbon; therefore, when performing an inversion of the historical environment change using information derived from organic carbon in marine sediments, the influence of mineralization on this information should be fully considered.

A 13 million-year record of Li isotope compositions in island carbonates: Constraints on bulk inorganic carbonate as a global seawater Li isotope archive

Lithium isotope (δ7Li) variations in marine carbonate sediments and rocks have been widely used to reconstruct global seawater Li isotope compositions and then trace the paleo-weathering processes. However, there are still debates on whether ancient carbonates can faithfully document original seawater δ7Li signals, as δ7Li values of shallow-water carbonates are tightly related to carbonate mineralogy and diagenetic alteration. In this study, we present high-resolution δ7Li, trace element and carbonate mineralogy data of shallow-water carbonate deposits from two shallow drillcores (Jiuzhang A and B) and a deep drillcore (XK-1) in the South China Sea. We compare these new δ7Li data to the ca. 13 Myr history of seawater δ7Li evolution from the middle Miocene to Pleistocene, in order to better constrain the effects of carbonate mineralogy and early diagenesis on δ7Li values of bulk inorganic carbonates. We observe that the δ7Li values of primary carbonate deposits in Jiuzhang A, B and the uppermost XK-1 drillcores (24.6% ± 1.6%, n = 37, 1σ) are significantly lower than modern seawater δ7Li values (Δ7Liprimary-seawater = ∼–6.0%). In contrast, marine diagenetic carbonates in the XK-1 drillcore exhibit δ7Li values of 28.7% ± 0.7% (n = 54, 1σ), approaching coeval seawater values (Δ7Limarine diagenetic-seawater = ∼–2.0%) and much higher than those of primary carbonate deposits. Meteoric diagenetic carbonates in the XK-1 drillcore show δ7Li values of 22.4% ± 1.6% (n = 46, 1σ), close to that of primary carbonate deposits in Jiuzhang A, B and the uppermost XK-1 drillcores, but significantly lower than coeval seawater δ7Li values (Δ7Limeteoric diagenetic-seawater = –5.0% to –9‰ for modern and Miocene seawater). Such δ7Li variations in shallow-water carbonates are attributed to variations in carbonate mineralogy (i.e., aragonite, high-Mg calcite and low-Mg calcite) and diagenetic regimes (fluid- or sediment-buffered conditions of marine and meteoric diagenesis). By comparing δ7Li data from the South China Sea to those from the Bahamas, we suggest strongly fluid-buffered conditions for Li isotopes during marine diagenesis, resulting in δ7Li values of marine limestones and dolostones approaching ambient seawater δ7Li signals. In contrast, meteoric diagenetic carbonates, likely marked by sediment-buffered conditions, may inherit the original δ7Li signals of primary carbonate deposits. Hence, full considerations of the carbonate mineralogy and diagenesis facilitate a better use of bulk inorganic carbonate-archived δ7Li to reconstruct paleo-weathering evolution in deep time lacking the skeletal fossil records.

Mid-Norian to Hettangian record and time-specific oolites during the end-Triassic Mass Extinction at Wadi Milaha, Musandam Peninsula, United Arab Emirates

The end-Triassic Mass Extinction (ETME) is generally regarded as a consequence of the environmental changes associated with the emplacement of the Central Atlantic Magmatic Province (CAMP) and ranks among the ‘big five’ mass extinctions in Earth history. A notable feature of the ETME is a halt in marine carbonate deposition followed by the formation of unusual facies such as carbonate cement fans and oolites in the early aftermath of the event. The ETME time interval has been well studied over the last few decades, in contrast to a few minor extinction events that preceded it, among them the extinctions associated with the Norian-Rhaetian boundary (NRB). This study provides new insights into these extinction events with complete mid-Norian to Hettangian δ18Ocarb and δ13Ccarb record from a key section at Wadi Milaha (Ras Al Khaimah Emirate, United Arab Emirates). Ooids are important proxies for palaeoenvironmental reconstruction. The post ETME oolite horizon is documented providing morphological classification as well as a detailed modal analysis of rock components and different types of coated grains. Through a multi-technique approach, we argue for the stability of the carbon cycle across the NRB extinction event and the existence of a hiatus at the TJB (Triassic-Jurassic Boundary) in Wadi Milaha. Our new morphological classification of post-extinction ooids is compatible with a major role for seawater geochemistry with respect to sedimentological processes, by example in the peculiar way ooids diversify and alternate with other kinds of coated grains.

Marine carbonate mining in the Southwestern Atlantic: current status, potential impacts, and conservation actions

Marine carbonate sediments have economic value because of their high concentration of calcium minerals and important trace elements. However, increasing mining interest in these stocks is threatening unique ecosystems, such as rhodolith beds, which provide many ecosystem goods and services. We review the potential of the unexplored Brazilian deposits and the rising conflicts with other blue economic sectors and biodiversity hotspots. The tropical Southwestern Atlantic Ocean, particularly the Brazilian Exclusive Economic Zone, has the largest deposit of marine limestone worldwide, which is very attractive to the global industry, with reserves measured at more than 1355,157,240 tons of CaCO3 and it is especially useful as a supply for agriculture and animal nutrition. This large mining potential raises concerns regarding licenses and potential impacts, especially considering the biological and socio-economic importance of extensive rhodolith beds, which may conflict with mining. Additionally, future dredging activities will take place in vulnerable ecosystems without adequate marine spatial planning (MSP). Currently, there is no long-term scientific information on the available carbonate stocks, stock recoverability, risks to connectivity with other ecosystems (e.g., coral reefs), and the reduced provision of ecosystem services which may affect activities such as artisanal fisheries. In this context, encouraging carbonate mining without science-based information and MSP accelerates the unsustainable exploitation of this important ecosystem. This activity will contribute to the degradation of tropical marine biodiversity and threaten the food security of traditional and vulnerable human communities, which is in opposition to the Sustainable Development Goals and reaching the 2030 United Nations Agenda.

The possible actiniarian sea anemone burrow Bergaueria hemispherica from the Pliensbachian (Lower Jurassic) of the Lusitanian Basin (Central Portugal)

Abstract The shallow marine carbonate deposits of the S. Miguel Formation in the Lusitanian Basin reveal erosional events exposing stiff substrates with abundant Bergaueria hemispherica . The ichnoassociation represented by B. hemispherica , Thalassinoides suevicus , Spongeliomorpha isp., Asterosoma ludwigae and Rhizocorallium commune is dated from lowermost Pliensbachian by the association with ammonites from the jamesoni Biozone, brevispina Subzone. The unlined forms of B. hemispherica include peripheral and bottom burrow concentrations of shell debris, annular-like structures in the burrow margin and paired burrows-to-linear clusters that are comparable with the penetrative burrowing mechanism, anchoring and feeding behaviours of sea anemones. From the ethological point of view, and comparing with modern behaviours of burrowing anemones, the B. hemispherica from the Lusitanian Basin may represent temporary burrowing and relocation of actiniarian anemones. Their comparison with either thenarian or athenarian actiniarians may evidence a preferred surficial feeding strategy on the organic-rich muddy sediments they burrowed.

Transfer efficiency of organic carbon in marine sediments

Quantifying the organic carbon (OC) sink in marine sediments is crucial for assessing how the marine carbon cycle regulates Earth’s climate. However, burial efficiency (BE) – the commonly-used metric reporting the percentage of OC deposited on the seafloor that becomes buried (beyond an arbitrary and often unspecified reference depth) – is loosely defined, misleading, and inconsistent. Here, we use a global diagenetic model to highlight orders-of-magnitude differences in sediment ages at fixed sub-seafloor depths (and vice-versa), and vastly different BE’s depending on sediment depth or age horizons used to calculate BE. We propose using transfer efficiencies (Teff’s) for quantifying sediment OC burial: Teff is numerically equivalent to BE but requires precise specification of spatial or temporal references, and emphasizes that OC degradation continues beyond these horizons. Ultimately, quantifying OC burial with precise sediment-depth and sediment-age-resolved metrics will enable a more consistent and transferable assessment of OC fluxes through the Earth system.

Reconstructing the lithium isotopic composition (δ7Li) of seawater from shallow marine carbonate sediments

Records of the lithium isotopic composition of seawater (δ7Lisw), preserved in the lithium isotopic composition of shallow-marine carbonate sediments (δ7Licarb), provide information about the links between silicate weathering and clay formation, the global carbon cycle, and Earth’s climate on geologic timescales. However, the record of δ7Lisw values in shallow marine carbonates is complicated by the effects of mineralogy (e.g., calcite vs aragonite) and diagenesis. Here we present measurements of bulk carbonate δ7Li values paired with a suite of stable isotope systems (δ44/40Ca, δ26Mg) and element abundance ratios (Li/(Ca + Mg), Sr/(Ca + Mg), Mg/(Ca + Mg)) in Neogene shallow-marine carbonates from sites in the Bahamas and southwest Australia. The studied sites span a range of depositional and diagenetic settings and exhibit large stratigraphic trends in δ7Li values that correlate with mineralogy, δ44/40Ca values, and/or element abundances. These trends differ from coeval planktonic foraminifera records of δ7Lisw and instead predominantly reflect local processes. We show, using a suite of geochemical analyses and a numerical model of early marine diagenesis, that the observed variability in bulk sediment δ7Li values can be quantitatively explained by the effects of mineralogy and diagenetic alteration under both fluid-buffered and sediment-buffered conditions. Using this framework, we show that it is possible to produce robust and accurate ‘snapshots’ of the δ7Li value of seawater in the geologic past from shallow-water marine carbonate sediments.

Evaluation of shallow-water corals and associated carbonate sediments as seawater Ba isotope archives in the South China Sea

Barium isotopes (δ138Ba) obtained in carbonates have a great potential for reconstructing past changes in marine productivity and associated biogeochemical cycling. Although coral skeletons and inorganic carbonates have been used as archives for seawater Ba isotopes, few studies have investigated other confounding factors that influence Ba isotope fractionation (e.g., vital effects and carbonate mineralogy), hindering their use as paleo-proxies. In this paper, we report Ba isotope data for multi-species corals, including paired sets of living and fossil coral skeletons in the inner shelf (Paipu Reef, Hainan Island) and the open-sea (Jiuzhang Reef corals) in the South China Sea (SCS). We also present Ba isotope datasets of bulk carbonate sediments from two shallow-water drill cores (A and B) in the Jiuzhang Reefs, SCS. The δ138Ba data for the Paipu Reef corals have a relatively narrow range of values (0.12‰ to 0.21‰, mean 0.17 ± 0.06‰; 2 SD, n = 8) regardless of living and fossil coral skeletons. The corals of Jiuzhang Reef show a relatively consistent δ138Ba value (0.30 ± 0.04‰; 2 SD, n = 4). The coral skeletal δ138Ba values show no significant differences across multiple species within the individual colony, which suggests that vital effects do not affect coral δ138Ba records. These findings, together with the fact that a relatively constant δ138Ba offset exists between coral skeletons and seawater, indicate that coral skeletons may be reliable archives for past seawater δ138Ba. All bulk carbonate sediment samples yield constant δ138Ba values of 0.38 ± 0.04‰ (2 SD, n = 30) with a fairly consistent deviation (Δ138Babulk_carb-sw = −0.21 ± 0.04‰) from the reported typical surface seawater of SCS. In addition, mass balance calculation suggests that Ba isotope fractionation between inorganic High-Mg calcite (HMC) and seawater is derived to be Δ138BaHMC-sw = −0.13 ± 0.12‰, exhibiting a difference less than Δ138Baaragonite-sw = −0.28 ± 0.04‰ in aragonite precipitation. Our findings suggest that shallow-water carbonates are reliable archives of past seawater δ138Ba when considering Ba isotope deviations during marine carbonate deposition.

Constraining marine anoxia under the extremely oxygenated Permian atmosphere using uranium isotopes in calcitic brachiopods and marine carbonates

The redox chemistry change in ancient oceans has profoundly shaped the evolutionary trajectories of animals. Uranium isotopes (δ238U) in marine carbonate sediments have widely been used to place quantitative constraints on the oxygenation state of the oceans through geological history. However, syndepositional and post-depositional diagenesis impose a positive and variable δ238U offset in the carbonate sediments relative to contemporaneous seawater, leaving uncertainties on quantification of anoxic seafloor areas in the past. Studies from modern settings suggest that Low-Magnesium Calcite (LMC) in articulate brachiopod shells are diagenetic resistant materials that may faithfully record the δ238U value of ancient seawater. However, this notation has not yet been validated in geological records. Here, we test this hypothesis by analyzing paired brachiopod shells and the host carbonate rocks from several Permian stratigraphic successions in South China. Forty-nine articulate brachiopod fossil shells and twenty-six host carbonate rocks from the Early Permian to the Late Permian were investigated. We performed a rigorous screening to monitor the diagenetic process that might have influenced the δ238U of the shells using a scanning electronic microscope, cathodoluminescent microscopy, and major and trace elements. We estimate that 53% of the shells preserve the primary seawater δ238U signals. Using the screened δ238U values of shells and bulk carbonates, we suggest there were four episodes of expanding marine anoxia during the Permian that are temporally coincident with periods of volcanism. The first two oceanic anoxic events occurred at a time when atmospheric pO2 levels were predicted to be higher than today. The last two events are temporally coincident or immediately preceding the end-Guadalupian and the end-Permian mass extinctions, respectively, confirming previous suggestions that marine anoxia was a critical factor in driving marine animal extinctions.

Coralline Algae at the Paleocene/Eocene Thermal Maximum in the Southern Pyrenees (N Spain)

During the Paleocene/Eocene Thermal Maximum, ~55.6 Ma, the Earth experienced the warmest event of the last 66 Ma due to a massive release of CO2. This event lasted for ~100 thousands of years with the consequent ocean acidification (estimated pH = 7.8-7.6). In this paper, we analyze the effects of this global environmental shift on coralline algal assemblages in the Campo and Serraduy sections, in the south-central Pyrenees (Huesca, N Spain), where the PETM is recorded within coastal-to-shallow marine carbonate and siliciclastic deposits. In both sections, coralline algae occur mostly as fragments, although rhodoliths and crusts coating other organisms are also frequent. Rhodoliths occur either dispersed or locally forming dense concentrations (rhodolith beds). Distichoplax biserialis and geniculate forms (mostly Jania nummulitica) of the order Corallinales dominated the algal assemblages followed by Sporolithales and Hapalidiales. Other representatives of Corallinales, namely Spongites, Lithoporella as well as Neogoniolithon, Karpathia, and Hydrolithon, are less abundant. Species composition does not change throughout the Paleocene/Eocene boundary but the relative abundance of coralline algae as components of the carbonate sediments underwent a reduction. They were abundant during the late Thanetian but became rare during the early Ypresian. This abundance decrease is due to a drastic change in the local paleoenvironmental conditions immediately after the boundary. A hardground at the top of the Thanetian carbonates was followed by continental sedimentation. After that, marine sedimentation resumed in shallow, very restricted lagoon and peritidal settings, where muddy carbonates rich in benthic foraminifera, e.g., milioliids (with abundant Alveolina) and soritids, and eventually stromatolites were deposited. These initial restricted conditions were unfavorable for coralline algae. Adverse conditions continued to the end of the study sections although coralline algae reappeared and were locally frequent in some beds, where they occurred associated with corals. In Serraduy, the marine reflooding was also accompanied by significant terrigenous supply, precluding algal development. Therefore, the observed changes in coralline algal assemblages during the PETM in the Pyrenees were most likely related to local paleoenvironmental shifts rather than to global oceanic or atmospheric alterations.

UNIQUE COLLECTIONS OF PALEONTOLOGICAL THIN SECTIONS FROM THE BORDERLINE MISSISSIPPIAN-PENNSYLVANIAN SEDIMENTS OF THE DONETS BASIN, STORED IN THE INSTITUTE OF GEOLOGICAL SCIENCES OF THE NATIONAL ACADEMY OF SCIENCES OF UKRAINE

The purpose of the article is to publicize and integrate into the world scientific space information about the unique collections of paleontological thin sections from the borderline Mississippian-Pennsylvanian of the Carboniferous of the Donets Basin, which were collected by outstanding Ukrainian paleontologists-stratigraphers D. E. Aizenverg, N. E. Brazhnikova, O. I. Berchenko, N. V. Vasylyuk during the second half of the 20th century and are currently stored in the Institute of Geological Sciences of the National Academy of Sciences of Ukraine. The collections originate from the stratotype and reference sections of the Zapaltyubinsky and Voznesensky Horizons of Donbas, established by D. E. Aizenverg and N. E. Brazhnikova in 1975, which make up the parastratotype section of the upper part of the Serpukhovian Stage. A brief description of the collections is provided, their scientific value and significance for conducting various types of micropaleontological and biostratigraphic research are highlighted. Micropaleontological studies and microfacies typification of marine carbonate sediments presented in thin sections were carried out, photodocumentation was done and an electronic catalog of collections of paleontological thin sections was created, containing information about the origin and place of preservation of thin sections, stratigraphic reference, a brief microfacies description of thin sections (with an indication of all detected organic remains), lists of discovered and identified foraminifera and algae, the e-mail address of the section, as well as a photo of the microfacies type of the limestone.

Sources and Cycling of Particulate Organic Matter in Baffin Bay: A Multi-Isotope δ13C, δ15N, and Δ14C Approach

The Canadian Arctic is warming three times faster than the rest of the planet. The impact of climate change on the Arctic carbon cycle, and in particular for Baffin Bay, remains poorly constrained. Sinking particulate organic matter (POMsink) is a key component of the biological carbon pump and provides a direct linkage between surface productivity and the preservation of carbon in marine sediments. While POMsink provides a rapid POM shunt to the deep ocean (days) the majority of marine POM is suspended (POMsusp) persists for years in the water column. Stable carbon (δ13C), nitrogen (δ15N) and radiocarbon (Δ14C) measurements are powerful tools for evaluating sources and cycling of POM. In this study, we measure depth-integrated (0-400m) POMsusp stable carbon (δ13C), nitrogen (δ15N) and radiocarbon (Δ14C) values at 11 stations in Baffin Bay. We use POM C:Na ratios to evaluate its diagenetic state. POMsusp δ13C and δ15N values ranged from −21.6‰ to −29.5‰, and +3.84‰ to +7.21‰, respectively. POMsusp Δ14C values ranged from −41.8‰ to +76.8‰. Together, our results suggest Baffin Bay POMsusp has multiple carbon and nitrogen sources. POMsusp δ13C and Δ14C are strongly correlated to surface salinity, indicating surface water has a strong influence on POMsusp isotopic composition and 14C-age. POMsusp from coastal Greenland stations have similar Δ14C values to surface dissolved inorganic carbon (DIC) and POM concentrations, consistent with primary production as the predominant POMsusp source in Eastern Baffin Bay. Positive POMsusp Δ14C values in central Baffin Bay suggest an accumulation of atmospheric “bomb” 14C in the sub-polar gyre. POMsusp exiting Davis Strait via the Baffin Island Current was determined to have a significant degraded, resuspended sediment component. Finally, POMsusp δ15N values highlight two distinct N sources in Baffin Bay: Pacific and Arctic nutrients at Northern gateway stations vs. the influx of Atlantic nutrients via Davis Strait along coastal Greenland. Overall, these first Baffin Bay POMsusp Δ14C values provide useful baseline data for rapidly changing Arctic ecosystem.

Stratigraphic variability of Upper Holocene marginal marine sediments along the Al Qahmah Coast of Red Sea, Saudi Arabia

The stratigraphic architecture of Upper Holocene sediments along the coast of Al Qahmah in southern Red Sea, Saudi Arabia, provides a high-resolution analog of marginal marine carbonate and siliciclastic sedimentation under variable climatic, tectonic, and sea-level conditions. The sediments include a basal shallow marine limestone and overlying beach, deltaic, fluvial, eolian, and sabkha siliciclastic deposits, comprising four stratigraphic units ranging from 10s to 100 s cm thick. A lithostratigraphy is established using subsurface stratigraphic and petrographic data from 64 trenches and three shallow refraction seismic sections. A chronostratigraphy is established using four age points and sedimentation rates. The entire interval has been deposited in the last ~4000 years. Significant stratigraphic variability is reflected by vertical and lateral changes in the thickness, type, and stratal geometry of the four units. Five major geological events are interpreted: Initial shallow marine carbonate deposition during a relative sea-level highstand was terminated by seaward progradation of deltaic-beach sediments during a slow shoreline regression. This is followed by a major stream channel incision during the maximum regression and a relative sea-level fall. The ensuing fluvial channel filling, transgressive ravinement, and deposition of beach sediments signify a relative sea-level rise. Finally, eolian, sabkha, and beach sediments have been deposited in a stabilized and diversified environmental setting under an arid climate. The lacuna associated with stream erosion and transgressive ravinement is up to ~400 years long, resulting in a stratigraphic completeness of ~88%. The sedimentation rate of the siliciclastic sediments is ~0.1 cm/year estimated at a scale of 1000s of years. Episodic syn-depositional faulting in the source area and depositional site, relative seal-level change, autogenic environmental shift, and/or climatic changes between humid and arid conditions have collectively played variable roles in the formation of the stratigraphic variability. The interpreted tectonic, relative sea-level, and climatic trends offer an important data point for future studies in the Red Sea region and beyond for the Late Holocene.

Differentiating the Causes of Aged Organic Carbon in Marine Sediments

AbstractAged organic carbon (OC) is widely observed in surficial sediments deposited on continental margins, resulting from several factors including old OC input and sedimentological processes. While the supply of old OC to marine sediments has been examined and quantified in a range of continent margin settings, there have been few attempts to constrain the extent to which hydrodynamic processes, specifically lateral transport, contribute to the old age of sedimentary OC. Here, we propose a mathematical index, bAgedOC, to differentiate the causes of sedimentary aged OC, and apply this approach to two typical sediment transport pathways that follow the supply and dispersal of terrestrial OC in the marine environment, and further extrapolate it to submarine canyon, Arctic and deep‐sea environments. The index, representing a modification of a widely used quantitative method, provides a novel approach to distinguish the contribution of lateral transport to the pre‐depositional aging of OC in the oceanic region.

INSIGHTS INTO THE ORIGIN OF SHALLOW MARINE DOLOSTONES, LONGWANGMIAO FORMATION (LOWER CAMBRIAN), NORTHEAST SICHUAN BASIN, CHINA: PETROGRAPHIC AND GEOCHEMICAL CONSTRAINTS

For a better understanding of the origin of Early Cambrian dolomites in the Sichuan Basin, which serve as valuable oil and gas reservoirs, we present and interpret complex multiparameter petrographic and geochemical analyses of dolomites in the Cambrian Longwangmiao Formation at the Yangsiqiao section. Our data show that these dolomites mainly occur in the middle and upper parts of the Longwangmiao Formation, and we identify two types of dolomites: micrite and fine-medium crystalline dolomites. The micritic dolomites, occasionally coupled with quartz and mica minerals, show dirty crystal surfaces, nonautogenous crystal shapes, and dark cathodoluminescence and mainly occur in pure micrite and granular dolostones, which retain the original sedimentary texture. Contrarily the fine-medium crystalline dolomites, mainly developed in crystalline and grain dolostones and generally coupled with residual calcites and altered sedimentary textures, have a dark heart-bright boundary texture under a polarized microscope and occasional zonal texture under cathode luminescence. Furthermore, the micritic dolomites have CaO and MgO contents approximately similar to those of the ideal stoichiometric dolomite, relatively high Sr concentration, Σ rare-earth element (REE) +Y concentrations, and δ13C and δ18O values located in the corresponding range of dolomite deposited from Early Cambrian marine water. However, light-REE enrichment (LREE), heavy-REE (HREE) depletion patterns, and high Al2O3 and SiO2 contents distinguish these micritic dolomites from typical marine carbonate deposits. Notably, the fine-medium crystalline dolomites have higher CaO content and lower MgO, Al2O3 and SiO2 contents, lower Sr and higher Fe and Mn concentrations than those of micritic dolomites. The ΣREE+Y concentrations and REE patterns of these fine-medium crystalline dolomites belong to the typical marine carbonate deposits. These features indicate considerable differences in origins between micrite and fine-medium crystalline dolomites. The micritic dolomites show a significant genetic response to the precipitation of seawater in shallow marine with the injection of terrestrial water during the syngenetic period, while the fine-medium crystalline dolomites have a typical response to the secondary metasomatism products of original calcites at the shallow burial stage.

Origin and Genesis of Solid Bitumen from the Sinian Dengying Reservoir in the Deyang–Anyue Rift within the Sichuan Basin (SW China): Evidence from Biomarkers and Microscopic Features

Deep-carbonate gas reservoirs are a significant field for conventional gas exploration in the Sichuan Basin, and industrial-grade gas reservoirs have recently been discovered in the second member of the Dengying Formation in the Deyang–Anyue rift. Drilling results have indicated that the large amount of solid bitumen that is commonly found in pores and fractures in the reservoir of the second member of the Dengying Formation. However, systematic studies have not yet been conducted on the solid bitumen of the second member of the Dengying Formation and its genesis and parent source remain unclear. This study is based on the systematic analysis of solid bitumen samples collected from new exploratory wells, with the aid of optical microscopy, scanning electron microscopy, and gas chromatography–mass spectrometry to clarify the genesis, thermal maturity, and parent source deposition environment of the solid bitumen. Electron microscopy and biomarker results indicate that bitumen is in a high-maturity stage and is a product of the thermal cracking of crude oil. Energy dispersive spectrometer results and the continuous distribution of n-alkanes indicate that the bitumen is not subjected to strong thermochemical sulfate reduction and biodegradation. Isoprenoids and terpenes suggest that the palaeoreserves associated with the bitumen of the second member of the Dengying Formation originate in reductive marine carbonate sediments. The combination of regional stratigraphic contact relationships, lithology, and biomarker characteristics implies that the Maidiping Formation muddy dolomite and the Dengying Formation algal dolomite are the potential parent sources of solid bitumen in the second member of the Dengying Formation.