Carbon Fiber-reinforced Epoxy Research Articles

Impact of plasma-modified pretreatment on the tensile properties of carbon fiber-reinforced epoxy composites

Abstract Low-temperature jet plasma modification technology is a surface treatment method designed to enhance the surface properties of materials without causing severe thermal damage. This technique modifies surface characteristics by creating plasma and utilizing ions and reactive groups within the plasma to chemically interact with the material’s surface. In this study, surface modification of carbon fibers was carried out by using low-temperature jet mixed oxygen plasma technology at treatment speeds of 25 mm/s, 50 mm/s, 100 mm/s, and 200 mm/s. Following the modification process, carbon fiber-reinforced epoxy composites were fabricated by using a hand-lay-up technique. Subsequently, the tensile properties of the carbon fiber composites were tested to evaluate the impact of the plasma treatment on their mechanical performance. The experimental results demonstrated a significant enhancement in the tensile properties of the composites when the carbon fibers were pretreated at a rate of 50 mm/s. This enhancement was evidenced by an impressive increase of 82.38% in tensile strength and 30.96% in tensile modulus compared to untreated samples. This signifies that low-temperature plasma treatment has a beneficial effect on enhancing the surface properties of carbon fibers and improving the performance of composites. This finding provides substantial support for the extensive application of carbon fiber composites.

Effects of carbon nanomaterials on the interfacial properties of carbon fiber reinforced epoxy resin composite

AbstractThe surface of carbon fiber is treated with sizing agent containing hydroxylated carbon nanotubes, fullerenols, and graphene oxide, respectively. The effects of carbon nanomaterials and their structures on the surface properties of carbon fiber, the interfacial properties and the mechanical properties of carbon fiber/epoxy composites are investigated. All three types of carbon nanomaterial can improve the interfacial bonding strength and modulus, thereby enhancing the interlaminar shear strength (ILSS) of composites. Moreover, the ILSS increases with the increase of interfacial bonding strength, due to the roughness and the number of active groups. Compared with the composite without carbon nanomaterials, the interfacial bonding strength of the three nanoparticle‐modified composites increased by 14%, 5% and 4%, the modulus increased by 10%, 26%, and 9%, and the ILSS increased by 14%, 8%, and 7%, respectively. The interfacial bonding strength has a more significant impact on the ILSS than the interfacial modulus.Highlights CNTs, graphene oxide and fullerenols regulate the surface characteristics of carbon fibers. The influence of carbon nanomaterials on the interfacial properties of composites. The relationship between the fiber surface, the interface and the composites.

High-performance carbon fiber-reinforced epoxy resin composites based on novel, environmentally friendly, stability, and heat-moisture resistant nano emulsion encapsulated POSS sizing agent interface modification

Considering the development of CFRPs, addressing the challenge through the simplistic industrial operational methods to achieve high strength and toughness in carbon fiber-reinforced epoxy resin (EP) composites (CFRPs) is imperative. In this work, an innovative approach introduced to improve the strength and toughness of CFRPs by application of a nano emulsion encapsulated polyhedral oligomeric silsesquioxane (POSS) sizing agent (POE sizing agent). The employment of a POE sizing agent markedly enhanced the surface energy and roughness of carbon fibers (CF) as well as the interface properties of CFRPs. Furthermore, the 10-PCF (10 wt% POE sizing CF) reinforced EP unidirectional CFRPs demonstrated superior strength and toughness. Relative to the DCF (Desizing CF) reinforced EP unidirectional CFRPs, their interlaminar shear strength, flexural strength, and unnotched impact strength increased by 24.9 %, 37.8 %, and 45.6 %, respectively, reaching 99.8 ± 2.3 MPa, 1376.8 ± 21.6 MPa, and 94.9 ± 4.6 kJ/m2. Concurrently, the 10-PCF reinforced EP composite laminates exhibited outstanding impact resistance, minimal damage area, and enhanced compressive strength after impact. Additionally, the strength, bundling, and flexibility of the sized CF were maintained, ensuring the processability of CF. The utilization of POE sizing agent for strength and toughness improvement in CFRPs offers a straightforward and industrially feasible approach. This research opens up a novel strategy for high-performance CF and CFRPs preparation.

Outstanding interlaminar strength of carbon fiber reinforced epoxy resin via graphene oxide chemical bridge bonding

Carbon fiber reinforced polymers (CFRPs) are susceptible to interlaminar failure under high shear stress, which reduces their service life. Herein, we report a strategy to address the interlaminar damage problem of CFRPs by utilizing graphene oxide (GO) as a bridge to chemically bond carbon fibers and epoxy resin. Amino groups were grafted on the surface of carbon fibers to react with GO, then active amino functional groups were introduced onto GO, enabling crosslink with the epoxy resin. The chemical bonding force and mechanical interlocking effect of GO tightly integrated the carbon fibers with the epoxy resin, greatly reducing relative slip under high shear stress. This flexible and robust connection resulted in a significant improvement in the interfacial adhesion strength of CFRPs. The GO content and type of amino reactants were optimized to fabricate CFRPs, and the interlaminar shear strength and transverse fiber bundle tensile strength were increased to 76.36 MPa and 34.2 MPa, which were 46.2 % and 77.2 % higher than those of pre-modification materials, respectively. This research demonstrates that the chemical bonding provided by grafting graphene oxide significantly enhances interlaminar bond strength, thereby extending the service life of CFRPs and offering a promising path for manufacturing high-strength composites.

Copper metallization of carbon fiber-reinforced epoxy polymer composites by surface activation and electrodeposition

The application of polymer metallization in lightweight and high-strength materials for the sporting goods, automotive, aerospace and construction sectors has attracted considerable attention. The present study aims to deposit a thin, uniform copper (Cu) layer on an epoxy‑carbon fiber (epoxy-Cf) composite material for lightweight, high-frequency radio reflector applications (Ka-Band and higher frequencies) required in space missions. In this work, a surface-activated electroplating technique in which the surface of the substrate is activated with a Sn/Ag system, followed by conventional electroplating is studied. Surface activation deposits layers of conducting metal ions on the surface of the epoxy-Cf composite, which significantly improves the electrical conductivity of the composite surface. The subsequent electrodeposition takes place from a CuSO4 solution with a pH value of 4 at three different current density values of 0.05 A/dm2, 0.5 A/dm2 and 1 A/dm2. The presence and abundance of metallic Cu over epoxy-Cf composite were confirmed by X-ray diffraction and X-ray photoelectron spectroscopy. The morphology and elemental composition of the coating were characterized by scanning electron microscopy equipped with energy dispersive spectroscopy. With current density and coating thickness, morphology of the deposit changed from cauliflower-like to spherical along with grain refinement. Microhardness test shows a hardness of 330 HV and the pull-off adhesion test gave a bond strength of 1.69 MPa for 27.56 μm thick copper deposit. A major challenge encountered during the deposition of Cu is the oxidation of the metal followed by immediate tarnishing. This issue has been effectively addressed by employing benzotriazole solution as a protective agent.

Impact of different matrix systems on mechanical, thermal, and electrical properties of carbon fiber reinforced epoxy resin matrix composites

AbstractCarbon fiber reinforced epoxy resin matrix composite is one of the most important composite materials in the world. Many researchers have conducted a lot of research on epoxy resin matrix systems in recent years, mainly to improve the problem with the short curing time of the matrix system and epoxy resin's high viscosity. The final aim is to enhance various aspects of composites' performance and optimize the production process. A new type of water dispersed epoxy resin matrix system is investigated in this paper and the target is to optimize the mechanical, thermal, and electrical performances of the composites with the water dispersed epoxy resin matrix by varying different doping particles and different resin/catalyst ratios. Through a series of experiments, it is evident that varying the ratio of resin to catalyst in the matrix system will not significantly improve the mechanical as well as thermal properties of the composites. However, increasing the amount of catalyst in the matrix system can greatly improve the electrical properties of its composite samples. In addition to this, the addition of doping particles to the matrix systems has the effect of slightly enhancing the tensile modulus, thermal conductivity, and electrical conductivity of their composites.Highlights A new water‐dispersed epoxy resin matrix system improves processing technology. Increasing amount of catalyst in the matrix system improves electrical resistivity. Adding particles to matrix systems has a slight effect on different properties.

Cryogenics performance enhancement of epoxy resin composites through negative expansion nanomaterials: Mechanism and predictive modeling

AbstractThe matrix cracking of carbon fiber reinforced epoxy resin based composites (CFRPs) at cryogenics (such as liquid nitrogen temperature) is a major issue affecting the normal operation of deep space and deep‐sea detectors, as microcracks caused by the thermal residual stress of both can reduce the structural integrity of the devices. In this work, we report an epoxy (EP) nanofiller CuO nanorods (CuO NRs) with negative thermal expansion properties at cryogenics. Experiments showed that CuO NRs can effectively inhibit the shrinkage of EP at cryogenics and improve the mechanical properties of EP at cryogenics. A temperature dependent prediction model for the tensile strength of EP/CuO NRs was proposed, and the predicted results were in good agreement with experimental results. Finally, through a combination of experiments and theory, it was demonstrated that the tensile strength of EP/CuO NRs at cryogenics is jointly enhanced by the enhancement effect of the nanomaterials and the axial compressive thermal residual stress between EP and CuO NRs.Highlights Successfully prepared CuO nanorods with negative expansion properties at low temperatures, and found that they can effectively inhibit the shrinkage of epoxy resin at cryogenics. At cryogenics, the expansion of CuO nanorods enhances their interface effect with epoxy resin and improves the tensile strength of epoxy resin composites. The theory of tensile strength of epoxy resin at cryogenics was proposed for the first time. Theoretical analysis shows that the low temperature residual thermal stress between CuO nanorods and epoxy resin is the main factor to improve its tensile strength.

Carbon nanotube as a conductive rheological modifier for carbon fiber-reinforced epoxy 3D printing inks

Rheological modifiers enable direct ink writing of polymers with low viscosity such as epoxy without requiring light or heat. Modifiers that conduct electrons and phonons impart multifunctional properties to 3D printed polymers. Here, we report the development of printable nanocomposite inks comprised of epoxy, carbon fibers (CFs), and carbon nanotubes (CNTs) to achieve excellent mechanical properties and multifunctionality via high electrical conductivity required for next-generation light weight aerospace, electronics, and energy applications. CF and CNT concentrations of 8.5 and 1.7 wt%, respectively, render the material shear-thinning with a high yield stress, hence printable and self-supporting after being printed. An average electrical conductivity of 10−2 S/cm and thermal conductivity of 0.3 W/m.K were measured for the 3D-printed multi-layer structures. Furthermore, tensile modulus, tensile strength, flexural modulus, and flexural strength were measured to be 5.8, 0.08, 6.0, and 0.1 GPa, respectively. Compared with other 3D printed conductive polymer nanocomposites with reported electrical conductivity and elastic modulus, the structures here have the highest specific elastic modulus. They also possess the highest electrical conductivity among the 3D printed polymeric composites of carbon nanomaterials with an elastic modulus above 1 GPa. This is due to the outstanding combination of CNTs, CFs, and epoxy. The results expand the range of polymer properties for multifunctional applications.

Compact-tension-shear specimen for orthotropic materials in fracture toughness testing

Conducting Compact-Tension-Shear (CTS) tests emerges as a promising research methodology to determine the fracture toughness of orthotropic materials in mixed-mode I&II. However, the absence of pertinent fracture parameter solutions incorporating material orthotropy impedes the further application and standardization of CTS testing. Therefore, this study performed a systematic two-dimensional finite element analysis (FEA) on orthotropic CTS specimens to evaluate critical fracture parameters, including the normalized stress intensity factors (YI, YII) and compliance (u). First, the impacts of three commonly cited boundary conditions (BCs) of CTS models were investigated, revealing that the simplified or equivalent methods developed for isotropic CTS models are no longer applicable. Subsequently, the suitable CTS models were used to analysis the coupling effects of material orthotropy (λ, ρ), crack length ratios (a/W), and loading angles (β). Findings indicated that YI or u no longer exhibit a monotonic relationship with respect to a/W or β under strong orthotropy. The impact of λ and ρ on fracture parameters is equally significant across different geometries and loading conditions. Further, the impact of orthotropy on YII is relatively small, while the more affected YI may have a difference compared to isotropic results of over 80%. Finally, CTS tests were carried out on the unidirectional carbon fiber-reinforced epoxy resin composite measuring the fracture toughness in mixed-modes I&II. The obtained fracture parameter solutions were applied and validated during the process. The acquired results are poised to contribute to the advancement of fracture toughness testing standardization for orthotropic materials under mixed-mode loading.

Panoramic View of Interface-Related Thermo-oxidative Aging of Carbon Fiber-Reinforced Epoxy Composites

Panoramic View of Interface-Related Thermo-oxidative Aging of Carbon Fiber-Reinforced Epoxy Composites

Determination of the In-Plane Shear Behavior of and Process Influence on Uncured Unidirectional CF/Epoxy Prepreg Using Digital Image Correlation Analysis

The investigation of the in-plane shear behavior of prepreg is crucial for understanding the generation of wrinkles of preforms in advanced composite manufacturing processes, such as automated fiber placement and thermoforming. Despite this significance, there is currently no standardized test method for characterizing uncured unidirectional (UD) prepreg. This paper introduces a ±45° off-axis tensile test designed to assess the in-plane shear behavior of UD carbon fiber-reinforced epoxy prepreg (CF/epoxy). Digital image correlation (DIC) was employed to quantitatively track the strains in three dimensions and the shear angle evolution during the stretching process. The influences of the temperature and stretching rate on the in-plane shear behavior of the prepreg were further investigated. The results reveal that four shear characteristic zones and wrinkling behaviors are clearly distinguished. The actual in-plane shear angle is significantly lower than the theoretical value due to fiber constraints from both the in-plane and out-of-plane aspects. When the off-axis tensile displacement (d) is less than 15.6 mm, the ±45° specimens primarily exhibit macroscale in-plane shear behavior, induced by interlaminar interface shear between the +45° ply and −45° ply at the mesoscale. The shear angle increases linearly with the d. However, when d > 15.6 mm, fiber squeezing and wrinkling begin to occur. When d > 29 mm, the in-plane shear disappears in the completely sheared zone (A). The reduction in the resin viscosity of the CF/epoxy prepreg caused by increased temperature is identified as the primary factor in lowering the in-plane shear force resistance, followed by the effect of the increasing resin curing degree. Higher shear rates can lead to a substantial increase in shear forces, eventually causing cracking failure in the prepreg. The findings demonstrate the feasibility of the test method for predicting and extracting uncured prepreg in-plane shear behaviors and the strain-rate and temperature dependency of the material response.

Investigation of fracture behavior and mechanical properties of epoxy composites supported with MWCNTs microscopically

Adding of a multi-walled carbon nanotubes (MWCNTs) to epoxy resin has shown promising results in improving fracture toughness in bulk epoxy and carbon fiber-reinforced epoxy composites (CFRP). using a hand layup proceeding followed by the so called vacuum bagging process method, carbon fiber-reinforced polymer multi-wall carbon nanotubes (MWCNTs) was added to an epoxy resin with a weight percentage mixing of 1% wt., 1.25% wt., and 1.5 % wt. MWCNTs. Furthermore, the specimen underwent analysis via Fourier-Transform Infrared (FTIR) spectroscopy, and X-ray Diffraction (XRD) spectroscopy, the composites were subjected to a microscopic examination using a Scanning Electron Microscope (SEM). FTIR and XRD verified the folding and unfolding of the polymer, in addition, the mechanical properties including tensile strength, bending stress, and impact behavior were investigated as well as the hardness test. The obtained results showed a significant improvement of about (40 %) in tensile strength, (53 %) in bending stress at 1 % wt. MWCNTs, and (70 %) percentage increment in the strength of Impact at 1.25 % wt. MWCNTs. And the gained hardness was about 40.5 HV which were compared with a reference substance named Carbon Fiber (CF) without any addition of nano materials. Carbon nanotubes have demonstrated their potential to enhance the mechanical properties of fiber-reinforced polymers, so this investigative study employs comprehensive characterization techniques, and demonstrates significant improvements in mechanical properties for the modified polymeric composite materials supported with nano materials.

Comparison of pin-loaded tensile behavior and failure behavior of thermosetting and thermoplastic composite

This study investigated the pin-loaded tensile behavior, bearing strength, and failure mechanisms of thermosetting and thermoplastic composite materials. Specifically, the investigation focuses on carbon-fiber-reinforced polyetherketoneketone (CF/PEKK) and carbon-fiber-reinforced epoxy (CF/EPOXY). Notably, CF/PEKK exhibited a shear-out failure mode, surpassing CF/EPOXY with a 56.4% higher peak load. The absence of crack propagation in CF/EPOXY, attributed to the presence of yarn at a 90∘ angle, leads to bearing failure. In contrast, CF/PEKK demonstrates a significantly higher bearing strength, approximately 150[Formula: see text]MPa greater than CF/EPOXY. This discrepancy in performance suggests that CF/PEKK holds promise as a structural material for applications involving the fastening of thermoplastic composites, presenting a viable alternative to traditional thermosetting composites. The findings imply that the unique failure mechanisms and enhanced mechanical properties of CF/PEKK make it a compelling candidate for use in scenarios where thermosetting composites are conventionally applied. This study contributes valuable insights into the potential advancements and applications of thermoplastic composites in structural materials, paving the way for optimized and innovative engineering solutions.

Micromechanical modeling for longitudinal tensile property of unidirectional CFRP considering dispersion of fiber properties

Longitudinal tensile failure prediction has always been the focus of research on unidirectional (UD) Carbon Fiber Reinforced Polymer (CFRP). In this paper, the longitudinal tensile tests of unidirectional T800 grade carbon fiber reinforced epoxy resin composite were carried out first. The experimental stress–strain curves show that there are obvious progressive damages before the final failures of the specimens. However, this phenomenon is usually neglected in most of the existing investigations and tests to only obtain elastic modulus and ultimate strength. Thus, a Representative Volume Element (RVE) model based on micromechanics was established using finite element method, considering the randomness of fiber spatial distribution and fiber strength. The tensile strength of fiber monofilaments was assumed to follow a statistical two-parameter Weibull distribution. The failure process of UD composite under longitudinal tensile load was simulated by explicit finite element method. The stress–strain curves obtained by simulation are in good agreement with the experimental results. Finally, the influence of different boundary conditions on the calculation of the RVE was studied. It is found that the final failure strengths of the RVE with uniform displacement boundary conditions are similar to the case of periodic boundary conditions, while the former has higher computational efficiency.

Experimental and numerical study of the effects of fiber orientation on stress concentration of CFRE

Carbon fiber reinforced composites are broadly employed, as structural members, in many industrial applications especially in the avionic industry due to their high strength-to-weight ratio. Circular holes are commonly used in these members for fastening, bearing, reducing weight, and others. Therefore, several experimental and analytical studies were introduced to figure out the stress concentration behavior around the vicinity of the holes under different loading conditions. However, no reports are delivered to study the effect of fiber orientation on the stress concentration factor of unidirectional carbon fiber reinforced epoxy (CFRE) composites with a hole under tension. Thus, the current work is targeted to understand the relationship between stress concentration factor (SCF) and fiber orientation in CFRE orthotropic plates. The unnotched and notched composite samples, with four different fiber orientations, were experimentally investigated in a tension test. The SCF of samples was calculated using analytical and computational FE methods. The failure criterion of open-hole tensile (OHT) test samples was also analyzed. The experimental results demonstrated that there is no significant effect of fiber orientation on the normalized strength. Yet based on the stiffness matrix of isotropic materials, a pronounced effect of the fiber orientation on the SCF is detected when using analytical calculations. The present research arises the need for further investigations to find a correlation between experimental and analytical results of SCF in unidirectional CFRE with a central hole at different fiber orientations.

Multiscale analysis method and experiments for the transverse mechanical property of unidirectional fiber-reinforced composites

Carbon fiber-reinforced epoxy matrix composite laminates have been widely used in the case of advanced aero-engines, due to their high specific mechanical properties and mature production technology. In order to predict accurately the transverse mechanical properties of composites, this paper developed a multiscale analysis method which consists of three scales: At the microscale, an interfacial cohesive zone model is established based on atomic potential energy to describe the interface. At the mesoscale, a unit cell model is established to represent the fiber, matrix, and interface. At the macroscale, the homogenization method, failure criteria, and damage degradation models are utilized to predict transverse mechanical properties. The results of predictions are compared with experimental tests, and it is found that the maximum errors are less than 3%. Furthermore, the predicted damage evolution path aligns with the experimental results, thus validating the accuracy of the multiscale analysis method. By employing the multiscale analysis method, the effects of interfacial strength on the macroscopic transverse mechanical properties are analyzed. The simulation results indicate that: The interfacial strength has a more pronounced influence on the transverse strength and ultimate strain compared with the transverse modulus. Reducing the interfacial strength has a greater influence on the transverse modulus, strength, and ultimate strain than increasing the interfacial strength. The interfacial cohesive zone model can reflect the nonlinearity of epoxy matrix composite materials. Overall, the multiscale analysis method proves to be effective in accurately predicting the transverse mechanical properties of composites, and provides insights into the interfacial strength’s role in these properties.

Effect of carbon nanotubes on thermoset curing and mechanical properties of carbon fiber reinforced epoxy resin laminates fabricated by self‐resistance electric heating

AbstractSelf‐resistance electric (SRE) heating for the curing of carbon fiber reinforced plastic (CFRP) offers the benefits of saving energy consumption and reducing investment in equipment. In this work, the investigation was carried out to illustrate the effect of carbon nanotubes (CNTs) addition (0.5, 1.0, and 1.5 wt%) on the thermoset curing and mechanical properties of carbon fiber‐reinforced epoxy laminates fabricated by SRE heating method. The results show that adding CNTs can improve the temperature uniformity and interlayer‐resin flow during the SRE heating process and have a limited influence on the curing degree of CFRP composites. The tensile strength in the longitudinal direction of the composites increased with the increase of CNT addition. Meanwhile, the flexural strength and interlaminar shear strength had the maximum value with the CNTs content of 0.5 wt% and decreased significantly at the CNTs content of 1.5 wt%. It concludes that the appropriate content of CNTs addition has the potential to improve the thermoset curing performance and mechanical properties of the CFRP laminate composites fabricated by SRE heating.Highlights This study focuses on the effect of CNT addition on SRE heating for CFRP. The addition of CNTs improved the temperature uniformity during SRE heating. The addition of CNTs can reduce the voids of SRE‐cured CFRP composites. Threshold value of CNTs affected the mechanical performance of SRE‐cured CFRP.

Modal and stress behavioral for CFRP composite lifting lug

Purpose In the present study, a steel lifting lug is replaced with a composite (carbon fiber-reinforced epoxy [CFRP]) lifting lug made of a carbon/epoxy composite. The purpose of this paper was to obtain a composite lifting lug with a higher level of strength that is capable of carrying loads without failure. Design/methodology/approach The vibration and static behaviors of steel and composite lifting lugs have been investigated using finite element analysis (FEA), ANSYS software. The main consideration in the design of the composite (CFRP) lifting lug was that the displacement of both steel and composite lugs was the same under the same load. Hence, by using the FEA displacement result of the steel lifting lug, the thickness of the composite lifting lug is determined using FEA. Findings Compared to the steel lifting lug, the composite (CFRP) lifting lug has much lower stresses and much higher natural frequencies. Static behavior was experienced by the composite lifting lug, showing a reduction in von Mises stress, third principal stress and XZ shear stress, respectively, by 48.4%, 34.6% and 89.8%, respectively, when compared with the steel lifting lug. A higher natural frequency of mode shape swaying in X (258.976√1,000 Hz) was experienced by the composite lifting lug when compared to the steel lifting lug (195.935√1,000 Hz). The safe strength of the design composite lifting lug has been proven by FEA results, which showed that the composite (CFRP) lifting lug has a higher factor of safety in all developed stresses than the steel lifting lug. According to von Mises stress, the factor of safety of the composite lifting lug is increased by 76% when compared to the steel lifting lug. The von Mises stress at the edge of the hole in the composite lifting lug is reduced from 23.763 MPa to 20.775 MPa when compared to the steel lifting lug. Originality/value This work presents the designed composite (CFRP) lifting lug, which will be able to carry loads with more safety than a steel one.

Design and study of biomimetic resin matrix composites based on shellfish structure

Differences in microstructure can often lead to large differences in mechanical properties. Here, the composition, microstructure, and mechanical properties of mussel, scallop, and ostreidae were researched. And subsequently, three bionic models were designed based on the microstructures of the three shellfish. Three models were prepared by printing the substrate with light-cured resin and filling with carbon fiber reinforced epoxy resin. The mechanical properties and reinforcement mechanisms of the three models were also investigated. The bending fracture force, compression fracture, and the impact fracture energy of mussels was best of three shellfish. The bionic model 1 with mimic mussel structure has good mechanical properties. Bending strength of model 1 is 42.80 ± 7.00 MPa which was 5.42% higher than bionic model 2 and bionic model 3, and 33.75% higher than that of the pure epoxy resin (32.00 MPa). The absorbed energy of the model 1 is 63.53 ± 2.56%, which is 3.82% and 7.89% higher than model 2 and model 3, respectively. The fracture showed obvious toughness fracture. The unique crack deflection induced by the structure also leads to enhanced mechanical properties. This study provides new design ideas and references for the structural design of high-strength composites.

Mechanical properties of a carbon fiber reinforced epoxy resin composite improved by integrating multi-walled carbon nanotubes and graphene nanoplatelets

The pairs of nanofillers prepared by graphene nanoplatelets (GNPs) and multi-walled carbon nanotubes (MWCNTs) were added to the epoxy matrix in various ratios to produce hybrid epoxy nanocomposites. The effects of the presence of these nanofillers at 0.1–0.4 wt.% on the mechanical and thermal properties were tested. Likewise, carbon fiber reinforced MWCNT/GNP modified epoxy nanocomposite laminates were also manufactured and tested. The dispersion of nanofiller in the polymer matrix was evaluated by Scanning Electron Microscopy (SEM). It was determined that the hybrid composite consisting of a MWCNT:GNP ratio of 1:3 and a nanofiller ratio of 0.3 wt.% showed the best mechanical properties with a tensile strength of 75.1 MPa. The presence of GNPs and MWCNT nanofillers in epoxy/carbon fiber laminates influenced positively the tensile strength and strain but negatively the elastic modulus. Glass transition temperature of epoxy increased from 87.25°C to 114.67°C for MWCNT:GNP ratio of 1:1 (0.3 wt.%).