Carbon Capture And Utilization Research Articles

An Overview of Waste-to-Energy Incineration Integrated with Carbon Capture Utilization or Storage Retrofit Application

An Overview of Waste-to-Energy Incineration Integrated with Carbon Capture Utilization or Storage Retrofit Application

In situ spectroelectrochemical study of acetate formation by CO2 reduction using Bi catalyst in amine-based capture solution.

Carbon capture and utilization (CCU) are technologies sought to reduce the level of CO2 in the atmosphere. Industrial carbon capture is associated with energetic penalty, thus there is an opportunity to research alternatives. In this work, spectroelectrochemistry was used to analyze the electrochemical CO2 reduction (eCO2R) in CO2 saturated monoethanolamine (MEA)-based capture solutions, in a novel CCU process. The in situ Fourier transform infrared (FTIR) spectroscopy experiments show that at the Bi catalyst, the active species involved in the eCO2R is the dissolved CO2 in solution, and not carbamate. In addition, the products of eCO2R were evaluated under flow, using commercial Bi2O3 NP as catalyst. Formate and acetate were detected, with normalized FE for acetate up to 14.5%, a remarkable result, considering the catalyst used. Acetate is formed either in the presence of cetrimonium bromide (CTAB) as surfactant or at higher current density (> -100 mA cm-2) and the results enabled the proposition of a pathway for its production. This work sheds light on the complex reaction environment of a capture medium electrolyte and is thus relevant for an improved understanding of the conversion of CO2 into value-added products and to evaluate the feasibility of a combined CCU approach.

Worlds apart? Investigating acceptance and usage demands of carbon-based cosmetics and clothing across European countries

BackgroundGlobal warming and the increasing risk of natural disasters force us all to act. As the reduction of carbon dioxide (CO2) emissions has been proven effective but insufficient on its own, Carbon Capture and Utilization (CCU) technologies emerged to fill the gap. Using CCU technologies, CO2 is captured and further processed into valuable products instead of being emitted into the atmosphere.MethodThis study investigates the prevailing public perception of such CCU-based products by the example of clothing and cosmetics. We applied the method of conjoint measurement to experimentally examine context-related factors (= attributes) in different usage settings and explored the consumers’ decision profiles for or against the usage of CCU-based products (cosmetics and clothing). Conjoint measurements were realized as an online experiment, addressing acceptance patterns and preferences in four European countries (Germany, Norway, Spain, and Poland). In addition, we assessed general attitudes and affective assessments of the CCU products. A total of N = 828 participants took part in the study, and the international subsamples were comparable.ResultsResults revealed that health compatibility is the main adoption-driving factor in the decisions for or against the use of the products. Still, attributes like the environmental impact, product quality, and information flow play an important role as well, even though to a lesser extent. Participants from different countries significantly differ in their cognitive and affective evaluations of acceptance-related attributes.ConclusionsThe outcome provides insights into differences in Pan-European comparison and helps to understand the public motives and country-specific terms of use for CCU-based products, effectively establishing recommendations for policy and governance.

Experiments and mechanism of kinetics/stability of CO2 capture by Ce/Zr carrier-loaded MgO-based adsorbents

Magnesium oxide (MgO) has demonstrated tremendous potential in carbon capture and utilization (CCU) technology. However, it still faces limitations such as low adsorption kinetics and poor stability. In this study, the sol–gel combustion method was employed to synthesize MgO/molten salt composite adsorbents supported on Ce/Zr carriers. The investigation focused on the influence of carrier composition on adsorption performance. The experimental results revealed that as the loading of CeO2 increased, the adsorbent materials transitioned from a porous foam-like connectivity to the formation of a shell structure. Interestingly, the low content of CeO2 facilitated enhanced CO2 diffusion and hindered the aggregation of MgO aggregates, resulting in improved adsorption performance. Furthermore, the adsorbents supported on ZrO2 demonstrated excellent particle size stability and cyclic stability due to the higher Tamman temperature of ZrO2 and the uniform dispersion of MgO on ZrO2. Utilizing density functional theory, a surface configuration of CeO2/ZrO2 catalyst-modified MgO (100) was constructed to elucidate the enhanced adsorption mechanism of CeO2/ZrO2 on MgO. The cluster model revealed a strong interaction between cluster O atoms and CO2 molecules, enhancing the charge transfer capability of the MgO surface towards CO2 and consequently strengthening its adsorption performance.

Life cycle assessment of synthetic natural gas production from captured cement’s CO2 and green H2

Research on the environmental benefits of carbon capture and utilization (CCU) in cement production so far, has predominantly emphasized energy efficiency enhancements and CO2 emission reductions at a CCU product level, neglecting broader environmental consequences for the sector. This research broadens this perspective by providing an extensive life cycle assessment (LCA) of a circular Portland cement (CPC) model. Synthesized methane is used as input fuel through green hydrogen and calcium-looping (CaL) post-combustion captured CO2 from cement flue gas. Comparative analysis with ordinary Portland cement (OPC) reveals significant reductions in climate change and fossil resource use environmental impact categories. However, trade-offs are evident in acidification, water use, and minerals and metals resource consumption. The electrolysis system is a critical contributor due to the high electricity demand for hydrogen production, and its environmental impact depends largely on the renewable electricity source. The wind-based electrolysis model yields the most favourable results, followed by mixed (50% solar – 50% wind) and solar scenarios. These findings offer valuable insights for the cement industry, supporting stakeholders decision making on the adoption of sustainable circular production methods.

Recent advancements in the application of electrospun nanofibers for carbon dioxide capture and utilization

The escalating CO2 emissions in recent years underlined the need for advanced Carbon Capture and Utilization (CCU) technologies. This context has spurred the exploration of novel materials for promoting CCU efficiency, among which electrospun nanofibers have emerged as a promising candidate. Electrospinning coupled with various post-treatment (such as heat-treating, in-situ growth, selective removal, etc.) offers a versatile approach to fabricate diverse nanofibers, including polymeric, carbonaceous, metallic, and composite fibers, with tunable surface morphologies and chemical properties. This paper provides a comprehensive review of electrospun nanofibers in CCU processes, including adsorption, membrane separation and absorption, electrochemical and photo-electrochemical reduction, thermal catalytic hydrogenation, and more. Each CCU technology is examined in depth to cover the recent research achievements with a specific focus on the contributions of electrospun nanofibers. Lastly, a critical discussion and a list of potential future research directions for this evolving field are provided.

CARBON CAPTURE AND UTILIZATION (CCU): A REVIEW OF EMERGING APPLICATIONS AND CHALLENGES

As the global community grapples with the urgent need to mitigate the impacts of climate change, Carbon Capture and Utilization (CCU) has emerged as a promising and multifaceted strategy to address carbon emissions. This review paper provides a comprehensive examination of the current state of CCU technologies, focusing on both the emerging applications and the challenges inherent in their implementation. The first section offers an overview of diverse carbon capture methods, ranging from pre-combustion to direct air capture, highlighting key advancements in technologies such as chemical absorption, membrane separation, and adsorption. Subsequently, the paper delves into the various pathways of carbon utilization, exploring applications in the production of fuels, carbon-based materials, and chemical synthesis. Notable breakthroughs in power-to-gas technologies, utilization in construction materials, and industrial applications are discussed in detail. The core of the review is dedicated to unveiling the emerging applications of CCU, with a specific emphasis on its role in agriculture and soil enhancement, integration with renewable energy systems, and collaboration with other industries. The potential economic and environmental benefits of these applications are explored to underscore the transformative impact of CCU on sustainable development. However, the journey towards widespread CCU adoption is not without challenges. This paper identifies and analyzes technical hurdles related to efficiency, scalability, and cost-effectiveness. Additionally, it examines the regulatory, policy, and societal challenges that may hinder the seamless integration of CCU technologies. Case studies of successful CCU projects provide practical insights, emphasizing lessons learned and best practices. The paper concludes by outlining future prospects and opportunities in the field of CCU, emphasizing the need for continued research, development, and international collaboration. It calls for a concerted effort to overcome challenges and harness the full potential of CCU in contributing to global carbon reduction goals. This comprehensive review aims to serve as a valuable resource for researchers, policymakers, and industry professionals involved in climate change mitigation, providing a nuanced understanding of the current landscape, opportunities, and challenges associated with Carbon Capture and Utilization.
 Keywords: Carbon Capture and Utilization (CCU), Applications, Challenges.

EU-Bioenergies: Status and Future Prospects

For climate protection and a sustainable economy, the European Union is pursuing a policy of switching from fossil to renewable energies, which should lead to a reduction in greenhouse gases (GHG) and a reduction in dependence on energy imports. This report uses publicly available databases and analyses to examine the extent to which these goals are achieved or are achievable by means of bioenergy (fuel, heat, electricity). In addition, EU regulations and databases relevant to bioenergy are critically scrutinised. Today, bioenergy accounts for around 10% of Europe's energy supply, making up more than half (59%) of renewable energies. There is potential to further increase bioenergy, but the future contribution to energy supply and independence from imports is rather to be estimated as moderate. The evaluation of GHG suffers from the fact that the official databases do not meet the requirements for a scientific evaluation. In order to make a sustainable contribution to the EU targets, besides energy, all other options for the use of biomass, the use of biogenic CO2 through carbon capture and utilisation (CCU) and the combination of bioenergy and carbon capture and sequestration (CCS) should be integrated. To promote the implementation of such an integrated approach, the pricing of GHG should be combined with incentives for the upscaling of sustainable bioenergy, CCU and CCS.

A novel optimization method of carbon reduction strategies implementation for industrial parks

The effects of various energy conservation and carbon reduction (ECCR) strategies can differ significantly despite equal investment. Given limited amount of capital expenditure, managers and planners of industrial parks must carefully select from different ECCR strategies and implementation technologies to maximize investment returns. This study establishes mathematical models for four ECCR strategies: forestry carbon sequestration (FCS), carbon capture and utilization (CCU), waste heat recovery (WHR), and photovoltaic (PV). A universal ECCR planning optimization model is constructed to maximize annual economic benefits or carbon emission reduction. Using an industrial park in southern China as a case study, genetic algorithms are utilized to solve the model and validate its feasibility. The study analyzes three key parameters: capital expenditure caps, carbon trading price in the Emission Trading Scheme, and transportation distance of captured CO2 products for sensitivity. The results demonstrate considerable economic benefits of the CCU strategy when demand matches appropriately. However, in cases with limited capital expenditure, implementing small-scale FCS strategies in industrial parks is not advisable from both an economic and environmental perspective.

Synthesis of Cobalt-Based Nanoparticles as Catalysts for Methanol Synthesis from CO2 Hydrogenation.

The increasing emission of carbon dioxide into the atmosphere has urged the scientific community to investigate alternatives to alleviate such emissions, being that they are the principal contributor to the greenhouse gas effect. One major alternative is carbon capture and utilization (CCU) toward the production of value-added chemicals using diverse technologies. This work aims at the study of the catalytic potential of different cobalt-derived nanoparticles for methanol synthesis from carbon dioxide hydrogenation. Thanks to its abundance and cost efficacy, cobalt can serve as an economical catalyst compared to noble metal-based catalysts. In this work, we present a systematic comparison among different cobalt and cobalt oxide nanocomposites in terms of their efficiency as catalysts for carbon dioxide hydrogenation to methanol as well as how different supports, zeolites, MnO2, and CeO2, can enhance their catalytic capacity. The oxygen vacancies in the cerium oxide act as carbon dioxide adsorption and activation sites, which facilitates a higher methanol production yield.

Pyrene-Based Nanoporous Covalent Organic Framework for Carboxylation of C-H Bonds with CO2 and Value-Added 2-Oxazolidinones Synthesis under Ambient Conditions.

The selective carbon capture and utilization (CCU) as a one-carbon (C1) feedstock offers dual advantages for mitigating the rising atmospheric CO2 content and producing fine chemicals/fuels. In this context, herein, we report the application of a porous bipyridine-functionalized, pyrene-based covalent organic framework (Pybpy-COF) for the stable anchoring of catalytic Ag(0) nanoparticles (NPs) and its catalytic investigation for fixation of CO2 to commodity chemicals at ambient conditions. Notably, Ag@Pybpy-COF showed excellent catalytic activity for the carboxylation of various terminal alkynes to corresponding alkynyl carboxylic acids/phenylpropiolic acids via C-H bond activation under atmospheric pressure conditions. Besides, carboxylative cyclization of various propargylic amines with CO2 to generate 2-oxazolidinones, an important class of antibiotics, has also been achieved under mild conditions. This significant catalytic activity of Ag@Pybpy-COF with wide functional group tolerance is rendered by the presence of highly exposed, alkynophilic Ag(0) catalytic sites decorated on the pore walls of high surface area (787 m2 g-1) Pybpy-COF. Further, density functional theory calculations unveiled the detailed mechanistic path of the Ag@Pybpy-COF-catalyzed transformation of CO2 to alkynyl carboxylic acids and 2-oxazolidinones. Moreover, the catalyst showed high recyclability for several cycles of reuse without significant loss in its catalytic activity and structural rigidity. This work demonstrates the promising application of Pybpy-COF for stable anchoring of Ag NPs for successful transformation of CO2 to valuable commodity chemicals at ambient conditions.

Scenario Development for Evaluating Carbon Capture and Utilization Concepts Using Steel Mill Exhaust Gases with Linear Optimization Models

Utilizing exhaust gases from the steel mill generation to produce chemicals presents a promising avenue for carbon capture and utilization (CCU) concepts. Employing a model-based mathematical approach, specifically mixed-integer linear programming (MILP), enables the identification of optimal production concepts. To evaluate the long-term feasibility under uncertain future conditions, the construction of hypothetical scenarios to depict possible future states is necessary. This study introduces novel and tailored scenarios for a specific CCU concept aimed at producing methanol, ammonia, urea and/or acetic acid from steel mill exhaust gases by the year 2040 to enhance decision-making processes for identifying the optimal concept. These scenarios provide comprehensive insights into potential future conditions, spanning technical, economic and ecological domains. Unlike prior studies that focus on individual key factors, this approach involves analyzing the interactions of 24 identified key factors within the investigated CCU concept. The method yields five distinct scenarios: (1) Business as Usual (BAU), (2) CO2 Reduction and Renewable Energy Target (RE-Boom), (3) Technical Improvement and Market Booming (Market-Boom), (4) Energy and Market Crisis (Crisis) and (5) Hydrogen Booming (H2-Boom). These five scenarios can be directly integrated into MILP models, enhancing the significance of the optimization results for identifying the optimal CCU concept.

One step closer: Laypeople’s perception of production steps for manufacturing CO2-based jet fuel

BackgroundThe need for greenhouse gas abatement measures grows as climate change threatens life on earth. Negative emission technologies, such as carbon capture and utilization (CCU), can reduce emissions from the transport sector, particularly aviation. However, the lack of support and low public acceptance can impact the successful introduction of new technologies. This study analyzes the factors that influence acceptance of the single production steps (capture, purification, conversion, and transport of CO2) of production of CO2-based jet fuels to identify acceptance hot spots and potential roll-out barriers.ResultsIn a quantitative survey with n = 543 German respondents, we find that transport of CO2 in comparison with capture, purification, and conversion of CO2 into hydrocarbons is perceived as less acceptable, efficient, and useful, more expensive as well as damaging for the environment and health. Furthermore, product-step specific risk perceptions, as well as benefit and barrier perceptions for CCU mainly predict people’s attitude towards the four production steps. A cluster-analysis revealed two groups, “Approvers” and “Sceptics”, which were characterized by distinctive perception profiles. Further analysis showed that sustainability (e.g., use of renewable energy) and efficiency (e.g., carbon removal and resource use) were of greater importance to Approvers.ConclusionsThe study’s results suggest the need for further research and information provision to enhance public understanding of the technology and its role as a part of circular economy approaches. Risk perceptions play a central role in determining attitudes towards CCU, which should be considered in future studies and communication strategies. The findings can inform policymakers, industry stakeholders, and communication experts working to promote sustainable aviation fuel technologies.

Advances in the direct electro-conversion of captured CO2 into valuable products

A comprehensive review of direct captured CO2 electro-conversion technology, a promising Carbon Capture and Utilization (CCU) technology that can achieve both techno-economic and environmental viability.

Early-Stage Impact Assessment Tool (ESTIMATe) for the Life Cycle Assessment of CO2-based chemicals

In the pursuit of climate change mitigation, the chemical industry is developing carbon capture and utilization (CCU) processes to eliminate fossil carbon feedstock. Life Cycle Assessment (LCA) of CCU processes...

Addressing the Effectiveness and Molecular Mechanism of the Catalytic CO2 Hydration in Aqueous Solutions by Nickel Nanoparticles.

Hydration of carbon dioxide in water solution is the rate limiting step for the CO2 mineralization process, a process which is at the base of many carbon capture and utilization (CCU) technologies aiming to convert carbon dioxide to added-value products and mitigate climate change. Here, we present a combined experimental and computational study to clarify the effectiveness and molecular mechanism by which nickel nanoparticles, NiNPs, may enhance CO2 hydration in aqueous solutions. Contrary to previous literature, our kinetic experiments recording changes of pHs, conductivity, and dissolved carbon dioxide in solution reveal a minimal effect of the NiNPs in catalyzing CO2 hydration. Our atomistic simulations indicate that the Ni metal surface can coordinate only a limited number of water molecules, leaving uncoordinated metal sites for the binding of carbon dioxide or other cations in solution. This deactivates the catalyst and limits the continuous re-formation of a hydroxyl-decorated surface, which was a key chemical step in the previously suggested Ni-catalyzed hydration mechanism of carbon dioxide in aqueous solutions. At our experimental conditions, which expand the investigation of NiNP applicability toward a wider range of scenarios for CCU, NiNPs show a limited catalytic effect on the rate of CO2 hydration. Our study also highlights the importance of the solvation regime: while Ni surfaces may accelerate carbon dioxide hydration in water restricted environments, it may not be the case in fully hydrated conditions.

Improving Stability of CO2 Electroreduction by Incorporating Ag NPs in N-Doped Ordered Mesoporous Carbon Structures.

The electroreduction of carbon dioxide (eCO2RR) to CO using Ag nanoparticles as an electrocatalyst is promising as an industrial carbon capture and utilization (CCU) technique to mitigate CO2 emissions. Nevertheless, the long-term stability of these Ag nanoparticles has been insufficient despite initial high Faradaic efficiencies and/or partial current densities. To improve the stability, we evaluated an up-scalable and easily tunable synthesis route to deposit low-weight percentages of Ag nanoparticles (NPs) on and into the framework of a nitrogen-doped ordered mesoporous carbon (NOMC) structure. By exploiting this so-called nanoparticle confinement strategy, the nanoparticle mobility under operation is strongly reduced. As a result, particle detachment and agglomeration, two of the most pronounced electrocatalytic degradation mechanisms, are (partially) blocked and catalyst durability is improved. Several synthesis parameters, such as the anchoring agent, the weight percentage of Ag NPs, and the type of carbonaceous support material, were modified in a controlled manner to evaluate their respective impact on the overall electrochemical performance, with a strong emphasis on operational stability. The resulting powders were evaluated through electrochemical and physicochemical characterization methods, including X-ray diffraction (XRD), N2-physisorption, Inductively coupled plasma mass spectrometry (ICP-MS), scanning electron microscopy (SEM), SEM-energy-dispersive X-ray spectroscopy (SEM-EDS), high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM), STEM-EDS, electron tomography, and X-ray photoelectron spectroscopy (XPS). The optimized Ag/soft-NOMC catalysts showed both a promising selectivity (∼80%) and stability compared with commercial Ag NPs while decreasing the loading of the transition metal by more than 50%. The stability of both the 5 and 10 wt % Ag/soft-NOMC catalysts showed considerable improvements by anchoring the Ag NPs on and into a NOMC framework, resulting in a 267% improvement in CO selectivity after 72 h (despite initial losses) compared to commercial Ag NPs. These results demonstrate the promising strategy of anchoring Ag NPs to improve the CO selectivity during prolonged experiments due to the reduced mobility of the Ag NPs and thus enhanced stability.

Cs promoted Ni/ZrO2-Al2O3 catalysts for dry reforming of methane: Promotional effects of Cs for enhanced catalytic activity and stability

Carbon Capture and Utilization (CCU) technologies offer a promising avenue for transforming captured CO2 into valuable products, serving as renewable fuels or precursors for high-value synthesis. This study explores the dry reforming of methane (DRM) as a viable pathway to convert captured CO2 and CH4 into syngas, achieving high equilibrium conversion through the use of suitable catalysts. Conventional nickel-based catalysts are susceptible to carbon deposition, necessitating innovative approaches to enhance their performance. A tubular microreactor was employed to conduct the reforming process at 800 °C, utilizing Cs-promoted Ni catalysts supported on 90 % Al2O3 and 10 % ZrO2-based support composition. Catalyst preparation involved the impregnation technique, and subsequent characterization employed N2-physisorption, XRD, H2-TPR, TGA, TPD, and Raman spectroscopy. The DRM reaction was systematically investigated using the Ni/ ZrO2- Al2O3 catalysts, with a specific focus on the catalytic effects of Cs promotion. Observations revealed that Cs incorporation onto the ZrO2- Al2O3 matrix led to a substantial increase in hydrogen yield and selectivity across all catalyst compositions, accompanied by a significant reduction in carbon deposition on the catalyst surface. The optimal Cs loading, determined to be 3 wt% over Ni/ ZrO2- Al2O3 catalyst, exhibited CO2 and CH4 conversions of 90 % and 87 %, respectively, with an H2/CO yield approaching 1 (0.95). This research underscores the potential of Cs-modified catalysts in enhancing the efficiency of DRM for CCU applications, providing valuable insights into optimizing catalyst formulations for improved performance in carbon transformation processes.

Practicable Artificial Photosynthesis: Its Relevance, Fundamental Challenges and Opportunities

The single main resource for the survival of humankind on this planet is the sunlight and it is freely coming to every home like the life-supporting gas, oxygen, is coming to every individual. When society becomes master in harvesting such a precious, Omnipresent, carbon-neutral, clean, freely and abundantly available renewable energy resource sunlight in a suitable form of chemical energy such as, H2, O2, CO, methanol, gasoline (petrol), diesel, etc., with a minimum conversion efficiency of 10% by using carbon dioxide (CO2) and water (H2O) as energy storing materials, which is referred to as the “Practicable Artificial Photosynthesis (PAP)” process, it can be employed for commercial practice with economic viability to meet all the energy needs of the society without any back-up by electricity generated at thermal power plants by burning greenhouse gas CO2 releasing fossil fuels. In fact, the PAP process is the only option available today for humankind to make energy, environment, economy, and life sustainable on our only habitable planet, Earth. In this article, (i) how the PAP process can change the global energy economy and energy dynamics of the world while solving all the humanities top 10 problems for the next 50 years, (ii) how the entire CO2 gas generated as a waste across the globe at all the major outlets can be eventually converted into petrol (i.e., gasoline) given the fossil fuels cannot sustain our civilization’s economic growth, (iii) the effectiveness of existing CO2 sequestration vs. carbon capture and utilization (CCU) processes, (iv) nature’s response to anthropogenic CO2 gas rise in the atmosphere, (v) steps involved in the realization of a desirable PAP process, (vi) why silicon photovoltaic cell (SPVC) solar panels cannot solve the energy problems of our society considering the outcome of Germany’s Energiewende program, etc., have been meticulously presented and described in this article.

Model-based techno–economic analysis of an integrated synthetic natural gas production system with direct air capture and water electrolysis

In this study, a techno-economic analysis is performed for an integrated system of carbon capture and utilization (CCU). The proposed system utilizes CO2 captured by a direct air capture (DAC) process using a metal–organic framework adsorbent. The captured CO2 is converted into a methane product, or synthetic natural gas (SNG), using hydrogen produced by water electrolysis. Rigorous mathematical models are used for the mass and energy balances in the major components of the proposed integrated system, allowing us to estimate the capital and operating costs and energy consumption. A sensitivity analysis is also performed to identify model parameters that significantly affect the SNG cost. Our analysis indicates that the thermal and electrical energies required to produce SNG are 0.409 MJ/Nm3-SNG and 19.6 kWh/Nm3-SNG, respectively, and the cost of SNG is within the range of 1.43–2.60 $/Nm3-SNG.