Capillary Channels Research Articles

Method of Calculating a Phase Separator with Direct Capillary Channels for the Vapor-liquid Phase Separation of Superfluid Helium

Method of Calculating a Phase Separator with Direct Capillary Channels for the Vapor-liquid Phase Separation of Superfluid Helium

Experimental investigation on the thermal performance of a large-size aluminum vapor chamber for multi-point heat sources

Abstract With the development of electronic information technology, the integration and power of electronic equipment continue to increase. As an efficient heat transfer element, vapor chambers are widely used in the field of heat dissipation of electronic devices. However, greater challenges have been posed in terms of higher heat dissipation capacity, larger size, and lighter weight. Therefore, a large-scale aluminum vapor chamber with a size of 340 mm×295 mm ×7.5 mm is designed for the heat dissipation of multi-point array heat sources. Multiple parallel porous ribs are sintered to form capillary wicking channels and vapor diffusion paths, which efficiently transfer the heat from the middle of the vapor chamber to the cold plate on the two sides. The transient working characteristics and heat dissipation performance under different working conditions are experimentally investigated. The results show that there is obvious temperature instability, which can be suppressed by the tilt of the vapor chamber and the increase of the heating power. Under the tilt condition, the temperature rises in the vertical direction due to the influence of gravity, while the inclination angle has basically no effect. The vapor chamber can work stably at the total heating power of 2100 W with the smallest thermal resistance 0.03 °C/W. The single-point heat flux can reach 7.3W/cm2 for the 128 heat sources. Compared to a traditional vapor chamber, the proposed aluminum vapor chamber provides a thermal management solution for large-size electronic devices with multiple heat sources.

Concentric Capillary Microfluidic Devices Designed for Robust Production of Multiple-Emulsion Droplets.

Multiple emulsions are used as templates for producing functional microcapsules due to their unique core-shell geometry. Employing glass capillary devices with coaxial channels has proven effective in creating uniform multiple-emulsion droplets. However, the use of partially miscible fluids, crucial for microcapsule production, often results in clogging and disrupts the stability of these devices. Here, we introduce innovative capillary microfluidic devices with concentric capillary channels, specifically designed to optimize the production of multiple-emulsion droplets while mitigating issues of precipitation and clogging. The key aspect of these devices is their configuration of two or three concentrically aligned capillaries, which form separate, coaxial microchannels for fluid injection. This unique alignment, achieved through rotational adjustments that leverage the natural off-center positioning of tapered capillaries, facilitates the simultaneous coaxial injection of various fluids into a droplet-forming junction, significantly reducing fluid contact before emulsification. The devices, featuring double and triple concentric capillary channels, consistently produce highly uniform double-, triple-, and quadruple-emulsion droplets with precisely controlled diameters and layer thicknesses. The minimal contact between fluids prior to emulsification in these devices broadens the usable range of fluid combinations, heralding new possibilities in microcapsule development for pharmaceutical and cosmetic applications.

Ray Tracing of the New Multi-Modal X-ray Imaging Beamline PolyX at SOLARIS National Synchrotron Radiation Centre

The aim of the presented research is to evaluate the potential performance of a new bending magnet X-ray beamline—PolyX, designed for microimaging and microspectroscopy at the National Synchrotron Radiation Centre SOLARIS in Krakow. Due to the short beamline length (<15 m), PolyX uses compact polycapillary and single-bounce monocapillary optics for X-ray focusing in the 4–15 keV energy range. Polycapillary optics require a dedicated approach for an efficient simulation of X-ray propagation in multiple capillary channels. Therefore, the PolyX beamline was ray traced by combining XRT (XRayTracer) and polycap libraries. In addition, to estimate the X-ray fluorescence spectra excited by focused beams, Monte Carlo simulations were conducted using XMI-MSIM. All simulations were aimed to estimate the crucial X-ray beam properties, i.e., the flux, the spot size, and the energy spectrum, for monochromatic and polychromatic X-ray beams.

Portable surface acoustic wave device platform coupled with a paper-based capillary fluidics for real-time biosensing applications

Surface acoustic wave (SAW) sensors have emerged as prominent real-time, label-free biosensors with diverse applications in immunoassays and nucleic acid detection. However, widespread adoption in diagnostics has been impeded by challenges such as miniaturization of instrumentation, microfluidics fabrication and high attenuation in liquid environments. In this study we address these limitations by presenting a portable platform capable of real-time monitoring of a SAW microarray chip comprising up to four sensing channels, combined with a novel paper-based capillary flow channel. For the fabrication of a portable, automated and versatile sensor platform, we integrated a microcontroller, RF components, and a micropump for flow control. Calibration procedures ensured accurate measurements for both amplitude and phase, with a low drift rate (0.72 mdB/h and 1.00 mdeg./h, respectively) and high resolution (2.10 mdB and 6.10 mdeg.), indicating stable operation with minimal interface electronics. The capillary flow channel, implemented by confining the fluid on the sensing surface using a nitrocellulose strip, facilitated laminar and continuous sample flow with minimum damping of the acoustic signal. The sensor system was evaluated with two SAW devices at 100 and 200 MHz using glycerol dilutions within the range of 1 % and 70 %, demonstrating real-time monitoring capabilities and linear correlations between amplitude and phase changes. To prove the biosensing and clinical validity of the SAW newly developed system, DNA adsorption on a poly(L-lysine)-graft-poly(ethylene glycol) (PLL-g-PEG) functionalized SAW-surface was demonstrated with a detection limit of 0.001 μg/mL. Our study demonstrates the feasibility of a portable SAW sensor system coupled with a low-cost and replaceable capillary flow channel for real-time monitoring and biomolecular detection.

Photothermal Backscatter Interferometry for Enhanced Detection in Capillary Electrophoresis.

Refractive index (RI) detection using backscatter interferometry (BSI) enables universal detection in capillary electrophoresis (CE). BSI detection is a versatile on-capillary approach that is easily integrated with capillary or microfluidic channels, straightforward to miniaturize, and inexpensive. The focused BSI light source can also double as the excitation source for fluorescence, enabling simultaneous universal (BSI) and specific (fluorescence) signals from the same detection volume. To improve BSI detection and expand orthogonal content, we integrate photothermal absorption with BSI detection. Nonradiative relaxation of an excited analyte releases heat into the surroundings, which modifies both the local RI and conductivity (viscosity) of the analyte zone. We recently showed that the BSI signal is sensitive to both RI and conductivity, which makes photothermal absorption a promising route to signal enhancement. Here, we use coaxially delivered BSI and photothermal absorption beams to characterize BSI, photothermal BSI, and fluorescence detection using the separation of test samples. We show that photothermal absorption leads to 3 orders of magnitude improvement in BSI detection limits at the powers studied and provides new opportunities for studying binding interactions with CE.

Evaporative cooling promotion using macroporous hydrogels with stable water transport and evaporation path

AbstractEvaporative cooling is being re‐evaluated in the context of eco‐systems and environmental friendliness to improve the efficiency of thermoelectric and photovoltaic power generation. One of the essential tasks to improve evaporative cooling performance is the development of materials that can maintain the evaporation path and supply the lost water. Here, we synthesized a macroporous hydrogel by freeze casting at a slow cooling rate. A series of open spaces was designed between the aligned columns of the hydrogel, and water is stably supplied by extensive capillary channels. In a cooling test, it was shown to be effective in reducing the target's equilibrium temperature. As the heat input increased, the cooling effect (that is, the temperature reduction by the hydrogels) tended to increase. In addition, under airflow, the effect was stable, and further enhanced. These results extend design strategies for hydrogel‐based evaporative cooling and offer opportunities to maximize cooling performance by searching for optimal surface shape and exploiting airflow conditions.

Motility and pairwise interactions of chemically active droplets in one-dimensional confinement.

Self-propelled droplets serve as ideal model systems to delve deeper into understanding the motion of biological microswimmers by simulating their motility. Biological microorganisms are renowned for showcasing a diverse array of dynamic swimming behaviors when confronted with physical constraints. This study aims to elucidate the impact of physical constraints on swimming characteristics of biological microorganisms. To achieve this, we present observations on the individual and pairwise behavior of micellar solubilized self-propelled 4-cyano-4'-pentyl-biphenyl (5CB) oil droplets in a square capillary channel filled with a surfactant trimethyl ammonium bromide aqueous solution. To explore the effect of the underlying Péclet number of the swimming droplets, the study is also performed in the presence of additives such as high molecular weight polymer polyethylene oxide and molecular solute glycerol. The capillary confinement restricts droplet to predominantly one-dimensional motion, albeit with noticeable differences in their motion across the three scenarios. Through a characterization of the chemical and hydrodynamic flow fields surrounding the droplets, we illustrate that the modification of the droplets' chemical field due to confinement varies significantly based on the underlying differences in the Péclet number in these cases. This alteration in the chemical field distribution notably affects the individual droplets' motion. Moreover, these distinct chemical field interactions between the droplets also lead to variations in their pairwise motion, ranging from behaviors like chasing to scattering.

A single-particle mechanofluorescent sensor

Monitoring mechanical stresses in microchannels is challenging. Herein, we report the development of a mechanofluorescence sensor system featuring a fluorogenic single polydiacetylene (PDA) particle, fabricated using a co-flow microfluidic method. We construct a stenotic vessel-mimicking capillary channel, in which the hydrodynamically captured PDA particle is subjected to controlled fluid flows. Fluorescence responses of the PDA particle are directly monitored in real time using fluorescent microscopy. The PDA particle displays significant nonlinear fluorescence emissions influenced by fluid viscosity and the presence of nanoparticles and biomolecules in the fluid. This nonlinear response is likely attributed to the torsion energy along the PDA’s main chain backbone. Computational fluid dynamic simulations indicate that the complete blue-to-red transition necessitates ~307 μJ, aligning with prior research. We believe this study offers a unique advantage for simulating specific problematic regions of the human body in an in vitro environment, potentially paving the way for future exploration of difficult-to-access areas within the body.

Expression of Concern for article entitled “Effect of nanoparticles shape on the cooling process of a lithium ion battery in geometry with capillary channels in the presence of phase change material”

Expression of Concern for article entitled “Effect of nanoparticles shape on the cooling process of a lithium ion battery in geometry with capillary channels in the presence of phase change material”

Agrochemical Characteristics of Light-Gray-Brown Salt Characteristic Soils of the Kura Part of Azerbaijan

Various methods of agrotechnical and reclamation measures related to soil salinization in the Kura-Araz lowland are considered. The focus is on deep plowing, which breaks the capillary channels of the soil, reduces evaporation and prevents further salinization. The need for proper soil cultivation before sowing and adaptation of sowing norms in saline areas to ensure optimal plant growth is highlighted. An integrated approach to improving soil fertility is described, including the application of organic and mineral fertilizers, as well as haymaking in the periods between irrigations. Particular emphasis is placed on the use of gypsum as a means to reduce absorbed sodium and improve soil structure, especially in areas with high salinity levels. The dosage of gypsum varies depending on the degree of soil salinity and can range from 5 to 15 t/ha. The authors emphasize that adequate water management and avoidance of over-irrigation are critical to preventing soil salinization.

A clean, simple, and efficient method for preparing vibration-reducing low-carbon bamboo building materials with high strength

Large-format bamboo panels prepared by bamboo flattening are adhesive-free and retain the natural structure of bamboo, making them ideal materials for interior architecture. However, due to poor dimensional stability and vibration-reducing properties, flattened bamboo easily deforms and vibrates when applied to building walls and floors due to ambient humidity changes or external excitation, impacting both comfort and structural safety. In this work, a clean, efficient, and simple densification process for flattened bamboo is developed to prepare low-carbon bamboo building materials with enhanced vibration reduction. The results indicated that the densification process reduced the vibration intensity of the flattened bamboo under excitation, changed its vibrational modes, avoided low-frequency resonance, and improved its vibration reduction and suppression properties. The dynamic stiffness of the densified bamboo increased to 3.23–3.63 times, while the root mean square (RMS) and transfer function value decreased by 20.84 % and 62.5 %, respectively. The MOE (16.2 GPa) and MOR (276 MPa) increased to 2.73 times and 2.22 times, respectively. The densified bamboo met the dimensional stability requirements of the GB/T 18102–2020 building material standards. Compared with damping, the increased stiffness played the primary role in improving the vibration-reducing properties of densified bamboo. The hydrothermal mechanical treatment changed the structure and composition. From a macroscopic perspective, the gradient structure of the vascular bundles and parenchyma cells was gradually plasticized and homogenized, compacting large capillary pores and channels such as those in parenchyma cells, vessels, and sieve tubes. On a microscopic level, defects such as pits, intercellular spaces, and micropores were filled, and microfibrils between the middle lamellae were tightly stacked, forming a mechanically-interlocked structure. At the molecular scale, there was an increase in the crystallinity and orientation of cellulose molecular chains, accompanied by an increase in hydrogen bond density. The densified bamboo developed in this study shows good application potential for vibration-reduction structures such as buildings and rail transit.

A New Capillary-Channel Agarose Sponge Assembled with Deep Eutectic Solvent Based Magnetic Fluid for Rapid Hemostasis and Prevention of Bacterial Infection.

A new composite sponge assisted by magnetic field-mediated guidance was developed for effective hemostasis. It was based on polydopamine capillary-channel agarose (PDA-CAGA) sponge as matrix; meanwhile, the combination of deep eutectic solvent (DES, choline chloride:glycerol = 1:1, M/M)-dispersed Fe3O4 nanoparticles after fabrication by tannic acid (DES-Fe3O4@TA) was applied as hemostatic magnetic fluid. This sponge had oriented and aligned capillary channels realized by a 3D printed pattern, which endowed them with obvious shape memory and liquid absorption performance. Computational simulation was performed to describe the fluid status in channels; DES-Fe3O4@TA exhibited good magnetic properties, fluidity, and stability. In addition, the sponge driven to react rapidly with the bleeding site under the effect of a magnetic field presented a shorter hemostasis time (reduced by 85.02% in the tail and 81.07% in the liver of rats) and less blood loss (reduced by 97.08% in the tail and 91.50% in the liver) than those of medical gelatin sponge (GS). Meanwhile, the multifunctional material also exhibited better biocompatibility, procoagulant performance, and significant inhibition on S. aureus and E. coli than GS. As a whole, this work proposed a new strategy for rapid hemostasis by designing a magnetic field assisted composite bacteriostatic material, which also expanded the applications of green solvents in the clinical management field.

Novel 3D textile structures and geometries for electrofluidics.

The integration of microfluidics with electric field control, commonly referred to as electrofluidics, has led to new opportunities for biomedical analysis. The requirement for closed microcapillary channels in microfluidics, typically formed via complex microlithographic fabrication approaches, limits the direct accessibility to the separation processes during conventional electrofluidic devices. Textile structures provide an alternative and low-cost approach to overcome these limitations via providing open and surface-accessible capillary channels. Herein, we investigate the potential of different 3D textile structures for electrofluidics. In this study, 12 polyester yarns were braided around nylon monofilament cores of different diameters to produce functional 3D core-shell textile structures. Capillary electrophoresis performances of these 3D core-shell textile structures both before and after removing the nylon core were evaluated in terms of mobility and bandwidth of a fluorescence marker compound. It was shown that the fibre arrangement and density govern the inherent capillary formation within these textile structures which also impacts upon the solute analyte mobility and separation bandwidth during electrophoretic studies. Core-shell textile structures with a 0.47mm nylon core exhibited the highest fluorescein mobility and presented a narrower separation bandwidth. This optimal textile structure was readily converted to different geometries via a simple heat-setting of the central nylon core. This approach can be used to fabricate an array of miniaturized devices that possess many of the basic functionalities required in electrofluidics while maintaining open surface access that is otherwise impractical in classical approaches.

Validation of Fluid Flow Speed Behavior in Capillary Microchannels Using Additive Manufacturing (SLA Technology)

This research explores fluid flow speed behavior in capillary channels using additive manufacturing, focusing on stereolithography (SLA). It aims to validate microchannels fabricated through SLA for desired fluid flow characteristics, particularly capillary-driven flow. The methodology involves designing, fabricating, and characterizing microchannels via SLA, with improvements such as an air-cleaning step facilitating the production of microchannels ranging from 300 to 1000 µm. Experimental validation assesses fluid flow speed behavior across channels of varying dimensions, evaluating the impact of channel geometry, surface roughness, and manufacturing parameters. The findings affirm the feasibility and efficacy of SLA in producing microchannels with consistent and predictable fluid flow behavior between 300 to 800 µm. This study contributes insights into microfluidic device fabrication techniques and enhances the understanding of fluid dynamics in capillary-driven systems. Overall, it underscores the potential of additive manufacturing, specifically SLA, in offering cost-effective and scalable solutions for microfluidic applications. The validated fluid flow speed behavior in capillary channels suggests new avenues for developing innovative microfluidic devices with improved performance and functionality, marking a significant advancement in the field.

Oriented Interpenetrating Capillary Network with Surface Engineering by Porous ZnO from Wood for Membrane Emulsification.

Membrane emulsification technology has garnered increasing interest in emulsion preparation due to controllable droplet size, narrower droplet size distribution, low energy consumption, simple process design and excellent reproducibility. Nevertheless, the pore structure and surface engineering in membrane materials design play a crucial role in achieving high-quality emulsions with high throughput simultaneously. In this work, an oriented interpenetrating capillary network composed of highly aligned and interconnected wood cell lumens has been utilized to fabricate an emulsion membrane. A novel honeycomb porous ZnO layer obtained by a seed prefabrication-hydrothermal growth method was designed to reconstruct wood channel surfaces for enhanced microfluid mixing. The results show that through the unique capillary mesh microstructure of wood, the emulsion droplets were smaller in size, had narrower pore-size distribution, and were easy to obtain under high throughput conditions. Meanwhile, a well-designed ZnO layer could further improve the emulsion quality of a wood membrane, while the emulsifying throughput is still maintained at a higher level. This demonstrates that the convection process of the microfluid in these wood capillary channels was intensified markedly. This study not only develops advanced membrane materials in emulsion preparation, but also introduces a brand-new field for functional applications of wood.

Self-aligned, inkjet-printed resistors on flexible substrates with excellent mechanical stability, high yield, and low variance

Resistors are basic yet essential circuit components that must be fabricated with high precision at low cost if they are to be viable for flexible electronic applications. Inkjet printing is one of many additive fabrication techniques utilized to realize this goal. In this work, a process termed self-aligned capillarity-assisted lithography for electronics (SCALE) was used to fabricate inkjet-printed resistors on flexible substrates. Capillary channels and reservoirs imprinted onto flexible substrates enabled precise control of resistor geometry and straightforward alignment of materials. More than 300 devices were fabricated using poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) as the resistive material and silver as the electrode material. By varying PEDOT:PSS ink formulation and resistor geometry, resistances spanning from 170 Ω to 3.8 MΩ were achieved. Over 98% of devices were functional and the relative standard deviation in resistance ranged from 3% to 18% depending on resistor length and ink composition. The resistors showed no significant change in resistance after 10 000 cycles of bend testing at 1.6% surface tensile strain. In summary, this work demonstrated a fully roll-to-roll compatible process for inkjet printing resistors with superior properties.

Design and Implementation of Large-Scale Hard Rock AMD Dewatering and REE Production

To develop a domestic Rare Earth Elements (REE) supply chain the Hydraulic Preconcentrate (HPC) produced at the Horseshoe bend treatment plant (HSB) was evaluated as a potential source for feedstock. After the clarifiers were flipped to the desired pH set points, a total of 24 Geobags were repeatedly filled and allowed to passively dewater. The Geobags evaluated were comprised of a mix of Woven, Non-woven, and Capillary Channel Fiber (CCF). The bags were constructed with either a composite of woven and nonwoven or only woven geotextile. Half of the bags of both types also included “fins” made of CCF to evaluate their impact on dewatering. Column Filtration Tests (CFTs) were performed onsite to provide laboratory value for hydraulic conductivity. Throughout their dewatering, the geobags were sampled to determine their rate of dewatering. Influent samples from HSB were also tested to produce a Specific Gravity (Gs), via pycnometer testing and Grain Size Distribution (GSD), via sieve and hydrometer analysis. The dewatering ability of the geobags was high regardless of bag material with a mean total solids percentage of approximately 40% across all samples after only one month of dewatering. The GSD performed on the HPC is gap graded with most particles having a diameter of approximately 0.5-0.05mm. Hydraulic conductivity values for the filter cakes during Column Filtration Testing ranged from 0.5 to 2.5 meters/day. This data will help to guide development of future large-scale HPC dewatering and the parametric design of an REE oxide production plant at the HSB site.

Programmable Water Sorption through Linker Installation into a Zirconium Metal-Organic Framework.

Hydrolytically stable materials exhibiting a wide range of programmable water sorption behaviors are crucial for on-demand water sorption systems. While notable advancements in employing metal-organic frameworks (MOFs) as promising water adsorbents have been made, developing a robust yet easily tailorable MOF scaffold for specific operational conditions remains a challenge. To address this demand, we employed a topology-guided linker installation strategy using NU-600, which is a zirconium-based MOF (Zr-MOF) that contains three vacant crystallographically defined coordination sites. Through a judicious selection of three N-heterocyclic auxiliary linkers of specific lengths, we installed them into designated sites, giving rise to six new MOFs bearing different combinations of linkers in predetermined positions. The resulting MOFs, denoted as NU-606 to NU-611, demonstrate enhanced structural stability against capillary force-driven channel collapse during water desorption due to the increased connectivity of the Zr6 clusters in the resulting MOFs. Furthermore, incorporating these auxiliary linkers with various hydrophilic N sites enables the systematic modulation of the pore-filling pressure from about 55% relative humidity (RH) for the parent NU-600 down to below 40% RH. This topology-driven linker installation strategy offers precise control of water sorption properties for MOFs, highlighting a facile route to design MOF adsorbents for use in water sorption applications.

Vat photopolymerization of large-aperture high performance SiC mirror through multiphase carbon infiltration modification

Vat photopolymerization technique (VPP) shows advantages in rapidly preparation of complex structure silicon carbide matrix composites (Si/SiC). However, compared with traditional preparation technology, the properties of Si/SiC prepared via VPP are insufficient due to the presence of residual Si and carbon. Herein, the reaction mechanism of Si and carbon were systematically studied. Multiphase carbon was introduced into porous SiC preform via carbon precursor infiltration pyrolysis (CPIP) and graphitization methods. The content of residual Si was significantly decreased after reactive melt infiltration (RMI), and the residual carbon was eliminated through partial graphitization of the carbon. The influence mechanism of the carbon content and crystallinity on the reaction process of Si and carbon was studied. It suggested that the diameter of capillary channel and crystallinity of carbon are the main factors affecting residual carbon content in the final body after RMI. The sample with multiphase carbon achieved the best performance after RMI. The residual Si content, bulk density, flexural strength and elastic modulus are 11.58%, 3.04 g/cm3, 280.09 MPa and 355.48 GPa. In addition, the lowest coefficient of linear expansion was 2.39×10−6 K−1. Finally, a large-aperture SiC mirror with a diameter of 500 mm was prepared. Therefore, this research lays a foundation for promoting the application of large-aperture Si/SiC prepared via 3D printing.