Motivated by the significance and complexity of exploring spatiotemporal patterns - regions within an urban environment, particularly in the context of extreme heat events- this research analyzes meteorological time series through complex network analysis. The data collected for the examination area is focused on Athens, Greece, and covers sections of the city’s urban landscape. The data was obtained from the Copernicus observation component of the European Union. Initially, the time series are transformed into networks using correlation network methodology, followed by examination of the discriminative capability of the topological measures of networks degree and modularity as community - region detection methods. Of particular interest is that our findings suggest that the proposed complex network analysis can lead to the extraction of spatial urban regions closely linked to land use and building heights in corresponding areas. These results may help investigate the spatial variability of heat in the urban environment and inform urban planning and management strategies in policy decision-making regarding the intensity of urban heat throughout the city and the planning of climate change adaptation strategies.