Zinc sorption/desorption phenomena in soils are important in determining the bioavailability of soil Zn to plants. Some soils of the Canterbury Plains, New Zealand are regarded as potentially Zn deficient, however there is little information available for these soils, or in fact for soils in general, on the factors that influence the sorption and desorption of soil Zn. In order to increase our understanding of soil Zn sorption/desorption phenomena, and hence improve our understanding of Zn bioavailability, the effect of Zn concentration and length of contact time on Zn sorption by, and desorption from, four surface soils from the Canterbury Plains has been examined. Zinc sorption isotherms were derived by sorption of Zn from solutions containing a range of Zn concentrations equivalent to 6, 12, 18, 24 and 30 μg g − 1 soil in the presence of a background electrolyte, 0.01 M Ca(NO 3) 2. Zinc desorption isotherms were derived from the Zn desorbed (μg g − 1 soil) after each of ten desorption periods, carried out by sequentially equilibrating single soil samples in Zn-free 0.01 M Ca(NO 3) 2. To establish changes in the desorbability of added Zn as a result of its reaction with soil, an aerobic incubation technique was used. The amount and pattern of release of Zn was markedly different between the experimental soils, indicating their differing capacities for the continuous supply of Zn to the soil solution. The cumulative desorption of Zn occurred more rapidly with the Lismore and Summit soils (lower Zn retention capacity) than with the Temuka and Waimakariri soils. Added Zn was found to desorb back readily from the Lismore and Summit soils, and Zn desorption appeared to closely follow the original sorption isotherms irrespective of the concentration of Zn added to these soils. This suggests that in these soils, desorption reactions could be described by the original sorption isotherm. The Temuka and to a lesser extent the Waimakariri soil, which have a higher capacity to retain added Zn showed poor reversibility of Zn sorption, there being a hysteresis effect in the desorption of recently sorbed Zn. For three of the four soils studied, the longer the contact period that elapsed before starting desorption, the less complete the Zn desorption that was achieved.
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