Calorimetry Tests Research Articles

Flame retardant, transparent, low dielectric and low smoke density EP composites implemented with reactive flame retardants containing P/N/B

For the purpose of investigating the modified flame-retardant epoxy resin (FREP) with the low smoke density release during combustion, the flame retardant containing P/N/B elements named DBT was synthesized with the raw materials of 4-Acetylphenylboronic acid, 3,5-diaminotriazole and DOPO. The DBT was added as a co-curing agent to an amine-cured epoxy resin system, and based on the DSC results of the resin, it was revealed that -NH- in the structure of the DBT was capable of facilitating EP curing. With the introduction of DBT, the transparency of FREP samples was slightly affected. On account of the excellent flame retardancy exerted by the DBT in the FREP system, the FREP samples reached the V-0 grade in UL-94 testing with an LOI of 35.9% at 5 wt% DBT addition. Meanwhile, the results of the cone calorimetry test demonstrated that in comparison with the epoxy resin, the PHRR, THR and av-EHC of the EP/DBT7.5 sample decreased by 34.0%, 35.4% and 18.68%, respectively. The DBT was effective in reducing the smoke density of EP, and the EP/DBT7.5 sample attained the HL1 level for DS (4) and VOF4. The chemical analyses for residual char revealed that DBT was mainly employed for flame retardancy and smoke suppression by forming P/B-containing chars in the condensed phase. There was no loss of mechanical properties of the FREP samples as the rigid groups were present in the DBT structure. Furthermore, it was noted that the FREP samples exhibited a decrease in dielectric loss and dielectric constant as the content increased.

A DNA Aptamer for 2-Aminopurine: Binding-Induced Fluorescence Quenching.

2-Aminopurine (2AP) is a fluorescent analog of adenine, and its unique properties make it valuable in various biochemical and biotechnological applications. Its fluorescence property probes local dynamics in DNA and RNA because stacking with the surrounding bases quench its fluorescence. 2AP-labeled DNA or RNA sequences have been used for the detection of genetic mutations, viral RNA, or other nucleic acid-based markers associated with diseases like cancer and infectious diseases. In this study, we isolated aptamers for 2AP using the library immobilization capture-SELEX technique. A dominating aptamer family was isolated after 15 rounds of selection. The Kd values for the most abundant 2AP1 aptamer are 209 nM in a fluorescence assay and 72 nM in an isothermal titration calorimetry test. A 32 nM 2AP limit of detection was tested based on its intrinsic fluorescence change upon aptamer binding. Additionally, we conducted some mutation analysis. Furthermore, we tested the selectivity of this aptamer and discovered that it can bind adenine and adenosine with approximately 100-fold lower affinity than 2AP.

Belite–ye’elimite–ferrite cements produced from London Clay

London Clay (LC) is generated in significant quantities from major infrastructure development projects within and around London, UK. Excavated LC spoils are typically landfilled or used for landscaping purposes with minimal value. This study investigates the feasibility of producing belite–ye’elimite–ferrite (BYF) cements using LC in combination with kaolin or low-grade bauxite. Six cement clinkers with varying compositions were synthesised at 1300°C. The phase composition of the synthesised clinkers was quantified using X-ray diffraction analysis (XRD) coupled with Rietveld refinement. The hydration behaviour, phase assemblage evolution and mechanical performance of the cements were examined using isothermal calorimetry, XRD, thermogravimetric analysis and compressive strength testing, respectively, up to 90 days of curing. It is demonstrated that LC can be used either on its own or with kaolin or low-grade bauxite to produce BYF cements with a wide range of composition: 31 to 64 wt% belite, 9.3 to 27 wt% ye’elimite and 2.1 to 31 wt% ferrite. The use of LC as the sole alumina source resulted in low compressive strength at early stages. Nevertheless, the strength developed over time, reaching 27.8 MPa at 90 days (0.5 w/b). Possible approaches to develop LC further for producing viable BYF cements are discussed.

Temperature and rate dependent shear characterization and modeling of spread-tow woven Flax/PP composite laminates

This paper investigates the in-plane shear behavior of spread-tow woven structured flax fiber-reinforced polypropylene composites, focusing on temperature and displacement rate effects. For this aim, the study includes bias-extension experiments to characterize the shear behavior of the material. Several experiments were conducted at different displacement rates and temperature levels. The temperature levels were chosen to encompass the material's behavior during solid and molten-state thermoforming, given the melting and decomposition temperatures acquired from differential scanning calorimetry and thermogravimetric analysis tests, respectively. A new fixture was designed and manufactured to allow pre-heating of the oven and rapid placement of the samples, which in turn, prevents their degradation for the time duration required to reach a uniform temperature distribution in the oven. During the experiments, the 3D digital image correlation technique accurately measured local deformations and strains on the specimen's surface under varying conditions. Further, a finite element model is developed, incorporating a fiber reorientation algorithm with a hypo-elastic shear model to simulate the material's temperature and rate-dependent behavior. The finite element shear angle distributions, as well as the shear angle-force and shear angle-displacement curves, are compared with the Digital Image Correlation (DIC) data and load measurements for different test conditions, showing good agreement between the numerical and experimental approaches.

High rubber elasticity and thermal conductivity in plasticized polyvinyl chloride film with flame retardancy and smoke suppression properties

AbstractFor hydrogenated nitrile‐butadiene rubber (HNBR) modified polyvinyl chloride (PVC), magnesium hydroxide and antimony trioxide are frequently employed as flame retardants. Fume silica is thought to be useful reinforced agent for rubber as well as efficient flame retardant for polymer‐based composites. The plasticized PVC and HNBR blend in this work were combined with three fillers mentioned above to create rubber‐plastic composites that performed well overall, with a notable improvement in combustion. The limiting oxygen index of the composites increased from 23.7% to 33.8% with no droplets falling during combustion, the smoke density rating decreased from 23.8% to 7.9%, and the maximum smoke density dropped from 95.5% to 15.5%. The cone calorimetry test findings revealed that the three fillers simultaneously prevented the emission of smoke and heat from combustion. High thermal conductivity is typically linked to excellent flame retardancy. The thermal conductivity of composites rose from 0.193 to 0.583 W m−1 K−1 with the addition of fillers. Furthermore, the low glass transition temperature and permanent set of improved composites reflect its softness and rubber elasticity. Thermogravimetric analysis was used to examine the thermal stability of the composites in nitrogen and air, and the results indicated the addition of fillers improved the thermal stability.

Experimental Investigation on the Mechanical and Dynamic Thermomechanical Properties of Polyether Ether Ketone Based on Fused Deposition Modeling

In this work, the mechanical and dynamic thermomechanical properties of PEEK based on FDM are experimentally investigated and evaluated comprehensively. The tensile failure mechanism of PEEK prepared by FDM and extrusion modeling (EM) was analyzed by fracture morphology observation. By conducting a differential scanning calorimetry (DSC) test, the crystallinity of PEEK prepared by FDM and EM was measured. The dynamic thermomechanical properties of PEEK were tested and analyzed by dynamic mechanical analysis (DMA). For FDM-prepared PEEK samples, the yield strength and elongation were 98.3 ± 0.49 MPa and 22.86 ± 2.12%, respectively. Compared with the yield strength of PEEK prepared by EM, the yield strength of PEEK prepared by FDM increased by 65.38%. The crystallinity of FDM-prepared and EM-prepared samples was calculated as 34.81% and 31.55%, respectively. Different processing methods resulted in differences in the microscopic morphology and crystallinity of two types of PEEK parts, leading to differences in mechanical properties. The internal micropores generated during the FDM processing of PEEK significantly reduced the elongation. Moreover, according to the DMA results, the glass transition activation energy of PEEK was obtained as ΔE = 685.07 kJ/mol based on the Arrhenius equation. Due to the excellent mechanical properties of PEEK prepared by FDM processing, it is promising for high-performance polymer applications in different fields.

Evaluating passive PCM performance in building envelopes for semi-arid climate: Experimental and numerical insights on hysteresis, sub-cooling, and energy savings

This study evaluates the performance of macro-encapsulated Phase Change Materials (PCMs) integrated into building envelopes for semi-arid climates, focusing on typical Moroccan construction using hollow concrete blocks. The primary objective is to assess the discrepancies between experimental and numerical analyses, particularly in hysteresis, sub-cooling, and energy savings. Given the widespread reliance on numerical tools like EnergyPlus for PCM simulations, the accuracy of manufacturer-provided latent heat values is investigated. The methodology involves constructing two identical test buildings, one equipped with PCM panels and another as a reference. Experimental data were collected in June 2023, assessing temperature fluctuations and energy savings. Differential Scanning Calorimetry (DSC) tests at varying scanning rates were conducted to analyze PCM behavior, including hysteresis and sub-cooling effects. Numerical simulations were then performed to compare energy performance. Besides, the results reveal that sub-cooling significantly limits PCM efficiency, with only 43 % of the PCM's latent heat capacity utilized. At the same time, hysteresis was found to be negligible in the field test. Cooling energy consumption was reduced by 20 %, with a corresponding 2.3 °C reduction in temperature fluctuations. However, the PCM's latent heat potential is underutilized due to sub-cooling. This research underscores the need for conducting DSC measurements at specific scanning rates to reflect regional climate conditions and suggests that simulation models should adjust latent heat utilization of the PCM. The study advocates for the use of composite PCMs, which could mitigate sub-cooling and enhance overall performance. These findings contribute to improving PCM integration in passive building designs, offering practical recommendations for better energy efficiency in semi-arid climates.

Pyrolysis models for pressure treated wood and wood–plastic composite

AbstractPressure treated wood (PTW) and wood–plastic composites such as Trex® are popular materials for the construction of decks and other auxiliary structures, which are known to significantly contribute to spread of wildland fires into communities. In this work, representative samples of these materials were studied to determine their pyrolysis and combustion properties to enable simulation of fire growth on the surface of these building products. The pyrolysis property development process followed a well‐established hierarchical approach where thermogravimetric analysis, differential scanning calorimetry, and microscale combustion calorimetry were used to parametrize kinetics and thermodynamics of the thermal decomposition and combustion, while controlled atmosphere pyrolysis and cone calorimetry tests performed on coupon‐sized samples were used to parameterize thermal transport properties and validate performance of the fully parametrized pyrolysis models. PTW decomposition was captured using four sequential reactions with one additional reaction used to model vaporization of water. Trex® board was found to consist of two distinct layers: a thin outer layer and an internal core. The pyrolysis model for this material was constructed using some known properties of high‐density polyethylene (PE) and the properties of PTW determined in this work. The outer layer was defined in the model to consist of PE and an inert additive, while the core was defined as a blend of PE and wood particles, which kinetics and thermodynamics of the thermal decomposition and combustion were successfully captured using the model developed for PTW.

The Study on Synthesis and Characterization of Insensitive Energetic Materials Based on 5‐(5‐Nitro‐1H‐1,2,4‐Triazol‐3‐yl)‐1H‐Tetrazole

ABSTRACTThe design and synthesis of insensitive energetic materials are a necessary and challenging work. The synthesis of novel nitrogen‐rich salts based on 5‐(5‐Nitro‐1H‐1,2,4‐triazol‐3‐yl)‐1H‐tetrazole (H2NTT) has been presented. Structural characterization of these two salts was accomplished by utilizing NMR, MS, IR spectroscopy, and X‐ray diffraction. The standard heats of formation were calculated, and the differential scanning calorimetry (DSC) and sensitivity test were carried out. Their detonation performances were estimated by EXPLO 5 program. These newly synthesized salts showed highly positive heat of formation and low sensitivity. It is noteworthy that the diaminoguanidine salt b exhibited good detonation performance superior to traditional explosive TNT (Trinitrotoluene), making it a prospective candidate for insensitive energetic material.

Evaluating the Net Energy Requirements for Maintenance Based on Indirect Calorimetry and Heart Rate Monitoring in Gestating Sows

The objectives of this study were (1) to determine the net energy requirements for the maintenance of gestating sows based on indirect calorimetry, and (2) to explore the feasibility of predicting the net energy requirements for the maintenance of gestating sows based on daily heart rate monitoring. In Exp. 1, six Landrace × Yorkshire crossbred reproductive sows with an initial body weight of 229.5 ± 14.9 kg at d 56 of gestation were randomly assigned to six diverse energy feeding levels using a 6 × 6 Latin square design. The experimental diet was formulated using corn, soybean meal, and wheat bran as major ingredients, and the six feeding levels were set as 1.2, 1.4, 1.6, 1.8, 2.0, and 2.2 times metabolizable energy for maintenance (100 kcal ME/kg BW0.75·d−1), respectively. The animal trial lasted for six periods with 9 days per period, encompassing 5 days of adaptation, 3 days of calorimetry in fed state, and 1 day of calorimetry in fasting state. In Exp. 2, six Landrace × Yorkshire crossbred pregnant sows with an initial body weight of 232.5 ± 12.5 kg at d 64 were fed a corn–soybean meal diet. All sows were tested in a respiratory calorimetry chamber for a 4 day calorimetry test. The heat production of the gestation sows was measured every 5 min using indirect calorimetry, and the heart rate of the gestating sows was recorded every minute using a belt-shape monitor. The results showed that the net energy requirements for the maintenance of gestating sows significant increased as the gestational stage progressed (p < 0.05), and a linear regression model revealed the average net energy requirement for the maintenance of gestating sows was 410 kJ/BW0.75 d−1 during late gestation (days 70–110). Moreover, the average heart rate of the gestating sows was 84 bpm, and the mathematical model developed to predict the net energy requirements for the maintenance of gestating sows was NEm(kcal/h)=19901+exp⁡[136−HR(bpm)43]. In conclusion, the average net energy requirement for the maintenance of sows during late gestation was 410 kJ/BW0.75 d−1, and the utilization of the heart rate monitoring method was found to provide a relevant, accurate prediction for the net energy requirements of sows.

Understanding Isoniazid Crystals Agglomeration Through Quality by Design and Artificial Neural Network Analysis

Introduction: The aims of this study were to determine and govern critical sources of variability in the process and to investigate the effect of excipients and processing conditions on the critical quality attributes (CQAs) of isoniazid (INZ) crystal agglomerates using a quality-bydesign (QbD) paradigm along with risk-based approach. Methods: The QbD paradigm is thoroughly exercised to determine the CQAs and to, link these CQAs to agglomerate properties and to recognize potentially significant input variables. Considering this, a risk assessment tool was executed with different excipients and processing conditions to define their effect on CQAs of agglomerates. Potential risk factors were recognized using an Ishikawa diagram and then investigated using principal component analysis and an artificial neural network. After that, all agglomerates were optimized using the design of the experiment. Results: The optimized INZ crystal agglomerates were characterized using various tools such as X-ray diffractometry, Fourier transform infrared spectroscopy, scanning electron microscopy, differential scanning calorimetry, gas chromatography, and stability testing. These characterizations confirmed that INZ did not undergo any structural modifications in the agglomerates. Conclusion: The results indicate that the QbD principles and risk assessment tool provide a valuable means to fully understand directly compressible INZ crystal agglomerates, which could be considered an exceptional alternative to the granulation method.

A P/Si-containing flame retardant towards simultaneous improvement of the toughness, transparency and fire safety of polycarbonate

Polycarbonate (PC) is a commonly used engineering plastic, but its poor flame retardancy limits its use. In this study, a DOPO-based flame-retardant (DOPO-TMTA) containing P and Si elements was synthesized via a simple method involving 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and 2, 4, 6-trivinyl-2, 4, 6-trimethylcyclotrisiloxane (TMTA). The PC/mDOPO-TMTA (m = 4, 6, 8) composites were prepared by melt blending PC with different loadings of DOPO-TMTA. The prepared PC/DOPO-TMTA composites had excellent flame retardancy while maintaining good transparency. The limiting oxygen index (LOI) of PC/8DOPO-TMTA reached 32.5 % and achieved a UL-94 V-0 rating. Moreover, cone calorimetry tests revealed that, compared with those of pure PC, the peak heat release rate (PHRR) and total heat release (THR) of PC/8DOPO-TMTA decreased by 39.0 % and 38.1 %, respectively. Compared with pure PC, PC/mDOPO-TMTA also maintained good mechanical properties, and the tensile and impact strengths were slightly improved. The synergistic flame retardancy of DOPO-TMTA on P/Si elements for the PC matrix was revealed by condensed phase and gas phase product analysis. This work provides a good reference for the preparation of PC composites with high transparency and excellent comprehensive properties.

Microstructure and martensitic transformation in quaternary NiTiHfV alloy

The effect of age hardening on the microstructure, martensitic transformation behavior, and shape memory properties of the (Ni50Ti30Hf20)95V5 alloy was investigated by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, differential scanning calorimetry, microhardness, and bending tests. The results demonstrate a significant influence of V addition on the microstructure of the alloy. V addition leads to the formation of a (Ni,V)2(Ti,Hf)-type Laves phase, which coexists with B19‘ martensite at room temperature. Aging at 550 °C results in precipitation hardening due to the formation of nano-scale orthorhombic H-phase, with the peak hardness observed after 3 h of aging. The alloy at peak hardness state exhibits higher transformation strain and lower unrecovered strain compared to the solution-treated sample. The aged sample achieves a maximum transformation strain of 1.56% under 500 MPa.

Maternal ingestion of cannabidiol (CBD) in mice leads to sex-dependent changes in memory, anxiety, and metabolism in the adult offspring, and causes a decrease in survival to weaning age

RationaleThe consequences of perinatal cannabidiol (CBD) exposure are severely understudied, but are important, given its widespread use and believed safety as a natural supplement. ObjectiveThe objective of this study was to test the health, metabolic, and behavioral consequences of perinatal CBD exposure on dams and their offspring raised to adult. MethodsPrimiparous female C57BL/6 J mice were orally administered 100 mg/kg CBD in strawberry jam to expose offspring during gestation, lactation, or both using a cross-fostering design. Adult offspring were metabolically profiled using indirect calorimetry and intraperitoneal glucose tolerance testing. Adults were behaviorally phenotyped, video recorded, and mouse position tracked using DeepLabCut. ResultsCBD was detected in maternal plasma using LC-MS 10-min post consumption (34.2 ± 1.7 ng/ul) and peaked within 30 min (371.0 ± 34.0 ng/ul). Fetal exposure to CBD significantly decreased survival of the pups, and decreased male postnatal development, but did not alter litter size, maternal body weight or pup birth weight. We observed many sex-dependent effects of perinatal CBD exposure. Exposure to CBD during gestation and lactation increased meal size, caloric intake, and respiratory exchange ratio for adult male offspring, while exposure during lactation decreased fasting glucose, but had no effect on clearance. Adult female offspring exposed to CBD during lactation showed increased drink size. Perinatal CBD exposure increased obsessive compulsive- and decreased anxiety-like behaviors (marble burying, light-dark box, elevated-plus maze) in female mice, decreased long-term object memory in male mice, and had no effect on attention tasks for either sex. ConclusionsWe conclude that orally-administered CBD during pregnancy affects behavior and metabolism in a sex-dependent manner, and mice are differentially sensitive to exposure during gestation vs. lactation, or both. Because long-term changes are observed following perinatal exposure to the drug, and exposure significantly decreases survival to weaning, more research during development is warranted.

Investigating Intumescent Flame-Retardant Additives in Polyurethane Foam to Improve the Flame Resistance and Sustainability of Aircraft Cabin Materials

Polyurethane (PU) foam has a high flammability and is widely used in aircraft interiors, presenting a significant danger to occupants. This study analysed three composite intumescent flame-retardant (IFR) coatings for flexible PU foam; expandable graphite (EG), ammonium polyphosphate (APP) and alginate (AG). The coatings were prepared in concentrations of 5 wt%, 10 wt%, and 50 wt% with an acrylic binder. The coated samples were characterised using cone calorimetry, SEM, and mechanical testing. The findings showed peak heat release rate, total heat release, and carbon dioxide production from the 10 wt% triple-layer coating (EG:APP:AG) was 52%, 32%, and 58% less than the PU control. The char of the 10 wt% triple-layer sample effectively suppressed smoke release and inhibited the transfer of fuel and gas volatiles. Mechanical testing demonstrated a 3.4 times increase in tensile strength and a 15.4 times increase in compressive strength (50% compression) compared to the control PU with the 10 wt% triple-layer coating. A fire dynamics simulator model was developed that demonstrated large-scale flammability modelling for commercial aircraft. Future work can explore the integration of IFR coatings into computational analysis. These new bio-based coatings produced promising results for aircraft fire safety and flammability performance for PU polymers.

Magnetic Phase-Change Microcapsules with High Encapsulation Efficiency, Enhancement of Infrared Stealth, and Thermal Stability

Due to energy shortages and the greenhouse effect, the efficient use of energy through phase-change materials (PCMs) is gaining increased attention. In this study, magnetic phase-change microcapsules (Mag-mc) were prepared by suspension polymerization. The shell layer of the microcapsules was formed by copolymerizing methyl methacrylate and triethoxyethylene silane, with the latter enhancing the compatibility of the shell layer with the magnetic additive. Ferric ferrous oxide modified by oleic acid (Fe3O4(m)) was added as the magnetic additive. Differential scanning calorimetry (DSC) testing revealed that the content of phase-change materials in microcapsules without and with ferric ferrous oxide were 79.77% and 96.63%, respectively, demonstrating that the addition of Fe3O4(m) improved the encapsulation efficiency and enhanced the energy storage ability of the microcapsules. Laser particle size analysis showed that the overall average particle sizes for the microcapsules without and with ferric ferrous oxide were 3.48 μm and 2.09 μm, respectively, indicating that the incorporation of magnetic materials reduced the size and distribution of the microcapsules. Thermogravimetric analysis indicated that the thermal stability of the microcapsules was enhanced by the addition of Fe3O4(m). Moreover, the infrared emissivity of the microcapsule-containing film decreased from 0.77 to 0.72 with the addition of Fe3O4(m) to the shell of microcapsules.

Vegetable oil-derived polyether-polyester thermosets: Solvent-free synthesis and mechanical properties

Vegetable oils differing in the number and kind of reactive chemical sites were investigated as potential feedstock in reactions involving epoxy rings to produce sustainable polymeric thermosets. Sustainable polyether-polyester matrices were synthesized through the mixing of three different vegetable oils (castor, tung and sunflower oil) with maleic anhydride to promote their chemical activation, and subsequently induce the reaction with polyethylene glycol diglycidyl ether (PEGDGE). The interactions between double bonds and/or hydroxyl groups present in vegetable oils, anhydrides and epoxy rings within a solvent-free medium promote the expected chemical crosslinking, yielding polymeric thermosets that encompass the Green Chemistry tenets. Fourier transform infrared spectroscopy, thermogravimetric analysis, and differential scanning calorimetry tests were employed to validate the chemical reactions taken place during the synthesis, as well as to monitor the kinetics of curing. Moreover, a rheological characterization was conducted to assess the influence of both the vegetable oil and the ratio of reactive components on the ultimate mechanical properties. Although chemical crosslinking was suitably attained in all the systems studied, a more reinforced network with values of the storage modulus (G’) of 54·105 Pa was obtained in those based on tung oil possessing the higher quantity of reactive functional sites; meanwhile, the presence of hydroxyl groups within the vegetable oil structure led to the production of more flexible thermosets (G’ of 6.2·105 Pa).

Effects of Li1.3Al0.3Ti1.7(PO4)3 solid-state electrolytes on the safety of hybrid solid–liquid batteries

Hybrid solid–liquid batteries (HSLBs) are emerging as promising solutions to address the safety issues of lithium-ion batteries. However, the effects of solid-state electrolytes (SSEs) on battery safety remain unclear, hindering the large-scale application of HSLBs. This paper presents a comprehensive investigation on the safety performance of HSLBs with different amounts of nano-sized Li1.3Al0.3Ti1.7(PO4)3 (LATP) SSEs in the LiNi0.9Co0.05Mn0.05O2 cathode under thermal, electrical, and mechanical abuse conditions. The HSLBs with LATP SSEs exhibit significantly enhanced tolerance to overcharge, as the battery with 5 wt% LATP does not go into thermal runaway throughout the whole overcharge process. In-depth characterizations reveal that the LATP additives experience electrochemical delithiation during overcharge and generate a protective coating layer on the cathode surface, thus effectively mitigating the cathode structural changes and cathode-electrolyte interfacial reactions. Benefiting from the coating layer, the HSLBs with LATP SSEs also exhibit reduced temperature rise rate and retarded thermal runaway during the accelerating rate calorimetry and oven tests, as well as enhanced rate performance and cycling stability. Finally, the safety, electrochemical performance, and cost of HSLBs and conventional LIBs are comprehensively compared through a radar graph, aiming to provide guidance for the rational design of high–energy density and high-safety batteries.

Synthesis and characterization of epoxy resin‐polydicyclopentadiene interpenetrating polymer networks by UV‐initiated simultaneously frontal polymerization

AbstractBy combination of UV curing and frontal polymerization, interpenetrating polymer networks (IPNs) based on diglycidyl ether of bisphenol‐A (DGEBA) epoxy resin and polydicyclopentadiene (PDCPD) were prepared by UV‐induced simultaneously frontal polymerization in this paper. Compared with the net DGEBA cured polymer, the tensile strength, elongation at break and impact strength of the IPNs were simultaneously improved. The maximum tensile strength and elongation at break of the IPNs reached 100 MPa and 4.64%, respectively, and the maximum impact strength reached 7.34KJ/m2 with an improvement of 115.2% over that of the net DGEBA cured polymer. Thermogravimetric analysis (TGA) results revealed that the IPNs could enhance the thermal stability. Data of the differential scanning calorimetry (DSC) and TGA testing shows that the IPN shows a single glass transition temperature (Tg) which is between the Tg of DGEBA and DCPD, indicating homogeneous phase and highly cross‐linked IPN formed. Morphologies and molecular structure of the IPNs polymer were observed by scanning electron microscope (SEM) and characterized by Fourier transform infrared spectroscopy (FTIR), respectively, whose results also proved the formation of ideal IPNs structures.

Engineering sulfonated carbon black for flame-retardant and smoke-suppressive polycarbonate with well-preserved mechanical performances

To cope with the practical demands of high-performance polycarbonate (PC) and explore the application of carbon black (CB) in flame retardant field, a sulfonated carbon black (CB-SS) was synthesized and applied to flame retardant PC in this work. Compared with PC/CB composite, PC/CB-SS composite displays better overall performances under the same flame retardant addition. The PC/3CB-SS composite with 3 wt.% of CB-SS achieves a vertical burning test (UL-94) V-0 rating with a limiting oxygen index (LOI) of 29.5%, and its peak heat release rate (PHRR) and total smoke release rate (TSR) are respectively reduced by 17% and 6% relative to those of PC/3CB with 3 wt.% of CB. The flame retardancy mechanism is proposed by analyzing the char residue obtained from cone calorimetry test, which confirms the synergistic flame-retardant effect between sodium sulfonate and CB in condensed phase. Moreover, PC/3CB-SS shows much better mechanical properties than PC/3CB, and its elongation at break is increased by 223% compared with that of PC/3CB. This is mainly due to the more even dispersion of CB-SS within PC and the stronger interfacial force between CB-SS and PC. This work provides an effective approach for the creation of fire-retardant and smoke-suppressive PC composites with well-preserved mechanical properties, contributing to expanding the industrial applications of PC.