CaCl2 Research Articles

Identification of high-performing soil groups in grazing lands using a multivariate analysis method

Understanding and quantifying the complex relationships between soil properties and vegetation health is important for sustainable land management and optimising agricultural productivity. This study tested a spatial data-driven framework to identify the soil groups associated with pasture health using publicly available gridded soil attribute layers from Soil and Landscape Grid of Australia (SLGA) over two adjacent southeast Australian river catchments. Principal component analysis (PCA) followed by isocluster unsupervised classification was applied to seventeen SLGA soil attribute layers to identify dominant soil patterns, which showed good spatial agreement with the Enhanced Vegetation Index (EVI) data derived from Landsat-8 imagery. The soil class demonstrating the highest EVI values (HVR class) and the lowest EVI values (LVR class) were determined. A comparison of these classes with soil types defined in the New South Wales Soil Landscape maps confirmed that the HVR class is predominated by agriculturally productive, basalt-derived 'Ant Hill' soils. The cation exchange capacity (CEC) ranging from ∼10 to 20 meq/100 g, clay content ranging from 20 % to 30 %, pHc (pH in calcium chloride solution) between 5 and 6, pHw (pH in water) between 5.5 and 6.5 and SOC between 2.5 % to 4 % were associated with higher EVI values in the HVR soil class within the study area. This study demonstrated an effective framework for identifying key soil attributes that affect agricultural productivity and pinpointing critical locations for grazing land productivity.

PH-responsive hydrogel containing curcumin-loaded lipid nanocapsules for oral curcumin’s stability, bioaccessibility and intestinal absorption improvement

A liquid formulation with suitable consistency and sustained release characteristics can improve compliance in users with dysphagia.In the study, we prepared curcumin-loaded lipid nanocapsules (Cur-LNCs) and incorporated it in a mixture of sodium alginate, dextrin, calcium chloride and sodium citrate to form a pH-responsive pre-hydrogel solution (SA-DEX:Cur-LNCs). The SA-DEX:Cur-LNCs exhibited a pH-responsive solution-gel conversion: solubilized at near neutral (pH = 7) and rapidly gelatinized to a strong elastic gel at stomach acid (pH = 2.5). The SA-DEX:Cur-LNCs could effectively improve the thermal and pH stability of Cur, and maintain its antioxidant effect. Interestingly, the bioaccessibility of SA-DEX:Cur-LNCs in gastrointestinal was significantly increased to 37.00% when compared with free Cur. The SA-DEX:Cur-LNCs also significantly improved the small intestinal absorption of Cur, being 16 times higher than that of free Cur. Therefore, incorporating lipid nanocapsule in pH-responsive pre-hydrogel provided a new oral administration platform of hydrophobic bioactive compounds for compliance improvement of users with dysphagia.

A Mouse Abdominal Aortic Aneurysm Model by Periadventitial Calcium Chloride and Elastase Infiltration.

Abdominal aortic aneurysm (AAA) is a life-threatening disease associated with high mortality rates. It is characterized by the permanent dilation of the abdominal aorta with at least a 50% increase in arterial diameter. Various animal models of AAA have been introduced to mimic the pathophysiological changes and study the underlying mechanisms of AAA. Among these models, the calcium chloride (CaCl2)- and elastase-induced AAA models are commonly used in mice. However, these methods have certain limitations. Traditional intraluminal porcine pancreatic elastase (PPE) perfusion is associated with high technical difficulty and a high rupture rate, while periadventitial administration of PPE yields inconsistent results. In addition, the CaCl2-induced AAA model lacks human AAA features, such as atherothrombosis and aneurysm rupture. Therefore, the combined application of CaCl2 and PPE has been proposed as an approach to enhance success rates and induce greater diameter increases in AAA animal models. This manuscript presents a comprehensive protocol for establishing a mouse AAA model through periaortic infiltration of PPE and CaCl2 in the infrarenal segment of the abdominal aorta. By following this protocol, we can achieve an AAA formation rate of approximately 90% with technical simplicity and reproducibility. Further ultrasound and histological experiments confirm that this model effectively replicates the morphological and pathological changes observed in human AAA.

Evaluation of The Performance of Enzyme-Induced Calcite Precipitations (EICP) Solutions Based on pH and Electrical Conductivity

Abstract EICP is an innovative, sustainable technology that utilizes specific chemicals, particularly urea and calcium chloride, in conjunction with the urease enzyme to induce the precipitation of calcium carbonate. The abovementioned technology is widely acknowledged as contemporary and environmentally responsible, aligning with established sustainability principles and green construction criteria. The quantity of precipitated calcium carbonate is contingent upon the composition of the materials employed in the precipitation process and their respective proportions. The investigation focused on determining the best percentage of calcium carbonate precipitation by conducting experiments on different concentrations of urea, calcium chloride, and the urease enzyme and examining the specific characteristics of the chemical solution that facilitate the precipitation process. The augmentation of urea and calcium chloride to a certain proportion resulted in a corresponding augmentation in the quantity of precipitated substances such as calcium carbonate. In the course of furthering the increase process, it was observed that the value of the precipitated materials remained constant and did not exhibit any further augmentation for some mixing ratios. According to the results of current study, the best ratio to precipitated calcium carbonate can be attributed to using an optimal ratio of 1 mol/L of urea and 0.5 mol/L of calcium chloride. Due to the notable efficacy of urease, the concentration increment of urease did not exhibit significant variation beyond 1 g/l. However, the alteration in the rate of reaction velocity will influence the outcome of EICP process. The experimental results and integration of several methodologies demonstrated a positive correlation between temperature elevation and reaction rate augmentation, resulting in a rapid reaction termination.

Study of Shoot Tip Necrosis Problems of Fegra Fig (Ficus palmata Forssk.) In Vitro in Saudi Arabia

This work studied the micropropagation of fegra fig (F. palmata Forssk.) during which we experienced the incidence of shoot-tip necrosis (STN). STN was evident during the shoot elongation stage, which was regenerated on Murashige and Skoog (MS) medium supplemented with 2 mg/L 6-benzylaminopurine. To alleviate SNT, we conducted a series of experiments and supplemented the medium with calcium chloride (40, 80, and 120 mg/L), ascorbic acid (50, 100, and 150 mg/L), silver nitrate (1, 2, and 3 mg/L), and boric acid (9.3, 12.4, and 15.5 mg/L). Results showed that all the treatments controlled STN at varying levels, and supplementation of medium with 3 mg/L silver nitrate reduced the incidence of STN from 80% to 24%. The regenerated shoots were rooted on the same medium with incubation of cultures in the dark for 3 weeks and subsequent 4 weeks of incubation under 16/8-hour light/dark photoperiod. The growth parameters (number of shoots and roots, length of the main shoot and root, fresh and dry weights), photosynthetic pigments (chlorophylls and carotenoids), and relative water content of plantlets were restored with the application of 3 mg/L silver nitrate to the medium. Incubation of cultures initially in the dark followed by 16/8-hour light incubation facilitated axillary shoot elongation. On the basis of our findings, it is recommended to culture the regenerated axillary shoots of fegra fig onto MS medium containing 3% sucrose, 1.5 mg/L activated charcoal, and 3 mg/L silver nitrate to manage STN effectively.

Numerical modeling of non-uniform corrosion of concrete reinforcement considering calcium leaching and chloride diffusion coupling effect

A novel numerical model is proposed for characterizing the nonuniform corrosion of steel bars. The proposed model corrects the anodic Tafel slope through the concentration of chloride and accounts for the adsorption-binding impact of chloride. The viability of the presented model is confirmed with regard to chloride diffusion and the distribution of steel corrosion products. The rebar-concrete interface's non-uniform distribution of oxygen and chloride concentrations along the circumferential direction influences the corrosion current density. Calcium leaching influences the migration of oxygen and chloride, and speeds up the electrochemical corrosion of the rebar.

Changes in cell wall components and its hydrolyzing enzymes of guava fruits due to chitosan and calcium chloride treatments during storage at room and low temperature

Changes in cell wall components and its hydrolyzing enzymes of guava fruits due to chitosan and calcium chloride treatments during storage at room and low temperature

Investigation study of methyl violet photodegradation over alginate-carboxymethyl cellulose/titanium(IV) oxide/covalent organic frameworks bio-nanocomposite beads under ultraviolet irradiation

Concerned about water treatment, it is of great importance to present new approaches for improving photocatalytic activity. Since photocatalysis is ubiquitous in almost all chemical manufacturing processes, the development of photocatalytic systems carries significance for our environment. In this regard, three different amounts of covalent organic frameworks decorated with titanium(IV) oxide nanoparticles (TiO2/COF hybrids) in Alginate-Carboxymethyl cellulose (Alg-CMC) blend matrix were prepared under ultrasound irradiation, which Citric acid and Calcium chloride acted as two green cross-linkages. Based on the physio-chemical analyses of these bio-nanocomposite (bio-NC) beads, the Alg-CMC blend polymer appeared to be the best candidate for a disparity of TiO2/COF hybrids. Not only did COF aid to increase the distribution of TiO2 nanoparticles, but it declined the bandgap energies. The resultant Alg-CMC/TiO2/COF (TiO2/COF = 15:6) bio-NC beads demonstrated efficient photodegradation activity towards Methyl violet (MV) under Ultraviolet light. The obtained results of scavenger studies indicated that superoxide radicals and electron agents played a major role in MV degradation. Further investigation confirmed that single oxygen addition and N-de-methylation could be two important pathways for the decomposition of MV by these bio-NC beads.

Strain sensors enhanced by a flexible, conductive hydrogel with superior transparency, frost resistance, and water retention

Flexible hydrogels have received significant attention for their excellent mechanical properties, fast response and good strain sensitivity. However, relatively little research has been conducted on the investigation of hydrogels that exhibit frost resistance, water retention, and transparency characteristics. In this paper, a new flexible strain sensors material was prepared by introducing calcium chloride (CaCl2) and hydrolysed keratin (HK) into the polyvinyl alcohol (PVA) system through complex chemical bond. The PVA/CaCl2/HK hydrogel exhibited excellent mechanical properties, with a tensile strength of 1.578 MPa and a maximum strain of 934 %. Moreover, it showed high transparency, with a transmittance of up to 90 %. The hydrogel demonstrated remarkable water retention properties with about 8 hours of dry resistance under constant temperatures of 40 °C, 60 °C, 80 °C and 100 °C. Additionally, it had excellent frost resistance with a glass transition temperature of −23 °C, making it environmentally tolerant and capable of maintaining long-term stability. Notably, during the experiment, the PVA/CaCl2/HK hydrogel exhibited excellent electrical conductivity and self-powered performance, with a power supply capacity of approximately 14.6 mV. The results of this work provide a promising direction for the development of electronic materials for powered hydrogel strain sensors.

Calcium-dependent HLA-DQ epitope revealed by EDTA mediated inhibition of antibody reactions in the Luminex single antigen bead assay.

Complement mediated interference with the detection of antibodies targeting HLA is a known limitation of the single antigen bead (SAB) Luminex assay. Ethylenediaminetetraacetic acid (EDTA) is currently the serum treatment of choice in most histocompatibility laboratories to block complement activation by chelating calcium. The purpose of this study was to investigate a serum with an antibody reactivity to HLA-DQ6, 7, 8 and 9 molecules, in the Luminex SAB assay, that was inhibited by treatment with EDTA. Serum was from a 55-year-old highly sensitised female renal transplant candidate that contained, among others, antibodies to an epitope containing the 74EL eplet, shared by HLA-DQ6, DQ7, DQ8 and DQ9 molecules. Serum samples were treated with EDTA, dithiothreitol (DTT), or heat prior to testing by SAB assay. EDTA-treated serum was also tested after the addition of calcium chloride (CaCl2). HLA-DQ-specific antibodies were isolated by adsorption/elution method using three informative donor cells and were tested in the absence or presence of EDTA. The antibody reactivity against HLA-DQ6, DQ7, DQ8 and DQ9 in the SAB assay was significantly inhibited by treating serum and eluates with EDTA and was restored by addition of CaCl2. The study represents the first description of a calcium-dependent epitope in HLA molecules. The relevance of this finding is that the treatment of sera with EDTA could lead to false-negative reactions in the SAB assay, which may compromise virtual crossmatching.

Individual or successiveseed priming with nitric oxide and calcium toward enhancing salt tolerance of wheat crop through early ROS detoxification and activation of antioxidant defense

Despite the considerable efforts reported so far to enhance seed priming, novel ideas are still needed to be suggested to this sustainable sector of agri-seed industry. This could be the first study addressing the effect of nitric oxide (NO) under open field conditions. The impacts of seed redox-priming using sodium nitroprusside (SNP) and osmo-priming with calcium chloride (CaCl2), both applied individually or successively, were investigated under salinity stress conditions on wheat plants (Triticum aestivum L.). Various parameters, including water relations, growth, yield, photosynthetic pigments, and antioxidant activities (enzymatic and non-enzymatic), were recorded to assess the outcomes of these priming agents on mitigating the negative impacts of salinity stress on wheat plants. Water consumptive use (ETa) and irrigation water applied (IWA) decreased with seeds priming. Successive priming with SNP + CaCl2 induced the greatest values of crop water productivity (CWP), irrigation water productivity (IWP), seed index, grain yield and grain nitrogen content.Under salinity stress, the dry weight of plants was decreased. However, hydro-priming and successive chemical priming agents using combinations of calcium chloride and sodium nitroprusside (CaCl2 + SNP & SNP + CaCl2) preserved growth under salinity stress.Individual priming with sodium nitroprusside (SNP) and calcium chloride (CaCl2) resulted in the lowest recorded content of sodium in the shoot, with a value of 2 ppm. On the other hand, successive priming using CaCl2 + SNP or SNP + CaCl2 induced the contents of potassium in the shoot, with values of 40 ppm and 39 ppm, respectively. Malondialdehyde decreased in shoot significantly withapplicationof priming agents. Successive priming with CaCl2 + SNP induced the highest proline contents in shoot (6 µg/ g FW). The highest value of phenolics and total antioxidants contents in shoot were recorded under successive priming using CaCl2 + SNP and SNP + CaCl2.Priming agents improved the activities of ascorbate peroxidase and catalase enzymes. The successive priming improved water relations (ETa, IWA, CWP and IWP) and wheat growth and productivity under salinity stress more than individual priming treatments.

Self-powered and degradable humidity sensors based on silk nanofibers and its wearable and human–machine interaction applications

Humidity sensors have received increasing attention due to their broad potential application in wearable devices, health monitoring, intelligent control, and other fields. However, traditional humidity sensors are prone to produce various toxic substances to pollute the environment after discarding. Also, they are prone to damage during use, which shortens their service life. Therefore, the development of eco-friendly, degradable, and repairable humidity sensors is of great significance for reducing e-waste and protecting the environment. Here, we started with the selection of materials by using silk nanofiber (SNF) film as the substrate material, copper/aluminum as electrodes, and calcium chloride as the electrolyte, combined with the working mechanism of the primary battery, to construct a self-powered humidity sensor. The humidity sensor exhibits excellent humidity sensing performance and good linearity within the range of 30–90 % relative humidity (RH). A single humidity sensor can output 346 mV at 90 % RH. After being damaged, the humidity sensor can be repaired with the help of water. When the ruptured SNF film encounters water molecules, the water molecules can prompt the hydrogen bonds between the SNFs to rearrange and connect, connecting the broken area. Young’s modulus retention rate of the repaired SNF film is over 85 %. The repaired humidity sensor can also output 328 mV. Additionally, an alkaline solution can completely degrade the humidity sensor in less than 80 min. The proposed humidity sensors have been applied to wearable self-powered wristbands, wireless monitoring systems, and non-contact human–machine interaction systems. Hence, we provide comprehensive research from the material level (SNFs) to the functional device level (the self-powered humidity sensor), and then to the system level (wearable and human–machine interface system). The research will open a new way for the design of the self-powered humidity sensor and have great potential applications in wearable electronics and human–machine interface applications.

Availability of antidotes for drug poisonings and doctors’ perspectives thereof

Drug poisoning is an important area of study in South Africa as a treatable cause of mortality. While research has been conducted on poisoning, there is a paucity of literature on the availability of antidotes in South Africa. The objectives of this study were to assess the availability of antidotes in selected teaching hospitals in the Southern Gauteng City-Region and to explore doctors’ experiences of antidote supply. The availability of antidotes in the emergency departments (EDs) and pharmacies was assessed and recorded using a data sheet that was completed in person at each of the teaching hospitals. A questionnaire exploring experiences of antidote supply was distributed to 126 doctors working in the EDs. Our results indicate that N-acetylcysteine, atropine, diazepam, clonazepam, sodium bicarbonate, vitamin K, calcium gluconate, naloxone, ethanol, and pyridoxine were present in all EDs; activated charcoal was present in 80%; lorazepam, glycopyrrolate, and calcium chloride in 60%; freeze-dried plasma in 40%; glucagon and desferrioxamine in 20%; and fresh frozen plasma, hydroxocobalamin, sodium nitrite, sodium thiosulfate, sodium calcium edetate, and intralipid were not present in any of the EDs. Doctors reported organophosphate poisoning and paracetamol overdose as the most common drug poisonings (81.7% and 14.3% of 126 respondents, respectively). Most doctors experienced no supply issues for N-acetylcysteine, calcium gluconate, sodium bicarbonate, or pyridoxine (85.7%, 83.3%, 87.3%, and 75.4% of 126 respondents, respectively). The antidotes to the most common poisonings reported by doctors were present in all EDs. However, concerns were raised about consistency of supply, which will be an important avenue for further research.

Comparison of nano-zinc oxide or calcium chloride incorporated polyvinyl alcohol/chitosan/anthocyanin films for active and intelligent packaging

Comparison of nano-zinc oxide or calcium chloride incorporated polyvinyl alcohol/chitosan/anthocyanin films for active and intelligent packaging

Biopolymeric Insulin Membranes for Antimicrobial, Antioxidant, and Wound Healing Applications.

Delayed wound healing increases the wound's vulnerability to possible infections, which may have lethal outcomes. The treatments available can be effective, but the urgency is not fully encompassed. The drug repositioning strategy proposes effective alternatives for enhancing medical therapies for chronic diseases. Likewise, applying wound dressings as biodegradable membranes is extremely attractive due to their ease of application, therapeutic effectiveness, and feasibility in industrial manufacturing. This article aims to demonstrate the pleiotropic effects during insulin repositioning in wound closure by employing a biopolymeric membrane-type formulation with insulin. We prepared biopolymeric membranes with sodium alginate cross-linked with calcium chloride, supported in a mixture of xanthan gum and guar gum, and plasticized with glycerol and sorbitol. Human insulin was combined with poloxamer 188 as a protein stabilizing agent. Our investigation encompassed physicochemical and mechanical characterization, antioxidant and biological activity through antibacterial tests, cell viability assessments, and scratch assays as an in vitro and in vivo wound model. We demonstrated that our biopolymeric insulin membranes exhibited adequate manipulation and suitable mechanical resistance, transparency, high swelling capability (1100%), and 30% antioxidant activity. Furthermore, they exhibited antibacterial activity (growth inhibition of S. aureus at 85% and P. aeruginosa at 75%, respectively), and insulin promoted wound closure in vitro with a 5.5-fold increase and 72% closure at 24 h. Also, insulin promoted in vivo wound closure with a 3.2-fold increase and 92% closure at 10 days compared with the groups without insulin, and this is the first report that demonstrates this therapeutic effect with two administrations of 0.7 IU. In conclusion, we developed a multifunctional insulin-loaded biopolymeric membrane in this study, with the main activity derived from insulin's role in wound closure and antioxidant activity, augmented by the antimicrobial effect attributed to the polymer poloxamer 188. The synergistic combination of excipients enhances its usefulness and highlights our innovation as a promising material in wound healing materials.

Nano-carbon octadecahedron: in situ carbonization of DTAB of aggregates in concentrated calcium chloride solution

Morphologies play an important role in carbon nanomaterials. Carbon nanomaterials with different morphologies have different applications in different fields. However, carbon nano-polyhedra have been rarely reported in literatures. Nano-carbon octadecahedron were prepared by the interaction of DTAB of aggregates with a concentrated solution of calcium chloride at 600 °C and with a size of about 700 nm. A series of characterizations, such as SEM, FT-IR, XPS, XRD, Raman, etc., proved that it conforms to the basic characteristics of carbon nanomaterials and may be doped with Ca and carbon. Successful preparation of carbon octadecahedron suggests that the use of in situ carbonization in a concentrated salt system is a new and worthwhile approach to explore.

Analysis of the Soil Fertility Condition in Jiliba Village, Ganjam District, Odisha

An assessment of soil fertility was conducted in Jiliba village, situated in the Bellaguntha block of Ganjam district in the North-Eastern agroclimatic zone of Odisha, India. Analysis of physical and chemical properties was conducted on soil samples obtained at a depth ranging from 0 to 15 cm. The findings indicate that the predominant soil texture in the hamlet under study consisted of sandy loam and clay loam. The soil hue ranged from Dark Grey at 10 years old to Yellowish brown at 10 years old. The pH of the soil varied from somewhat acidic (5.5-6) to neutral (6.5-7.5). The electrical conductivity of the whole research area remained uniformly below 0.74 dSm-1. Approximately 77.5% of the research region exhibited soil organic carbon (SOC) levels below 0.5%. The available nitrogen concentration was insufficient, varying from 87.8 to 150.5 kg/ha, indicating a possible requirement for nitrogen fertilization to adequately sustain crop development. The phosphorus content in Brays exhibited significant variation, ranging from 4.7 to 198.2 kg/ha, providing evidence of geographic heterogeneity in phosphorus availability throughout the hamlet. The soil potassium level exhibited significant variation, ranging from 54.6 to 435.6 kg/ha, potentially impacting the absorption of nutrients and the production of crops. The Nutrient Index readings for nitrogen (1.0) and phosphorus (1.32) were below expected levels, suggesting the necessity of implementing nutrient management strategies to enhance soil fertility. The potassium Nutrient Index value of 1.87 indicates a moderate level of potassium availability in comparison to nitrogen and phosphorus. The extractable soil sulphur from calcium chloride (CaCl2) ranged from 6.4 to 126.7 kg/ha, underscoring the significance of sulphur for crop fertilization. Modest variations in exchangeable calcium (Ca2+) and magnesium (Mg2+) levels suggest differences in soil cation exchange capacity and nutrient availability. The micronutrient levels exhibited variation, with copper (Cu) concentration ranging from 2.026 to 4.210 parts per million (ppm), zinc (Zn) concentration ranging from 0.736 to 4.440 ppm, manganese (Mn) concentration ranging from 19.0 to 79.0 ppm, and iron (Fe) concentration ranging from 44.36 to 160.64 ppm. The concentration of boron soluble in hot water varied from extremely low to medium (0.15 to 0.68 mg/kg), suggesting different degrees of boron accessibility for plant absorption. Finally, it is essential to fill the research gaps concerning soil fertility and nutrient dynamics in order to establish sustainable agricultural practices and guarantee food security in the region.

Preparation of Oxidized Pellets from Sulfuric Acid Residue Containing Zinc and Lead by Chlorination Roasting and Its Mechanism of Dezincing and Lead Removal

The utilization of sulfur acid residue is an urgent problem confronting sulfuric acid production enterprises, especially the application of sulfur acid residue (SAR) containing lead and zinc. A method combining chlorination roasting using CaCl2 with pelletizing for processing SAR containing lead and zinc was used in this study, and the effect of calcium chloride on pelletizing performance was studied; in addition, the removal behavior of lead and zinc was also studied by using polarized light microscopy (Zeiss double Axioskop 40A), X ray diffraction, SEM and EDS. The results showed that CaCl2 migrated to the surface of the pellets during drying, and this phenomenon resulted in a lower removal rate of lead and zinc inside the pellets than outside the pellets during the preheating phase. When the roasting temperature was 1220 °C, with an increase in the basicity of pellets, the silicate minerals in the pellets gradually decomposed, the hematite particles were gradually refined, and more lead or zinc minerals were exposed, which further increased the removal rate of lead and zinc in the pellets. Finally, the SAR pellets with Pb and Zn removal rates up to 91.33 and 97.88%, and a compressive strength of 2789 N, could be obtained, which is very beneficial to the sustainable development of sulfuric acid mills.

Enhancing kaolin's structure for efficient removal of lead ions from aqueous solutions

This research demonstrates a novel methodology for structurally modifying kaolin clay to efficiently remove toxic lead ions from water through adsorption. Kaolin was systematically treated with hydrochloric acid, cetylpyridinium chloride surfactant, and calcium chloride to enhance its physico-chemical properties. BET surface area analysis, transmission electron microscopy, scanning electron microscopy, and BJH pore size measurements confirmed successful intercalation of surfactants between kaolin sheets, increasing the surface area from 43.2 to 57.1 m2 g-1 and inducing larger mesopores. Operational factors such as pH, dosage of adsorbent, time spent in contact, starting lead concentration, and temperature were tuned using batch adsorption tests. Maximum lead uptake of 29.58 mg g-1 was attained at pH 5, 20 mg adsorbent dose, 30 mg L-1 initial lead concentration, 80 min contact time, and 30°C temperature. Pseudo-second order kinetics and Sips isotherm models aptly characterized the adsorption, indicating chemisorption on heterogeneous sites. Positive enthalpy and entropy changes signified an endothermic and irreversible process. Regeneration studies demonstrated stable performance over five adsorption-desorption cycles. This comprehensive methodology integrates acid, surfactant, and cationic treatments to synthesize an eco-friendly kaolin adsorbent with enhanced selectivity and adsorption capacity for removing toxic lead from water.

Effect of Low Temperature Heating of Potassium-Depleted Soils on Secondary Potassium Release to Calcium Chloride and Wood Vinegar and Fixation

Effect of Low Temperature Heating of Potassium-Depleted Soils on Secondary Potassium Release to Calcium Chloride and Wood Vinegar and Fixation