Carbonate Compensation Depth Research Articles

Diverse Carbonates in Exoplanet Oceans Promote the Carbon Cycle

Carbonate precipitation in oceans is essential for the carbonate-silicate cycle (inorganic carbon cycle) to maintain temperate climates. By considering the thermodynamics of carbonate chemistry, we demonstrate that the ocean pH decreases by approximately 0.5 for a factor of 10 increase in the atmospheric carbon dioxide content. The upper and lower limits of ocean pH are within 1–4 of each other, where the upper limit is buffered by carbonate precipitation and defines the ocean pH when the carbon cycle operates. If the carbonate compensation depth (CCD) resides above the ocean floor, then carbonate precipitation and the carbon cycle cease to operate. The CCD is deep (>40 km) for high ocean temperature and high atmospheric carbon dioxide content. Key divalent carbonates of magnesium, calcium and iron produce an increasingly wider parameter space of deep CCDs, suggesting that chemical diversity promotes the carbon cycle. The search for life from exoplanets will benefit by including chemically more diverse targets than Earth twins.

Sensitivity of marginal basins in recording global icehouse and regional tectonic controls on sedimentation. Example of the Cergowa Basin, (Oligocene) Outer Carpathians

Global sea-level fall during the late Eocene-Oligocene icehouse, in conjunction with the Alpine orogenesis, resulted in the epicontinental Paratethys Sea formed at the northern margin of the Tethys Ocean. Among the Paratethys sub-basins, the foreland Dukla Basin hosted dark dysoxic Menilite Shales. Within these the lenticular body of deep-marine Cergowa Beds was deposited. Due to its marginal position and orogenic activity, the Cergowa depocenter was sensitive to a broad range of influences reflected by: separation from and re-connection with the Tethys Ocean; reactions to global sea-level change; variations in calcareous nannoplankton palaeoecology and fluctuations in water chemistry; changing sediment gravity flow mechanisms; facies progradation and basin tectonics; palaeotransport direction; and changes in the calcite compensation depth. The proximal north-western part of the Cergowa depocenter consisted of two troughs evolving towards the south-east into an unconfined distal area. This is shown by palaeocurrent patterns changing down current from low-dispersion to fanning out distributions. Sedimentation during the succeeding NP23 nannoplankton zone was controlled by glacio-eustatic shallowing, enhanced by tectonic uplift, both resulting in isolation from the Tethys Ocean, forming a brackish environment affected by fluvial supply. Aggrading sand-rich proximal turbidite facies common at this stage include hyperpycnally-generated sustained turbidites that were sourced from shelf-edge delta, as well as hybrid event beds that reflect erosion of morphologically unbalanced slopes modified by fold-thrust tectonics. Nannoplankton of the succeeding NP24 zone documents normal salinity of an open sea that was reconnected with the Tethys Ocean, which is contrary to the global cooling and related eustatic sea-level lowstand during this time. At this stage, deposits of low-density turbidity currents predominate and form a succession prograding towards the south-east. Therefore, the oceanic reconnection was likely controlled by local subsidence, the rate of which exceeded the rate of deposition, especially in the south-east. The reconnection also influenced the calcite compensation depth level and resulted in an increase in coccolithophore productivity, recorded by laminated pelagic limestone interbeds within the youngest fining-upwards part of the Cergowa Beds succession. This fining-upwards sequence of low-density turbidites reflects retrogradation of the arenaceous material within the distributary system and a transition to mudstone-dominated disoxic facies of the Menilite Beds, being the most productive hydrocarbon and helium source rock unit in the Outer Carpathians. These processes and relationships show that due to the marginal position of the synorogenic basin, the Cergowa Beds record environmental sensitivity to extrabasinal and intrabasinal factors, and a broad range of global, regional, and local influences, thus providing insights applicable to research into the evolution of other basins placed in a similar context.

Response of Magnetic Minerals to the Mid-Brunhes Climate Event Recorded in Deep-Sea Sediments of the West Philippine Sea

The Mid-Brunhes Event (MBE) was one of the most important global climate events since 800 ka. The deep-sea palaeoceanographic changes in the Western Pacific might have been more sensitive to the MBE and they have not been well documented yet. In this study, we investigated a deep-sea core collected from the Western Philippine Sea and then obtained the magnetism record since around 900 ka. The MBE signal in the deposition process was derived from the concentration-dependent (χ, χARM and SIRM) and the grain-size-dependent magnetic parameters (χARM/χ and χARM/SIRM). Across the MBE, the content of magnetic minerals and the fluctuation of the grain size decreased. Both the content and grain-size indices calculated from magnetic parameters are well correlated with the glacial–interglacial alternations and display a major shift at the MBE. The decreased grain size of magnetic minerals may be associated with the flourishing biota in the tropical Pacific during interglacial intervals. The accumulation of magnetic minerals in the Western Philippine Sea was mainly regulated by the sediment accumulation rate, which may be related to the shoaling of the carbonate compensation depth. Overall, this study expanded the environmental magnetism record for the MBE, suggested a new possible influence of this critical climatic event on the deep-sea deposition process in Western Philippine Sea and inferred the interactions between various environmental systems on glacial–interglacial timescales.

A ∼ 50 kyr record of carbonate (pteropods) preservation from the Laccadive Sea, Northern Indian Ocean

To evaluate the preservation pattern of pteropods and their relationship with climatic and oceanographic history in the Laccadive Sea, temporal variation analysis of pteropod abundance was carried out. We employed preservation indices from calcite (Globigerina bulloides%, Globorotalia menardii abundance), as well as aragonite (e.g., total pteropod abundance, Limacina Dissolution Index (LDX), fragmentation ratio) as a proxy. To determine if pteropod shells have been preserved over time, we used estimated pteropod abundance. The pteropod preservation record displays excellent preservation during cold stadials, evidenced by the lower values of aragonite dissolution proxies than during the interglacials/interstadials, similar to the preservation records from other northern Indian Ocean cores. The shallow aragonite compensation depth (ACD), weaker oxygen minimum zone (OMZ), and the lower southwest monsoon (SWM)-induced productivity is thought to be the cause of the basin-wide pteropod preservation events during the cold stadials (ACD). Additionally, during an intense northeast monsoon (NEM), the advection of cold, low-saline waters from the Bay of Bengal to the Laccadive Sea, as well as the intrusion of southern-sourced intermediate water ventilation, may have caused a deep vertical mixing of oxygen-rich surface waters, raised the pH of thermocline waters and deepened the ACD. However, the local fluctuations in the water mass properties, such as the increased productivity maxima, the intense OMZ, and shallow ACD, as well as changes in the aragonite, are responsible for the poor pteropod abundance, poor preservation and strong dissolution during the Holocene, Bølling-Allerød (B/A) and interstadial periods.The calcification proxy indicates that the aragonite undersaturation and reduced calcification occurred during 19–16.5 kyr, preferably due to the depletion in the oceanic alkalinity caused by enhanced upwelling-induced carbonate ion exchange between the intermediate and deep water. In contrast, the preferential dissolution of smaller shells in the sediments (marked by increased average shell size and higher values of Limacina dissolution index (LDX)) corresponds to strengthened OMZ and shallower ACD, pointing towards the post-depositional dissolution of aragonite shells. Therefore, the overall decrease of pteropod content of the deposits in the stadial/interstadials suggests a combination of monsoon-associated changes in water column properties, variability in aragonite saturation, intermediate water ventilation and sediment rate.

The History of Cenozoic Carbonate Flux in the Atlantic Ocean Constrained by Multiple Regional Carbonate Compensation Depth Reconstructions

AbstractThe Atlantic is the only ocean basin almost entirely surrounded by passive margins, and a major global long‐term sink of carbonate carbon that has evaded subduction. Quantifying the history of carbonate accumulation in the Atlantic has been limited by the absence of well‐defined regional carbonate compensation depth (CCD) models. We determine the CCD for the northern North Atlantic, central North Atlantic, and South Atlantic, and use these reconstructions to compute the carbonate carbon mass and carbonate carbon flux in a tectonic framework at 0.5 m.y. intervals since 66 Ma. We find that the total carbonate carbon mass of the Atlantic has grown 2.5‐fold from ∼1,500 Mt at 66 Ma to ∼3,800 Mt at present day. The overall Cenozoic increase in carbonate carbon flux toward the present day is punctuated by “carbonate crash” phases in the mid‐Eocene at ∼44–38 Ma and in the mid‐late Miocene at ∼19–8 Ma. During these times the flux decreases from ∼45 to ∼25 Mt C/yr, likely caused by carbonate dissolution and reductions in productivity. Reduced carbonate carbon flux in the mid‐Eocene also coincides with reduced calcification rates of small coccolithophores previously observed offshore Africa. After ∼8 Ma the carbonate carbon flux rises to a Cenozoic maximum of ∼75 Mt C/yr at ∼3 Ma, possibly driven by enhanced flux of nutrients into the ocean. Our CCD curves and the resulting carbonate accumulation history are useful for calibrating ocean chemistry models, and constraining global terrestrial weathering rates, climate perturbations, and carbon cycle models.

Carbonate weathering, CO2 redistribution, and Neogene CCD and pCO2 evolution

The carbonate compensation depth (CCD), δ13C of marine carbonate, atmospheric pCO2 and major ion composition of seawater provide constraints on how geological carbon cycle processes evolved over the Neogene. I use simple models and the LOSCAR ocean carbon system model to assess what changes in carbon fluxes to the ocean are necessary to explain observations since the early Miocene. The calculations consider estimates of early Miocene seawater temperatures and ion composition and a range of possible pCO2. Changes in shelf-basin partition could explain up to ≈45% the observed CCD deepening. Increased carbonate flux (likely range 28±12%) to the oceans is necessary to explain the rest. Despite changes in pCO2 from early Miocene values of 450–900 ppm to a pre-anthropogenic value of 280 ppm, the size of the total ocean-atmosphere carbon reservoir shows only moderate or no net change, implying that weathering and/or organic carbon burial result in little net CO2 consumption. Decreasing Ca++ and increasing deepwater carbonate saturation over the Neogene require a large increase in deepwater CO=3 and leads to decreasing DIC/TALK which is the main driver for falling pCO2. The primary driver of pCO2 reduction is redistribution of CO2 from the atmosphere to the oceans, not net removal of CO2 from excess silicate weathering or organic carbon burial. The main impact of tectonic perturbation of the carbon cycle during the Neogene is to enhance carbonate weathering while only weakly affecting the net balance of degassing vs. silicate weathering or kerogen oxidation vs. organic carbon burial.

Biotic and Paleoceanographic Changes Across the Late Cretaceous Oceanic Anoxic Event 2 in the Southern High Latitudes (IODP Sites U1513 and U1516, SE Indian Ocean).

Oceanic Anoxic Event 2, spanning the Cenomanian/Turonian boundary (93.9 Ma), was an episode of major perturbations in the global carbon cycle. To investigate the response of biota and the paleoceanographic conditions across this event, we present data from International Ocean Discovery Program sites U1513 and U1516 in the Mentelle Basin (offshore SW Australia; paleolatitude 59°–60°S in the mid‐Cretaceous) that register the first complete records of OAE 2 at southern high latitudes. Calcareous nannofossils provide a reliable bio‐chronostratigraphic framework. The distribution and abundance patterns of planktonic and benthic foraminifera, radiolaria, and calcispheres permit interpretation of the dynamics of the water mass stratification and provide support for the paleobathymetric reconstruction of the two sites, with Site U1513 located northwest of the Mentelle Basin depocenter and at a deeper depth than Site U1516. The lower OAE 2 interval is characterized by reduced water mass stratification with alternating episodes of enhanced surface water productivity and variations of the thickness of the mixed layer as indicated by the fluctuations in abundance of the intermediate dwelling planktonic foraminifera. The middle OAE 2 interval contains lithologies composed almost entirely of radiolaria reflecting extremely high marine productivity; the low CaCO3 content is consistent with marked shoaling of the Carbonate Compensation Depth and ocean acidification because of CaCO3 undersaturation. Conditions moderated after deposition of the silica‐rich, CaCO3‐poor rocks as reflected by the microfossil changes indicating a relatively stable water column although episodes of enhanced eutrophy did continue into the lower Turonian at Site U1516.

Unusual bromine enrichment in the gastric mill and setae of the hadal amphipod Hirondellea gigas.

The hadal amphipod Hirondellea gigas is an emblematic animal of the Pacific trenches, and has a number of special adaptations to thrive in this 'extreme' environment, which includes the deepest part of the Earth's ocean. One such adaptation that has been suggested is the presence of an 'aluminum gel shield' on the surface of its body in order to prevent the dissolution of calcitic exoskeleton below the carbonate compensation depth. However, this has not been investigated under experimental conditions that sufficiently prevent aluminum artefacts, and the possibility of other elements with similar characteristic X-ray energy as aluminum (such as bromine) has not been considered. Here, we show with new electron microscopy data gathered under optimized conditions to minimize aluminum artefacts that H. gigas actually does not have an aluminum shield-instead many parts of its body are enriched in bromine, particularly gastric ossicles and setae. Results from elemental analyses pointed to the use of calcite partially substituted with magnesium by H. gigas in its exoskeleton, in order to suppress dissolution. Our results exemplify the necessity of careful sample preparation and analysis of the signals in energy-dispersive X-ray spectroscopic analysis, and the importance of analyses at different electron energies.

Geochronological Evidence Inferring Carbonate Compensation Depth Shoaling in the Philippine Sea after the Mid-Brunhes Event

Carbonate compensation depth (CCD) is an important factor in the global deep ocean and in global carbon cycling; however, its variabilities have not been well documented in previous studies. In this study, we investigate two deep-sea cores collected from the Philippine Sea in terms of geochronology and geochemical properties over the past ~900 kyr. The principle results are as follows: (1) Two magnetozones are determined from the sediment’s magnetic records, which can be correlated with the Brunhes and Matuyama chrons in the geomagnetic polarity timescale. (2) The age models can be refined by tuning the Ba and Sm intensities of the two studied cores to the global ice volume, and the estimated sediment accumulation rate is ~4 mm/kyr. (3) Chalky mud and the bulk carbon δ13C record vary abruptly at ~430 ka and imply 200 m shoaling of the CCD. Based on these results, a close link is inferred between marine productivity, aeolian dust, and CCD changes, which can be correlated with a major change that occurred during the Mid-Brunhes Event. Therefore, we propose that the sedimentary processes in the Philippine Sea are evidence of global climate change, providing a unique window to observe interactions between various environmental systems.

Sediment accumulation rates and particle mixing at northwestern Pacific seamounts

Cobalt-rich ferromanganese crusts are present on seamount summits throughout the northwestern Pacific at water depths of approximately 1000 to 2500 m, where they are often associated with unconsolidated sediments. Sedimentation rates at the summits of seamounts calculated from ages 14 C were 0.61 to 2.05 cm kyr −1 , higher than those of the surrounding abyssal plain. Sediments at seamount summits consist almost entirely of carbonate, which may contribute to higher sedimentation rates at summits than at seamount feet, which are below the carbonate compensation depth. The shallowest mixing layer depth and the smallest particle mixing coefficient (estimated from 210 Pb data) at the summit areas than at the foot of seamounts; suggest a weak bioturbation activity in the peaks. The difference in bottom-water dissolved oxygen and particulate organic matter concentrations between the summits and feet of the seamounts in the northwestern Pacific may contribute to this difference in bioturbation activity. • Sediment cores were collected from three guyots in the northwestern Pacific • Sediment accumulation rates on seamount summits were 0.61–2.05 cm kyr −1 • Mixing layer depth/particle mixing coefficients imply weak bioturbation on summits • Dissolved oxygen and particulate organic matter may markedly influence bioturbation

Revisiting the Carbonate Chemistry of the Sea of Japan (East Sea): From Water Column to Sediment

In this study, we investigated the carbonate system in sediments and water columns from five stations in the Sea of Japan (East Sea) (JES) during the R/V Hakuho Maru KH-10-2 research cruise in the summer of 2010. The total alkalinity (TA) and pH were measured. Adopting a saturation degree of 91% and 80% for the lysocline depth and calcite compensation depth (CCD), respectively, we found that those depths corresponded to 1360 and 1980 m. A comparison of the calcite saturation depths, lysocline depths, and CCD depths obtained for 1999 and 2010 suggests that acidification of the interior of the JES occurred. Sediment cores were retrieved using a multi-corer. In the sediment cores, a sharp decrease in the pH by 0.3–0.4 pH units was observed in the subsurface horizons (0–10 cm) compared with the pH of the seawater from the bottom horizons. The TA in the porewaters was significantly higher than that in the overlying seawater. The anaerobic degradation of organic matter is probably the main cause for the increasing TA in the sediments. The porewaters were significantly undersaturated with calcite and aragonite, except in that from the shallowest station, where the sediments below 7.5 cm were saturated, and even supersaturated, with calcite and aragonite. A linear correlation between the dissolved inorganic carbon and the TA for sediments with a slope of 0.9993 was found, despite there being potentially different ways for the diagenesis of the organic matter to occur. The diagenesis of organic matter in the top sediments of the JES forms gradients of TA and CO2* concentrations on the interface of “bottom water–sediments”. Averaged fluxes of TA and dissolved inorganic carbon (DIC) from the sediments to the bottom waters estimated by means of Fickian diffusion were calculated as 44 and 89 mmol/(m2 year) for TA and DIC, respectively.

Quantifying the controlling mineral phases of rare-earth elements in deep-sea pelagic sediments

Recent studies suggest that pelagic sediments can enrich rare-earth elements (REE) acting as a significant reservoir for the global REE budget as well as a potential resource for future exploitation. Although Ca-phosphate (e.g., bioapatite fossils) and Fe-Mn (oxyhydr)oxides (e.g., micronodule) have been considered important REE carriers in deep-sea sediments, the proportion of REE held by each mineral phase remains enigmatic. Here, we have investigated the sediments from two promising REE-rich prospective areas: the Tiki Basin in the Southeast Pacific (TKB) and the Central Indian Ocean Basin (CIOB). The mineral grains including bioapatite fossils and Fe-Mn micronodules have been inspected individually by in-situ microscale analytical methods. Correspondently, the REE bound to Ca-phosphate and Fe-Mn (oxyhydr)oxides have been sequentially extracted and quantified. The crucial role of Ca-phosphate is substantiated by sequential leaching which reveals its dominance in hosting ~69.3–89.4% of total REE. The Fe-Mn (oxyhydr)oxides carry ~8.2% to 22.0% of REE in bulk sediments, but they account for ~70.0–80.5% of Ce owing to their preferential adsorption of Ce over the other REE. Surface sediment on modern seafloor can accumulate high REE contents resulting from the REE scavenging by the host phases within the range of sediment-seawater interface. Differences between TKB and CIOB samples indicate that the REE enrichment in the deep-sea environment may be controlled by multiple factors including the productivity of overlying seawater (e.g., phosphorus flux), water depth relative to carbonate compensation depth (CCD), sedimentation rate, redox condition, and hydrothermal vent input (e.g., Fe-Mn precipitations).

The Nazca Drift System – palaeoceanographic significance of a giant sleeping on the SE Pacific Ocean floor

AbstractThe evolution and resulting morphology of a contourite drift system in the SE Pacific oceanic basin is investigated in detail using seismic imaging and an age-calibrated borehole section. The Nazca Drift System covers an area of 204 500 km2 and stands above the abyssal basins of Peru and Chile. The drift is spread along the Nazca Ridge in water depths between 2090 and 5330 m. The Nazca Drift System was drilled at Ocean Drilling Program Site 1237. This deep-water drift overlies faulted oceanic crust and onlaps associated volcanic highs. Its thickness ranges from 104 to 375 m. The seismic sheet facies observed are associated with bottom current processes. The main lithologies are pelagic carbonates reflecting the distal position relative to South America and water depth above the carbonate compensation depth during Oligocene time. The Nazca Drift System developed under the influence of bottom currents sourced from the Circumpolar Deep Water and Pacific Central Water, and is the largest yet identified abyssal drift system of the Pacific Ocean, ranking third in all abyssal contourite drift systems globally. Subduction since late Miocene time and the excess of sediments and water associated with the Nazca Drift System may have contributed to the Andean orogeny and associated metallogenesis. The Nazca Drift System records the evolution in interactions between deep-sea currents and the eastward motion of the Nazca Plate through erosive surfaces and sediment remobilization.

Characteristics of polymetallic enrichment on oceanic red bed in Matano Formation, Baturubei, Central Sulawesi, Indonesia

The Matano Formation on Sulawesi Island has Cretaceous oceanic red bed (CORB) facies, but there is no further research on the geochemical characteristics of the sedimentary rocks. This study aims to classify the CORB of the Matano Formation and reveal the polymetallic element enrichment in CORB by using the X-ray fluorescence (XRF) analysis method. Matano Formation in the research area consists of two different facies: radiolarites facies and red clay facies. Radiolarites facies grouped as Si-ORB, dominated by siliceous pelagic bioclastic and deposited under oxic environment. The red clay facies grouped as Al-ORB, the components dominated by hemipelagic material with a small amount of silica shelled pelagically and deposited under reduction environment. Red clay facies have higher enrichment elements Mn, V, Ni, Zn and La than radiolarites facies. Oceanic red bed facies of Matano Formation deposited in basin plain environment below carbonate compensation depth in a passive margin tectonic setting.

Exploring the paleoceanographic changes registered by planktonic foraminifera across the Cenomanian-Turonian boundary interval and Oceanic Anoxic Event 2 at southern high latitudes in the Mentelle Basin (SE Indian Ocean)

Planktonic foraminiferal population dynamics and benthic foraminiferal and radiolaria distributions combined with δ13C and δ18O measurements of both bulk carbonate and foraminifera provide clues concerning the paleoceanographic changes across the Cenomanian-Turonian boundary interval and the Oceanic Anoxic Event 2 (OAE 2) at southern high latitudes. Samples analyzed are from Integrated Ocean Discovery Program (IODP) Expedition 369 Site U1516 in the Mentelle Basin (eastern flank of the Naturaliste Plateau, Indian Ocean, SW Australia). Site U1516 was located at 60°–62°S paleolatitude during the mid-Cretaceous, and it is the first high latitude locality in the Southern Hemisphere where planktonic foraminifera are consistently recorded across the OAE 2 interval and its associated positive δ13C excursion. The sedimentary record at Site U1516 consists of a sequence of alternating black, dark greenish gray, and light greenish gray claystone in the Cenomanian that grade to white and light gray calcareous chalk interbedded with chert in the Turonian. The correlation between the δ13C and δ18O profiles at Site U1516 and the European reference section at Eastbourne (England) coupled with the integrated calcareous plankton biostratigraphy and stable isotopic data at Site U1516, indicate that a complete record of OAE 2 at Site U1516 was recovered. Below and in the lower part of OAE 2, the planktonic foraminiferal assemblages are dominated by small-sized (125–38 μm) opportunistic species of Microhedbergella and radiolaria indicating a dominantly eutrophic regime. Above the onset of OAE 2, a trough in the δ13C profile (Plenus Carbon Isotope Event: P-CIE) coinciding with a δ18O increase may correspond to the Plenus Cold Event as observed at low latitudes, although no evidence of cooling is registered in the microfossil assemblages. At Site U1516, the middle part of OAE 2 at the initiation of the plateau phase of the δ13C profile is masked by absence of carbonate, by the highest TOC values, and high biogenic silica (dominance of radiolaria) indicating this interval corresponded to a time of highly stressed eutrophic conditions with possible shoaling of the Carbonate Compensation Depth (CCD). Above this interval, bulk isotopic results yield lower δ13C values, and the CaCO3 increases are associated with the presence of even smaller-sized Microhedbergella showing cyclic fluctuations in absolute abundances with benthic foraminifera indicating dominantly eutrophic conditions likely affected by upwelling of nutrient-rich and δ13C-depleted intermediate water masses. Toward the top of OAE 2 and across the Cenomanian-Turonian boundary interval, the planktonic foraminiferal assemblages show changes in composition (e.g., Microhedbergella is replaced by Muricohedbergella), species occupying relatively deep ecological niches appear and an overall increase in diversity is observed. These features coupled with the foraminiferal species-specific δ13C and δ18O patterns reveal that Site U1516 occupied a paleoceanographic setting still affected by eutrophy likely related to enhanced input of nutrients but with episodes of stability with ecological/thermal separation in the surface waters. This interval also records the highest sea surface water paleotemperatures values estimated as 20°–23°C based on δ18O values of foraminiferal test and assuming seawater δ18O values of −1‰V-SMOW. Mesotrophic to oligotrophic conditions persisted after the OAE 2 and throughout the Turonian as evidenced by a diverse planktonic foraminiferal assemblage with different species occupying separate ecological niches in the mixed layer and thermocline.

Centennial to millennial-scale changes in thermocline ventilation in the Arabian Sea: insights from the pteropod preservation record

The Arabian Sea hosts one of the three thickest oxygen minimum zones (OMZs) of the world ocean. Mid–depth oxygen depletion profoundly influences the chemistry of thermocline waters (HCO3ˉ, CO32ˉ and pH), which in turn significantly influences the preservation state of carbonates. The carbonate preservation is primarily controlled by the degree of saturation level of seawater with respect to the calcite and aragonite. The seawater in OMZ is undersaturated with respect to the aragonite (a metastable polymorph of CaCO3). Pteropod test being aragonitic in composition is therefore highly susceptible to the dissolution and dissolves completely below the aragonite compensation depth (ACD). Because of the current condition of intense OMZ due to high primary productivity, enhanced respiration of sinking organic carbon and reduced thermocline circulation; the ACD is shallow, lying in the middle of the OMZ. Hence, preservation record of pteropods in sea–floor sediment archives past changes in thermocline oxygen condition, carbonate chemistry, the ACD and OMZ intensity. High resolution records of various pteropod preservation indices (total pteropod abundance, transparent Limacina inflata abundance, fragmentation index) in a sediment core from the lower OMZ of the Indian margin (off Goa) enabled to investigate aragonite preservation/dissolution events and their links with the changes in ACD and OMZ intensity in the eastern Arabian Sea during the last 70 kyr BP. The proxy records reveal centennial to millennial scale changes in aragonite preservation condition in concert with Northern Hemisphere climatic events (Dansgaard–Oeschger (D–O) cycles and Heinrich events). The pteropod preservation spikes apparently correspond to the Northern Hemisphere cold events (D–O stadials and Heinrich events). Whereas, the pteropod tests were either poorly preserved or completely dissolved during the warm phases of D–O cycles (interstadials). The aragonite preservation events are attributed to the low monsoon induced productivity combined with the increased thermocline ventilation by Subantarctic Mode and Antarctic Intermediate Waters (SAMW–AAIW) resulting a weak OMZ and deeper ACD. The novel proxies (abundances of Globorotalia menardii, a planktic foraminifera and Styliola subula, a pteropod species) are used to gain better insights in to the variability of thermocline ventilation and OMZ intensity through time.

Sedimentary record of Upper Triassic impact in the Lagonegro Basin, southern Italy: Insights from highly siderophile elements and Re-Os isotope stratigraphy across the Norian/Rhaetian boundary

The Norian and Rhaetian transition (Late Triassic) is characterized by a faunal turnover in major pelagic groups, such as radiolarians, conodonts, and ammonoids. Although catastrophic events such as emplacements of large igneous provinces and/or extraterrestrial impacts have been suggested to account for this biotic turnover, firm evidence based on geochemistry of sedimentary successions is still lacking. In order to assess environmental changes across the Norian/Rhaetian boundary (NRB), we report high–resolution stratigraphic variations for whole-rock major, trace, and highly siderophile element abundances, together with Re–Os isotope ratios for the Sasso di Castalda section in Lagonegro Basin, southern Italy. The section consists of a continuously exposed sequence of upper Norian (Sevatian) through the lower Rhaetian of a deep basinal deposits. Our data demonstrated that the upper Norian section records important events in stratigraphically ascending order: (1) a depositional environment moved below the Carbonate Compensation Depth, leading to the carbonate-biosilica transition associated with a slight depletion of elements favored in heavy minerals such as Zr, Hf, and Ti, (2) an input of Rochechouart impact components detected by platinum-group element anomaly, and (3) a transient change of redox state into low oxygen (dysoxic to suboxic) conditions marked by increases of V, U, and Re. This sequence of events suggests that the Rochechouart impact predates the major environmental changes resulting in faunal turnover at the NRB. Although their direct causal relationships are highly questionable given the small size of impactor and the interval between the impact horizon and the NRB, the possibility of triggering subsequent environmental and biotic collapses cannot be ruled out. This study provides the first identification of Rochechouart impact horizon in marine strata, which could be an important event marker for further studies on contemporaneous sections in the Lagonegro Basin and other localities.

Arcoid bivalve biodiversity during Eocene doubthouse cooling: Contrasting the active Cascadia Margin coldspot with the intracratonic Paris Basin hotspot

Response to the Eocene doubthouse interval of global climate cooling (53–33.5 Ma) is explored in arcoid bivalves of the families Parallelodontidae, Cucullaeidae, Arcidae, and Noetiidae. An anomalous biodiversity hotspot in the intracontinental Paris Basin of Northern Europe is contrasted with an equally anomalous coldspot at comparable latitude on the tectonically active Cascadia Margin of western North America. Reevaluation of arcoid shell morphology and an annotated glossary of shell features accompanies illustration and discussion of eight exemplar species, identifying new characters and distinguishing those with a strong phyletic signal from those representing functional convergence or developmental differences specific to size or age. Biodiversity anomalies cannot be attributed to any single factor. However, contributing factors include tectonic setting, correlates of bathymetric and sedimentary setting, sediment geochemistry, ocean gateway events, reorganization of current systems and water masses, deepening of the calcium carbonate compensation depth, patterns in the development of sea ice and polar ice storage, changes in sea level, and changes in atmospheric carbon dioxide and the carbon cycle. Opening of the Tasman Gateway and Drake Passage, thermal isolation of Antarctica, and evolution of a Pacific psychrosphere are correlated with the early appearance of cold-water molluscan taxa on the active Cascadia Margin along with the unrelated onset of arc volcanism, subduction, and geochemical changes associated with methane and sulfide seepage. Persistence of a shallow carbonate platform and proliferation of molluscan diversity in spite of global cooling is more difficult to explain, and understanding biogeographic anomalies requires additional climate proxy records. History of the western margin of North America includes an earlier Mesozoic volcanic arc and forearc basin in central and northern California with abundant basal arcoids, negating the need for westward migration out of the Tethyan region to the Cascadia Margin during the Paleogene.

Recording Fidelity of Relative Paleointensity Characteristics in the North Pacific Ocean

AbstractNorth Pacific Ocean sediments are important archives of geomagnetic field and paleoenvironmental evolutions, yet late Quaternary sedimentary sequences in the North Pacific Ocean are less explored because of generally low sedimentation rates and the challenge of dating sediments deposited below the calcite compensation depth. Core NP02 sediments from the North Pacific Ocean contain three visible tephra layers, which are identified as the To‐Of, Spfa‐1, and Kt‐3 tephra, respectively. An age model for core NP02 is established based on tephra correlation and one radiocarbon date, which gives a mean sedimentation rate of ∼11.6 cm/kyr. Magnetic analyses suggest the dominance of two remanence carriers; detrital vortex state and biogenic single domain magnetite. Variable depth offsets between the relative paleointensity (RPI) signals carried by the two remanence carriers adds a negligible age error (<0.5 kyr) to the core NP02 RPI record. Pronounced RPI amplitude variations are observed, and the Rockall and Laschamp excursions are identified in the core NP02 RPI record based on the age model. The fidelity of the core NP02 RPI record is further verified by comparison with other RPI stacks and records, and we demonstrate that the RPI variations can assist in chronology refinement.

The Biodiversity and Distribution of Abyssal Benthic Foraminifera and Their Possible Ecological Roles: A Synthesis Across the Clarion-Clipperton Zone

Benthic foraminiferal research in the North Pacific has a long history, with works published over a century ago providing important information about the taxonomy and distribution of morphospecies. These studies focused mainly on areas outside the Clarion-Clipperton Zone (CCZ). Our knowledge of foraminiferal faunas within the CCZ originates largely from recent baseline investigations related to likely future seabed mining of the polymetallic nodule deposits. These have revealed highly diverse assemblages of sediment-dwelling morphospecies among the meiofauna and macrofauna, as well as megafaunal xenophyophores and nodule-attached fauna. Morphological analyses have been complemented by metabarcoding studies that yielded even higher numbers of molecular species (Operational Taxonomic Units - OTUs). Monothalamids, the vast majority undescribed, constitute a substantial proportion of both morphological and molecular datasets, with multichambered agglutinated and calcareous foraminifera being less common. Their importance in this abyssal (>4,000 m depth) habitat likely reflects food limitation combined with carbonate dissolution close to and below the carbonate compensation depth. Literature records, supported in a few cases by genetic data, suggest that many morphospecies found in the CCZ have wide geographical distributions across the Pacific abyss and in other oceans. At smaller spatial scales (several 100s of kilometers) there is a general uniformity in assemblage composition. Nevertheless, many morphospecies are too rare to conclude anything about their geographical distributions. Similarly, the part played by benthic foraminifera in CCZ ecosystems is largely a matter of speculation, although their abundance across different size classes suggests that it is significant. Meiofauna-sized taxa that consume freshly-deposited organic detritus may be important in carbon cycling, particularly at the shallower, more eutrophic eastern end of the CCZ. Megafaunal xenophyophores can provide habitat structure for other organisms, potentially enhancing benthic biodiversity. Foraminifera of all sizes could be among the earliest recolonisers of disturbed or redeposited sediments. Their potential contributions in terms of both ecology and biodiversity make these protists significant members of benthic communities in the CCZ.