Cement Stone Research Articles

Influence of metakaolin on physical and mechanical properties of cement stone heat-resistant binder from mineral-technogenic raw materials of the Aral region

The results of studies of the influence of metakaolin obtained from kaolin of the Khodzhakul deposit on the process of formation of cement stone based on heat-resistant binder from mineral-technogenic raw materials of the Aral Sea region are presented. It has been established that metakaolin allows one to control the processes of hydration, setting and hardening of the cement mass. The high degree of hydration of aluminous cement in the presence of metakaolin provides porosity and sufficiently high compressive strength of the cement stone in the last 14‒28 days of hardening. Increasing the concentration of metakaolin in the cement mixture to 15 % affects not only the process of liquefying the cement mortar, reducing the setting and hardening time of the cement mass, but also increases the compressive strength of the cement stone. New formations of hydration products have been studied.

Investigation Report on Characteristics Strength Partial Replacement of Fine Aggregate with Copper Slag and Granite Powder

Concrete is one of the most widely used construction materials, consisting of cement, fine aggregates, coarse aggregates, and water. Traditionally, Ordinary Portland Cement (OPC), river sand, and Hard Broken Granite (HBG) stone are used in concrete production. However, the over-extraction of these natural resources has led to environmental concerns and increased costs. This has created a need for sustainable alternatives that maintain concrete’s quality and performance. This study investigates the partial replacement of fine aggregates with copper slag and granite powder in M25 grade concrete. Copper slag, a by-product of copper smelting, and granite powder, obtained during granite stone cutting, possess physical and chemical properties that make them suitable for concrete. Additionally, Pozzolana Portland Cement (PPC) is examined as a sustainable alternative to OPC. PPC, with its pozzolanic characteristics, enhances workability, chemical resistance, and long- term strength while reducing the carbon footprint. The research evaluates the mechanical and chemical properties of concrete incorporating PPC, copper slag, and granite powder. The study also highlights the environmental and economic benefits, demonstrating how these materials can contribute to sustainable construction practices. By promoting the use of industrial by-products and alternative binders, this research aims to develop high-performance, eco-friendly concrete suitable for modern construction needs. Keywords: Concrete, sustainable construction, fine aggregate replacement, copper slag, granite powder, Pozzolana Portland Cement (PPC), M25 grade concrete, industrial by-products, environmental sustainability.

Development of geopolymer binders

The scale of consumption of raw materials is large, and to a greater extent, it is the building materials industry that has a detrimental effect on the environment, thereby disturbing the pristine appearance and landscape of nature. Production volumes of Portland cement clinker have exceeded the mark of 5 billion tons per year. But the key dilemma lies in the emission of greenhouse gases, because during the high-temperature processing of raw materials to produce clinker, carbon dioxide, methane and nitrous oxide are released into the atmosphere. At the same time, slag-alkali and geopolymer binders can be considered as an alternative to resource-intensive Portland cement; they have found practical application in many developed countries of the world. A large backlog of research has allowed the authors of the work to model materials of both technogenic and natural origin “technogenic reaction powder – natural component – alkaline activator” in one binder system. Microanalysis confirmed the effectiveness of the integrated use of sodium silicofluoride and finely dispersed bentonite additives in the binder system, which had a beneficial effect on the pore structure of the stone and the properties of the cement stone. Using a properly designed binder composition “aspiration dust – finely dispersed bentonite – sodium silicofluoride – alkaline binder”, it is possible to obtain high-quality and durable composites with a low carbon footprint, thereby solving many environmental problems.

Polypropylene Fiber as a Factor of Reduction of the Total Shrinkage Strain of Expanded Clay Concrete

Statement of the problem. The article presents the development features of the total shrinkage strain of expanded clay concrete, expanded clay fiber-reinforced concrete, expanded clay steel-reinforced concrete, and expanded clay fiber-steel-reinforced concrete. According to the analytical review, the shrinkage strain decrease as a result of the fibers adding was noted by the researchers without analyzing the reason for the phenomenon. Therefore the purpose of the study is to establish the reason for the decrease of the shrinkage strain of expanded clay concrete with the addition of polypropylene fibers. Results. It has been confirmed that the polypropylene fiber addition reduces the total shrinkage strain of expanded clay concrete by 29—34 % on the 120th day with the volume content of fibers of 0.36 %. Empirical dependences of deformations compatibility for expanded clay fiber-reinforced concrete and expanded clay fiber-steel-reinforced concrete are set forth. Conclusions. It has been experimentally established that fiber is a significant factor on the first days of the concrete mixture hardening, when the elastic modulus of the fiber is greater than or equal to the elastic modulus of the cement stone. Fibers act as a bond and affect the redistribution of shrinkage stresses within the composite, thus reducing the values of the total shrinkage strain.

Utilization of waste phosphogypsum in high-strength geopolymer concrete: Performance optimization and mechanistic exploration

Phosphogypsum (PG) is an industrial waste produced during the manufacture of phosphoric acid. In this study, dihydrate phosphogypsum (DPG), ground granulated blast furnace slag (GGBFS), fly ash (FA), Portland cement clinker (PCC), sulfate alumina cement clinker (SACC), water reducer, sand, and stone were combined to create a phosphogypsum-based geopolymer (PBG) concrete. Concrete mix design was carried out based on the principle of maximum packing density, and the effects of water reducer type, sand ratio, water-to-binder ratio, and DPG content on PBG concrete properties were investigated. Results indicated that compared to SiKa ViscoCrete 540P (SVC 540P) water reducer, Melflux PLUS 1087L (MP1087L) significantly enhanced the performance of PBG concrete. With a water-to-binder ratio of 0.34, a sand ratio of 32.2 %, and a PG:GGBFS:FA ratio of 5:4:1, the 28-day unconfined compressive strength (UCS) of the concrete exceeded 60 MPa. The concrete primarily consisted of phases such as dihydrate gypsum (CaSO4·2H2O), ettringite (Ca6(Al(OH)6)2(SO4)3(H2O)26), polymer (-Si-O-Al-), quartz (SiO2), albite (Na(AlSi3O8)) and Muscovite ((K,Na)Al2(Si,Al)4O10(OH)2). Using two mild alkalis as activators, PBG concrete can avoid the efflorescence often associated with geopolymer preparation and can cure at 20 °C. PBG concrete offers high strength, ease of preparation, and environmental benefits, providing a new avenue for the reuse of PG.

Analysis of Changes in the Stress–Strain State and Permeability of a Terrigenous Reservoir Based on a Numerical Model of the Near-Well Zone with Casing and Perforation Channels

A finite element model, which includes reservoir rock, cement stone, casing, and perforation channels, was developed. The purpose of the study is to create a geomechanical model of the zone around the well, which includes support elements and perforation channels. This model will help predict changes in the productivity coefficient of a terrigenous reservoir and determine the most efficient mode of operation of a producing well. In order to exclude the stress concentration within the casing–cement stone and cement stone–rock, the numerical model applies contact elements. As a result, structural elements slip, while the stresses are redistributed accurately. The numerical simulation of a stress state in the near-well zone was carried out by using the developed model with differential pressure drawdown on the terrigenous reservoir, one of the oil fields in the Perm region. It is shown that the safety factor of the casing reaches roughly 3–4 units. The only exceptions are the upper and lower parts of the perforations, where this parameter is close to one unit. The safety factor of cement stone accounts for 2–3 units. However, parts with its lowest value (1.35) are also concentrated near the perforation channels. In order to analyze the change in permeability, the dependence of the safety factor on effective stresses was taken into account. Therefore, it was found that, in the upper and lower parts of perforations, the stresses decreased, while permeability rose by up to 20% of the initial value. An increase in differential pressure drawdown, on the contrary, can lead to a permeability reduction of 25%, especially in the lateral parts of the perforations. Areas of rock destruction under tensile and compressive forces were identified by using the Mohr–Coulomb criterion. It is estimated that with an increase in pressure drawdown, the areas of rock destruction under tensile force disappear, while the areas of rock destruction under compression increase. After further analysis, it was found that, with the maximum pressure drawdown of 12 MPa, the well productivity index can decrease by 15% due to the reservoir rock compaction.

Numerical simulation of the stress-strain state near the injection well at deep disposal facilities for liquid radioactive waste

Relevance. The need to predict deformations of the earth's surface near injection wells pumping liquid radioactive waste, as well as their stability when pressure changes in the well during injection. Aim. To perform a numerical analysis of the stress-strain state of the structural elements of the injection well and the surrounding rock mass using the finite element method, to determine the magnitude of the deformations of the earth's surface and define the stability of the well and the strength of the cement stone at the maximum injection pressure of liquid radioactive waste. Objects. Near-wellbore zone of one of the injection wells located at the liquid radioactive waste injection site. Methods. Numerical finite element method for calculating the stress-strain state of the near-wellbore zone, taking into account the distribution of the elastic properties of rocks along the simulated section and the main structural elements of the well. Results. The authors have developed the numerical finite element scheme of one of the injection wells, taking into account its main structural elements, as well as allowing you to set the pressure distribution within the exploited horizon during the injection of waste. In the model, the distribution of the elastic properties of rocks along the section was set, taking into account their lithological features. The authors carried out the analysis of the hydrodynamic parameters of the well operation and determined the maximum pressure at the wellhead during the injection of liquid radioactive waste, equal to 1.71 MPa. Numerical modeling of the stress-strain state of the near-wellbore zone was performed in two stages: for the conditions of an idle well and taking into account the pressure distribution at the maximum waste injection pressure. The distribution of vertical displacements at the level of the earth's surface, as well as at the top of the operational horizon at the maximum pressure of liquid radioactive waste injection, is obtained. It is shown that at such a pressure, the largest uplifts will be: on the earth's surface – 4.5 cm, on the top of the production horizon – 11 cm. An assessment of the stability of the well structural elements at a maximum waste injection depth of 280 m, corresponding to the maximum pressure, showed that the stresses in the well and cement stone are much lower than the values that can lead to their violation. For cement stone, the safety factor at a maximum pressure of 1.71 MPa was equal to 7.8.

Degradation of Concrete Cement Stone Under the Influence of Aspergillus niger Fungi

The concepts of physical and chemical transformations occurring in cement concrete under conditions of microbiological deterioration can be used to control the processes of the destruction of cement concretes in order to ensure the required durability and to predict the service life of products. The study of changes in the structural and phase composition of cement stone made of Portland cement grade CEM I 42.5N in the process of fungal deterioration for 6 months when moistened, as well as a sample of a concrete wall exposed to fungal microorganisms for 20 years, was carried out. Diffractograms of the studied cement stone samples contain a large number of pronounced narrow peaks and indicate a highly crystalline structure of phases with the presence of an X-ray amorphous phase of calcium hydrosilicates and tobermorite gel in the cement stone. Changes in the structure of cement stone under the influence of fungi are confirmed by the data of a derivatographic analysis. A decrease in the content of calcium hydrosilicates and ettringite, as well as other crystalline phases in cement stone, leads to a decrease in compressive strength by about 15% over 6 months of fungal degradation. Similar changes after 20 years of exposure to microorganisms suggest deterioration in the strength characteristics of concrete.

СОСТОЯНИЕ КАРБОНАТНО-КАЛЬЦИЕВОГО РАВНОВЕСИЯ КАЗАХСТАНСКОЙ ЧАСТИ БАССЕЙНА РЕКИ ЕРТИС

The materials of our own studies of the carbonate-calcium equilibrium in the Kazakh part of the Ertis river basin, conducted in July 2023, are presented. It has been established that the rivers and lakes of the Ertis basin differ in the state of carbonate-calcium equilibrium. This difference is due to a number of factors: carbonate alkalinity, total mineralization, pH value, water temperature, which in turn depend on the physical and geographical conditions of the region. The Kara Ertis River, its tributaries and Ertis itself in all areas have water unsaturated with calcium carbonate, containing aggressive CO2 in concentrations (0.02...5.50 mg/dm3), which do not pose a danger to concrete structures on Portland cement. The amount of supersaturation of CaCO3 water in rivers ranges from 0.03...0.92. In the isolated lakes Orlovskoye, Kurkol and Eski Ertis, an excess of the main equilibrium indicators was noted compared to rivers, the water in them becomes supersaturated with calcium carbonate by an average of 1.16...5.82 times. The water of the Balkyldak wastewater storage lake does not contain aggressive CO2, however, according to the content of normalized magnesium ions, chloride and sulfate ions, the water shows an aggressive effect on the cement stone of hydraulic structures of varying degrees.

True Triaxial Crack Stress Thresholds and Deformation Characteristics of Cement Stone Subjected to Sulfuric Acid Corrosion

True Triaxial Crack Stress Thresholds and Deformation Characteristics of Cement Stone Subjected to Sulfuric Acid Corrosion

Effects of Typical Supplementary Cementitious Materials (SCMs) on the Bonding Property of Cement with Casing under Shallow Formation of Deep-Water Environment

Due to low temperature environments and other factors, the performance of cement slurry is affected by deep-water shallow formation cementing, which makes it difficult to ensure the interface bonding quality. The objective of this study is to investigate the effect of fly ash (FA), metakaolin (MK), and microsilica (MS) as supplementary cementitious materials (SCMs) by replacing 5–20% of the cement on the bonding property of cement with casing in the shallow formations of deep-water environments. This is based on the cementing conditions for the 20″ surface casing in the deep-water shallow formation of the LS18-1 well area. Under the 30 °C experimental conditions, the results showed that the compressive and bonding strength of cement with FA and MS decreased gradually as their dosage increased. In contrast, compared with the control group (BG0), the compressive strength of the MK group increased by 25.6%, 32.1%, and 24.2% under the optimal dosages (MK15, MK15, MK20) at 3, 7, and 14 days (d), and the bonding strength increased by 73.6% at 3 d (MK15) and 34.9% at 7 d (MK15). The test analysis showed that MK can promote cement hydration and generate more hydration products, which are conducive to cement-casing interface cementation. Additionally, it can improve the pore structure, reduce the fractal dimension of the pore volume, and ensure a more reasonable distribution of cement stone crack openings.

Study on the Compressive and Tensile Properties of Latex-Modified Cement Stone.

The integrity of wellbores is essential for the safe and efficient operation of drilling activities. Cement plays a critical role in this process, serving as a primary barrier that isolates the casing from the surrounding formation. To ensure the proper application of cement in wells, a thorough understanding of its mechanical properties is essential. Latex-modified cement stone (LMCS) offers significant advantages due to its anti-channeling, anti-corrosion, and mechanical characteristics. This study examined the mechanical properties of LMCS through uniaxial and triaxial compression and Brazilian splitting tests. Under uniaxial compression, the elastic modulus, Poisson's ratio, and compressive strength of LMCS were found to range from 4.08 to 8.29 GPa, 0.05 to 0.46, and 15.82 to 22.21 MPa, respectively. In triaxial compression tests with confining pressures of 2 MPa, 4 MPa, 6 MPa, 8 MPa, and 10 MPa, the elastic modulus ranged from 4.48 to 6.87 GPa, Poisson's ratio from 0.05 to 0.16, and compressive strength from 27.38 to 39.58 MPa. The tensile strength of LMCS ranged from 2.34 to 3.72 MPa. Moreover, the compressive strength of LMCS increased with confining pressure, showing enhanced resistance to failure due to the confining effect. However, the rate of increase gradually diminished. Strength criteria for LMCS, including Mohr-Coulomb and Drucker-Prager parameters, were derived from the triaxial compression tests. These strength criteria parameters provide a useful reference for developing the constitutive model of LMCS and for simulating triaxial compression conditions. The findings of this research offer valuable insights that can guide the construction of oil and gas wells.

Increasing the reliability of oil and gas well fastening with polycomponent plugging systems

Purpose. Development of effective composite plugging systems for reliable fastening of oil and gas wells in difficult mining-geological conditions of deposits of Ukraine. Methods. The proposed research is based on an analytical and industrial study of the problems of the well construction and fastening in the conditions of chemogenic deposit occurrence when applying the analysis of geophysical research materials. The research of tamponage solutions and buffer liquids was carried out using standard devices and methods that meet the set of requirements for testing cements and technological systems for well construction. Processing of research results was carried out in MATHSAD and EXCEL. Composite cement CEM V according to the European standard EN 197-1, tamponage cement 1-G, krents - high-basic C2F CaSO4 and low-basic 3(CF) CaSO4 calcium sulfoferites were used for the research. Findings. It was established that the basic plugging material, as well as technological solutions for fastening wells in difficult mining-geological conditions, do not ensure compliance of the well as an engineering structure with operational reliability indicators. As a result, violations in the fastening system are quite often recorded, which require significant time and financial costs for their elimination, and sometimes lead to well liquidation. In order to increase the reliability of fastening wells, it is necessary to use multi-component tamponade systems modified by krents. Calcium sulfoferrite admixtures have been proved to accelerate the kinetics of early strength and contribute to the formation of cement stone with improved characteristics. The need to use effective buffer systems to improve the quality of fastening is substantiated. Originality. On the basis of assessment, systematization and detailed study of geophysical material and features of well fastening under the conditions of exposure to chemogenic sediments, the necessity of using composite plugging material was established. The conducted studies have proved that to ensure reliable fastening of wells in difficult mining-geological conditions, it is necessary to use multicomponent composite plugging material modified by calcium sulfoferites with accelerated kinetics of early strength, which form cement stone with a densely packed structure. Practical implications. Based on the industrial material evaluation and detailed laboratory studies, technological solutions have been developed to increase the reliability of well fastening due to the introduction of multi-component composite plugging material modified by krents and buffer liquids.

INFLUENCE OF MECHANICAL ACTIVATION ON THE PROPERTIES OF CEMENT-WATER COMPOSITIONS WITH THE ADDITION OF GROUND LIMESTONE

The paper considers the issue related to determining the effect of mechanical activation of a mineral binder on the properties of both hardening and hardened cement-water compositions. The mechanical activation of cement in combination with the consumption of ground limestone, the amount of which was adjusted in the range from 0 to 40 % of the cement mass, is relevant for this study. The effect of mechanical chemical activation of Portland cement only and Portland cement with the addition of 20 and 40 % ground limestone on changing the water-solid ratio of equiviscous compositions was studied. It was shown that mechanical and chemical activation of a cement-water composition has a positive effect on reducing the W/S ratio of equiviscous compositions from 0.42 (no activation) to 0.38 (activation period 180 sec). The obtained experimental results indicate the presence of an induction period of heating of the cement paste both on Portland cement not subject to mechanical activation (this period is approximately 6 hours from the moment of interaction of cement with water) and on Portland cement subject to mechanical activation. In this case, the induction period was no more than 2 hours. Joint mechanical activation of an aqueous mixture of Portland cement and ground limestone ensures acceleration of the hydration processes of the binder, which is confirmed by the intensification of the exothermic heating of the filled cement-mixing compositions. The positive role of mechanical activation is also reflected in the acceleration of the thickening rate of the compositions, which was recorded by the kinetics of the decrease in the diameter of their spread over time. The positive role of mechanical activation in reducing the effective viscosity of cement-containing compositions is confirmed, which ensures a decrease in their water-solid ratio by an average of ‒ 8 ... 10 %. A positive effect of mechanochemical activation of Portland cement with the addition of ground limestone on the strength of cement stone at the age of 3 days has been revealed. Experimental studies indicate that only due to mechanical activation the strength of samples made of cement stone with the addition of ground limestone can be increased by almost 25...30 %.

Development and Evaluation of Insulation Materials for Deepwater Cementing.

Marine oil and gas resources are abundant in deepwater regions, where the shallow seabed harbors natural gas hydrate layers due to the cold temperature and high-pressure environment. Hydrates are prone to thermal decomposition, which can compromise the integrity of cement sealing and even lead to accidents like blowouts. While current low-hydrated heat cement systems mitigate hydrate decomposition from cement hydration heat during the waiting period for cementing, they do not address heat transfer from deep strata to shallow hydrate layers through fluid circulation in the tubing during deep oil and gas development. Rather than utilizing costly pipe insulation technology, adjusting the thermal conductivity of well cement emerges as a cost-effective approach to prevent heat loss in the wellbore to the hydrate layer and thus inhibit hydrate decomposition. The critical aspect lies in utilizing insulation functional materials. This study delves into the functional and structural design of insulation materials suitable for cement slurry systems in well cementing, outlining the preparation methods and processes for two insulation materials (SDBW and SDBW-II) tailored for deepwater well cementing. SDBW and SDBW-II are both nuclear shell structural materials. The core is made of high-strength hollow microspheres, produced by using a reverse suspension polymerization method to form spheres followed by high-temperature sintering. The shell consists of a wear-resistant BPA epoxy resin layer, with the surface of SDBW-II also containing highly reflective glass microspheres. Incorporating 20% of material SDBW into the cement reduces the thermal conductivity of the cement stone from 0.8 to 0.31 W·(m·K)-1 while achieving a compressive strength of 6 MPa after 24 h at 20 °C. Material SDBW-II offers both thermal resistance and reflection functions, increasing reflectivity (R) from 0.3 to 0.5. By adding 20% of this material to the cement, under the same conditions, although the compressive strength decreases to 4.2 MPa, the thermal conductivity can be reduced to 0.27 W·(m·K)-1. Furthermore, there is no significant change within 180 days, demonstrating long-term thermal insulation stability. These developed insulation materials can effectively improve the thermal insulation performance of the cement sheath, thereby maintaining the stability of the upper natural gas hydrate layer in the oil and gas production process of deepwater wells, providing an innovative solution for the long-term operation of deepwater oil and gas wells.

Experimental study on the deformation and failure characteristics of cement stone under true triaxial stress state

The cement stone is widely utilized to fill the gap between the formation and the casing in wells. A clear understanding of the deformation and failure mode of cement stone under true triaxial stress state is necessary to ensure the safety and stability of wells. To analyze the three-dimensional deformation and failure characteristics of cement stone, the loading paths with constant Lode angle were employed in conducting true triaxial tests on cement stone. The stress-strain curve and failure mode of cement stone are first analyzed. Then, the three-dimensional deformation characteristics are discussed in meridian and deviatoric planes. Both peak strength and deformability increase with minimum principal stress, but show a tendency to increase and then decrease with intermediate principal stress coefficient. With the increase of minimum principal stress and intermediate principal stress coefficient, the failure mode of cement stone transforms from brittle to ductile behavior. Under elastic stage, the strain path in the meridian plane is a straight line, and is under constant Lode angle within the deviatoric plane. Due to the existence of plastic strain, the strain path in the meridian plane displays a downward convex shape. The strain path in the deviatoric plane deviates from the reference of constant Lode angle for stress, directly reflecting the Lode angle dependence of deformation. Both deformation and failure characteristics of cement stone are dominated by the three-dimensional stress state. Besides, deformation of cement stone is closely related to the failure characteristics of cement stone.

ASSESSMENT OF THE INFLUENCE OF INORGANIC PIGMENTS ON THE TECHNOLOGICAL PROPERTIES OF DECORATIVE CEMENTS

The article presents the results of research on the influence of inorganic pigments on the technological properties of decorative cements. It has been established that regardless of the color of the pigment, with an increase in its quantity in the system, we get a more saturated and bright color of cement stone, but at the same time there is a negative effect of pigments and technological and physical and mechanical properties of artificial stone. The research was conducted on cement systems based on white Portland cement without additives and on cement systems based on white Portland cement modified with polycarboxylate superplasticizer. An increase in the amount of pigment, regardless of its color, leads to an increase in the water consumption of the cement system, however, when a superplasticizer is introduced, the effect of the pigment is not so significant. At the same time, the introduction of a superplasticizer reduces the water consumption of white cement without the introduction of pigments by an average of 37-40%. In addition, it was established that the introduction of pigments affects the hardening time of cement systems. At the same time, pigments, depending on their color and dosage, have different effects on both the start and end of aging. With an increase in the pigment content in a cement system without a plasticizer, the time of the onset of hardening increases, and the introduction of a permanent pigment has the greatest effect on the end of hardening of such a system. The introduction of pigments into plasticized cement systems increases both the start and end time of hardening. As the number of pigments of all colors increases, the strength of the samples decreases. At the same time, the red pigment leads to the greatest decline in strength at all stages of hardening. The decrease in strength can be explained by the increased water consumption, and, as a result, the increased porosity of pigmented samples compared to samples without the introduction of pigments. Further research aimed at finding additives that will reduce the negative impact of inorganic pigments on the processes of hydration and hardening of the cement system, and therefore on the durability of the obtained artificial stone, will be relevant. At the same time, it is important to preserve the intensity of the color and the absence of sediment formation.

Seismic resilience assessment of sheet-pile wharves in liquefiable soils using different liquefaction countermeasures

Seismic resilience assessment is essential for maintaining the functionality of sheet-pile wharves in liquefiable soils, preventing significant damages and minimizing losses during earthquakes. This study delves into the seismic resilience of sheet-pile wharves, focusing specifically on the effectiveness of four different liquefaction countermeasure techniques: anchor lengths, cement deep mixing, stone columns, and soil compaction. As such, an advanced two-dimensional (2D) Finite Element (FE) computational framework is established, motivated by a typical large-scale sheet-pile wharf configuration. Within this framework, a recently developed multi-yield surfaces plasticity model is employed, with the modeling parameters calibrated through undrained stress-controlled cyclic triaxial tests and a centrifuge test. Subsequently, the impacts of these liquefaction countermeasures on the seismic resilience of the sheet-pile wharves are systematically investigated. Additionally, the effectiveness of combining longer anchor lengths with the other three mitigation techniques to enhance the seismic resilience of the sheet-pile wharves are examined. It is demonstrated that the synergistic effects of different liquefaction countermeasures can further reduce the liquefaction potential, thereby improving the seismic resilience. Overall, the FE analysis technique and the resulting insights are highly significant for the seismic resilience assessment of equivalent sheet-pile wharves in liquefiable soils, particularly when implementing such liquefaction mitigation countermeasures.

Synthesis and performance study of amphoteric polymer suspension stabilizer for cementing slurry at ultra-high temperature

As the number of ultra-deep wells increases, maintaining the suspension stability of cement slurry at ultra-high temperatures becomes increasingly challenging; the development of a suspension stabilizer suitable for ultra-high temperature environments is imperative. Therefore, this study synthesized a temperature-resistant polymer suspension stabilizer (LHAP) using 2-acrylamide-2-methylpropanesulfonic acid (AMPS), N, N-dimethyl acrylamide (DMAA), 4-acryloylmorpholine (ACMO), and quaternary ammonium cationic hydrophobic long-chain monomer hexadecyl dimethylallyl ammonium chloride (DMAAC-16) as raw materials. It was applied to maintain the suspension stability of cement slurry at ultra-high temperatures. The molecular structure and molecular weight of LHAP were characterized and tested using infrared spectroscopy, nuclear magnetic hydrogen spectroscopy, and Ubbelohde viscometer. The thermal stability and viscosity-temperature performance of LHAP were measured using thermogravimetric analysis and rheometer, respectively. Through the segmented density difference testing of cement stone columns, the suspension stability effect of LHAP on cement slurry under high temperature was evaluated. The suspension stabilization mechanism of LHAP was studied through fluorescence probe testing, variable temperature UV visible light testing, variable temperature particle size distribution testing, Zeta potential analysis, Environmental Scanning Electron Microscopy (ESEM) analysis, and scanning electron microscopy (SEM) analysis. The results indicated that the polymer suspension agent LHAP had excellent temperature resistance, and the molecules didn’t undergo significant thermal degradation below 302 ℃. At high temperatures of 220 ℃, LHAP could maintain the suspension stability of cement slurry, and the segmented density difference of cement columns was less than 0.01 g/cm3. Mechanism analysis revealed that in addition to enhancing temperature resistance by introducing sulfonic acid groups and rigid rings, LHAP also effectively maintains the stability of the slurry suspension at ultra-high temperatures by coordinating electrostatic interactions and molecular associations. LHAP can effectively solve the settlement instability problem of cement slurry under ultra-high temperature, which is beneficial for improving the safety and quality of cementing construction in ultra-deep wells.

Development of cement slurries with additives of nanoclay particles for the construction of oil wells at elevated temperatures

Relevance. Strength decrease is a phenomenon that becomes more pronounced as the temperature rises above 110°C. It is characterized by significant chemical and microstructural changes that Portland cement undergoes at high temperatures. Adding silica particles (SiO2) to cement can significantly increase cement resistance to strength reduction when the temperature exceeds 110°C. Nanoclays are currently used in the cement industry to increase the strength of the cement matrix due to their ability to fill capillary micropores and due to their relatively small particle size. Aim. To investigate the effect of adding nanoparticles (nanoclay) to Saudi grade G cement on compressive and tensile strength, and cement stone permeability under high temperature conditions (300°С). Objects. Six samples of cement mortars with different concentrations of nanoclay, cement stones from, tested after 7 and 28 days of hardening at 25 and 300°C. Methods. Cement chemical composition was evaluated by the X-ray fluorescence method with the WORKSTN-V Olympus Vanta X-ray fluorescence analyzer. Cement physical composition was evaluated by the method of ray diffraction on the Mastersizer 2000 laser particle size analyzer. The test of the grouting stone samples was carried out in accordance with ISO 10426-2:2003 on a hydraulic press 65-L1132. The tensile strength of the samples by the Brazilian method was tested in accordance with ASTM D 3967-08 standard on a hydraulic press 65-L1132. The permeability of the samples was determined by single-phase stationary filtration at a facility for studying the filtration and capacitance properties of the PIK-OFP-UCH core in accordance with ISO 10426-2:2003. Results. The data obtained showed that cement destruction at extremely high temperatures can be avoided by using nanoclay (up to 3% by weight of cement). The microstructure of the cement matrix was significantly affected due to the aggregation of nanoparticles when more than 3% of nanoclay was added. All rheological characteristics of the cement slurry were improved by the addition of nanoclay particles.