Calc-alkaline Research Articles

The Initial Subduction Time of the Proto-Tethys Ocean in the Eastern Section of the East Kunlun Orogen: The Constraints from the Zircon U-Pb Ages and the Geochemistry of the Kekesha Intrusion

The Cambrian period marks a crucial phase in the initial subduction of the Proto-Tethys Ocean beneath the East Kunlun Orogen. Studying the I-type granites and mafic–ultramafic rocks formed during this period can provide valuable insights into the early Paleozoic tectonic evolution of the region. This paper incorporates petrology, LA-ICP-MS zircon U-Pb geochronology, and whole-rock major and trace element data obtained from the Kekesha intrusion in the eastern section of the East Kunlun Orogen. The formation age, petrogenesis, and magmatic source region of the intrusion are revealed, and the early tectonic evolution process of the subduction of the Proto-Tethys Ocean is discussed. The Kekesha intrusion includes four main rock types: gabbro, gabbro diorite, quartz diorite, and granodiorite. The zircon U-Pb ages are 515.7 ± 7.4 Ma for gabbro, 508.9 ± 9.8 Ma for gabbro diorite, 499.6 ± 4.0 Ma for quartz diorite, and 502.3 ± 9.3 Ma and 501.6 ± 6.2 Ma for granodiorite, respectively, indicating that they were formed in the Middle Cambrian. The geochemical results indicate that the gabbro belongs to the high-Al calc-alkaline basalt series, the gabbro diorite belongs to the medium-high-K calc-alkaline basalt series, the quartz diorite belongs to the quasi-aluminous medium-high-K calc-alkaline I-type granite series, and the granodiorite belongs to the weakly peraluminous calc-alkaline I-type granite series, all of which belong to the medium-high-K calc-alkaline series that have undergone varying degrees of differentiation and contamination. Gabbro and gabbro diorite exhibit significant enrichment in light rare earth elements (LREEs), depletion in heavy rare earth elements (HREEs), and an enhanced negative anomaly in Eu (Europium). Compared to gabbro and gabbro diorite, quartz diorite and granodiorite exhibit more pronounced enrichment in LREEs, more significant depletion in HREEs, and an enhanced negative anomaly in Eu. All four rock types are enriched in large-ion lithophile elements (LILEs) such as Cs, Rb, Th, Ba, and U, and are depleted in high-field-strength elements (HFSEs) such as Nb, Ta, and Ti. This indicates that these rocks originated from the same or similar mixed mantle source regions, and that they are formed in the island-arc tectonic environment. This paper suggests that the gabbro and gabbro diorite are mainly derived from the basic magma formed by partial melting of the lithospheric mantle metasomatized by subducted slab melt in the oceanic crust subduction zone and mixed with a small amount of asthenosphere mantle material. Quartz diorite results from the crystal fractionation of basic magma and experiences crustal contamination during magmatic evolution. Granodiorite forms through the crystal fractionation of basic magma, mixed with partial melting products from quartz diorite. While the lithology of the intrusions differs, their geochemical characteristics suggest they share the same tectonic environment. Together, they record the geological processes associated with island-arc formation in the East Kunlun region, driven by the northward subduction of the Proto-Tethys Ocean during the Early Paleozoic. Based on regional tectonic evolution, it is proposed that the Proto-Tethys Ocean began subducting northward beneath the East Kunlun block from the Middle Cambrian. The Kekesha intrusion formed between 516 and 500 Ma, marking the early stages of Proto-Tethys Ocean crust subduction.

Late Triassic Felsic and Mafic Magmatism in the South Qinling Orogen, Central China: Insights from the Petrology, Zircon U-Pb Geochronology, and Geochemistry of the Huoshaodian Pluton

The petrology, geochemistry, and zircon U-Pb chronology of the Huoshaodian pluton in the Liuba area of the western part of the South Qinling tectonic belt are investigated in this study. The Huoshaodian pluton consists of gabbro, quartz diorite, and granodiorite, and the dominated rock type is quartz diorite. The results indicate that the Huoshaodian pluton belongs to the calc-alkaline series. In the chondrite-normalized REE, all of the samples showed similar patterns, with an enrichment of light REEs and depletion of heavy REEs, but they showed slight differences in the degrees of Eu anomalies. The primitive mantle-normalized trace element diagram reveals an enrichment of large-ion lithophile elements (LILEs) and light rare earth elements (LREEs), as well as depleted high field strength elements (HFSEs). The zircon U-Pb dating results reveal that the gabbro, quartz diorite, and granodiorite have crystallization ages of 214.9 ± 0.58 Ma, 215.0 ± 1.2 Ma, and 215.4 ± 1.9 Ma, respectively, indicating that the Huoshaodian pluton was emplaced during the late Triassic period (214.9–215.4 Ma). In terms of petrogenesis, the gabbro of the Huoshaodian pluton originates from a transitional lithospheric mantle that has undergone fluid metasomatism and partial melting. Specifically, it originated through 1%–2% garnet spinel peridotite undergoing partial melting. In addition, the gabbro underwent a slight degree of contamination by crustal materials during its ascent and intrusion, with some continental crust material being incorporated. The quartz diorite and granodiorite of the Huoshaodian pluton are formed through partial melting processes occurring within the normal lower crust. Combined with the previous studies on the early Mesozoic tectonic evolution of the South Qinling, this study proposes that the formation mechanism of the Huoshaodian pluton may be as follows: in the early Triassic, the Mianlue Ocean subducted northward beneath the Qinling microblock, resulting in a large-scale continental-continental collision between the North China Block and the Yangtze Block; when the oceanic crust subducted to a certain depth, the detachment of the subducting slab triggered the upwelling of mantle material. The heat from mantle-derived magma caused the partial melting of the mafic lower crust, while the mafic magma entered into the upper granitic magma chamber and began to mix. Due to the high viscosity contrast and temperature difference between the two end-member magmas, incomplete mixing led to the formation of a melt with distinct adakitic characteristics and a mafic melt representing mantle-derived material.

The Mekkam Inlier (Eastern Morocco): A Magmatic Domain with Mixed Characteristics: Contribution of Petrographic and Geochemical Data

The Mekkam inlier is located 50 km southeast of the town of Taourirt, in northeastern Morocco. It offers a great opportunity for the study of Variscan magmatism in Morocco. This inlier is punctuated by small magmatic bodies which we will characterize through a petrographic and geochemical study to situate this inlier in its geotectonic context. The petrographic study revealed the existence of three trends: acidic, intermediate, and basic, which are represented by facies ranging from granites to basanites, including andesites, rhyolites, trachytes, dacites, quartz microdiorites, Aplite and microgranites. All these facies have a mineralogical assemblage dominated by quartz, plagioclase, oligoclase, potassium feldspar, pyroxene, and biotite; the most abundant accessory minerals are zircon and apatite. Green hornblende is found in microdiorites and dacites. The geochemical analysis, conducted through the examination of major elements, trace elements, and rare earth elements, has uncovered the presence of two distinct magmatic series: a calc-alkaline series of the island arc type or active continental margin, and another alkaline series of syn-collision. Based on this combined data, we propose that the Mekkam sector represents a magmatic arc developed within a compressional tectonic regime located above a subduction zone, which was later followed by an intracontinental collision phase.

Geochemical Characteristics of Felsic Volcanic Rocks in Active Continental Margin above Ridge Subduction: A Case Study of the Neoproterozoic Suxiong Formation in the Western Yangtze Block

An N-S trending Neoproterozoic magmatic belt is preserved along the western margin of the Yangtze Block, which is characterized by predominant felsic and minor mafic-ultramafic rocks. However, four geodynamic models have been proposed to elucidate the formation of these rocks. In this paper, we present geochronological and geochemical data for dacite crystal tuff, rhyolitic welded tuff, and rhyolite from the Suxiong Formation. These findings, combined with the previously published Sm-Nd isotopic data, aim to provide robust constraints on the genesis of these felsic rocks and offer additional support for the geodynamic model of ridge subduction occurring beneath the western margin of theYangtze Block. Our study reveals that a fresh sample of dacite crystal tuff has a weighted average age of 813 ± 20 Ma. Major elemental data indicate that the samples have predominately peraluminous compositions. In addition, the rhyolites belong to the High-K Calc-alkaline Series and the dacite crystal tuffs are affiliated with the Calc-alkaline Series. They show seagull-shaped chondrite-normalized Rare Earth Elements (REE) patterns with negative Eu anomalies. Multi-element spider diagrams suggest they are enriched in Light Rare Earth Elements (LREE) and Large-Ion Lithophile Elements (LILE) and display Nb-Ta depletion. Additional geological, mineralogical, and geochemical clues suggest these rocks were derived from partial melting of associated Kangding Tonalite-Trondhjemite-Granodiorite (TTG) suites under low-pressure and high-temperature condition. This conclusion is also supported by the Sm-Nd isotopic compositions obtained from previous studies. The rocks have an A-type affinity and belong to A2-type group. On Rb-Hf-Ta triangular plot, they fall in the «volcanic arc» field and are thought to form at an «active continental margin». Moreover, these rocks are comparable in trace-element geochemistry to the rhyolites and dacites of Coast Range in western California, southern Alaska. In conclusion, we proposed that the 813 Ma felsic volcanic rocks of the Suxiong Formation were formed above a slab window driven by ridge subduction. This idea offers additional evidence for supporting a geodynamic model of ridge subduction existing along the western margin of the Yangtze Block during the Neoproterozoic era.

U-Pb AGE AND GEOCHEMICAL TYPIFICATION OF THE SARAM MASSIF ROCKS (WESTERN TRANSBAIKALIA): EARLY JURASSIC GRANITOID MAGMATISM

The paper presents data on the geological position, age and features of the material composition of the Saram massif granitoids, located in the northwestern part of the Malkhan ridge of Western Transbaikalia. The structure of the massif involves two-phase rocks corresponding to syenite, early-phase moderate-alkali granite and late-phase leucogranite families. The silica content (wt. %) varies from 63.8 to 71.2 in the early-phase granitoids and from 73.2 to 77.1 in the late phases. The early-to-late-phase rocks of the massif are mostly ferruginous (Fe*=0.77–0.88 and 0.80–0.93, respectively). Based on a high modified alkaline lime index (MALI) (8.75–9.97) and relatively low SiO2 contents, the early-phase rocks can be referred to as alkaline rocks, and the late-phase rocks – as calc-alkaline rocks. According to the aluminum saturation index, the early-phase rocks (0.93–1.07) correspond to moderate-to-high-alumina rocks, and the late-phase rocks (1.09–1.13) – to high-alumina formations. Granitoids are geochemically and mineralogically different from typical agpaitic A-type granites and correspond to a special group of aluminous A-type rocks. The two phase magmatic zircon U-Pb dating yielded the 175–177 Ma age (Early Jurassic). The formation of granitoids in the Saram massif is temporally synchronous with intensive orogenesis in Transbaikalia, probably caused by the closure of the Mongol-Okhotsk Ocean.

Petrogenesis of Permian Granodiorite and Diorite in Eastern Jilin Province and Its Constraints on the Late-Stage Evolution of the Paleo-Asian Ocean

The Solonker-Xar Moron-Changchun-Yanji Suture Zone is the result of the final closure of the Paleo-Asian Ocean (PAO). However, the closure time of the PAO in Northeast China remains controversial. The Hunchun area is located in the easternmost part of the Solonker-Xar Moron-Changchun-Yanji Suture Zone. Tectonism and magmatism in the Hunchun area can provide important information for understanding the late-stage evolution of the PAO. In this study, our zircon U-Pb ages show that the granodiorites and diorites in the Hunchun were formed at 282.3–251.4 Ma. This geochronological evidence suggests prolonged Permian magmatism in the Hunchun area. Whole-rock geochemistry, zircon trace, and Lu-Hf isotope data show that all the intrusive rocks are mainly calc-alkaline series to arc tholeiite series. Granodiorites are I-type granites formed by the partial melting of juvenile lower crust derived from the mantle. Diorites show similar characteristics to the sanukitic high-Mg diorite and are formed by the partial melting of the depleted mantle metasomatized by subduction sediments and/or slab-derived fluids. These results indicate that the Permian diorites and granodiorites in the Hunchun area formed in an active continental margin setting related to the subduction of the PAO plate. Significantly, sudden changes in the whole-rock Sr/Y and (La/Yb)N ratios and zircon εHf(t) values are observed in the Late Permian-Early Triassic igneous rocks in the eastern Central Asian Orogenic Belt (CAOB). This indicates that the final closure of the PAO in Northeast China likely occurred in the Late Permian-Early Triassic.

The Petrogenesis of Devonian Volcanism and Its Tectonic Significance in the Kalatag Area, Eastern Tianshan, Xinjiang, China

The Kalatag mineralization belt is an important metallogenic belt of polymetallic mineral deposits in the northern part of eastern Tianshan, and its age and tectonic setting are still controversial. We identified a set of Devonian volcanic rocks hosted in the Early Palaeozoic package of dominantly marine sediments with a small amount of terrestrial rocks. This study presents petrological, U–Pb geochronology, and geochemical data for the volcanic rocks. The ages of the rhyolite (407.2 ± 1.9 Ma) and basaltic andesite (380.4 ± 2.8 Ma) suggests that the Kalatag belt is a Devonian volcanic succession. These rocks consist mainly of marine calc–alkaline lava, tuff, pyroclastic rocks, and minor terrestrial basaltic andesite. The lavas are characterized by the enrichment of light rare earth elements and strongly depleted in Nb and Ta, typical of island arc magmatic rocks. The volcanic rocks probably originated from the partial melting of the mafic lower crust which was modified by subducted slab-related fluids. During their ascent through the crust, these volcanic rocks underwent variable extents of fractional crystallization (rhyolites) and crustal contamination (basaltic andesites). Combined with the results of previous studies, we suggest that the Devonian rocks formed in an island arc related to the northward subduction of the Northern Tianshan Ocean with a crustal thickness of ~35–40 km.

Early Jurassic petrogenesis of the retro-arc volcanism of northwestern Patagonia, Argentina: Evidence from Lu-Hf isotopes and whole-rock geochemistry

Located in the north-western Patagonian Massif, the Loncón Complex offers insight into the Upper Sinemurian syn-rift phase of this Patagonian sector. New whole-rock geochemistry and zircon Lu–Hf isotopic data, combined with adjacent volcanic depocentres such as the Lonco Trapial Formation, the Cañadón Chileno Complex, the Cerro Piche Graben Formation, the Comallo Volcanic Sedimentary Complex as well as the Colomichicó Formation from the Neuquén syn-rift phase, allow us to constrain the tectonic characteristics and evolution of the Jurassic retro-arc system of Patagonia. The effusive and explosive volcanism registered by andesitic lava flows and dykes and rhyolitic pyroclastic deposits defines subalkaline and calc-alkaline series. Additionally, the eruptive rocks show significant enrichment in light rare-earth elements and large-ion lithophile elements, and lower La/Ta, Ba/Ta and higher Th/Ta than the effusive rocks. Both units show depletion in high field strength elements (e.g., Nb, Ta, Zr, and Hf), and relatively high Nb/U, Ta/U, moderate La/Yb and low Th/Ta and Sr/Y ratios. Negative and positive εHf zircon values (−4.8 to +4.1) reveal the rocks were derived from the partial melting of a metasomatised mantle, which underwent moderate crustal contamination during its emplacement. These I-type hybrid magmas are generated on an extensional tectonic setting, probably caused by the retreating of the orogen, during Sinemurian times. This intraplate extension is considered slightly before the Early Jurassic Chon Aike (V1) episode.

Petrogenesis and Geochronology of Late Devonian Intrusive Rocks in Eastern Tianshan, Xinjiang, China: Subduction Constraints of the North Tianshan Ocean

We conducted a study on the petrology, geochemistry, and zircon U–Pb dating of Late Devonian intrusive rocks in the Tulargen area of the Eastern Tianshan Orogenic Belt, Xinjiang, China. These intrusive rocks primarily consist of gabbro (382 ± 5 Ma), tonalite (370.9 ± 2.7 Ma), and biotite monzogranite (362.8 ± 4.4 Ma). Gabbro belongs to the low-K calc-alkaline series of quasi-aluminous rocks, with a high Al2O3 content (16.46–20.34 wt.%) and Mg# value (64.55–67.73). Tonalite and biotite monzogranite, which belong to the high-K calc-alkaline series, are metaluminous or weakly peraluminous and also exhibit high Al2O3 contents (14.6–15.87 wt.%) and Mg# values (40.12–62.47). These rocks are enriched in light rare-earth and large-ion lithophile elements (Rb, Ba, and K) and depleted in heavy rare-earth and high-field-strength elements (e.g., Ta, Nb, and Ti), characteristics typical of island-arc magmatic rocks. Gabbro melts are primarily derived from the mantle and result from the partial melting of a depleted mantle that has undergone fluid metasomatism due to subducted plates. Tonalite exhibits high 176Hf/177Hf and εHf(t) values, with a younger two-stage model age (tDM2) derived from partial juvenile crust melting. The source magma of the biotite monzogranite originated from partial metabasalt melting at a medium crustal depth combined with a new lower crustal material. We concluded that the Late Devonian intrusive rocks in this area formed within the island-arc tectonic setting are associated with the subduction of the North Tianshan Ocean.

Petrogenesis of early Paleozoic syn-collisional granitoids and enclaves in Western Kunlun, Northwest China: Implications for the growth of continental crust

The Western Kunlun Orogenic Belt (WKOB), along the northwestern margin of the Qinghai–Xizang Plateau, was formed by the collision of Gondwana-derived terranes to the south and the Tarim Block to the north and was closely associated with closure of the Proto-Tethys Ocean during the late Neoproterozoic to early Paleozoic. We present a combined zircon UPb geochronology, whole-rock composition, and Sr–Nd–Hf isotopic study of syn-collisional granitoid plutons and mafic microgranular enclaves (MMEs) in the region. Zircon UPb dating yields ages of 443.8 ± 4.4, 451.9 ± 4.2, 462.9 ± 3.5, and 456 ± 4.2 Ma for the Tongayoupuagezi, Shanjie, and Pishigai plutons and MMEs from the Pishigai pluton, respectively. The granitoids are metaluminous to weakly peraluminous (A/CNK = 1.00–1.17) and belong to the high-K calc-alkaline series. They have (87Sr/86Sr)i ratios of 0.7058–0.7154, εNd(t) values of −8.78 to −0.93, and εHf(t) values of −19.72 to +6.87. The MMEs have variable SiO2 contents (45.7–60.2 wt%) and are more mafic than the host granitoids, but have similar Sr–Nd–Hf isotopic compositions to the host granitoids [(87Sr/86Sr)i = 0.7102–0.7110; εNd(t) = −6.57 to −3.56; εHf(t) = −7.17 to −1.81]. The MMEs are fragments of cumulates formed during the early stages of magma evolution. The granitoids were produced by the partial melting of a mélange source. The new data support the view that the Middle–Late Ordovician syn-collisional granitoids with MMEs distributed along the WKOB represent a magmatic response to terrane collision. This suggests that juvenile crustal growth in older orogenic systems, which occurs by arc addition, also involves some vertical addition during the final stage of orogenic collision. Our study suggests that mélange diaper melting is a key mechanism of crustal growth during the syn-collision stage in continental collision zones, associated with slab breakoff.

The role of magma recharge and mixing in producing compositional modality in post-collisional volcanic rocks, Konya Volcanic Field, Central Anatolia (Türkiye)

The Neogene Erenlerdağ-Alacadağ (ErAVC) and Sulutas (SVC) volcanic complexes in the Konya Volcanic Field, Türkiye have distinctly different unimodal and bimodal compositional variations, respectively. They occurred in graben-like extensional basins behind the retreating Cyprus subduction zone between the African and Eurasian plates. We here investigate their compositional modality by using new and published whole-rock major and trace element and Sr-Nd-Pb isotope data.Both complexes are characterized by basaltic to rhyodacitic high-K calc-alkaline rocks with the geochemical signatures of orogenic volcanism, except for minor alkaline rocks in the SVC. Mass-balance models suggest that major element variations can be largely explained by the fractional crystallization of amphibole, plagioclase, and Fe-Ti oxides. However, Sr-Nd-Pb isotopes show correlations with SiO2 indicating that open-system processes played a role in their differentiation. Modeling of AFC (Assimilation and Fractional Crystallization) involving a recharge situation shows that low degrees of crustal assimilation (rate of assimilation/rate of fractional crystallization, r < 0.2 and crust/magma ratio, ρ: 15–16 %) of lower and upper crust-like rocks was involved in the differentiation of the ErAVC and SVC, respectively. However, the modeling suggests that magma recharge (β: rate of magma recharge/rate of assimilation) was more efficient in the ErAVC (β: 3.45, % ∼52.5 rate of recharge) relative to that of the SVC (β: 2.15, % ∼36.55 rate of recharge). We conclude that for the ErAVC and SVC, different parental magmas derived from the subduction-modified mantle source followed distinct differentiation paths in the crust, and their compositional modality was mainly controlled by the magma recharge and mixing process.

Composite Granitic Plutonism in the Southern Part of the Wadi Hodein Shear Zone, South Eastern Desert, Egypt: Implications for Neoproterozoic Dioritic and Highly Evolved Magma Mingling during Volcanic Arc Assembly

The Abu Farayed Granite (AFG), located in the southeastern desert of Egypt, was intruded during the early to late stages of Pan-African orogeny that prevailed within the Arabian–Nubian Shield. The AFG intrudes an association of gneisses, island arc volcano–sedimentary rocks, and serpentinite masses. Field observations, supported by remote sensing and geochemical data, reveal a composite granitic intrusion that is differentiated into two magmatic phases. The early granitic phase comprises weakly deformed subduction-related calc–alkaline rocks ranging from diorite to tonalite, while the later encloses undeformed granodiorite and granite. Landsat-8 (OLI) remote sensing data have shown to be highly effective in discriminating among the different varieties of granites present in the area. Furthermore, the data have provided important insights into the structural characteristics of the AFG region. Specifically, the data indicate the presence of major tectonic trends with ENE–WSW and NW–SE directions transecting the AFG area. Geochemically, the AFG generally has a calc–alkaline metaluminous affinity with relatively high values of Cs, Rb, K, Sr, Nd, and Hf but low contents of Nb, Ta, P, and Y. The early magmatic phase has lower alkalis and REEs, while the later phases have higher alkalis and REEs with distinctly negative Eu anomalies. The AFG is structurally controlled, forming a N–S arch, which may be due to the influence of the wadi Hodein major shear zone. The diorite and tonalite are believed to have been originally derived from subduction-related magmatism during regional compression. This began with the dehydration of the descending oceanic crust with differential melting of the metasomatized mantle wedge. Magma ascent was long enough to react with the thickened crust and therefore suffered fractional crystallization and assimilation (AFC) to produce the calc–alkaline diorite–tonalite association. The granodiorite and granites were produced due to partial melting, assimilation, and fractionation of lower crustal rocks (mainly diorite–tonalite of the early stage) after subduction and arc volcanism during a late orogenic relaxation–rebound event associated with uplift transitioning to extension.

Petrogenesis and tectonic evolution of mineralized mafic intrusions in the Eastern Desert of Egypt: Implications for gold–sulfide genesis

The whole–rock chemistry, mineral chemistry, and remote sensing data of the Atud–UmKhasila Neoproterozoic mafic intrusions in the Eastern Desert of Egypt show two different mafic plutons: (1) the metagabbro–diorite complex; and (2) the G. Atud gabbros. Both of these contain two types of Cu–Ni–Fe–sulfide mineralizations. Multispectral remotely sensed images of Landsat 8 OLI/TIRS, Sentinel 2–B, and ASTER1T were used to give an overview of hydrothermal alteration signatures and distinguish different lithological units. The G. Atud gabbros are intruded into the metagabbro–diorite complex and consist mainly of olivine gabbros, while the metagabbro–diorite complex comprises metagabbros, diorites, and quartz diorites. They were formed under high fO2 (ΔFMQ= +1.43 to + 0.33) with a higher crystallization temperature (∼ 900–1100 °C) and pressure (∼ 6.0 kbar on average) at 18 km depth relative to associated metagabbros. Like magmatic sulfides in mafic intrusions, the G. Atud gabbros contain disseminated grains of pyrrhotite, pentlandite, chalcopyrite, and pyrite, up to 5 vol%. On the other hand, sulfide deposits (up to 30 vol%) such as pyrite, As–bearing pyrite, arsenopyrite, and gold with minor sphalerite and galena at the Atud gold mine, are related to the metagabbro–diorite intrusion. They are found as disseminations, patches, microveinlets, and bands. The sulfide deposits and economic gold are spatially concentrated in smoky quartz veins (up to 25 g/t) and metasomatic alteration zones, i.e., silicification and hematization of metagabbros (0.32 g/t), phyllic, argillic, and propylitic alteration, and carbonate–silicified zones, along gabbroic intrusive contacts, which all follow the Najd NW–SE shear zone. They are possibly of hydrothermal origin (epigenetic). They are also precipitated by mineralized fluids (rich in Si, K, Fe, Pb, Ag, Au, As, S, Ni, Zn, Cu, CO2, and H2O) that have been derived from a mixed magmatic–metamorphic source. The high Au contents with As–bearing pyrite and arsenopyrite in both Fe–rich and smoky quartz veins are related to the interaction between Fe from metagabbro–diorites and the Au(HS)-2 compound as well as the crystallization of pyrite, which reduced the sulfur contents in the mineralized fluids and hence led to gold precipitation. The late intrusion of G. Atud gabbros into metagabbro–diorite rocks enhanced the circulation of sulfide-gold-bearing hydrothermal fluids towards the contacts of the latter ones. These fluids along the shear zones cause metasomatic alteration in addition to leaching and the collection of sulfides and gold in the metagabbros. The protoliths of metagabbro–diorite rocks have a calc–alkaline nature and were formed in a volcanic arc setting, while the G. Atud gabbros were crystallized from Mg-rich tholeiitic melts in the extensional rift (e.g., rifted arc) setting as a result of asthenospheric upwelling due to the slab detachment and/or lithospheric delamination. The Atud gold–sulfide mineralization was related to the thermal uplifting–extensional tectonism. The enrichment of the G. Atud gabbros in LILE, alongside LREE over HFSE, reflects their derivation from a metasomatized mantle source during a rifted arc following the subduction processes.

Comparative Study of Sulfides from Porphyry, Skarn, and Carbonate-Replacement Mineralization at the Recsk Porphyry-Mineralized Complex, Hungary

A calc–alkaline dioritic–andesitic–dacitic intrusive–volcanic complex of Early Oligocene (30 Ma) age and its Mesozoic sedimentary basement at Recsk host a well-preserved porphyry–skarn–polymetallic carbonate-replacement–epithermal mineral system. The unique occurrence offers an exceptional possibility to study these related mineralization types at a single locality. This study presents the textural–paragenetic, compositional characteristics, and systematics of sulfide mineral assemblages for the porphyry, skarn, and carbonate-replacement ore types, which are currently situated at a depth of 500–1200 m below the present surface. Detailed petrography combined with EPMA analyses of molybdenite, galena, sphalerite, tetrahedrite-group minerals and Bi-bearing sulfosalts allows for the establishment of characteristic mineral and chemical fingerprints for each mineralization type. Rhenium concentration in molybdenite, occurring as rare disseminations and quartz–carbonate veinlets in altered host rocks in all three mineralization types, shows a decreasing trend towards the more distal mineralization types. High Re contents (x¯ = 1.04 wt.%, max. up to 4.47 wt%) are typical for molybdenite from the porphyry mineralization, but Re is not homogeneously distributed, neither within individual molybdenite crystals nor on a mineralization scale. Copper and Se show opposite behavior in molybdenite, both becoming enriched in the more distal mineralization types. Silver, Bi, and Se concentrations increase in galena and tetrahedrite-group minerals, both towards the country rocks, making them the best candidates for vectoring within the whole hydrothermal system. For tetrahedrite-group minerals, Ag, Bi, Se, together with Sb and Zn, are the suitable elements for fingerprinting; all these are significantly enriched in the distal carbonate-replacement mineralization compared to the other, more proximal ore types. Additionally, further trends can be traced within the composition of sulfosalts. Lead-bearing Bi sulfosalts preferentially occur in the polymetallic carbonate-replacement veins, while being under-represented in the skarn and porphyry mineralization. Porphyry mineralization hosts Cu-bearing Bi sulfosalts dominantly, while skarn is characterized by Bi-dominated sulfosalts. Sphalerite, although present in all mineralization types, cannot be used for fingerprinting, vectoring, or thermobarometry based on EPMA measurements only. Trace element contents of sphalerite are low, often below the detection limits of the analyses. This is further complicated by the intense “chalcopyrite disease” occurring throughout the distal mineralization types. All the above-listed major, minor, and trace element ore mineral characteristics enable the characterization of the Recsk ores by mineral geochemical fingerprints, providing a possible vectoring tool in porphyry Cu–(Mo)–Au-mineralized systems.

Spatiotemporal distribution and mechanism of Mesozoic magmatism in the Taiwan Strait and its adjacent areas: insights from seismic, geochemical, and geochronological data

ABSTRACT This paper presents a complete map of the Mesozoic volcanic-plutonic complexes in the Taiwan Strait and its adjacent areas in terms of seismic profiles, ages, geochemistry, isotopic systematics, and published data. Two periods of igneous activity in the Taiwan Strait can be distinguished by seismic profiles: Jurassic (200.4–148.2 Ma); and Latest Jurassic/Cretaceous to Maastrichtian (144–66 Ma), of which the Cretaceous is the best preserved and could possibly be the most widespread. Mesozoic magmatic activity with the NE-striking distribution was migrating southeastward (oceanward). LA-MC-ICPMS zircon U – Pb dating yields the age data of 109.5 ± 0.4 Ma for PTDH1 granodiorite and 92.6 ± 0.4 Ma for PTDH4 rhyolite in the Taiwan Strait, respectively. The 581.66-m-thick Upper Jurassic volcanic rocks of the Chuan2 well are the thickest Mesozoic igneous rocks in the Taiwan Strait. The petrogenetic discrimination diagram of the Cretaceous volcanic-plutonic complexes along the coast of South China and the Taiwan Strait generally is belonging to volcanic arc or intraplate type calc-alkaline rock series. The high potassium calc-alkaline rock series of the Cretaceous volcanic-plutonic complexes that is most widely distributed in the coastal areas of South China and the Taiwan Strait. They are controlled by the subduction of the Palaeo-Pacific domain.

1.38 Ga magmatism and the extension tectonics in East Kunlun, northern Tibetan Plateau

Numerous Paleo- to Mesoproterozoic magmatic rocks were emplaced during the assembly, accretion and break-up of the Columbia supercontinent, and are keys to illustrating the supercontinent circle. The geological, petrological, geochronological and geochemical data of the newly discovered meta-felsic and meta-mafic magmatic rocks from the Wulonggou area are presented in this study to shed light on the Mesoproterozoic geodynamic setting of the Central Kunlun Belt and the Qaidam Block. Zircon U-Pb geochronological results indicate that the crystallization ages of the meta-felsic samples are 1385–1376 Ma, and the meta-mafic is 1379 ± 25 Ma (MSWD=0.17). Samples from the meta-felsic unit have SiO2 contents of 68.37–73.03 wt% and belong to the high-K calc-alkaline series. They exhibit similar REE distribution patterns and display enrichment in light rare earth elements (LREES) and negative Eu anomalies. Enrichments in Rb, Ba, Th, U and K, depletion in Nb, Ta, Sr, P and Ti are seen in the primitive mantle-normalized trace element pattern diagram. Magmatic zircons from different meta-felsic samples yield variable εHf(t) values of −8.14 to + 9.37 corresponding to ca. 1.7–2.0 Ga two-stage Hf model ages. Samples from the meta-mafic unit have low SiO2 concentrations of 49.87–50.43 wt%, high contents of Fe2O3T, MgO, CaO and TiO2, and Mg# values of 52–58. They show low total REE concentrations of 19.8–30.4 µg/g, and depletion in LREES, flat HREES distribution patterns with (La/Yb)N of 0.27–0.53 and insignificant Eu anomalies. Flat distribution pattern of high field strength elements (HFSEs) is observed in the primitive mantle-normalized trace element pattern diagram. They display similar immobile elements’ concentrations and distribution patterns, low Ti/Y, Nb/Y, La/Yb, and high Nb/La ratios, comparable with the present-day normal middle ocean ridge basalt. Zircons from the meta-mafic sample have mostly positive εHf(t) values ranging from −0.10 to + 4.10 with a single stage Hf model ages of ca. 1.7–2.0 Ga. The geochemical result implies that the meta-felsic unit was generated by partial melting of the Paleoproterozoic juvenile mafic lower-crustal material with mantle attributions, and the meta-mafic unit was probably from partial melting of the lithospheric mantle. Synthesizing the above evidences, Wulonggou Mesoproterozoic meta-magmatic rocks are a bimodal suite formed in a continental extensional tectonic setting which is probably related to the break-up of the Columbia supercontinent.

Petrogenesis and Geodynamic Mechanisms of Porphyry Copper Deposits in a Collisional Setting: A Case from an Oligocene Porphyry Cu (Au) Deposit in Western Yangtze Craton, SW China

The Xifanping deposit is a distinct Cenozoic porphyry Cu (Au) deposit located in the Sanjing porphyry metallogenic belt 100–150 km east of the JinshajFiang fault in the western Yangtze craton. We present new zircon U–Pb–Lu–Hf isotopic studies and geochemical data of the ore-bearing quartz monzonite porphyry from the Xifanping deposit to determine their petrogenesis and geodynamic mechanisms. LA–ICP–MS zircon U–Pb dating yielded precise emplacement ages of 31.87 ± 0.41 Ma (MSWD = 0.86) and 32.24 ± 0.61 Ma (MSWD = 1.8) for quartz monzonite porphyry intrusions, and 254.9 ± 5.1 Ma (MSWD = 1.7) for inherited zircons of the monzonite porphyry. The ore-bearing monzonite porphyry is characterized by high-K calc–alkaline to shoshonite and peraluminous series, relatively enriched in light over heavy REEs, with no distinct Eu anomalies, as well as enrichment in LILEs and depletion of HFSEs, with adakitic affinities. The zircon Lu–Hf isotope data ranged from εHf(t) values of −2.94 to +3.68 (average −0.47) with crustal model (TDM2) ages ranging from 0.88 to 1.30 Ga, whereas the inherited zircons displayed positive εHf(t) values ranging from +1.83 to +7.98 (average +5.82), with crustal model (TDM2) ages ranging from 0.77 to 1.17 Ga. Results suggest that the Xifanping porphyry Cu (Au) deposit is related to two periods of magmatic activities. Early magmas were generated from the Paleo-Tethys oceanic subduction during the Late Permian. The subsequent porphyry magma was likely formed by the remelting of previously subduction-modified arc lithosphere, triggered by the continental collision between the Indian and Asian plates in the Cenozoic. The deep magmas and late hydrothermal fluids took advantage of the early magma transport channels along tectonically weak zones during the transition from an extrusive to an extensional–tensional tectonic environment. Early dikes from remelted and assimilated crust contributed to the two age ranges observed in the porphyry intrusions from the Xifanping deposit. The juvenile lower crust materials of the early magmatic arc were potential sources of the Cenozoic porphyry magmas, which has significant implications for mineral exploration and the geological understanding of porphyry Cu deposits in this region.

Petrography and Geochemistry of the Farchana-Hadjerhadid Granitoids (Ouaddaï Massif, Eastern Chad)

Work in the Farchana-Hadjerhadid sector is focused on petrography, with the main aim of mapping the geological formations of the eastern Ouaddaï Massif in order to identify petrographic types and gain an understanding of the geodynamic history of this area. The fieldwork showed that the Farchana-Hadjerhadid granitoids consist mainly of granites and diorites and are intersected by numerous pegmatite veins. Microscopic observation shows that the diorite is made up of plagioclase, amphibole, biotite, and quartz. The granite is composed of alkali feldspar, quartz, amphibole, plagioclase, and biotite. The granitoids in the study area are moderately differentiated (SiO2 = 55.62% to 71.67%) and belong to the medium to highly potassic calc-alkaline series. They are ferriferous type I metaluminous granitoids (A/CNK &lt; 1.1). The parent magma was derived from the partial melting of the metabasalts, and the petrographic types evolved by assimilation and fractional crystallization.

Petrogenetic implications, geochemistry and tectonic framework of albitite hosted magnetite in North Delhi Fold Belt: Application of geochemistry and apatite chemistry

The iron ore bodies in the form of lensoidal and pocket type deposits occur within the Meso to Neo-Proterozoic meta-sedimentary rocks and albitites of Ajabgarh Group of Delhi Supergroup in Khetri basin, Western India. These are exposed as detached and linear ore bodies at the southern (western flank) and south-eastern (eastern flank) part of the Khetri copper deposit which follows the regional trend of the host rocks. The detailed field and petrographic studies reveal that the magnetite and hematite are associated with major silicates like quartz, actinolite, muscovite, biotite, albite and, K-feldspar. Some minor occurrences of apatite, sphene, ilmenite and monazite are also found. This work is focused on understanding the evolution of albitite-hosted magnetite with respect to tectonic signatures, the source of mineralizing fluid, and its spatial relationship with the regional albitites and meta-sediments. To interpret the above, whole rock geochemistry of albitite rocks, magnetite ore and mineral chemistry of fluorapatite, were adopted.The whole rock geochemistry of albitite suggests that the parent rocks are of calc-alkaline magma series that are originated from the subduction-related rift zone of volcanic arc environment. The apatite chemistry signifies that these are evolved from the highly fractionated granitic rocks (granitoid) at moderate to high oxidizing conditions. Some deformed apatite grains are also encountered having small distorted monazite inclusions. Thus, it has an indication of high-temperature metasomatic/hydrothermal fluids that may be responsible for the removal of REEs from apatite and re-nucleate as monazite inclusions within it. Therefore, the overall evidence and associations of albitite with apatite-magnetite is demonstrating that the source rock of the study area could have evolved from the arc system of active continental margin which was abundant with Fe, U, REEs, etc. Hence, the sources rocks were suitably metasomatized by hydrothermal fluids channelized through the regional shear zone and simultaneous precipitation of the magnetite in the study area. The dominance of magnetite, associated REEs, apatite, and non-association of sulfide minerals with the magnetite in the area of study has close similarities with the IOA type deposits.

Configuration of the early-mid Cenozoic extensional arc volcanism of the North Patagonian and the Southern Central Andes (33–44°S)

The late Eocene to earliest Miocene volcanic arc of the Southern Central Andes (33–40°S) and North Patagonian Andes (40–44°S) exhibits distinctive features that shed light on the dynamics of subduction-related volcanic activity in extensional tectonic settings. This period is particularly significant in the Andes, as it records the opening of forearc, intra-arc, and retroarc extensional basins, accompanied by high-volume volcanism, preceding the middle-late Miocene final major uplift phase of the Andes. This extensional event occurred in two phases, associated with changes in the geometry and dynamics of the subduction system: from oblique convergence at low rates during the late Eocene-early Oligocene to an orthogonal convergence at high rates during the late Oligocene-early Miocene. This study presents a compilation of field, petrographic, geochemical, and isotopic data from volcanic sequences in the North Patagonian Andes and the Southern Central Andes, aiming to analyze petrogenetic processes at different stages of arc evolution.During the late Eocene to early Oligocene, subduction-related volcanism occurred in a wide area from 100 to 300 km from the trench. In this period, magmatic arc rocks exhibit intermediate composition and a relatively homogeneous geochemical signature, transitional between tholeiitic and calc-alkaline series, with a marked subduction-related signature. These magmas originated from depleted mantle sources with high slab-derived fluid and sediment contributions and limited crustal interactions. In contrast, the late Oligocene to earliest Miocene volcanic activity, at the peak of the extensional regime, displays significant geochemical differences along the Andes. In the Southern Central Andes (33–40°S), volcanism displays compositions similar to those of the previous stage with varying influence from the subducting slab. In some sectors, magmas register the climax of the extensional conditions, whereas the youngest volcanic rocks towards the north (33–34°S) present evidence of the onset of contractional tectonics, demonstrated by the increased interaction of the magmas with a progressively thickened crust. In the North Patagonian Andes (40–44°S), subaerial and subaqueous arc-related lava flows are interbedded with marine deposits, indicating a rapid subsidence regime. These rocks exhibit geochemical features transitional from arc to E-MORB and even OIB compositions, which suggest a genesis primarily dominated by decompression melting of a heterogeneous mantle source. Above all, the contrasting nature of late Eocene-early Miocene arc products in the Southern Central and Patagonian Andes highlights that no single process can explain the changes in composition, distribution, and evolution of arc magmatism; rather, it is a combination of factors, including variations in subduction zone configuration and mantle dynamics and composition.