Cake Layer Research Articles

An increase in sludge loading rate induces gel fouling in membrane bioreactors treating real sewage

The main objective of this study was to investigate the cause of gel fouling in membrane bioreactors (MBRs) treating real sewage in terms of soluble microbial products (SMPs) and microbial aspects. Two anoxic/oxic-MBRs were operated as the control reactor (S1) and the sludge loading rate increased reactor (S2). The reactors were operated under low-temperature around 11 °C conditions. Membrane permeability substantially decreased in S2, and gel layer biofilm was formed on membrane surface. In contrast, the permeability of S1 gradually decreased and cake layer formed. When gel fouling occurred, the protein and polysaccharide of SMP in S2 were 47 and 23 mg L−1, which were significantly lower than those recorded in S1 accounted for 118 and 68 mg L−1, respectively. Furthermore, the total organic carbon concentration of SMPs was 24 mg L−1, which was lower than the influent in S2, accounted for 62 mg L−1. Finally, Campylobacteraceae which exists in sewage and uncultured OD1, dominated the gel layer biofilm in S2, unlike the cake layer biofilm in S1. These results indicated that the gel layer biofilm might be composed of influent substances, demonstrating the importance of influent decomposition in MBR for gel fouling mitigation.

Comprehensively understanding fouling properties of cake and bulk sludge in an anammox membrane bioreactor: Focusing on the composition, interfacial thermodynamics and microbial community

A more comprehensive investigation into fouling properties of cake and bulk sludge played an essential role in better understanding membrane fouling caused by the bio-cake formation in an anammox membrane bioreactor (MBR). In this work, the cake and bulk sludge from a stable anammox MBR were analyzed with the composition, interfacial thermodynamics and microbial community. Physicochemical analysis indicated that cake sludge agglomerated into larger flocs with a denser structure and a higher protein/polysaccharide (PN/PS) ratio as compared with bulk sludge. It also revealed that cake sludge was found to have looser protein secondary structures and more hydrophobic components than those of bulk sludge, which means the differences in surface hydrophobicity between two sludges might play a key role in revealing anammox sludge aggregation and further cake layer formation process. The dominant role of hydrophobic attraction energies between cake sludge and membrane surface at a shorter separation distance (< 2 nm), after the analysis of the extended Derjaguin-Landau-Verwey-Overbeek (XDLVO) method, confirmed cake layer formation process related with surface hydrophobicity. Furthermore, biological analysis demonstrated that the relative microbial abundances of Candidatus_Brocadia and Candidatus_Kuenenia in cake sludge were much greater than those of bulk sludge, implying a higher biofouling potential for them. Overall, this study fills the gap in understanding the mechanism between anammox sludge properties and cake formation, which provides basic knowledge for membrane fouling control in anammox MBR.

Developing a sustainable process for the cleaner production of baker's yeast: An approach towards waste management by an integrated fermentation and membrane separation process

Baker's yeast industries generate highly polluted effluents, especially the cell free broth (i.e., vinasse) characterized by high chemical oxygen demand, nitrogen, and salts. In this work, it was found that the residual by-products (i.e., ethanol and acetic acid) and salts in the vinasse severely inhibited the cell growth, which hindered the reuse of the vinasse for the production of Saccharomyces cerevisiae. Through optimizing a suitable control strategy, the productions of ethanol and acetic acid were eliminated. Then, a nanofiltration membrane (i.e., NF5) was preferred for preliminarily and simultaneously separating and concentrating valuable molecules (i.e., invertase, food grade proteins and pigments) in the vinasse, and the main fouling mechanism was cake layer formation. Subsequently, a reverse osmosis membrane (RO) was suitable to separate and concentrate salts in the NF5 permeate, where the membrane fouling was negligible. Finally, the RO permeate was successfully reused for the production of S. cerevisiae. In addition, without calculating the benefit from the recovery of the valuable molecules, the cost of the integrated process can be decreased by 59.8% compared with the sole triple effect evaporation. Meanwhile, the volume of the fresh water used in the fermentation process can be decreased by 68.8%. Thus, it is a sustainable process for the cleaner production of baker's yeast using the integrated fermentation and membrane separation process.

Effects of pre-treatments on the filtration performance of ultra-low pressure gravity-driven membrane in treating the secondary effluent: Flux stabilization and removal improvement

Gravity-driven membrane (GDM) filtration is a promising technology for decentralized water and wastewater treatment due to its negligible energy consumption and low maintenance. This study investigated the flux development and permeate quality of the GDM process in treating the secondary effluent, as well as the influences of two practical pre-treatments, including GAC filter and microfiltration (MF), on its filtration performance. The results indicated that the GAC filter could significantly enhance the removal of organic contaminants (i.e., DOC, UV254, and fluorescent substances), with an average removal of 70 % for DOC and 80 % for UV254, respectively. Meanwhile, GAC/GDM systems exhibited a superior removal performance of manganese and sulfamethoxazole (SMX) for more than 95 % and 80 %, respectively. Furthermore, the optimized mixing ratio between GAC permeates and secondary effluent was 7:3 (GAC7:3) to reach a flux level close to the GDM control and achieve a superior permeate water quality than the other processes. The flux of GDM control could stabilize at the level of 5.47 ± 0.71 L m−2h−1 during long-term filtration. Unexpectedly, limited flux improvements were observed with the pre-treatments, and the stable flux of GAC/GDM and MF/GDM was close to or slightly lower than the GDM control. In GDM control, a rough, heterogeneous, and porous biocake layer was observed on the membrane surface. By contrast, the cake layer structures in the GDM system coupled with pre-treatments appeared denser, compact, and homogeneous, resulting in relatively lower stable flux relative to the GDM control. The economic assessment indicated that the optimized process of GAC7:3 showed a significant cost advantage in the small and medium-scale water reuse scenarios. These findings were beneficial to develop new energy-saving membrane-based technology for the reclamation of wastewater.

Improving filter cake sealing properties for high-density ilmenite drilling fluid

Drilling fluids must be cautiously designed to form an impermeable filter cake layer that diminishes the intensity of solid and mud invasion during drilling of a well. Inability to abate solid and mud invasion can cause adverse effects on the productivity of the drilled well. As a result, a variety of additives have been proposed for improving filter cake's sealing properties, which are also utilized to control fluid filtration. This work investigates the role an amorphous volcanic glass (perlite), a novel filtration agent, to amend the quality of filter cake layer that formed using ilmenite (FeTiO3) drilling fluid. The characteristics of the filter cake were evaluated in terms of the filtration behavior, filter cake thickness, permeability and porosity. In order to accomplish this aim, several concentrations of perlite particles were loaded to the Ilmenite weighted drilling fluid. The tests were conducted under high-pressure high-temperature environment according to API standards. The results of the drilling fluid (containing perlite) were compared with a reference drilling fluid (zero concentration of perlite). It is observed that the perlite containing formulation has improved filtration properties. The flake-shaped perlite particles blocked the filter cake pores and accordingly produced an impermeable filter cake. There was a drastic drop in the filter cake overall permeability after adding perlite concentration of 3 lb/bbl, from 6.09 × 10−3 Darcy to 1.46 × 10−3 Darcy and a significant drop (55%) in the associated filtration volume from 18.5 cm3 to 8.5 cm3. Moreover, perlite-based filter cake lowered the pore size of the filter cake and decreased the filter cake thickness by 45%.

Treatment of Municipal Wastewater by Hollow Fiber Dynamic Membrane Bioreactors

AbstractIn this study, an aerobic membrane bioreactor (MBR) with a polyester fabric hollow fiber filter is used for municipal wastewater treatment. This polyester fabric filter is used as support material for dynamic membrane formation in the MBR. High treatment performance is obtained in the permeate achieving over 93% of chemical oxygen demand removal efficiency and low particulate material concentration (&lt;10 mg L−1). The system is operated for 58 d without any clogging. The average transmembrane value is found as around 598 mbar after the system reaches stable conditions. Morphological analyses including confocal laser scanning microscopy, environmental scanning electron microscopy, energy‐dispersive X‐ray, and Fourier transform infrared spectroscopy are performed to obtain a detailed understanding of the cake layer formation. The use of hollow fiber dynamic membranes can provide compact membrane volume with high surface area, thus, the volume of the reactor can be further decreased.

Fouling mechanisms in anoxic-aerobic sequencing batch membrane bioreactor based on adapted Hermia models and main foulant characteristics

Various derivatives of Hermia models (complete pore blocking, intermediate pore blocking, cake layer formation, and standard pore blocking) and different assessments of foulant characteristics have long been used to determine the membrane fouling mechanisms. Accordingly, this study aims to adapt Hermia models and their combination according to the operating conditions of an anoxic-aerobic sequencing batch membrane bioreactor (A/O-SBMBR). In addition, fouling mechanisms of the A/O-SBMBR were assessed using these models along with the main foulant characteristics. Models fitting with the transmembrane pressure (TMP) data indicated that the intermediate-standard model was accounting for the increased fouling during the whole regular operating period, with the residual sum of squares (RSS) of 58.3. A more detailed study on the distinct stages of TMP curve showed that the intermediate-standard model had the best fit in stages of 2 and 3, with the RSS equal to 2.6 and 2.8, respectively. Also, the complete-standard model provided the best description of the fouling mechanism in stage 4, with the RSS of 12.5. Different analyzes revealed how the main foulant characteristics affect the occurrence of intermediate, complete and standard fouling mechanisms in the A/O-SBMBR, which is consistent with the fitting results of the adapted Hermia models. The modeling and experimental methods used in the presented study provided a valuable basis to prevent and control membrane fouling in membrane bioreactors.

Enhancing ultrafiltration of algal-rich water using ferrate activated with sodium percarbonate: Foulants variation, membrane fouling alleviation, and collaborative mechanism

Ultrafiltration (UF) is a reliable method to treat algal-rich water, whereas severe membrane fouling has impeded its actual application. To improve UF performance and alleviate membrane fouling resulted by algal foulants, a novel strategy coupling ferrate (Fe(VI)) and sodium percarbonate (SPC) was proposed. During the coupling process, Fe(VI) was activated by SPC to generate high-valent Fe intermediates (Fe(V) and Fe(IV)), which played a crucial role in high-efficiency oxidation for algal foulants, and the in-situ formed Fe(III) particles decomposed by Fe(VI) also enhanced the coagulation and adsorption capacity to the coupling system. Under the triple effects of coagulation, adsorption and oxidation, the algal foulants were efficiently eliminated. The zeta potential increased from −32.70 mV to −6.56 mV at most, the particle size was significantly enlarged, and the generated flocs possessed a great settleability. The morphology, viability, and integrity of algae cells were effectively maintained. The dissolved organic matters and fluorescent organics were efficiently removed, as well as macromolecular organics were reduced into lower molecular weight components. With the collaborative effect of Fe(VI) and SPC, the terminal specific flux was increased from 0.29 to 0.92, and the reversible and irreversible fouling resistances were reduced by 98.5% and 69.4%, individually. The surface functional groups were changed, and the dominant mechanisms were also converted to pore blocking from cake layer filtration. Overall, the experimental results would provide some new thoughts in actual production for algal-rich water treatment and UF membrane fouling alleviation.

Molecular levels unveil the membrane fouling mitigation mechanism of a superpotent N-rGO catalytic ozonation membrane: Interfacial catalytic reaction pathway and induced EfOM transformation reactions

This study investigated the membrane fouling self-cleaning of N-doped reduced graphene oxide (N-rGO)-tailored ceramic membrane with ozone (N-rGO-CM-O/F) at the molecular level. Density functional theoretical (DFT) revealed the principle of interfacial catalytic reaction, and the transformation of foulants was probed using Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) and various spectroscopic techniques. Results showed that ozone could be aggregated on the N-rGO-CM surface and formed abundant •OH. This made humic acid-like substances blocking membrane pores to be sufficiently and preferentially removed in N-rGO-CM-O/F by 18-types reactions of catalytic ozonation. Conversely, CM-O/F preferentially removed protein-like substances that formed the cake layer. Due to the stronger catalytic ozonation ability and efficient fouling mitigation behavior, N-rGO-CM-O/F showed higher water flux as 1.96 times than that of CM-O/F. Overall, this study provided molecular insight into the mechanism of membrane fouling mitigation, which will facilitate the design and application of advanced catalytic membranes.

A novel gravity sedimentation - Forward osmosis hybrid technology for microalgal dewatering

A novel gravity sedimentation - forward osmosis (G-FO) hybrid reactor was built up for separating and concentrating the biomass from the algal-rich water (microalgal dewatering). The extracellular organic matter (EOM) from Chlorella vulgaris (C. vulgaris) was divided into dissolved EOM (dEOM) and bound EOM (bEOM). Water flux, flux recovery rate and moisture content (MC) were investigated. Through sedimentation rate, zeta potential and hydrophilicity/hydrophobicity to analyze the experimental results. Scanning electronic microscopy (SEM) was used to observe the different morphologies of accumulated algae cells and EOM on the surface of the membrane. The results showed that cell + bEOM solution had the fastest sedimentation rate and fewest negative charge, so the pollutants accumulated more easily on the membrane surface, resulting in the highest flux decline. Its algal cake layer was the densest from the view of SEM. Cell + bEOM + dEOM solution had the lowest flux decline and the cake layer was the loosest. Cell + bEOM solution had the most severe irreversible fouling and the lowest flux recovery rate (FRR). The membrane fouling of cell solution was lower than that of cell + bEOM + dEOM solution, and the FRR of cell solution was almost 100%. According to the nonionic macro-porous resin fraction results of EOM, cell + bEOM + dEOM solution contained more hydrophilic components, resulting in the lowest MC. On the contrary, cell + bEOM solution showed the highest MC, which contained more hydrophobic components. Effects of bEOM and dEOM on microalgae dewatering performance of a novel gravity sedimentation - forward osmosis (G-FO) hybrid system were investigated, which provided a theoretical basis for large-scale application of FO technology for microalgae dewatering.

Effect of peroxydisulfate oxidation catalyzed with ordered mesoporous carbons on controlling ultrafiltration membrane fouling by algal organic matter.

As typical ordered mesoporous carbons (OMCs) materials, CMK-3 and CMK-8 were proposed for catalyzing peroxydisulfate (PDS), and the OMCs/PDS process was combined with membrane filtration to remove algal extracellular organic matter and mitigate membrane fouling. The CMK-3/PDS process achieved substantial reduction of dissolved organic carbon and UV254, followed by CMK-8/PDS. The degradation behavior of fluorescent organics demonstrated the superior performance of OMCs/PDS, while the decomposition of high molecular weight (MW) compounds and generation of lower MW organics were observed. Generally, CMK-3 possessed higher catalytic activity on PDS compared with CMK-8 and powdered activated carbon. The CMK-3/PDS process distinctly decreased the fouling resistances for polyether sulfone and polyvinylidene fluoride membranes, with the reversible resistance reduced by 59.5-83.2% and irreversible resistance declined by 71.7-73.0%. In the meanwhile, CMK-3/PDS prolonged the volumes to the transition period, and postponed the cake layer's generation. The characterization of the membrane morphologies and chemical compositions also showed effective alleviation of fouling. The generated SO4-, OH, O2- and 1O2 as major active oxidation species provided radical as well as non-radical reaction ways for pollutants removal. Overall, our study provides some new ideas for membrane-based combined water purification processes.

Modification of Thin Film Composite Membrane by Chitosan-Silver Particles to Improve Desalination and Anti-Biofouling Performance.

Reverse osmosis (RO) desalination is a technology that is commonly used to mitigate water scarcity problems; one of its disadvantages is the bio-fouling of the membranes used, which reduces its performance. In order to minimize this problem, this study prepared modified thin film composite (TFC) membranes by the incorporation of chitosan–silver particles (CS–Ag) of different molecular weights, and evaluated them in terms of their anti-biofouling and desalination performances. The CS–Ag were obtained using ionotropic gelation, and were characterized by Fourier transform infrared spectroscopy (FTIR), high-resolution scanning electron microscopy (HR-SEM), energy-dispersive X-ray spectroscopy (EDX), thermogravimetric analysis (TGA) and dynamic light scattering (DLS). The modified membranes were synthetized by the incorporation of the CS–Ag using the interfacial polymerization method. The membranes (MCS–Ag) were characterized by Fourier transform infrared spectroscopy (FTIR), atomic force microscopy (AFM) and contact angle. Bactericidal tests by total cell count were performed using Bacillus halotolerans MCC1, and anti-adhesion properties were confirmed through biofilm cake layer thickness and total organic carbon (%). The desalination performance was defined by permeate flux, hydraulic resistance, salt rejection and salt permeance by using 2000 and 5000 mg L−1 of NaCl. The MCS–Ag-L presented superior permeate flux and salt rejection (63.3% and 1% higher, respectively), as well as higher bactericidal properties (76% less in total cell count) and anti-adhesion capacity (biofilm thickness layer 60% and total organic carbon 75% less, compared with the unmodified membrane). The highest hydraulic resistance value was for MCS–Ag-M. In conclusion, the molecular weight of CS–Ag significantly influences the desalination and the antimicrobial performances of the membranes; as the molecular weight decreases, the membranes’ performances increase. This study shows a possible alternative for increasing membrane useful life in the desalination process.

Performance evaluation of membrane bioreactor coupled with self-forming dynamic membrane

In the present study, Conventional Membrane Bioreactor (C-MBR) and Modified Membrane Bioreactor (M-MBR) were run consequently to compare the fouling reduction through incorporated modification. M-MBR was developed by introducing a Self-forming dynamic membrane (SFDM) formed on a nylon cloth filter ahead of a flat sheet membrane. The coarse cloth filter and fine cloth filter had a pore size of 125 μm and 37 μm, respectively and it took 45 min and 12 min to form a dynamic membrane on them. The C-MBR experienced frequent fouling with cake layer resistance (RC) as the dominant one which contributed to 83.98% of total resistance (RT). Whereas in M-MBR the cake layer resistance (67.86% of RT) and pore blocking resistance (RP) (1.31% of RT) was less compared to C-MBR. The formed SFDM on nylon cloth filters led to the reduced RC and RP in M-MBR. Therefore, the operation of M-MBR was prolonged, which took 150 days to reach 8.6 KPa (0.057 KPa/day). Eventually, it was concluded that the modification made in this study significantly reduced the fouling.

Enhanced energy production and biological treatment of swine wastewater using anaerobic membrane bioreactor: Fouling mechanism and microbial community

This study aimed to reveal the membrane fouling mechanisms during anaerobic membrane bioreactor (AnMBR) operation for swine wastewater treatment under different organic loading rates (OLR). Results showed that AnMBR could achieve high pollutant removal (71.9–83.6 %) and energy recovery (0.18–0.23 L-CH4/g-COD) at an OLR range of 0.25–0.5 g-COD/g-VSS.d, realizing energy production. However, higher OLR would aggravate the membrane fouling due to accumulation of fine sludge particles, organic foulants, and extracellular polymeric substances (EPS) on cake layer. Based on the high-throughput sequencing, microbial communities significantly changed and fouling-causing bacteria (e.g. Pseudomonas, Methanosarcina and Methanothrix) enriched in the cake layer at higher OLR conditions, leading to lower membrane permeability. Backwash can effectively remove the cake layer from the membrane surface and recover membrane permeability. The present study provides important information about membrane fouling and microbial information that could have significant impact on large-scale AnMBR application.

Cake Layer Fouling Potential Characterization for Wastewater Reverse Osmosis via Gradient Filtration.

It is of great importance to quantitatively characterize feed fouling potential for the effective and efficient prevention and control of reverse osmosis membrane fouling. A gradient filtration method with microfiltration (MF 0.45 μm) → ultrafiltration (UF 100 kDa) → nanofiltration (NF 300 Da) was proposed to extract the cake layer fouling index, I, of different feed foulants in this study. MF, UF, and NF showed high rejection of model suspended solids (kaolin), colloids (sodium alginate and bovine serum albumin), and dissolved organic matters (humic acid) during constant-pressure individual filtration tests, where the cake layer was the dominant fouling mechanism, with I showing a good linear positive correlation with the foulant concentration. MF → UF → NF gradient filtration tests of synthetic wastewater (i.e., model mixture) showed that combined models were more effective than single models to analyze membrane fouling mechanisms. For each membrane of gradient filtration, I showed a positive correlation with the targeted foulant concentration. Therefore, a quantitative assessment method based on MF → UF → NF gradient filtration, the correlation of combined fouling models, and the calculation of I would be useful for characterizing the fouling potentials of different foulants. This method was further successfully applied for characterizing the fouling potential of real wastewater (i.e., sludge supernatant from a membrane bioreactor treating dyeing and finishing wastewater).

Treatment of Wastewater from a Grass Carp Pond with Multiple-Batch Forward Osmosis by Using Sucrose as a Draw Solution

Forward osmosis (FO), a green and economical membrane technology driven by a natural concentration gradient, has attracted increasing attention for wastewater treatment because it consumes less energy and removes large amounts of pollutants. In this research, an approach based on an FO mechanism that could improve the concentration of organic pollutants in wastewater collected from grass carp ponds was proposed. The wastewater serving as a feed solution (FS) was concentrated by FO, and sucrose was used as a draw solution (DS). The multiple chemical oxygen demand (COD) variation, the water flux, and the reverse solute flux during the FO process were investigated. The results indicated that the water flux and the reverse solute flux had similar trends in the processing of batch experiments 1–8, and the concentrating multiple of organic contaminants reached a maximum of 3.5 in the whole study. In addition, membrane fouling was studied via a scanning electron microscope (SEM), and a loose cake layer was deposited on the membrane surface. Moreover, findings from energy dispersive scanning (EDS) analysis showed that the fouling substances in the support layer of the membrane were mainly organic compounds and silica. In contrast, the dominant contaminants of the active layer contained several microelements (such as K and Ca) in addition to organic compounds. Three-dimensional (3D) fluorescence analysis confirmed that the FS components could enter the DS and the chemical components of the sucrose solution could also enter the FS. The findings of this study provide a new view on selecting a DS and protecting the aquaculture environment.

Identification of dissimilatory nitrate reduction to ammonium (DNRA) and denitrification in the dynamic cake layer of a full-scale anoixc dynamic membrane bioreactor for treating hotel laundry wastewater

Identification of dissimilatory nitrate reduction to ammonium (DNRA) and denitrification in the dynamic cake layer of a full-scale anoixc dynamic membrane bioreactor (AnDMBR) for treating hotel laundry wastewater was studied. A series of experiments were conducted to understand the contributions of DNRA and canonical denitrification activities in the dynamic cake layer of the AnDMBR. The dynamic cake layer developed included two phases - a steady transmembrane pressure (TMP) increase at 0.24 kPa/day followed by a sharp TMP jump at 1.26 kPa/day four to five days after the AnDMBR start-up. The nitrogen mass balance results showed that canonical denitrification was predominant during the development of the dynamic cake layer. However, DNRA activity and accumulation of bacteria equipped with a complete DNRA pathway showed a positive correlation to the development of the dynamic cake layer. Our metagenomic analysis identified an approximately 18% of the dynamic cake layer bacterial community has a complete DNRA pathway. Pannonibacter (1%), Thauera (0.8%) and Pseudomonas (3%) contained all genes encoding for funcional enzymes of both DNRA (nitrate reductase and DNRA nitrite reductase) and denitrification (nitrate reductase, nitrous oxide reductase and nitric oxide reductase). No other metagenome-assembled genomes (MAGs) possessed a complete cononical denitrification pathway, indicating food-chain-like interactions of denitrifiers in the dynamic cake layer. We found that COD loading rate could be used to control DNRA and canonical denitrification activities during the dynamic cake layer formation.

Identification of fouling mechanisms in cross-flow microfiltration of olive-mills wastewater

Microfiltration (MF) is recognized as a promising green process that can efficiently treat different types of wastewater. However, the efficiency, economic viability and technological feasibility of MF can be severely affected by fouling. The occurrence of specific fouling mechanisms depends on the specific membrane materials and related physico-chemical properties, characteristics of solutes present in the feeding solution, and operating conditions. The present study aims at evaluating the extent of membrane fouling and its impact on flux decline during olive mills wastewater (OMWW) microfiltration in a semi-pilot plant. The possibility to restore the initial membrane performance was evaluated in terms of cleaning efficiency (CE). OMWW MF was carried out using both polymeric (polyvinylidene fluoride, PVDF) and ceramic membranes (zirconia and α-alumina) at transmembrane pressures (TMP) up to 1.7 bar. The highest permeate flux was obtained using α-alumina membrane (35.4 ± 1.6 L m−2 h−1 at 1.2 bar TMP), the zirconia membrane, despite a slight decrease in flux compared to the alumina membrane, allowed the better restoration of the initial water permeability after cleaning procedures (CE =74 %). PVDF membrane was found to be the least suitable for treatment of OMWW due to low permeate flux (5.3 L m−2 h−1 at 1.2 bar TMP) and the inability to restore initial water permeability (CE = 8 %).Each peculiar fouling mechanism was estimated by fitting the experimental filtration data to the linearized equations of the Hermia model, single and multistage, corresponding to pore blocking (complete, intermediate and standard) and cake formation.Results indicated that for α-alumina and zirconia membranes the dominant fouling mechanism was cake layer formation. For the PVDF membrane Hermia multistage model revealed that the initial flux decline is appropriately described by standard pore blocking whereas after the first 10 min of operation the fouling mechanism switched to cake layer formation.

Oxidation and coagulation/adsorption dual effects of ferrate (VI) pretreatment on organics removal and membrane fouling alleviation in UF process during secondary effluent treatment

Ultrafiltration (UF) has been widely used in water and advanced sewage treatment. Unfortunately, membrane fouling is still the main obstacle to further improvement in the system. Fe (III) salt, a type of traditional coagulant, is often applied to mitigate UF membrane fouling. However, low molecule organic weight cannot be effectively removed, thus the water quality after single coagulation treatment does not effectively meet the standard of subsequent water reuse during secondary effluent treatment. Recently, it has been found that potassium ferrate (Fe (VI)) has multiple functions of oxidation, sterilization and coagulation, with other studies proving its good performance in organics removal and membrane fouling mitigation. However, the respective contributions of oxidation and coagulation/adsorption have not yet been fully understood. The oxidation and coagulation/adsorption effects of Fe (VI) during membrane fouling mitigation were investigated here. The oxidation effect of Fe (VI) was the main reason for organics with the MW of 8–20 kDa removal, and its coagulation/adsorption mainly accounted for the smaller amounts of molecular organics removed. The oxidation of Fe (VI) was the main method for overcoming membrane fouling in the initial filtration; it largely alleviated the standard blockage. The formation of a cake layer transformed the main membrane fouling alleviation mechanism from oxidation to coagulation/adsorption and further removed smaller amounts of molecule organics with the increase of filtration cycles and Fe (VI) dosages. The main fouling mechanism altered from standard blocking and cake filtration to only cake filtration after Fe (VI) treatment. Overall, the mechanism of the oxidation and coagulation/adsorption of Fe (VI) were differentiated, and would provide a reference for future Fe (VI) pretreatment in UF membrane fouling control during water and wastewater treatments.

PETITE FOURS VARIASI FILLING DAN TOPPING BUAH NANAS SEBAGAI HIDANGAN STAND PESTAS

Petite fours are small cake dishes, biscuits or various kinds of pastries which are decorated with cooked chocolate, fondant, cream, fruits that are specially decorated, known as bite size or the size of one or two bites. Currently, the party stand dish in the form of petite fours is not widely served because people think that petite fours is an expensive dish. The use of pineapple as a filling or topping on petite fours is rarely found. The purpose of writing is to develop the writer's knowledge and skills in the field of cuisine, especially patisserie, in processing Petite Fours with variations of filling and topping of pineapple as a party stand dish. The method used in this manufacture is an experimental method, namely testing the recipe five times, resulting in petite fours with variations of filling and topping of pineapple as a party stand dish. The party stand dish is the Mini Cake Layers Pineapple.