Cadmium Zinc Sulfide Research Articles

Investigations on the effects of rGO incorporation on the photosensitivity of (Cd:Zn)S nanocrystalline thin film-based visible photodetectors by hydrothermal synthesis

Reduced graphene oxide-incorporated cadmium zinc sulphide (rGO–CZS) thin films were synthesised on glass substrates by hydrothermal-assisted chemical bath deposition. The effect of the rGO concentration (0.5–2 wt%) on the photosensitivity of the films was established along with the structural, morphological and optical properties of the composite films. The structural investigations by XRD analysis ensured that the prepared samples are nanocrystalline with hexagonal structure of cadmium zinc sulphide. Scanning electron microscopy showed aggregated sphere-like CZS nanoparticles enveloped with rGO flakes. The average particle size attained from TEM image is approximately 8 nm. The presence of various functional groups was scanned by FTIR analysis. Further, we established the characteristics of the rGO–CZS nanocomposite films as visible-light photodetectors. The photosensitivity, photo response and detectivity of the devices were found to increase with rGO concentration. (2 wt%) rGO–CZS detector exhibits highest photosensitivity of the order of 106, photoresponse of 18.5 mA/W and specific detectivity of 2.08 × 1012 Jones. This work demonstrates fast and simple preparation process of rGO–CZS visible-light detectors with high sensitivity, responsivity and good stability. The enhancement of sensitivity and responsivity can be attributed to the excellent electron conductivity and mobility due to the warm interfacial contact between CZS nanoparticles and the rGO sheet.

Electrodeposited CdZnS/CdS/CIGS/Mo: Characterization and Solar Cell Performance

Copper indium gallium and di-selenium (CIGS) films have been successfully deposited by the electrodeposition technique. The as-deposited films were annealed at 450°C for 40 min. The (CdS) and cadmium–zinc sulfide (CdZnS) used as buffer and window layer, respectively, were synthesized by the chemical bath deposition technique. The prepared samples were characterized for structure by x-ray diffraction. The morphology of the deposited films was analyzed by scanning electron microscopy. Atomic force microscopy and UV–Vis spectroscopy were used for surface roughness and optical properties. A typical solar cell structure consists of CdZnS–CdS and CIGS–Mo as window, buffer and absorber layer, respectively. The device performance was measured under AM 1.5 global spectrum for 1000 W/m2 irradiance, where the obtained efficiencies were in the range of 2–3%. Open-circuit voltage was 345 mV, short circuit current was 16.8 mA/cm2 and the fill factor was 38.18%.

Thin film characterization of Ce and Sn co-doped CdZnS by chemical bath deposition

Abstract Cerium and tin co-doped cadmium zinc sulfide nanoparticles (CdZnS:Ce)Sn were synthesized by chemical bath deposition method with a fixed concentration of Ce (3.84 mol%) and three different concentrations of Sn (2 mol % and 4 mol% and 6 mol%). They showed broad photoluminescence spectra in the visible region under the ultraviolet excitation with a wavelength of 325 nm. The photoluminescence emission peaks were obtained at 540 nm, 560 nm and 570 nm for CdZnS, CdZnS:Ce and (CdZnS:Ce)Sn thin films, respectively having different concentrations of Sn. It has been observed that the photoluminescence emission peak shifted to higher wavelength region with an increase in intensity by Ce doping and Ce–Sn co-doping. Further enhancement in luminescence peak intensity has been observed by increasing concentration of Sn in (CdZnS:Ce)Sn films. Average crystallite size, measured from XRD data, was found to be increased with increasing concentration of Sn. An increase in the concentration of Sn shifted the UV-Vis absorption edge toward the higher wavelength side. Energy band gap for undoped CdZnS and Ce–Sn co-doped CdZnS varied from 2.608 eV to 2.405 eV. The SEM micrographs of CdZnS and (CdZnS:Ce)Sn films showed the leafy-like and ball-like structures. The presence of Sn and Ce was confirmed by EDAX analysis.

ZnS assisted Zn doping in CdZnS electrodeposition

Many reports have been published elsewhere on making thin films of cadmium zinc sulphide (CdZnS) using different techniques. This article summarizes a method developed to form CdZnS by incorporating electrodeposited Cd and S atoms simultaneously to the chemically formed ZnS material in the electrolytic bath at the conducting surface of fluorine doped tin oxide (FTO) coated glass substrate. Moreover, the mechanism of formation of CdZnS is proposed as a solid state reaction between electrodeposited Cd and S atoms on the glass/FTO substrate with adsorbed ZnS particles from the electrolytic bath. The precursors used for Cd, S and ZnS in the electrolyte were aqueous solutions of CdCl2, ZnCl2 and Na2S2O3. Two different methods were tested to form ZnS within the electrolyte bath where one forming ZnS in the bath at the beginning of electrodeposition of Cd and S and in the other one, ZnS is formed before the electrodeposition of Cd and S. The results of the band gap measurements show an undulation which is closer to the band gap energy of CdS indicating probable codeposition of one or more materials such as CdS, (2.42 eV), ZnS (3.7 eV), CdO (2.2 eV), and ZnO (3.2 eV) along with CdZnS. The Tauc plot resulted by the material produced in method 1 has shown an undulation at the onset of Tauc plot which is near the band gap energy of CdS indicating the codeposition of CdS with CdZnS, but the Tauc plot of CdZnS electrodeposited from method 2 has shown clear separation in band gaps from 2.44 – 2.52 eV, when the annealing temperature, the Zn2+ ion concentration in bath and the electrodeposition pH were varied. These thin films were also characterized by photoelectrochemical (PEC) cell analysis, x-ray diffraction (XRD), energy dispersive x-ray analysis (EDXA) and scanning electron microscopy (SEM) techniques.

Monitoring of the Mechanism of Mn Ions Incorporation into Quantum Dots by Optical and EPR Spectroscopy

Synthesis of nanoparticles doped with various ions can significantly expand their functionality. The conditions of synthesis exert significant influence on the distribution nature of doped ions and therefore the physicochemical properties of nanoparticles. In this paper, a correlation between the conditions of synthesis of manganese-containing cadmium sulfide or zinc sulfide nanoparticles and their optical and magnetic properties is analyzed. Electron paramagnetic resonance was used to study the distribution of manganese ions in nanoparticles and the intensity of interaction between them depending on the conditions of synthesis of nanoparticles, the concentration of manganese, and the type of initial semiconductor. The increase of manganese concentration is shown to result in the formation of smaller CdS-based nanoparticles. Luminescent properties of nanoparticles were studied. The 580 nm peak, which is typical for manganese ions, becomes more distinguished with the increase of their concentration and the time of synthesis.

CdSe/ZnS core-shell quantum dot assisted color conversion of violet laser diode for white lighting communication

Abstract By color-converting the violet laser diode (VLD) with a cadmium selenide and zinc sulfide (CdSe/ZnS) core-shell-quantum dot (QD) doped polydimethylsiloxane (PDMS) film, the VLD + CdSe/ZnS core-shell-QD transferred white-light with improved color rendering index (CRI) is demonstrated for high-speed indoor visible lighting communication. To facilitate hue saturation value (HSV) of the VLD + CdSe/ZnS core-shell-QD white-lighting module, dual-sized CdSe/ZnS core-shell-QDs with two luminescent wavelengths centered at 515 and 630 nm are doped into the PDMS. The CdSe/ZnS core-shell-QD doped PDMS phosphor with the optimized thickness of 2.5 mm serves as the beam divergent color-converter, which not only excites red (R) and green (G) fluorescence to detune the correlated color temperature (CCT) and CRI of the mixed red/green/violet (RGV) white-light, but also remains the residual VLD signal for data transmission. With a divergent angle of 127°, such a VLD + CdSe/ZnS core-shell-QD can deliver cold white-light with a CCT of 6389 K and a CRI of 63.3 at Commission International de l’Eclairage coordinate of 0.3214, 0.2755. Most important, the residual VLD light component is relatively weak with its wavelength out of the peak optical sensitivity region of the human retina centered at 441 nm. The directly encoded VLD + CdSe/ZnS core-shell-QD white light successfully carries the 16-quadrature amplitude modulation (QAM) discrete multitone data, which supports the maximal transmission data rate of 9.6 Gbit/s with a bit error ratio (BER) of 3.59 × 10−3.

On the influence of relative humidity on the oxidation and hydrolysis of fresh and aged oil paints

Modern oil paintings are affected by conservation issues related to the oil paint formulations and to the fact that they are often unvarnished, and in direct contact with the environment. Understanding the evolution of the molecular composition of modern oil paint during ageing, under the influence of environmental factors, is fundamental for a better knowledge of degradation phenomena and risk factors affecting modern art. We investigated for the first time the influence of relative humidity on the chemical composition of modern oil paints during curing and artificial ageing. For this purpose, modern oil paint layers naturally aged for 10 years were further artificially aged in low and high relative humidity conditions. Moreover, the influence of RH% on the curing of fresh paint layers was studied. The paints used in the experiments are from three suppliers (Old Holland, Winsor&Newton, and Talens), and contain cadmium or cadmium zinc sulfide as main pigment. The changes in the composition of extracts of paint samples were investigated by direct electrospray mass spectrometry with a quadrupole-time of flight mass analyser (ESI-Q-ToF). The obtained mass spectral data were interpreted by means of principal component analysis (PCA) operated on a data set containing the relative abundance of ions associated to significant molecules present in the extracts, and also by calculating the ratios between the signals relative to fatty acids, dicarboxylic acids and acylglycerols, related to hydrolysis and oxidation phenomena. The same paint samples were also analysed, in bulk, by pyrolysis gas chromatography mass spectrometry (Py-GC/MS), achieving chemical information on the total lipid fraction. High performance liquid chromatography (HPLC) ESI-Q-ToF was carried out for the characterisation of the profile of free fatty acids (FFA) and acylglycerols, defining the nature of the oils used in the paint formulations, and for the determination of the degree of hydrolysis. This study demonstrated that relative humidity conditions significantly influence the chemical composition of the paints. Ageing under high RH% conditions produced an increase of the formation of dicarboxylic acids compared to ageing under low RH%, for all paints, in addition to a higher degree of hydrolysis, followed by evaporation of free fatty acids.

Comparison of electrical characteristics of zinc oxide and cadmium sulfide films covered with 8-hydroxyquinoline for diode applications

In the present work, n-ZnO/p-8HQ and n-CdS/p-8HQ thin film heterojunctions were fabricated using spin coating and chemical bath deposition (CBD) techniques, respectively. The letter “n” indicates that the film is an n-type semiconductor, and the letter “p” is a p-type semiconductor. The thin films of ZnO covered with 8-hydroxyquinoline (8HQ) and CdS covered with 8HQ were investigated for electrical characteristics. The crystal structure of the films was investigated by X-ray diffraction (XRD) and scanning electron microscope (SEM) techniques. The optical properties of the films were investigated through a ultraviolet–visible spectrophotometer (UV–Vis spectrometer). The experimental results show that the conduction mechanism in the films is ohmic. The experimental results also reveal that ZnO thin films have diode properties with 8HQ while CdS does not have diode properties with 8HQ.

Optimization of CdxZn1-xS compound from CdS/ZnS bi-layers deposited by chemical bath deposition for thin film solar cells application

In this paper, we report results on the processing of cadmium zinc sulfide (CdxZn1-xS) ternary compound starting from the deposition of cadmium sulfide (CdS)/zinc sulfide (ZnS) bi-layers buffer configuration and a subsequent thermal annealing for its application to thin film solar cells. The impact of different CdS/ZnS bi-layers buffer configurations as effective alternative to the single CdS buffer layer, as well as the physical and chemical properties of the equivalent CdxZn1-xS ternary compound are presented and discussed. Results on physical properties optimization of CdxZn1-xS ternary compound for future applications to thin film solar cells are presented.

Towards high-efficiency CZTS solar cell through buffer layer optimization

Cu2ZnSnS4 (CZTS)-based solar cells show a promising performance in the field of sunlight-based energy production system. To increase the performance of CZTS-based solar cell, buffer layer optimization is still an obstacle. In this work, numerical simulations were performed on structures based on CZTS absorber layer, ZnO window layer, and transparent conducting layer n-ITO with different buffer layers using SCAPS-1D software to find a suitable buffer layer. Cadmium sulfide (CdS), zinc sulfide (ZnS) and their alloy cadmium zinc sulfide (Cd0.4Zn0.6S) were used as potential buffer layers to investigate the effect of buffer thickness, absorber thickness and temperature on open-circuit voltage (Voc), short-circuit current (Jsc), fill factor (FF) and efficiency (η) of the solar cell. The optimum efficiencies using these three buffer layers are around 11.20%. Among these three buffers, Cd0.4Zn0.6S is more preferable as CdS suffers from toxicity problem and ZnS shows drastic change in performance parameters. The simulation results can give important guideline for the fabrication of high-efficiency CZTS solar cell.

Host sensitized lanthanide photoluminescence from post-synthetically modified semiconductor nanoparticles depends on reactant identity

This work investigates the photoluminescence characteristics where cadmium selenide (CdSe) and zinc sulfide (ZnS) nanoparticles are treated post-synthetically by the trivalent lanthanide cations (Ln3+) [Ln = Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb] separately to form either CdSe/Ln or ZnS/Ln nanoparticles. Host sensitized Ln3+ emission was found to be present only in CdSe/Eu, CdSe/Tb, ZnS/Eu, ZnS/Tb and ZnS/Yb nanoparticles. In all the cases tuning of emission of the nanoparticles has been observed, irrespective of the presence or absence of host sensitization. The elemental compositions of CdSe and ZnS nanoparticles upon post-synthetic treatment show a remarkable difference. Incorporation of lanthanides in the nanoparticles is evident with significant alteration in the anionic content, and complete cation exchange of either Cd2+ or Zn2+ by Ln3+ has not been detected; as evaluated from energy dispersive X-ray spectroscopy. Further evaluation on this comes from considering thermodynamic parameters of inter cation interaction. In cases where the host sensitized Ln3+ emission have been observed, luminescence lifetime measurements reveal significant protection of Ln3+ in the nanoparticles. Noticeable difference in photophysical properties for a given Ln3+ has been realized in the two hosts. The photophysical observations have been rationalized using (i) charge trapping mediated host sensitized dopant emission, (ii) autoionization of excited electrons, and (iii) environment induced photoluminescence quenching. The post-synthetic modification discussed in the present work provides an easy and less synthetically demanding room temperature based protocol to avail lanthanide incorporated (doped) semiconductor nanoparticles that can potentially use the unique emission properties of the lanthanide cations.

Influence of cadmium precursor concentrations on the structural, optical and electrochemical impedance properties of CdZnS thin films

Thin films of cadmium zinc sulfide (CdZnS) were deposited on microscopic glass substrates using the chemical bath deposition method and the effects of the Cd precursor concentrations on the morphological, structural and optical properties of the films were studied. The surface morphology as revealed by scanning electron microscope showed closely packed nano particles randomly spread on the surface of the glass substrates. The x-ray diffraction studies showed that the thin films were polycrystalline and the crystallite sizedecreased with increase in the concentration of the Cd precursor. While the optical absorbance decreased, the bandgap energy increased as the concentration of the cadmium source increased. Electrochemical studies were performed by cyclic voltammetry analysis and impedance measurements at low frequency ranges. Simulation model on the impedance model was carried out to obtain a more quantitative analysis of the data. The ternary CdZnS thin film developed in this work could be useful as window layer in solar cell fabrication.

Bacterial Synthesis of Cadmium and Zinc Sulfide Nanoparticles: Characteristics and Prospects of Application

Nanoparticles of cadmium sulfide (NpCdS) and zinc sulfide (NpZnS) are shown to be formed in the presence of Shewanella oneidensis MR-1 bacteria. These nanoparticles were located in the culture liquid and had a spherical shape. The nanoparticles were characterized by a small range of size distribution; the maximal size of NpCdS and NpZnS was approximately 5–6 nm; over 70% of the nanoparticles had a size of approximately 2–4 nm. The effective diameter of NpCdS and NpZnS was 158.9 nm and 219.3 nm, respectively. The value of the ζ-potential of NpCdS and NpZnS was –22.43 and –31.46 mV, respectively, which characterized the aqueous suspensions of these nanoparticles as metastable. The selectivity of the adsorption of certain proteins from the common pool of the protein molecules, synthesized by S. oneidensis MR-1 strain during cultivation, on the surface of nanoparticles is ascertained. Independently of the chemical nature of the particles (NpCdS and NpZnS), the protein molecules adsorbed on their surface are shown to have similar molecular weights. For the first time, biogenic NpCdS and NpZnS are used to develop a model composite system by the immobilization of amine-containing poly(glycidyl methacrylate) (PGMA) microspheres on the surface.

Preparation of cadmium zinc sulfide (Cd1−xZnxS) thin films from acidic chemical baths

Ternary cadmium zinc sulfide (Cd1−xZnxS) thin films were deposited by chemical bath deposition method for the entire range of 0 ≤ x ≤ 1 from acidic chemical bath using tartaric acid and hydrazine as a complexing agents. The X-ray diffraction (XRD) studies revealed that the deposited thin films had hexagonal crystal structure in the range of 0 ≤ x ≤ 0.6 and pure cubic phase at x = 1, whereas, the thin films deposited in the range of 0.72 ≤ x ≤ 0.9 had a mixed cubic and hexagonal structures. Furthermore, the XRD results showed that the crystalline size and lattice constants were decreased linearly with the gradual incorporations of zinc ion in the Cd1−xZnxS thin films. The optical spectroscopy investigation established that the band gap of the deposited ternary thin films found in the range of 3.84 eV to 3.94 eV. The scanning electron microscope studies illustrated that the surface morphologies of the prepared thin films were formed from spherical grains. The presence of cadmium, sulfur and Zinc elements in the synthesized thin films were confirmed by the energy dispersive x-ray analyses. The unusual large band gap obtained for pure cadmium sulfide and ternary Cd1−xZnxS thin films deposited under the present deposition condition together with the preferred orientation along the (002) plane make these thin films useful as a buffer layer in thin film solar cells.

Impact of γ-Radiation on Photothermoluminescence of Polypropylene-CdS/ZnS Composites

We have obtained polypropylene-based (PP) specimens of polymer composites with various volume fractions of binary compound based on cadmium sulfide and zinc sulfide (CdS/ZnS). Their photothermoluminescence, photostimulated by UV exposure, was studied before and after exposure to γ-radiation. The photothermoluminescence (PTL) method revealed an increased concentration of local levels in the range of 500–600 nm of the semiconductor loading agent and in the phase-boundary layer of the polymer-loading agent due to impact of γ-radiation with doses up to 100 kGy. It was demonstrated that composites with the composition PP–(CdS/ZnS) 90 (10 vol %) are characterized by an intensification of relaxation processes at a temperature 300 K, which can be regarded as an improvement in the performance properties of the obtained composites. The radiothermoluminescence (RTL) method revealed an increase in the intensity of the RTL and PTL peaks due to introduction of binary CdS/ZnS compounds into the PP.

Hollow microspheres consisting of uniform ZnxCd1-xS nanoparticles with noble-metal-free co-catalysts for hydrogen evolution with high quantum efficiency under visible light

Utilizing solar energy in order to produce hydrogen from water is one of the key technologies to deal with energy and environment issues. A photocatalyst with a small band gap, good charge separation, and high stability plays an important role in this process. Recently, zinc cadmium sulfide (ZnxCd1-xS) has caught researchers’ attention due to its unique photocatalytic properties such as the wide range of visible light energy absorption and strong stability during water splitting. Moreover, a unique feature of this semiconductor is the capability of modifying its band gap structure by changing the Zn/Cd ratio. Herein, a series of ZnxCd1-xS solid solutions was synthesized by utilizing metal-glycerate followed by calcination in air and sulfuration under flowing H2S. As a result, a homogeneous hexagonal wurtzite ZnxCd1-xS solid solution could produce hydrogen in a wide range of visible light region. Moreover, using MoS2 as a cocatalyst resulted in the same amount of hydrogen as Pt. The best result was obtained for the Zn30Cd70S solid solution that showed a hydrogen evolution of 12 mmol h−1 g−1 under solar simulator. The calculated quantum efficiencies (QE) in visible light region are: 46.6% at 400 nm to 23.4% at 500 nm as well as 11.3% at 550 nm. There are among the highest QE that have been ever reported for this kind of material under visible light region.

Studies of the absorbance peak on the N719 dye influence by combination between Cadmium Selenide (CdSe)QDs and Zinc Sulfide(ZnS)QDs

The absorption rate of the photoanode can be influenced by the combination between the difference semiconductor quantum dot sensitizer. Six samples were prepared with difference weight percent (wt%) of ZnS from 0% to 50% and constant wt% of CdSe which then will be called as semiconductor QDs were immersed in 0.5mM of N719 dye. The purity of ZnS powder and CdSe powder was determined using x-ray diffraction (XRD).The ultraviolet-visible spectrophotometry (Uv-Vis) use to investigate the absorption spectrum and absorbance peak of this sample. 50 wt% of ZnS is the best composition to increase the absorbance peak of the photoanode. The Cyclic voltammetry (CV) of varying wt% of ZnS, found that the 40 wt% of ZnS is suitable combination for a DSSC’s photoanode and produced the higher current.

Quantum dot solar cell studies on the influence of Cadmium Selenide(CdSe)QDs and the Zinc Sulfide(ZnS)QDs in the photoanode

The mixture between the difference semiconductor quantum dot sensitizer which is cadmium selenide(CdSe) and zinc sulfide (ZnS) into the Dye-synthesis solar cell (DSSCs) can affect the value of resistance and capacity photoanode in the system.In this experiment, each sample consists difference weight percent of Zinc sulfide and the constant weight percent of CdSe. Docter blade technique is used to stick and spread evenly the mixture CdSe/ZnS QD on the surface of the thin film. To prove the assembled of CdSe/ZnS on the thin film were observed using Scanning Electron Microscopy (SEM). The resistance and capacity of the photoanode were characterized by using impedance spectroscopy(EIS). The smallest resistance is 37.1kΩ produce by CdSe/ZnS(20 wt%) and the largest resistance 825KΩ produce by CdSe/ZnS(50 wt%) while the highest capacity is 12 µF in the CdSe/ZnS(40 wt%) and the lowest capacity is CdSe/ZnS(20 wt%) which is 538 nF. The most suitable composition to be used as photoanode is CdSe/ZnS(40 wt%) because it has high capacity and low resistance.

Influence of Zinc Content in Ternary ZnCdS Films Deposited by Chemical Bath Deposition for Photovoltaic Applications

Cadmium Zinc Sulfide thin films with different Zn concentration were synthesized in aqueous solution by chemical bath deposition (CBD) method using CdSO4, ZnSO4, CH4N2S for Cd+2, Zn+2, and S−2 ions source, respectively. The as-deposited films are well homogeneous, adherent and free from pinholes. The incorporation of Zn in CdS was found to be dependent on the annealing temperature. Structure, morphology, elemental analysis, optical and photoelectrochemical (PEC) properties of ZnCdS were characterized using X-ray diffraction, atomic force microscopy, energy dispersive spectroscopy, transmission electron microscopy and UV-Vis absorption measurements, respectively. According to EDS analysis the films are non-stoichiometric due to a deficit of sulfur, which becomes more important as the Zn content increases. The absorption edge shifts toward the lower wavelength region and hence the bandgap of the films increases as the Zn content increases. The values of optical absorption edge are found to change from 2.42 eV for CdS and 2.90 eV for ZnS thin films. The PEC and linear sweep voltammetry performance of the Zn doped CdS films were examined by chronoamperometry technique which provided a significant high potential current due to increase of the electrical conductivity as compared to CdS film.

The deposition of thin films of cadmium zinc sulfide Cd1\u2212xZnxS at 250\xa0\xb0C from spin-coated xanthato complexes: a potential route to window layers for photovoltaic cells

Thin films of Cd1−xZnxS (CZS) were prepared by a novel spin coating/melt method from cadmium ethylxanthato [Cd(C2H5OCS2)2] and zinc ethylxanthato [Zn(C2H5OCS2)2] in x ratios of 0–0.15 and of 1. A solution of the precursor(s) in THF was spin coated onto a glass substrate and then heated at 250 °C for 1 h under N2. The thickness of the film formed can be controlled by varying the solution composition and/or the spin rate of the coating. A total metal precursor solution concentration of 50 mM was used in all cases. The films were characterized by p-XRD, SEM, EDX, ICP-AES, XPS, UV–Vis absorption spectroscopy, Raman spectroscopy and resistivity measurements. The band gaps of the films were between 2.35–2.58 and 3.75 eV (0 ≤ x ≤ 0.15 and at x = 1). The resistivity of Cd1−xZnxS films was found to vary linearly with zinc contents, and the properties of the films suggest potential application to photovoltaics as window layers. This work is the first study to demonstrate Cd1−xZnxS thin films by a spin coating/melt method from xanthato precursors.