Activity For Combustion Research Articles

Catalytic Combustion of Biodiesel Wastewater on Red Mud Catalyst

The resource utilization of red mud (RM) has attracted widespread attention for achieving the waste-to-waste treatment goal. In this work, the RM catalysts were synthesized at different calcination temperatures by a simple method. The calcination temperature had a great effect on catalyst activity in the catalytic combustion of biodiesel wastewater. The RM catalyst calcined at 350 °C (RM350) exhibited the best catalytic activity. The chemical oxygen demand (COD) and COD removal rate of the treated wastewater reached almost 0 mg/L and 100%, respectively. The COD removal rate was significantly higher than 90.703% of the catalyst prepared by α-Fe2O3 at the same calcination temperature. Characterization results showed that the RM catalyst exhibited a high specific surface area of 60.03–64.15 m2/g and a well-developed mesoporous structure, as the calcination temperature did not exceed 400 °C, which was beneficial for adsorption and diffusion. Meanwhile, most of the Fe2O3 in the catalyst existed in an amorphous form and was abundantly presented on the catalyst surface, significantly lowering the reduction temperature of the catalyst and enhancing its reducibility. Furthermore, the α-Fe2O3 in the catalyst had higher dispersion, leading to an increase in utilization efficiency.

Wildfire Smoke Contributions to Polycyclic Aromatic Hydrocarbon Loadings in Western Canadian Urban Surface Grime.

Wildfires emit large amounts of polycyclic aromatic hydrocarbons (PAHs) into the atmosphere. As PAHs emitted from anthropogenic sources are known to accumulate in urban surface grime present on building exteriors and windows, we hypothesized that PAH-containing wildfire smoke plumes could similarly increase PAH grime loadings. To explore this hypothesis, we coupled analysis of PAHs in grime samples collected from August to November 2021 in two historically smoke-affected Canadian cities, Calgary and Kamloops, with contemporaneous field- and model-based indicators of wildfire influence. In Calgary, a single wildfire smoke day contributed over 20% of total grime PAH loadings during this study's 3-month sampling period, which implies that wildfire inputs have the potential to dominate the grime composition during a typical wildfire season. In Kamloops, although the PAH congener profile displayed a sustained background wildfire influence, total PAH loadings were dominated by a hyper-local combustion event, which highlights that even small-scale urban combustion activities have the potential to control pollutant loadings on nearby surfaces. In both locations, temporal PAH congener profiles showed no evidence of reactive loss, implying that biomass burning contributes to the presence of a persistent PAH reservoir available for direct exposure or runoff-mediated contamination of downstream environmental compartments.

Emerging investigator series: open dumping and burning: an overlooked source of terrestrial microplastics in underserved communities.

Open dumping and burning of solid waste are widely practiced in underserved communities lacking access to solid waste management facilities; however, the generation of microplastics from these sites has been overlooked. We report elevated concentrations of microplastics (MPs) in soil of three solid waste open dump and burn sites: a single-family site in Tuttle, Oklahoma, USA, and two community-wide sites in Crow Agency and Lodge Grass, Montana, USA. We extracted, quantified, and characterized MPs from two soil depths (0-9 cm and 9-18 cm). The average of abundance of particles found at community-wide sites three sites (18, 460 particles kg-1 soil) equals or exceeds reported concentrations from currently understood sources of MPs including biosolids application and other agricultural practices. Attenuated total reflectance Fourier transformed infrared (ATR-FTIR) identified polyethylene as the dominant polymer across all sites (46.2-84.8%). We also detected rayon (≤11.5%), polystyrene (up to 11.5%), polyethylene terephthalate (≤5.1), polyvinyl chloride (≤4.4%), polyester (≤3.1), and acrylic (≤2.2%). Burned MPs accounted for 76.3 to 96.9% of the MPs found in both community wide dumping sites. These results indicate that solid waste dumping and burning activities are a major source of thermally oxidized MPs for the surrounding terrestrial environment with potential to negatively affect underserved communities.

Thermally induced structural evolution of a silicate-ceria material boosting the activity of low-concentration methane combustion on its supported palladium catalyst

Thermally induced structural evolution of a silicate-ceria material boosting the activity of low-concentration methane combustion on its supported palladium catalyst

Source attribution, health risk analysis, and policy implications of PAHs and NPAHs in PM in Northern Mexico

This research investigates the concentrations, sources, and health risks of polycyclic aromatic hydrocarbons (PAHs) and nitrated PAHs (NPAHs) in particulate matter with an aerodynamic diameter of 10 m or less (PM) from critical urban centers in northern Mexico: Metropolitan Monterrey Area (MMA), Chihuahua (CHI), and Ciudad Juárez (CDJ). Advanced gas chromatography-mass spectrometry (GC-MS and GC-NCI-MS) revealed significant PAHs concentrations, with levels in MMA reaching 108.89 ± 99.90 ng/m, CHI at 100.69 ± 122.60 ng/m and CDJ at 73.26 ± 90.85 ng/m. Significantly, 3-nitrofluoranthene (3N-FLA) and 1-nitropyrene (1N-PYR), known for their potent toxicity, were among the most prominent NPAHs, with total concentrations in MMA, CHI, and CDJ at 470.32 pg/m, 247.26 pg/m, and 193.20 pg/m, respectively. Source apportionment using diagnostic ratios (DRs) and principal component analysis (PCA) indicated that biomass burning, vehicular emissions, and industrial activities were the primary sources of MMA. At the same time, CHI and CDJ were influenced more by industrial and diesel emissions. Health risk assessments based on benzo[a]pyrene equivalent (BaPeq) concentrations and excess cancer risk (ECR) demonstrated moderate to significant cancer risks, with CDJ exhibiting the highest NPAHs-related risk. This study makes several significant contributions: it presents the first analysis of PAHs and NPAHs levels in these urban areas, identifies key emission sources, and quantifies associated health risks, providing essential data for developing targeted public health policies and environmental regulations.

Characterization of Sunflower Waste Carbonization: Energy Balance and Water Holding Properties

This paper characterizes the carbonization process of biomass wastes, including sunflower husk pellets and sunflower sponge stalk pellets, at carbonization temperatures of 450 and 550 °C. These studies are important because of the reductions in wood resources for the preparation of barbecue charcoal, as well as agricultural benefits in terms of soil additives. In terms of energy balance, the obtained pyrolysis ensures the autothermal process. The heating characteristics of fixed bed showed that, due to the difference in bulk density, the bed temperature of the sunflower husk pellets reached 450 °C in 110 min, whereas the bed temperature of the sunflower stalk sponge reached the same temperature in 200 min. Additionally, the energy used for the sunflower husk carbonization increased from 2.9 kWh at 450 °C to 3.3 kWh at 550 °C, while the sunflower stalk sponge increased from 3.5 to 3.9 kWh. The combustion characteristics assessed using TGA showed that the carbonization of sunflower husk leads to obtained biochar with a higher combustion activity than biochar derived from sunflower stalk sponge. According to the experimental results, biochar from sunflower husk pellets has a higher water content capacity and water absorption rate than biochar from sunflower stalk sponge pellets.

Levels, Sources and Risk Assessment of Carbonaceous and Organic Species Associated with PM2.5 in Two Small Cities of Morelos, Mexico

A study of carbonaceous species, polycyclic aromatic hydrocarbons (PAHs), and nitro-PAHs associated with PM2.5 was conducted to assess their carcinogenic potential and associated health risks in the two main cities of the State of Morelos: Cuernavaca and Cuautla. The annual median concentrations in Cuernavaca of organic carbon (OC) and elemental carbon (EC) were 6.2 µg m−3 and 0.6 µg m−3, respectively, whereas in Cuautla, OC concentrations averaged 4.8 µg m−3 and EC 0.6 µg m−3. OC/EC ratios, total carbonaceous aerosols (TCA), primary (POC) and secondary organic carbon (SOC), as well as elemental carbon reactive (ECR) were estimated, also showing prevalence of primary emissions such as biomass burning. The seventeen PAHs recommended by the EPA and twelve nitro-PAHs were measured using gas chromatography–mass spectrometry. The annual median sum of PAHs was 9.7 ng m−3 in Cuernavaca and 11.2 ng m−3 in Cuautla, where carcinogenic high-molecular-weight compounds were the most dominant; the annual median sums of nitro-PAHs were 287 pg m−3 and 432 pg m−3, respectively. Diagnostic ratios were applied to identify potential sources of PAH emissions, suggesting that fuel combustion is the major contributor in both sites, followed by coal biomass burning and agricultural activities. The annual carcinogenic potential as benzo(a)pyrene equivalent was 2.2 ng m−3 for both sites. The lifetime excess cancer risk from PAH inhalation was estimated to range from 1.8 × 10−4 to 2 × 10−4 in Cuernavaca and from 1.5 × 10−4 to 2.2 × 10−4 in Cuautla, similar to values observed in other urban regions globally.

Co-Ce Clay-Based Materials: Their Feasibility as Catalysts for Soot and CO Oxidation Reactions

A series of Co-Ce clay-based catalysts were prepared via the wet impregnation method and tested for the catalytic combustion of diesel soot and carbon monoxide. The objective of this work was to find a suitable catalyst with an optimized active phase composition in order to structure this system using a 3D-printing technique. The physicochemical characterization indicated that the support was mainly composed of kaolinite and quartz. When supported on commercial clay, the mixture of oxides (Co3O4 spinel and CeO2 fluorite) had higher activity than the individual oxides. The formation of a solid Co-Ce solution was verified along with a synergistic effect between these two selected metal oxides. The optimal molar composition was Co:Ce = 90:10. The corresponding catalyst showed the highest catalytic activity for soot combustion, with 335 °C being the temperature of the maximum combustion rate. Also, it produced the best system for CO oxidation. This formulation showed a balanced proportion of Co3+ and Co2+ on the surface and had the highest content of Ce3+ surface species among the catalysts prepared, which played a key role in the oxidation reactions studied.

Contribution of Anthropogenic and Lithogenic Aerosol Fe in the East China Sea

AbstractAerosol deposition is one of the major processes providing bioavailable Fe to the surface ocean. However, the quantification of aerosol Fe flux in the surface ocean is highly challenging operationally. In this study, we measured both Fe isotopic composition and specific elemental ratios in 5 size‐fraction aerosols collected over the East China Sea (ECS) to quantify the relative contribution of lithogenic and anthropogenic aerosol Fe. Both the isotopic and elemental ratios indicate that anthropogenic aerosol Fe mainly originates from high‐temperature combustion activities with the end member of the δ56Fe to be −4.5‰. We found that the Cd/Ti ratio is a much more reliable proxy to quantify the contribution of anthropogenic aerosol Fe in coarse aerosols than δ56Fe in the ECS. Attributed to extremely high deposition velocities and high total Fe concentrations for large size aerosols, lithogenic aerosols are still the dominant dissolved aerosol Fe source in the ECS.

Analysis of the compound effect of mine water on coal spontaneous combustion and its application in coal fire prevention

The research on mine fire control has confirmed that the probability of CSC (Coal Spontaneous Combustion) after mine water treatment is higher than raw coal (RC). However, the current research on the effect of mine water on CSC is sketchy, which is not close to real water environment of the mine, and there is a lack of in-depth and systematic discussion on the compound effect of the characteristic components of mine water on the process of CSC. According to the actual mine environment, this paper prepared samples soaked by different types of mine water under different conditions, then the compound effect of mine water on CSC is studied by means of thermogravimetric, infrared and gas analysis. The results show that the characteristic temperature point T1 of coal samples after mine water treatment increases significantly, with a maximum increase of 11 °C, while T2-T4 decreases to different degrees, with a maximum decrease of 13 °C. The maximum apparent activation energy decreased by 32 %, which decreased by 40.6KJ/mol. The release of CO and CO2 is 1–2 times that of raw coal. The content of organic functional groups is 1.1–1.8 times higher than that of raw coal. The changes of these parameters are enhanced with the increase of acidity of mine water, which indicates that mine water can promote the spontaneous combustion activity of coal. The promoting effect mainly comes from the swelling effect of water, and the inhibiting effect is mainly related to the inorganic salts in mine water, but the inorganic salts contained in the mine water are not enough to reach the concentration that can inhibit CSC, so the overall performance of mine water is to promote the CSC. This study is conducive to understanding the influence mechanism of actual mine water environment on CSC, and provides a theoretical support for control of CSC and comprehensive utilization of mine water.

Study of thermal decomposition and mechanical sensitivity of ETPE propellants

Abstract In this paper, the thermal decomposition characteristics and mechanical sensitivity of ETPE propellant were characterized by differential scanning calorimeter (DSC), vacuum stability tester (VST), impact sensitivity tester and friction sensitivity tester, and the main factors affecting the safety performance of ETPE propellant were studied. The results show that ETPE propellant has good thermal stability under 185°C. The combustion activation energy of ETPE propellant is slightly lower than that of HTPB propellant. By using 100°C heating method, the net added gas of ETPE propellant is 0.81ml/g, which meets the evaluation standard of stability qualification, and the propellant did not spontaneously combust under various high temperature test conditions. By reducing the amount of fine AP and controlling the amount of RDX, it is conducive to reducing the probability of the “hot spot” generated by the propellant under the external excitation energy, reducing the mechanical sensitivity of propellant and improving the safety performance of propellant.

Effect of citric acid-ethylene glycol binders on the washcoat adhesion and activity of monolithic catalysts for the catalytic oxidation of dichloromethane

Supported Pt-Co/HZSM-5 catalyst was considered to have excellent activity and stability in the catalytic combustion of chlorinated VOCs, which face challenges in scale-up application. Herein, we used an organic binder (citric acid-ethylene glycol, denoted as CA-EG) to coat the catalyst slurry on honeycomb cordierite. Citric acid can help to synthesize a stable slurry and preserve the activity of the original catalyst powder compared to traditional binders (Al or Si gel). The structure of the reticular long-chain organics in CA-EG makes it highly adhesive and the CA-EG coating has excellent resistance to mechanical stability. Catalyst characterization shows that the catalysts using CA-EG as the binder had enhanced redox properties, richer surface adsorbed oxygen and a more complete pore structure. This resulted in catalysts with lower T90 and lower by-product yields. The monolithic Pt-Co/HZSM-5 catalyst exhibited excellent activity in the oxidation of dichloromethane (T50 = 246.9 °C and T90 = 334.1 °C), and showed stability for at least 48 h (at 90 % conversion with no noticeable drop). Moreover, the water resistance of the monolithic catalyst was also excellent. This study proved that the CA-EG binder is very suitable for the coating process of zeolite-based catalysts.

Total gaseous mercury in Kathmandu, a South Asian metropolis: Temporal variations, sources apportionment and health risk assessment

South Asia is a global hotspot of air pollution gaining attention due to its severe implications, in which atmospheric mercury (Hg) could cause detrimental health effects in metropolitan areas. In this study, first-time year-round (January – December 2019) mean total gaseous mercury (TGM) concentration at Kathmandu, Nepal - a sub-tropical city in South Asia was reported at 9.9 ± 10.0 ng m-3. Seasonal TGM variation at Kathmandu showed highest concentration in winter (16.8 ± 16.9 ng m-3) and lowest in summer (2.9 ± 2.1 ng m-3). Generally higher daytime TGM concentration as opposed to night-time TGM indicated Hg build-up within atmospheric boundary layer due to low wind speed and high humidity. Events with high wind speed (> 30 m s-1) induced regional pollutant transport from nearby brick kilns and cement factories. Principal component analysis associated a major part of TGM with PM2.5 and CO and indicated the remarkable influence of fuel combustion and vehicular emissions. Backward trajectory and potential source contribution factor analysis further indicate the impact of regional Hg emissions and transboundary emissions from India towards Nepal, which expands beyond the Himalayas and the Tibetan Plateau. Prominent low-grade coal burning and kilning activities in winter spiked up TGM concentrations, resulting in the highest health quotient (HQ = 0.24) value, which could significantly impact public health. Our study presented the most comprehensive set of continuous annual atmospheric Hg monitoring data from Nepal in the South Asian region. The results serve as a baseline for regional atmospheric Hg levels and offer a critical reference for assessing and addressing air pollution concerns in Nepal as well as throughout South Asia.

Formula Optimization of Propolis Transfersome Gel, Aloe Vera, Gotu Extract: Formula Design, Formulation Evaluation and Cell Regeneration Test in Diabetic Wounds

The study was conducted to determine the optimal formula of transfersome propolis gel, aloe vera extract and gotu gotu leaf extract and test it against diabetic wounds in male white rats (Rattus norvegicus). The gel was created with an optimal formulation resulting from the application of a Design Expert with Cutimed as a positive control of burns on the backs of male white rats (Rattus norvegicus). Formula optimization was carried out using a Simple Lattice Design with variations of carbopol, TEA and glycerin. Activity tests of propolis transferosome gel, aloe vera extract and gotu gotu extract were conducted on 20 rats. The data results were statistically analyzed using the SPSS One Way ANOVA method. Phytochemical screening on aloe vera and gotu gotu showed the presence of flavonoid compounds, tannins and saponins. Transfersome propolis has a particle size of 88.55 nm and a zeta potential of -24.13 mV. The optimal formula produces a clear preparation in white, a distinctive odour, a stable viscosity of 19980 cps, dispersion power of 6.67 cm, adhesion of 4.07 seconds and pH of 6.45. The burn activity test had the fastest effectiveness on day 12 but did not differ significantly from the customized control.

Multifaceted Assessment of Agricultural Extension in Conflict Affected Areas of Mindanao, Philippines

Agricultural extension in conflict affected areas has received limited research attention. Yet agricultural extension undertaken within a group–based facilitation framework can have many benefits via livelihood improvement, human and social capital development. In this paper, an extension model adapted for conflict affected areas is briefly described and then assessed from multiple viewpoints – physical, economic, lifestyle, social capital and environmental. This was done in two case study sites in conflict affected areas of Mindanao, Philippines. Major positive physical, economic and lifestyle changes were revealed at both case study sites, as were changes in knowledge, attitude, skills, and aspirations and social capital. Some positive environmental aspects were also noted. Income and savings were up 64 and 108 percent respectively, with those income changes being reflected in additional expenditures on basic items such as food clothing and education. Knowledge, attitudes skills and aspirations (which can be regarded as intermediate steps towards livelihood improvement) all increased substantially. Various social capital indicators were judged to have improved. From an environmental perspective, there were decreases in charcoal production and slash and burn activity. Tree planting and soil fertility increased. Most of these assessment parameters, but especially social capital with its implication for trust and human interaction, are relevant to peace building. With the passage of the Bangsamoro Organic Law, there is expected to be a strong increase within the Philippines and internationally in funding the promotion of agricultural livelihood activities in Mindanao. The multifaced assessment of benefits is somewhat unique and the resulting quantification of the benefits demonstrates that additional funding and more diverse applications could be warranted.

Investigation of size-segregated particulate matter and carbonaceous components in Phnom Penh, Cambodia.

This study investigated the size-segregated carbonaceous components of particulate matter (PM), including ultrafine particles (UFP or PM0.1), across three distinct urban settings in Phnom Penh, Cambodia: an educational site (University of Health Sciences, UHS), an institutional site (Ministry of Environment, MoE), and a residential area near a landfill. A cascade impactor-type sampler equipped with an inertial filter was used to collect size-segregated particles down to UFPs. Carbonaceous species, including organic carbon (OC) and elemental carbon (EC), were analyzed using a thermal/optical carbon analyzer to determine their composition and ratios. The results indicated no significant differences in mass concentration between weekdays and weekends at all sites; however, PM profiles varied across the location. The UHS site displayed higher EC levels in UFP, with concentrations suggesting significant local vehicular emissions, underscored by a lower OC/EC ratio (2.39 ± 1.13) compared to other sites. In contrast, the landfill site exhibited higher OC components in finer particles, suggesting emissions from organic sources such as waste burning and cooking activities, evidenced by higher OC/EC ratios across all particle sizes (e.g., OC/EC ratio in UFP at 3.78 ± 0.98). The MoE site presented a balanced profile with moderate levels of both OC and EC, influenced by its proximity to natural dispersion factors like the Tonle Sap River. Additionally, air mass backward trajectory analysis integrated with hotspot data indicated transboundary influences, particularly from agricultural burning in surrounding provinces, including Vietnam. Therefore, both local and transboundary emissions influenced the PM levels in Phnom Penh city.

Analyzing Morphology and Composition of Coarse Aerosol Particles in Bangkok, Thailand: Implications to Sources and Impacts of Aged Aerosols on Ecosystem Health and Climate Dynamics

During dry seasons, elevated aerosol levels across Thailand pose nationwide problems. Understanding and addressing this issue is challenging due to the dynamic nature of aerosol modification and generation during transport. This study investigates the morphology and elemental compositions of coarse aerosol particles in Bangkok, Thailand, during the dry seasons of 2020/21. Through scanning electron microscopy (SEM) coupled with energy-dispersive X-ray spectrometry (EDS), the study reveals a complex mixture of anthropogenic, mineral, biogenic, and marine aerosols. Anthropogenic sources, including biomass burning, vehicular emissions, and industrial activities, contribute to carbonaceous particles like soot aggregates and tar balls. Mineral dust particles, predominantly calcium-rich and aluminosilicate, originate from various sources including construction, industry, and natural processes. Aging processes alter the composition and properties of both carbonaceous and mineral particles, influencing nutrient deposition, carbon sequestration, cloud condensation nuclei formation, and light scattering. These processes have multifaceted impacts on ecosystem health and climate dynamics, highlighting the need for further research and mitigation strategies to address the environmental consequences of aged aerosol particles in urban environments like Bangkok.

Boosting catalytic activity of Pd/LaxCe1-xMnO3 catalysts in methane combustion by a plasma-treated strategy

An innovative plasma-treated strategy was employed to prepare LaxCe1-xMnO3 (LCMO) perovskite oxides. Pd nanoparticles were loaded onto plasma-treated (P) and air-calcined (T) LCMO respectively, forming the corresponding Pd/LCMO catalysts. The results indicated that the introduction of Pd and plasma treatment largely boost the catalytic activity in methane combustion. Among these catalysts, the Pd/LCMO-P catalyst shows the best performance in CH4 oxidation, giving T90 of 425 °C. It was revealed that the morphology structure and surface defects were strongly affected by plasma treatment, further affecting the dispersion and chemical state of Pd species via surface interaction. The superior performance should be ascribed to the good redox properties (high Mn4+/Mn3+ ratio), rich surface-active oxygen species, and enhanced oxygen mobility (weakened Pd-O and Mn-O chemical bonds). Besides, the distributions of cerium in the surface and crystal lattice of LMO also improved metal-support interaction and the oxygen mobility, that boosted CH4 oxidation. This plasma-treated strategy provided an effective path to develop the efficient combustion catalyst for superior performance.

Synergistic effect as a function of preparation method in CeO2-ZrO2-SnO2 catalysts for CO oxidation and soot combustion

The development of catalysts based on environmentally desirable components is a topical challenge. In the present work, we consider the effects of the preparation method on phase composition, porous structure, nature and distribution of active sites as well as synergistic behavior of components in two series of CeO2-ZrO2-SnO2 catalysts for soot combustion and CO oxidation. The catalysts prepared by the citrate method feature rather large SnO2 aggregates distributed on CeO2 and/or ZrO2 oxides. On the contrary, the catalysts prepared by the CTAB-templated approach feature a uniform distribution of oxide species and usually show higher activity in both CO oxidation and soot combustion. In both series, the activity and characteristics of catalysts are enhanced due to the synergistic effects arising when two or more oxide components coexist in their composition, and the degree of synergy is a function of the preparation method. The features of the most active catalysts combine (1) high specific surface area and pore volume, (2) high microstrain values, (3) coexisting oxygen vacancies of different nature, (4) high H2 consumption at low temperatures, and (5) high fraction of adsorbed active oxygen species.

Experimental study of ammonia energy ratio on combustion and emissions from ammonia-gasoline dual-fuel engine at various load conditions

Achieving carbon neutrality necessitates the adoption of zero-carbon fuels in engine applications, with ammonia emerging as an up-and-coming candidate due to its favorable safety profile and advantages in storage and transportation. This study experimentally investigated the feasibility of an ammonia-gasoline dual-fuel (AGDF) engine to achieve comparable power output and satisfactory carbon reduction without changing the main structural parameters of the engine. A four-cylinder, naturally aspirated, spark ignition engine was used to investigate the impact of ammonia energy ratio (AER), engine base torque and engine speed on the engine performance, combustion evolution and emission characteristics. The findings reveal that the brake thermal efficiency (BTE) in AGDF mode is lower than in gasoline-only mode, primarily due to the reduced combustion activity. However, this efficiency decline becomes noticeable only when the AER exceeds 15 %. Additionally, at high AERs and high engine base torques, the delayed effect of ammonia fuel on the main combustion period results in a double-peak pattern, which limits the energy output but presents opportunities for phase optimization. The study also examined three incomplete combustion emissions, each exhibiting distinct behaviors. Except for ammonia slip, adding ammonia fuel does not significantly affect carbon monoxide (CO) and unburned hydrocarbons (UHC) emissions, particularly at AERs below 25 %. Nevertheless, nitrogen oxide (NOx) emissions under AGDF combustion are significantly higher than under gasoline alone in most instances. Crucially, the study demonstrates the carbon reduction potential of ammonia fuel across different engine loads, with a maximum carbon dioxide (CO2) reduction of 46.8 % at a 35 % AER. It is anticipated that further optimization of the combustion phase will improve the capability for carbon reduction.