Burial Of Sediments Research Articles

Above Ground Carbon Stock Estimates of Mangrove Forest Using Worldview-2 Imagery in Teluk Benoa, Bali

Mangrove forests have a role as an absorbent and a carbon sink to a reduction CO2 in the atmosphere. Based on the previous studies found that mangrove forests have the ability to sequestering carbon through photosynthesis and carbon burial of sediment effectively. The value and distribution of carbon stock are important to understand through remote sensing technology. In this study, will estimate the carbon stock using WorldView-2 imagery with and without distinction mangrove species. Worldview-2 is a high resolution image with 2 meters spatial resolution and eight spectral bands. Worldview-2 potential to estimate carbon stock in detail. Vegetation indices such as DVI (Difference Vegetation Index), EVI (Enhanced Vegetation Index), and MRE-SR (Modified Red Edge-Simple Ratio) and field data were modeled to determine the best vegetation indices to estimate carbon stocks. Carbon stock estimated by allometric equation approach specific to each species of mangrove. Worldview-2 imagery to map mangrove species with an accuracy of 80.95%. Total carbon stock estimation results in the study area of 35.349,87 tons of dominant species Rhizophora apiculata, Rhizophora mucronata and Sonneratia alba.

Geochemical constraints on the temperature and timing of carbonate formation and lithification in the Nankai Trough, NanTroSEIZE transect

Information about diagenetic processes and temperatures during burial of sediments entering the subduction zone is important for understanding changes in physical properties and seismic behavior during deformation. The geochemistry of authigenic carbonates from accretionary prisms can serve as proxies for conditions during carbonate cementation and resultant lithification. We report results from the Nankai accretionary prism recovered from Integrated Ocean Drilling Program (IODP) sites C0011 and C0012 and we document continued cementation of deep sediment sections prior to subduction. Elemental and isotope data provide evidence for complex mixing of different isotopic reservoirs in pore waters contributing to carbonate chemical signatures. Carbon stable isotope values exhibit a broad range (δ13CV-PDB=+0.1‰ to −22.5‰) that corresponds to different stages of cement formation during burial. Carbonate formation temperatures from carbonate-clumped isotope geochemistry range from 16°C to 63°C at Site C0011 and 8.7°C to 68°C at Site C0012. The correspondence between the clumped-isotope temperatures and extrapolations of measured in situ temperatures indicate the carbonate is continuing to form at present. Calculated water isotopic compositions are in some cases enriched in 18O relative to measured interstitial waters suggesting a component of inherited seawater or input from clay-bound water. Low oxygen isotope values and the observed Ba/Ca ratios are also consistent with carbonate cementation at depth. Strontium isotopes of interstitial waters (87Sr/86Sr of 0.7059–0.7069) and carbonates (87Sr/86Sr of 0.70715–0.70891) support formation of carbonates from a mixture of strontium reservoirs including current interstitial waters and relic seawater contemporaneous with deposition. Collectively our data reflect mixed sources of dissolved inorganic carbon and cations that include authigenic phases driven by organic carbon and volcanic alteration reactions. Physical properties of input sediments continue to undergo modification by carbonate cementation at present. Due to ongoing recrystallization, temperatures from carbonate-clumped isotopes reflect the modern geothermal gradient and may serve as useful measures of geothermal gradients in other siliciclastic basins where carbonate cementation occurs. We conclude that clumped-isotope signatures in authigenic carbonates from accretionary prisms are important proxies for the timing and conditions of cementation in active margins. Our results highlight the importance of using multi-proxy approaches to elucidate the history of carbonate cementation, particularly to establish carbonate precipitation at depth and its potential impact on the physical and mechanical properties of the sediment prior to subduction.

Origin and fate of sedimentary organic matter in the northern Bay of Bengal during the last 18 ka

The Northern Bay of Bengal (NBoB) is a globally important region for deep-sea organic matter (OM) deposition due to massive fluvial discharge from the Ganges-Brahmaputra-Meghna (G-B-M) rivers and moderate to high surface productivity. Previous studies have focused on carbon burial in turbiditic sediments of the Bengal Fan. However, little is known about the storage of carbon in pelagic and hemipelagic sediments of the Bay of Bengal over millennial time scales. This study presents a comprehensive history of OM origin and fate as well as a quantification of carbon sediment storage in the Eastern Bengal Slope (EBS) during the last 18ka. Bulk organic proxies (TOC, TIC, TN, δ13CTOC, δ15NTN) and content and composition of total hydrolysable amino acids (THAA) in a sediment core (SO188-342KL) from the EBS were analyzed. Three periods of high OM accumulation were identified: the Late Glacial (LG), the Bölling/Alleröd (B/A), and the Early Holocene Climatic Optimum (EHCO). Lower eustatic sea level before 15ka BP allowed a closer connection between the EBS and the fluvial debouch, favoring high terrestrial OM input to the core site. This connection was progressively lost between 15 and 7ka BP as sea level rose to its present height and terrestrial OM input decreased considerably. Export and preservation of marine OM was stimulated during periods of summer monsoon intensification (B/A and EHCO) as a consequence of higher surface productivity enhanced by cyclonic-eddy nutrient pumping and fluvial nutrient delivery into the photic zone. Changes in the THAA composition indicate that the marine plankton community structure shifted from calcareous-dominated before 13ka BP to siliceous-dominated afterwards. They also indicate that the relative proportion of marine versus terrestrial OM deposited at site 342KL was primarily driven by relative sea level and enlarged during the Holocene. The ballasting effect of lithogenic particles during periods of high coastal proximity and/or enhanced fluvial discharge promoted the export and preservation of OM. The high organic carbon accumulation rates in the EBS during the LG (18–17ka BP) were 5-fold higher than at present and comparable to those of glacial upwelling areas. Despite the differences in sediment and OM transport and storage among the Western and Eastern sectors of the NBoB, this region remains important for global carbon sequestration during sea level low-stands. In addition, the summer monsoon was a key promotor of terrestrial and marine OM export to the deep-ocean, highlighting its relevance as regulator of the global carbon budget.

Investigation of biodegradation in three different sediment cores from a shellmound (sambaqui) of Brazil, using Ascaris lumbricoides eggs as a model

For more than 30years, paleoparasitologists attempted to recover parasite remains from burial sediments and archaeological layers in Brazilian shellmounds. These sites are located along the shoreline of the country especially at the South and Southeastern regions, and for that reason they are exposed to frequent rainfall. Most of the shellmounds were built in coastal plains, associated with waterbodies, under the influence of high tides and/or inundation. Biodegradation is a factor that affects parasite preservation, especially in open archaeological sites. However, this hypothesis has never been tested in sediments from shellmounds. This study aimed to experimentally evaluate the biodegradation of Ascaris lumbricoides eggs and DNA from three intact cores collected from a shellmound. The cores and control sediments were collected from archaeological profiles composed of different materials. Each core received about 1,000,000 recent eggs, and water was poured over twice a week during 45days, simulating the main climate condition of the environment. The water was collected at the end of each core to observe the egg movement through the archaeological layers of the cores. Soil was sampled in different levels: 31 soil samples from the cores and 12 control samples were analyzed by the spontaneous sedimentation technique and 23 soil samples from the cores and all the control samples were analyzed for the DNA of the parasite. Parasitological evidence was only found in the superficial layers and very few eggs were recovered. Bioactivity caused destruction of most of the eggs and DNA. This research also supports the previous hypothesis that taphonomic factors probably are responsible for fewer findings of A. lumbricoides eggs in South American archaeological sites, especially in open environment sites.

Experimental deformation partitioning in obliquely converging orogens with lateral variations of basal décollement rheology: Inferences for NW Zagros, Iran

The rheology of décollement materials fundamentally constrains the kinematic evolution and tectonic architecture of orogenic belts. In this paper, we present the result of an experimental program designed for investigating, by sandbox analog modeling, the impact of the spatial distribution of décollement rheology underneath an inner carbonate platform-basin-outer carbonate platform paleogeographic architecture undergoing traspressional deformations. Our models indicate that viscous décollements at the base of both platforms favor the outward propagation of deformation, duplexing in the Inner Platform (that faces the wedge toe), and deep burial of basinal sediments. On the other hand, frictional rheologies favor internal shortening in the basin, strong uplift and limited burial. Application of experimental results to better constrain the late Cretaceous tectonic evolution of the NW Zagros is discussed.

Global pulses of organic carbon burial in deep-sea sediments during glacial maxima.

The burial of organic carbon in marine sediments removes carbon dioxide from the ocean–atmosphere pool, provides energy to the deep biosphere, and on geological timescales drives the oxygenation of the atmosphere. Here we quantify natural variations in the burial of organic carbon in deep-sea sediments over the last glacial cycle. Using a new data compilation of hundreds of sediment cores, we show that the accumulation rate of organic carbon in the deep sea was consistently higher (50%) during glacial maxima than during interglacials. The spatial pattern and temporal progression of the changes suggest that enhanced nutrient supply to parts of the surface ocean contributed to the glacial burial pulses, with likely additional contributions from more efficient transfer of organic matter to the deep sea and better preservation of organic matter due to reduced oxygen exposure. These results demonstrate a pronounced climate sensitivity for this global carbon cycle sink.

Production, exportation and preservation of silicoflagellates in Alfonso Basin, Gulf of California

Limited areas of sea floor have the physiochemical conditions that allow for the formation and preservation of high resolution (yearly or close to yearly) laminated sediments that can function as a historic proxy for past oceanographic and climate conditions. We evaluated and established the fidelity of the sedimentary record in recording these signals by analyzing silicoflagellates production, changes in species composition, skeletal settling and their subsequent burial in bottom sediments at Alfonso Basin. The data series from December 2005 to February 2008 showed similar tendencies in both the vertical flux and overlying euphotic zone (Zeu) production of silicoflagellates. Both series were numerically dominated by Octactis pulchra with maxima values being recorded for the mixed water column period. Observed differences occurred during the studied years in both magnitude and in flux composition. The presence of a mixed assemblage with (warm–temperate–cold) species such as Dictyocha fibula var. robusta, Dictyocha epiodon and Distephanus speculum could be explained by a synchronization of trends between a predominantly positive Pacific Decadal Oscillation and a positive North Pacific Gyre Oscillation climate phases that were the background conditions underlying the early 2006 through 2007 El Niño event. A Morisita's similarity index value of 97.5% between winter trap and Zeu samples combined with an annualized settling factor of 0.45, suggests that Alfonso Basin is a favorable settling environment for silicoflagellates. However, core-top sediments showed an attenuation of record fidelity (burial factor=0.25) resulting in a modified record for the production and settling of skeletons. O. pulchra that were not preserved in sediments as the dominant species and with this removal, the signal was also lost of the highest silicoflagellate production season (Mixing-cyclonic eddy periods) from the sedimentary record of the Alfonso Basin.

Fate and behaviour of marine organic matter during burial of anoxic sediments: Testing CH2O as generalized input parameter in reaction transport models

The precise modelling of organic matter degradation is key in unravelling the marine carbon cycle and to constrain methane and carbonate formation within sediments. So far, different model approaches for calculating organic matter degradation have been developed. The term “organic matter” is considered in different ways in the diverse models and the simplification “CH2O” is often used. In this work, we test the common approach of “CH2O” as a simplification for total degradable organic matter. The focus of our study is on shallow to 500m deep anoxic marine sediments. We performed hydrogeochemical modelling in different ocean drilling program (ODP) case studies with single organic compounds and with a mixture of organic compounds that considers the most reactive compounds in marine sediments. The modelling results indicate that the distribution of carbon species (carbonates, methane, CO2, and alkalinity) generated by the degradation of organic carbon is dependent on the type of organic matter that is given in the model for remineralization. The closer the nominal oxidation state of the organic carbon that is remineralized in the model calculations is to the oxidation state of carbon in methane (−4), the more methane is produced and less carbonates (carbon oxidation state of +4) precipitate. Simulation results suggested that the commonly and often used “CH2O” as initial input in reaction transport models is a valid simplification of complex organic matter. However, the better the model input parameters are constrained, the better will be the conclusions on the marine carbon cycle and methane formation.

Decadal carbon discharge by a mountain stream is dominated by coarse organic matter

Rapid erosion in mountain forests results in high rates of biospheric particulate organic carbon (POC) export by rivers, which can contribute to atmospheric carbon dioxide drawdown. However, coarse POC (CPOC) carried by particles >∼1 mm is rarely quantified. In a forested pre-Alpine catchment, we measured CPOC transport rates and found that they increase more rapidly with water discharge than fine POC (<1 mm) and dissolved organic carbon (DOC). As a result, decadal estimates of CPOC yield of 12.3 ± 1.9 t C km–2 yr–1 are higher than for fine POC and DOC, even when excluding 4 extreme flood events. When including these floods, CPOC dominates organic carbon discharge (∼80%). Most CPOC (69%) was water logged and denser than water, suggesting that CPOC has the potential to contribute to long-term sedimentary burial. Global fluxes remain poorly constrained, but if the transport behavior of CPOC shown here is common to other mountain streams and rivers, then neglecting CPOC discharge could lead to a large underestimation of the global transfer of biospheric POC from land to ocean.

Effects of sediment burial disturbance on macro and microelement dynamics in decomposing litter of Phragmites australis in the coastal marsh of the Yellow River estuary, China.

From April 2008 to November 2009, a field decomposition experiment was conducted to investigate the effects of sediment burial on macro (C, N) and microelement (Pb, Cr, Cu, Zn, Ni, and Mn) variations in decomposing litter of Phragmites australis in the coastal marsh of the Yellow River estuary. Three one-off sediment burial treatments [no sediment burial (0 mm year(-1), S0), current sediment burial (100 mm year(-1), S10), and strong sediment burial (200 mm year(-1), S20)] were laid in different decomposition sites. Results showed that sediment burials showed significant influence on the decomposition rate of P. australis, in the order of S10 (0.001990 day(-1)) ≈ S20 (0.001710 day(-1)) > S0 (0.000768 day(-1)) (p < 0.05). The macro and microelement in decomposing litters of the three burial depths exhibited different temporal variations except for Cu, Zn, and Ni. No significant differences in C, N, Pb, Cr, Zn, and Mn concentrations were observed among the three burial treatments except for Cu and Ni (p > 0.05). With increasing burial depth, N, Cr, Cu, Ni, and Mn concentrations generally increased, while C, Pb, and Zn concentrations varied insignificantly. Sediment burial was favorable for C and N release from P. australis, and, with increasing burial depth, the C release from litter significantly increased, and the N in litter shifted from accumulation to release. With a few exceptions, Pb, Cr, Zn, and Mn stocks in P. australis in the three treatments evidenced the export of metals from litter to environment, and, with increasing burial depth, the export amounts increased greatly. Stocks of Cu and Ni in P. australis in the S10 and S20 treatments were generally positive, evidencing incorporation of the two metals in most sampling times. Except for Ni, the variations of C, N, Pb, Cr, Cu, Zn, and Mn stocks in P. australis in the S10 and S20 treatments were approximated, indicating that the strong burial episodes (S20) occurred in P. australis marsh in the future would have little influence on the stocks of these elements. With increasing burial depths, the P. australis was particularly efficient in binding Cu and Ni and releasing C, N, Pb, Cr, Zn, and Mn, implying that the potential eco-toxic risk of Pb, Cr, Zn, and Mn exposure might be very serious. This study emphasized the effects of different burials on nutrient and metal cycling and mass balance in the P. australis marsh of the Yellow River estuary.

Uniform carbon fluxes in shallow lakes in alternative stable states

Shallow lakes process large amounts of carbon (C) via gross primary production (GPP) and respiration (R), but C fluxes are highly variable among lakes. We used a two-prong approach to determine whether C fluxes differed between two alternative stable states observed in shallow lakes. First, we used a replicated whole-lake experiment where we manipulated fish densities in four experimental lakes to induce shifts from the phytoplankton-dominated state (turbid state) to a submersed macrophyte-dominated state (clear state), and determined whether whole-lake GPP, R, and net aquatic production (NAP) changed in response to the manipulation. We also compared lake metabolism in the four experimental lakes to four lakes in a turbid state and four lakes in a clear state. Second, we used sediment cores from 68 shallow lakes to test whether modern burial rates of organic C differed between lakes in clear and turbid states. Biomanipulation in the experimental lakes reduced abundance of fish and phytoplankton and increased abundance of aquatic invertebrates and submerged macrophytes. However, there was no significant change in GPP, R, or NAP. Similarly, GPP, R, and NAP did not differ among experimental lakes, turbid-state lakes, or clear-state lakes. Lastly, organic C burial in sediments did not differ between lakes in clear vs. turbid states, though variability among sites was high. High light and nutrient availability facilitate rapid transitions between two alternative groups of competing, rapidly growing primary producers in shallow lakes. These characteristics facilitate relatively uniform C fluxes at the ecosystem scale despite substantial differences in community structure.

Macronutrient processing by temperate lakes: A dynamic model for long-term, large-scale application

We developed a model of the biogeochemical and sedimentation behaviour of carbon (C), nitrogen (N) and phosphorus (P) in lakes, designed to be used in long-term (decades to centuries) and large-scale (104–105km2) macronutrient modelling, with a focus on human-induced changes. The model represents settling of inflow suspended particulate matter, production and settling of phytoplankton, decomposition of organic matter in surface sediment, denitrification, and DOM flocculation and decomposition. The model uses 19 parameters, 13 of which are fixed a priori. The remaining 6 were obtained by fitting data from 109 temperate lakes, together with other information from the literature, which between them characterised the stoichiometric incorporation of N and P into phytoplankton via photosynthesis, whole-lake retention of N and P, N removal by denitrification, and the sediment burial of C, N and P. To run the model over the long periods of time necessary to simulate sediment accumulation and properties, simple assumptions were made about increases in inflow concentrations and loads of dissolved N and P and of catchment-derived particulate matter (CPM) during the 20th century. Agreement between observations and calculations is only approximate, but the model is able to capture wide trends in the lakewater and sediment variables, while also making reasonable predictions of net primary production. Modelled results suggest that allochthonous sources of carbon (CPM and dissolved organic matter) contribute more to sediment carbon than the production and settling of algal biomass, but the relative contribution due to algal biomass has increased over time. Simulations for 8 UK lakes with sediment records suggest that during the 20th century average carbon fixation increased 6-fold and carbon burial in sediments by 70%, while the delivery of suspended sediment from the catchments increased by 40% and sediment burial rates of N and P by 131% and 185% respectively.

Ecosystem-based carbon footprinting of marine engineering projects

Dredging projects use large amounts of fuel, which leads to substantial carbon dioxide (CO2) emissions. Until now, reducing the carbon footprint of dredging projects has mainly involved investigating the possibilities of dredging schemes and vessels that are more fuel efficient. A reduction in the order of 10–20% may be within reach, most of it is a win–win situation since fuel reduction will also reduce costs. A further reduction in carbon dioxide emissions may be possible on a project-by-project basis but will involve a trade-off between dredging costs and carbon dioxide emissions. Marine engineering projects also have an impact on primary production and formation of organic carbon and on sedimentation processes and burial of organic carbon in sediments. Both impacts influence carbon sequestration and can be a substantial or even overriding factor in the ‘carbon footprint’ of a project. The carbon footprint of a marine engineering project is often larger and more complex than previously anticipated. However, a more comprehensive carbon footprint also shows that a significant reduction in carbon dioxide emissions is possible when the designs and dredging and maintenance schemes stimulate sequestration of organic carbon in the wider environment.

Distribution, source and chemical speciation of phosphorus in surface sediments of the central Pacific Ocean

The abundance of five forms of phosphorus (P) in surface sediments from the central Pacific Ocean (4.5–15ºN, 154–143ºW) was determined using a sequential extraction procedure (SEDEX) to examine the distribution and source of different P species. Total P (TP) concentrations ranged from 13.2 to 119µmol-P/g with an average of 48.6±27.4µmol-P/g. Within the TP pool, total inorganic P (TIP) concentrations varied from 11.1 to 121µmol-P/g, while total organic P (TOP) concentrations ranged from undetectable to 4.8µmol-P/g. Inorganic P was generally the predominant form in surface sediments, comprising on average up to 93% of sedimentary TP, leaving <16% as TOP. Among the five P species, the authigenic or CaCO3-bound P and detrital P were the two major P species (comprising on average 43.4±13.5% and 45.7±14.8% of TP, respectively), followed by the refractory organic P, representing 6.7±2.4% of TP. Fe-bound P accounted for 3.3±1.3% of TP, and exchangeable or adsorbed P made up less than 1% of TP. The spatial distribution of different sedimentary P species showed that higher concentrations of detrital P and Fe-bound P were both found at around 11°N, suggesting similar sources for these two P species. Much of the detrital P was derived from atmospheric sources in the study area, where heavy rainfall in the intertropical convergence zone between 3°N and 11°N has been widely reported. Compared with other marine environments, the central Pacific Ocean had relatively higher detrital P, but lower abundance of adsorbed-P and Fe-bound P. These unquine results suggested that most of the labile P could have been released into the water column during its settling from the surface to the seafloor, or that atmospheric inputs of refractory P were an important source for sedimentary P, accounting for an average of 63% of the TP, in the central Pacific Ocean. High proportions of authigenic P in deep-sea sediments, on the other hand, implied that oceanic sediments are an important sink for reactive P species. Relatively lower OC/Org-P and OC/Preact ratios suggested a higher sedimentary burial for Org-P and/or attested the importance of detrital P derived from atmospheric sources in the central Pacific Ocean.

Assessing the potential of amino acid &amp;lt;sup&amp;gt;13&amp;lt;/sup&amp;gt;C patterns as a carbon source tracer in marine sediments: effects of algal growth conditions and sedimentary diagenesis

Abstract. Burial of organic carbon in marine sediments has a profound influence in marine biogeochemical cycles and provides a sink for greenhouse gases such as CO2 and CH4. However, tracing organic carbon from primary production sources as well as its transformations in the sediment record remains challenging. Here we examine a novel but growing tool for tracing the biosynthetic origin of amino acid carbon skeletons, based on naturally occurring stable carbon isotope patterns in individual amino acids (δ13CAA). We focus on two important aspects for δ13CAA utility in sedimentary paleoarchives: first, the fidelity of source diagnostic of algal δ13CAA patterns across different oceanographic growth conditions, and second, the ability of δ13CAA patterns to record the degree of subsequent microbial amino acid synthesis after sedimentary burial. Using the marine diatom Thalassiosira weissflogii, we tested under controlled conditions how δ13CAA patterns respond to changing environmental conditions, including light, salinity, temperature, and pH. Our findings show that while differing oceanic growth conditions can change macromolecular cellular composition, δ13CAA isotopic patterns remain largely invariant. These results emphasize that δ13CAA patterns should accurately record biosynthetic sources across widely disparate oceanographic conditions. We also explored how δ13CAA patterns change as a function of age, total nitrogen and organic carbon content after burial, in a marine sediment core from a coastal upwelling area off Peru. Based on the four most informative amino acids for distinguishing between diatom and bacterial sources (i.e., isoleucine, lysine, leucine and tyrosine), bacterially derived amino acids ranged from 10 to 15 % in the sediment layers from the last 5000 years, and up to 35 % during the last glacial period. The greater bacterial contributions in older sediments indicate that bacterial activity and amino acid resynthesis progressed, approximately as a function of sediment age, to a substantially larger degree than suggested by changes in total organic nitrogen and carbon content. It is uncertain whether archaea may have contributed to sedimentary δ13CAA patterns we observe, and controlled culturing studies will be needed to investigate whether δ13CAA patterns can differentiate bacterial from archeal sources. Further research efforts are also needed to understand how closely δ13CAA patterns derived from hydrolyzable amino acids represent total sedimentary proteineincous material, and more broadly sedimentary organic nitrogen. Overall, however, both our culturing and sediment studies suggest that δ13CAA patterns in sediments will represent a novel proxy for understanding both primary production sources, and the direct bacterial role in the ultimate preservation of sedimentary organic matter.

Thermal maturity of Carboniferous to Eocene Sediments of the Alpine–Dinaric Transition Zone (Slovenia)

The Alpine–Dinaric Transition Zone in Slovenia comprises the fold and thrust belt of the Southern Alps (South Karawanken Range, Julian Alps), Slovenian Basin and the Dinarides. The Slovenian Basin located between the Julian and Dinaric carbonate platforms evolved during Middle Triassic time and remained in a deep marine setting till the Late Cretaceous. The thermal history of Carboniferous to Eocene rocks in that area was investigated using vitrinite reflectance (VR) data, apatite fission track analysis and numeric 1D basin modeling. The study shows that maturity patterns are mainly controlled by the thickness of Upper Cretaceous to Eocene flysch deposits, filling the accommodation space. Therefore the thermal overprint reaches a maximum (>4%Rr) in Triassic to Cretaceous sediments of the Slovenian Basin and decreases towards the north and south. Minor sedimentary burial of the Adriatic Carbonate Platform and the Julian Alps results in a lower thermal overprint (<1.5%Rr). The thickness of flysch sediments was about 5km in the area of the Sava Folds, but significantly higher in the central part of the Slovenian Basin. Heat flow during maximum burial in Eocene time was in the order of the global average (60mW/m2). Cooling of Paleozoic and Mesozoic sediments below 110°C occurred between Late Eocene and Early Oligocene times in different parts of the study area. Nappe stacking due to Early (Dinaric) and Late Cenozoic (Alpine) compressional tectonics did not influence the thermal maturity of the sediments.

Superposition of burial and hydrothermal events: post‐Variscan thermal evolution of the Erzgebirge, Germany

AbstractThe post‐Variscan thermal history of the Erzgebirge (Germany) is the result of periods of sedimentary burial, exhumation and superimposed hydrothermal activity. The timing and degree of thermal overprint have been analysed by zircon and apatite (U–Th)/He and apatite fission track thermochronology. The present‐day surface of the Erzgebirge was exhumed to a near‐surface position after the Variscan orogeny. Thermal modelling reveals Permo‐Mesozoic burial to temperatures of up to 80–100 °C, although the sedimentary cover thins out towards the north resulting in maximum burial temperatures of less than 40 °C. This thermal pattern was locally modified by Cretaceous hydrothermal activity that reset the zircon (U–Th)/He thermochronometer along ore veins. The thermal models show no significant regional exhumation during Cenozoic times, indicating that the peneplain‐like morphology of the basement is a Late Cretaceous feature.

Biogeochemical drivers of the fate of riverine mercury discharged to the global and Arctic oceans

AbstractRivers discharge 28 ± 13 Mmol yr−1 of mercury (Hg) to ocean margins, an amount comparable to atmospheric deposition to the global oceans. Most of the Hg discharged by rivers is sequestered by burial of benthic sediment in estuaries or the coastal zone, but some is evaded to the atmosphere and some is exported to the open ocean. We investigate the fate of riverine Hg by developing a new global 3‐D simulation for Hg in the Massachusetts Institute of Technology ocean general circulation model. The model includes plankton dynamics and carbon respiration (DARWIN project model) coupled to inorganic Hg chemistry. Results are consistent with observed spatial patterns and magnitudes of surface ocean Hg concentrations. We use observational constraints on seawater Hg concentrations and evasion to infer that most Hg from rivers is sorbed to refractory organic carbon and preferentially buried. Only 6% of Hg discharged by rivers (1.8 Mmol yr−1) is transported to the open ocean on a global basis. This fraction varies from a low of 2.6% in East Asia due to the barrier imposed by the Korean Peninsula and Japanese archipelago, up to 25% in eastern North America facilitated by the Gulf Stream. In the Arctic Ocean, low tributary particle loads and efficient degradation of particulate organic carbon by deltaic microbial communities favor a more labile riverine Hg pool. Evasion of Hg to the Arctic atmosphere is indirectly enhanced by heat transport during spring freshet that accelerates sea ice melt and ice rafting. Discharges of 0.23 Mmol Hg yr−1 from Arctic rivers can explain the observed summer maximum in the Arctic atmosphere, and this magnitude of releases is consistent with recent observations. Our work indicates that rivers are major contributors to Hg loads in the Arctic Ocean.

High rates of organic carbon burial in fjord sediments globally

Fjords have been hypothesized to be hotspots of organic carbon burial. A global compilation of organic carbon data and sedimentation rates shows that fjords sequester twice as much carbon as other ocean regions.

Control of nitrogen and phosphorus transport by reservoirs in agricultural landscapes

Reservoirs often receive excess nitrogen (N) and phosphorus (P) lost from agricultural land, and may subsequently influence N and P delivery to inland and coastal waters through internal processes such as nutrient burial, denitrification, and nutrient turnover. Currently there is a need to better understand how reservoirs affect nutrient transport in agricultural landscapes, where few prior studies have provided joint views on the variation in net retention/loss among reservoirs, the role of reservoirs apart from natural lakes, and differences in effects on N versus P, especially over time frames >1 year. To address these needs, we compiled water quality data from many rivers in intermediate-to-large drainages of the Midwestern US, including tributaries to the Upper Mississippi River, Great Lakes, and Ohio River Basins, where cropland often covers >50 % of the contributing area. Incorporating 18 years of data (1990–2007), effects of reservoirs on river nutrient transport were examined using comparisons between reservoir outflow sites and unimpeded river sites (N = 869, including 100 reservoir outflow sites) supported by mass balance analysis of individual reservoirs (n = 17). Reservoir outflows sites commonly had 20 % lower annual yields (mass per catchment area per year) of total N and total P (TP) than unimpeded rivers after accounting for cropland coverage. Reservoir outflow sites also had lower interannual variability in TP yields. The mass balance approach confirmed net N losses in reservoirs, suggesting denitrification of agricultural N, or N burial in sediments. Net retention of P ranged more widely, and multiple systems showed net P export, providing new evidence that legacy P within reservoir systems may mobilize over the long-term. Our results indicate that reservoirs broadly influence the downstream transport of N and P through agricultural river networks, including networks where natural lakes and wetlands are relatively scarce. This calls for a more complete understanding of agricultural reservoirs as open, connected features of river networks where biogeochemical processes are often influential to downstream water quality, but potentially sensitive to changes associated with sedimentation, eutrophication, infrastructure aging, and reservoir management.