To constrain the compressibility of natrocarbonate liquids, sound-speed measurements were made on 11 liquids in the CaCO3–Li2CO3–Na2CO3–K2CO3 quaternary system from 808 to 1323 K at 1 bar with a frequency-sweep acoustic interferometer. CaCO3 concentrations range from 15 to 50 mol% in four of the experimental liquids. The sound-speed data for all liquids were converted to isothermal compressibility (β T ), which were fit to an ideal mixing model with respect to composition; the average residual is 1.2 %. Fitted values (±1σ) of the partial molar compressibility (10−2 GPa−1) at 1100 K were derived for CaCO3 (5.36 ± 0.13), Li2CO3 (8.09 ± 0.06), Na2CO3 (10.62 ± 0.07), and K2CO3 (14.09 ± 0.06); these values translate to bulk modulus values of 18.7, 12.4, 9.4, and 7.1 GPa, respectively, reflecting the relatively large compressibility of carbonate liquids. The data are additionally used to estimate the partial molar volume and compressibility of the CO2 component dissolved as carbonate in nephelinite liquids; the density of this dissolved component at 1423 K and 1 GPa ranges from 1.62, 1.71 to 1.83 g/cm3 when it is complexed with K+, Na+, and Ca2+, respectively, and is estimated to be ~2.05 and 2.14 g/cm3 when complexed with Fe2+ and Mg2+, respectively. The results from this study can be applied to natrocarbonate liquids, such as those erupted from Oldoinyo Lengai volcano in Africa, and indicate a melt density of ~2.19 g/cm3 at 1150 °C and 1 GPa, which is ~18 % less dense than the average melt density (~2.67 g/cm3) calculated for associated Mg-poor nephelinite liquids at the same conditions and volatile-free. However, the dissolution of 10.1 wt% H2O and 8.7 wt% CO2 in the average nephelinite melt (based on volatile contents reported in the literature for these magmas) reduces its density to ~2.14 g/cm3 at 1150 °C and 1 GPa, eliminating the buoyancy contrast with the natrocarbonate melt. In turn, it is highly likely that the natrocarbonatite melts contained significant amounts of dissolved H2O and, as an example, the addition of 10 wt% H2O lowers the melt density by ~14 % to ~1.88 g/cm3, and therefore re-establishes a large density contrast with the volatile-rich nephelinite melts.
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