Bulk Modulus Research Articles

Axial compression behavior of concrete-filled prefabricated aligned steel fiber UHPC tubes

This study presents an innovative composite column system featuring exceptional ductility and versatility, suitable for replacing traditional concrete columns or UHPC composite columns. The composite column, comprised of concrete-filled aligned steel fiber ultra-high performance concrete (UHPC) tubes (ASFUTs), offers superior mechanical properties. Apart from its function as a formwork, the ASFUT provides exceptional rigidity and lateral confinement capabilities, enabling it to withstand substantial axial forces directly. Initially, steel fibers were aligned using an electromagnetic field. Computed Tomography (CT) imaging elucidated an average inclination angle of 16.36° between the fibers and the circumference of ASFUT sections. Compared to conventional UHPC, aligned steel fiber UHPC demonstrates an average 9.1 % increase in compressive strength and an average 129.67 % increase in maximum equivalent tensile. This enhancement can be attributed to the improved fiber bridging effect resulting from the orientation of fibers. Then, the mechanical properties of the concrete-filled ASFUT columns were evaluated by axial compression testing of eight specimens with different fiber contents, shapes, and orientations. The findings indicate that the ASFUTs outperform conventional concrete-filled UHPC tubes, exhibiting notable enhancements across various performance metrics. Specifically, at a fiber volume fraction of 1 %, the concrete-filled ASFUT exhibits a compressive strength, elastic modulus, ductility, and energy dissipation capacity that are 1.12 times, 1.03 times, 1.25 times, and 1.54 times respectively, in comparison to conventional concrete-filled UHPC tubes. Finally, an advanced predictive model for estimating the axial bearing capacity of ASFUT concrete columns was proposed, offering valuable insights for structural design optimization and widespread implementation.

Interfacial Glucose to Regulate Hydrated Lipid Bilayer Properties: Influence of Concentrations.

A series of atomistic molecular dynamics (MD) simulations were carried out with a hydrated 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) bilayer with the variation of glucose concentrations from 0 to 30 wt % in the presence of 0.3 M NaCl. The study suggested that although the thickness of the lipid bilayer dropped significantly with the increase in glucose concentration, it expanded laterally at high glucose levels due to the intercalation of glucose between the headgroups of adjacent lipids. We adopted the surface assessment via the grid evaluation method to compute the deviation of the bilayer's key structural features for the different amounts of glucose present. This suggested that the accumulation of glucose molecules near the headgroups influences the local lipid bilayer undulation and crimping of the lipid tails. We find that the area compressibility modulus increases with the glucose level, causing enhanced bilayer rigidity arising from the slow lateral diffusion of lipids. The restricted lipid motion at high glucose concentrations controls the sustainability of the curved bilayer surface. Calculations revealed that certain orientations of of interfacial glucose with the of lipid headgroups are preferred, which helps the glucose to form direct hydrogen bonds (HBs) with the lipid headgroups. Such lipid-glucose (LG) HBs relax slowly at low glucose concentrations and exhibit a higher lifetime, whereas fast structural relaxation of LG HBs with a shorter lifetime was noticed at a higher glucose level. In contrast, lipid-water (LW) HBs exhibited a higher lifetime at a higher glucose level, which gradually decreased with the glucose level lowering. The study interprets that the glucose concentration-driven LW and LG interactions are mutually inclusive. Our detailed analysis will exemplify small saccharide concentration-driven membrane stabilizing efficiency, which is, in general, helpful for drug delivery study.

Dependence of the M choice on the properties of Hf(M)SiCN (M = Nb, Ta, Ti, Zr) ceramic coatings: ab-initio and experimental study

The HfMSiCN coatings (M = Nb, Ta, Ti, Zr) are researched using ab-initio theoretical method and double glow plasma surface alloying. The aim is to enhance the high temperature stability and wear resistance of these coatings, alongside optimizing mechanical and thermodynamic properties. Firstly, the calculated mechanical properties for Hf0.5M0.5CN correlate with those experimental measurement for HfMSiCN. Secondly, the thermodynamic parameters exhibit that the Hf0.5Zr0.5CN has the lowest thermal expansion coefficient and higher bulk modulus at high-temperatures. Moreover, the wear rate of HfZrSiCN at 500 ℃ is less than 60% of its wear rate at 300 ℃. The superior wear resistance of HfZrSiCN coating is attributed to a friction-induced composite layer including a dense amorphous nanocomposite surface layer and a nano-friction glaze layer supported by nanograins.

Characterization of bacterial cellulose produced by the KomEt strain isolated from a kombucha SCOBY

Bacterial cellulose (BC) is gaining interest, due to its actual and potential applications in the biomedical, cosmetics and textile industries. In this study, mechanical, thermal, and chemical properties of BC produced from a novel strain, isolated from a kombucha symbiotic culture of bacteria and yeast (SCOBY), were evaluated. The highest obtained yields with this strain, after a 10-day fermentation, were 496 ± 14 g/L (native hydrated) and 19 ± 1 g/L (dry). Compression, including relaxation, and traction tests were performed on BC membranes in a hydrated state. The tested material revealed a 3-phase compression behaviour with a compression modulus of 235 ± 50 Pa. In terms of relaxation in water, BC membranes showed plastic deformation past 50 % compression. Regarding BC membrane under traction, analysis showed a 1090 ± 410 kPa Young Modulus, a 50 ± 10 % Elongation at Break and a 270 ± 80 kPa Ultimate Tensile Strength (UTS). Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) indicated that BC begins its degradation around 290 °C. Fourier-Transform Infrared spectroscopy (FTIR) of freeze-dried BC membranes confirmed the obtained biofilm to be BC. The results of this study provide valuable information on the potential applications of BC membranes in different industries including textile, biomedical and as a low-cost alternative to some synthetic polymers.

Structural, elastic, mechanical, electronic, and optical properties of cubic K2Pb2O3 from first-principle study.

Based on first principles, the structure, elasticity, mechanics, electronics, and optical properties of cubic K2Pb2O3 were studied. The structural parameters calculated by this method are close to the previous theoretical results. The elastic constant, bulk modulus, shear modulus, Young's modulus, Poisson's ratio, and mechanical stability are studied, and it is shown that cubic K2Pb2O3 is mechanically stable, isotropic, and brittleness. The electrical conductivity and chemical bonding of cubic K2Pb2O3 were analyzed based on the calculated band structure, density of states (DOS), and bond populations. The dispersion of optical functions, including the dielectric function, refractive index, extinction coefficient, reflectivity, absorption coefficient, and loss function, is displayed and analyzed. All computations have been carried out based on density functional theory (DFT) as implemented in the CASTEP code. The norm conservation pseudopotential method is used to exchange correlation functionals within the generalized gradient approximation (GGA).

Effect of Different Concentrations of Co Doping on the Properties of η′‐Cu6Sn5 and Ni3Sn4: First‐Principles Study

In the field of electronic packaging, Ni3Sn4‐based and η′‐Cu6Sn5‐based compounds are common Sn‐based intermetallic compounds into which doping of other appropriate elements has been widely studied. Herein, the structural stability, mechanical properties, and electronic structures of (Ni,Co)3Sn4 and η′‐(Cu,Co)6Sn5 are systematically investigated using first‐principles calculations. By comparing the heat of formation of the doped and undoped intermetallic compounds, it is found that the doped Ni3Sn4 structure has a higher heat of formation and a less stable structure, while the doped η′‐Cu6Sn5 structure has a lower heat of formation and a more stable structure. The doped Ni3Sn4 exhibits an increasing bulk modulus (B) and Young's modulus (E), and the doped η′‐Cu6Sn5 exhibits a gradually increasing bulk modulus (B). These findings suggest that doping improves the rigidity and elastic deformation properties of the two intermetallic compounds. And yet the anisotropy of both intermetallic compounds is decreasing as doping concentration increases. According to the calculations of the electronic structures, the doped (Ni,Co)3Sn4 structure and the doped η′‐(Cu,Co)6Sn5 structure exhibit stronger metallicity. In addition, stronger Co–Sn ionic bonds are formed in the doped Ni3Sn4 and η′‐Cu6Sn5 structures. This suggests that the doped Ni3Sn4 and η′‐Cu6Sn5 structures are harder.

Novel MoS2/montmorillonite hybrid aerogel encapsulated PEG as composite phase change materials with superior solar-thermal energy harvesting and storage

Phase change materials (PCMs) offer significant advantages in energy conversion and storage by facilitating the storage and release of thermal energy during phase transition processes. However, challenges such as leakage during PCM phase transitions and poor light absorption properties have constrained their application in the field of photothermal energy storage. In this study, Montmorillonite (Mt) and molybdenum disulfide (MoS2) has been used to design and synthesize hybrid aerogels (MoS2/Mt) boasting high mechanical strength and excellent photothermal conversion performance. These aerogels are then used to encapsulate polyethylene glycol (PEG) to prepare composite PCMs with outstanding solar-thermal conversion and storage performances. The results show that the synthesized MoS2/Mt-PEG composite PCMs exhibit high enthalpies of melting and solidification of 169.16 J/g and 170.78 J/g, respectively, while the aerogel supporting material has a high compressive modulus of 1.96 MPa. Moreover, the composite material displayed excellent thermal stability and leakage resistance after undergoing 30 melting-cooling cycles. Furthermore, the incorporation of MoS2 imparted outstanding light absorption properties to the MoS2/Mt-PEG composite, resulting in a high light absorption and photothermal conversion-storage efficiency of 93.4 % and 96.47 %, respectively. Synthesized composite PCMs also demonstrate outstanding performance in solar-thermal-electricity conversion, achieving a voltage output of 458 mV under illumination conditions and maintaining a sustainable voltage output even after removing the light source. Thus, the composite PCMs prepared in this work can meet the requirements of high enthalpy, effective leakage prevention, efficient solar-thermal conversion and solar-thermal-electricity conversion performance, thereby presenting potential applications in practical solar energy collection, conversion, and storage.

Compressive Behaviors of High-Strength Geopolymeric Concretes: The Role of Recycled Fine Aggregate

In this study, natural fine aggregates (NFAs) in high-strength fly ash (FA)/ground granulated blast furnace slag (GGBFS)-based geopolymer concretes were both partially and completely replaced by RFAs to prepare geopolymer recycled fine aggregate concrete (GRFC). Herein, the impacts of RFA content (0%, 25%, 50%, 75%, and 100%) on the fresh and hardened performance and microstructural characteristics of a GRFC were investigated. The results indicated that with increasing RFA substitution ratio, the setting time of the GRFC decreases. In addition, the compressive strength and elastic modulus decrease. However, owing to the enhanced adhesion of the geopolymer matrix and recycled aggregate, RFA has a relatively small impact on the compressive strength, with a maximum strength loss of 9.7% at a replacement level of 75%. When the RFA content is less than 75%, the internal structure of the concrete remains relatively compact. The incorporation of RFA in concrete has been found to adversely affect its compressive strength and elastic modulus, while simultaneously increasing its brittleness. The increase in dosage of RFA leads to a reduction in the compressive strength and elastic modulus of concrete, while partial failure occurs when the GRFC constitutes 100% of the RFA. The existing stress–strain model for conventional concrete is recalibrated for the GRFC. Observed by SEM, with increasing RFA, the damage is mainly concentrated at the interface associated with the attached cement. Although the recalibrated model predicts the stress–strain responses of the GRFC reasonably well, an acceptable range of deviation is present when predicting the residual stress due to the relatively high strength and brittle behavior of the GRFC during compression. Through this research, the applicability of RFA is expanded, making it feasible to apply large quantities of this material.

Estimating elastic properties of sediments by pseudo-wells generation utilizing simulated annealing optimization method

The hydrate concentration model considerably affects elastic properties, including bulk and shear modulus. Defining seismic properties of sediments, such as compressional and shear wave velocity and density, provides valuable information to identify rock facies and fluid types. This information commonly results from pre-stack seismic inversion, while post-stack seismic information provides acoustic impedance as a layer-based property. Traditionally, seismic inversion requires well logs to produce an initial guess of inversion routines and provide a low-frequency part of the amplitude spectrum. Eventually, seismic inversion methods could not be performed in the areas without well-log data, such as deep sea areas. In such cases, pseudo-well logs derived from pre-stack seismic data are a solution. Pseudo-well generation is a title used to estimate the elastic parameters of sediments in areas, such as deep marine environments, where drilled wells are absent or sparse. Metaheuristic optimization algorithms are suitable tools for minimizing the cost function as they best match real and synthetic seismic data. In this study, the SEAM earth model has been used as a reference to investigate the quality of pseudo-well generation utilizing a simulated annealing (SA) algorithm as an optimization method of property model change, which minimizes the cost function of seismic inversion. As a result, considering an initial model type of the SEAM model, simultaneous seismic inversion introduced the best compressional and shear wave velocities and density logs, which provide the best real and synthetic seismic data match when synthetic data is calculated from the simplified Zoeppritz equation.

Electrical and mechanical properties variation of Al2O3–CaO-CNT(3,3) nanomaterial due to Al vacancy and temperature: DFT approach

Al2O3–CaO-CNT(3,3) nanomaterial has demonstrated excellent electrical and mechanical properties in the absence of defects suitable for applications in microelectronics, batteries, and fuel cells. It is impossible to develop materials without the presence of defects. Therefore, this research work was instituted to investigate the electrical and mechanical properties of this nanomaterial in the presence of VAl defect (a defect with lower formation energy in Al2O3) through DFT. The calculations were based on the Perdew, Burke, and Ernzerh (PBE) exchange-correlation functional, which uses the generalized-gradient approximation of an all-electron technique. The nanomaterial's spin-up and spin-down energy gaps (EG) increased due to the defect, from 0.007 eV to 0.000 eV–0.560 eV and 0.129 eV respectively. However, these values are still lower than that of Al2O3, which is widely used as an insulator. The lowest and highest EG recorded was at 0 °C and 60 °C for spin down, and at 0 °C and 80 °C for spin up respectively. The presence of the defect in the nanomaterial also led to the degradation of some of the mechanical properties majorly along (0-10), where the maximum bulk modulus decreases from 48.73 GPa to 8.40 GPa, the compressibility also increases from 56.82 GPa to 90.68 GPa.

Pressure and temperature dependent ab-initio quasi-harmonic thermoelastic properties of tungsten

We present the ab-initio temperature and pressure dependent thermoelastic properties of body-centered cubic tungsten. The temperature dependent quasi-harmonic elastic constants (ECs) are computed at several reference volumes including both the phonon and the electronic excitations contribution to the free energy and interpolated at different temperatures and pressures. Good agreement with the experimental ECs on a single crystal at ambient pressure is found. The pressure and temperature dependence of the shear sound velocity measured on polycrystalline tungsten by Qi et al is also in agreement with theory. Some discrepancies are found instead for the compressional velocity at high temperature and this is attributed to the temperature derivative of the bulk modulus, higher in theory than in experiment. These conclusions are reached both by PBE and by PBEsol functionals. The two give elastic properties with a similar pressure and temperature dependence although the latter is closer to experiment at 0 K.

Comprehensive Analysis of Mechanical, Economic, and Environmental Characteristics of Hybrid PE/PP Fiber-Reinforced Engineered Geopolymer Composites

Engineered Geopolymer Composites (EGCs), known for their excellent tensile properties and lower carbon emissions, have gained widespread attention in the field of fiber-reinforced concrete. However, the high cost of high-performance synthetic fibers, a crucial component of EGCs, limits their practical engineering applications. In this study, by using low-cost PP fibers hybridized with PE fibers and adjusting the fly ash/ground granulated blast furnace slag (FA/GGBS) ratio, cost-effective, high-performing hybrid PE/PP-reinforced engineered geopolymer composites (H-EGCs) were developed. This study conducted axial compressive and tensile tests on H-EGCs with different FA/GGBS ratios (7:3, 6:4, and 5:5) and PP fiber replacement ratios (0%, 25%, 50%, 75%, and 100%), investigated the influence of FA/GGBS and PP fiber replacement ratio on static mechanical behavior, and evaluated the economic and environmental benefits based on mechanical performance indicators. The result indicated that the compressive strength of H-EGCs can reach 120 MPa when the FA/GGBS ratio is 5:5; however, an increase in FA/GGBS and PP fiber replacement ratio leads to a loss in compressive strength and elastic modulus. The incorporation of PP fibers in moderate amounts enhances ultimate tensile strain by reducing crack control ability, and the maximum tensile deformation capacity (7.82–9.66%) was obtained for H-EGCs with a PP fiber replacement ratio of 50%. The optimal economic and environmental benefits of H-EGCs are observed when the FA/GGBS ratio is 5:5 and the PP fiber replacement ratio is set at 50%.

Development of Biphasic Injectable Hydrogels for Meniscus Scaffold from Photocrosslinked Glycidyl Methacrylate-Modified Poly(Vinyl Alcohol)/Glycidyl Methacrylate-Modified Silk Fibroin.

The development of a hydrogel material with a modified chemical structure of poly(vinyl alcohol) (PVA) and silk fibroin (SF) using glycidyl methacrylate (GMA) (denoted as PVA-g-GMA and SF-g-GMA) is an innovative approach in the field of biomaterials and meniscus tissue engineering in this study. The PVA-g-GMA/SF-g-GMA hydrogel was fabricated using different ratios of PVA-g-GMA to SF-g-GMA: 100/0, 75/25, 50/50, 25/75, and 0/100 (w/w of dry substances), using lithium phenyl (2,4,6-trimethylbenzoyl)phosphinate (LAP) as a free radical photoinitiator, for 10 min at a low ultraviolet (UV) intensity (365 nm, 6 mW/cm2). The mechanical properties, morphology, pore size, and biodegradability of the PVA-g-GMA/SF-g-GMA hydrogel were investigated. Finally, for clinical application, human chondrocyte cell lines (HCPCs) were mixed into PVA-g-GMA/SF-g-GMA solutions and fabricated into hydrogel to study the viability of live and dead cells and gene expression. The results indicate that as the SF-g-GMA content increased, the compressive modulus of the PVA-g-GMA/SF-g-GMA hydrogel dropped from approximately 173 to 11 kPa. The degradation rates of PVA-g-GMA/SF-g-GMA 100/0, 75/25, and 50/50 reached up to 15.61%, 17.23%, and 18.93% in 4 months, respectively. In all PVA-g-GMA/SF-g-GMA conditions on day 7, chondrocyte cell vitality exceeded 80%. The PVA-g-GMA/SF-g-GMA 75:25 and 50:50 hydrogels hold promise as a biomimetic biphasic injectable hydrogel for encapsulated augmentation, offering advantages in terms of rapid photocurability, tunable mechanical properties, favorable biological responses, and controlled degradation.

Reinforcing ethyl cellulose aerogels with poly(lactic acid) for enhanced bone regeneration

Abstract Developing double porous biodegradable and biocompatible scaffolds that can incorporate and release drugs in a controlled manner holds immense potential in regenerative medicine. This study presents a synthesis method for preparing a macro-mesoporous scaffold, where poly(lactic acid) adds to the macroporous region and mechanical properties, and ethyl cellulose adds to the surface area (182 m2/g). High surface area enables the incorporation of model drug indomethacin with an entrapment efficiency of 17.0% and its later controlled release profile. The resulting scaffold has desirable mechanical properties in the range of a natural trabecular bone with a compressive modulus of 22.4 MPa. The material is stable in the simulated body fluids for 120 days before the slow degradation starts. In vitro studies demonstrate the material's ability to support bone cell adhesion, proliferation, and differentiation, promoting osteogenic activity. Overall, the unique combination of poly(lactic acid) and ethyl cellulose produces advanced materials with tailored macro and mesopore properties, remarkable mechanical properties, optimal degradation rate, and drug delivery potential, making it a promising candidate for bone scaffolds in regenerative medicine and tissue engineering.

Durability and microstructural evolution of high-performance ecological geopolymer concrete under low-pressure–salt-erosion–freeze–thaw cycling conditions

Environmental characteristics such as low pressure, high-frequency freeze–thaw cycles, and salt erosion in a plateau region have a significant impact on the mechanical properties and durability of concrete. To reveal the damage mechanism of high-performance ecological geopolymer concrete (HPEGPC) incorporating tunnel spoils, slag, and fly ash (FA) in extreme environments, this study used HPEGPC with 12 % alkali-activated binders (AABS) and a binding material to machine-made sand ratio of 0.36 and ordinary Portland cement concrete (OPCC) with 12.4 % cement and a water-cement ratio of 0.5 to simulate the deterioration process of mechanical properties and durability under the action of low-pressure–salt–erosion–freeze–thaw cycles. The mass, compressive strength, relative dynamic elastic modulus loss rate, microstructure, and pore evolution patterns of HPEGPC and OPCC were analysed using experimental and microscopic tests. The results showed that the HPEGPC was significantly more resistant to freezing and salt erosion than the OPCC in both standard and hypobaric environments. The interfaces of HPEGPC before and after the low-pressure–salt-erosion–freeze–thaw cycles underwent a developmental process from a dense structure with microcracks to microcracks expanding into fracture surfaces and the dispersion of hydration products. The cementitious materials of HPEGPC have a high percentage of non-hazardous and less hazardous pores, and their dense structure results in a high resistance to freezing and salt erosion. In addition, by establishing a damage decay model and damage accumulation model for the compressive strength and relative dynamic elastic modulus, this paper provides theoretical guidance for the application of HPEGPC under low pressure, salt erosion, and freeze–thaw cycle environments of the plateau.

Composite Thickness and Stiffness Analysis of the Nasal Septum.

Background: The nasal septum supports the structure of the nose and is frequently manipulated during septorhinoplasty. Objective: To compare measurements of thickness and compressive Young's modulus (YM) between different regions of nasal septa from human anatomic specimens. Study Design: Case series. Methods: Cartilaginous septa from human anatomic specimens were dissected. Septum thickness was measured at 24 points with regular intervals using a digital caliper. Compressive YM was determined at 14 regions using a force gauge. Two-tailed student's t-tests were used to compare the average thickness and YM between different regions. Results: Septa from 40 human anatomic specimens were included, with age ranging from 50 to 89. Fifty percent of specimens were female. The mean (standard deviation) thickness of the septum was 1.75 (0.76) mm. The mean YM was 2.38 (1.29) MPa. The septum was thickest near the maxillary crest (3.09 [1.17] mm) and the keystone area (2.52 [0.91] mm) and thinnest near the anterior septal angle (1.29 [0.58] mm). The septum was most stiff posteriorly (2.90 [1.32] MPa) and least stiff anteriorly (1.80 [1.15] MPa). Conclusion: The nasal septum is thickest posteriorly, inferiorly, and along its bony edges. The septum is stiffest posteriorly, ventrally, and along its bony edges.

Quantitative Insight into the Compressive Strain Rate Sensitivity of Polylactic Acid, Acrylonitrile Butadiene Styrene, Polyamide 12, and Polypropylene in Material Extrusion Additive Manufacturing

AbstractHerein, a research and engineering gap, i.e., the quantitative determination of the effects of the compressive loading rate on the engineering response of the most popular polymers in Material Extrusion (MEX) Additive Manufacturing (AM) is successfully filled out. PLA (Polylactic Acid), ABS (Acrylonitrile Butadiene Styrene), PP (Polypropylene), and PA12 (Polyamide 12) raw powders were evaluated and melt-extruded to produce fully documented filaments for 3D printing. Compressive specimens after the ASTM-D695 standard were then fabricated with MEX AM. The compressive tests were carried out in pure quasi-static conditions of the test standard (1.3 mm/min) and in accelerated loading rates of 50, 100, 150, and 200 mm/min respectively per polymer. The experimental and evaluation course proved differences in engineering responses among different polymers, in terms of compressive strength, elasticity modulus, toughness, and strain rate sensitivity index. A common finding was that the increase in the strain rate increased the mechanical response of the polymeric parts. The increase in the compressive strength reached 25% between the lowest and the highest strain rates the parts were tested for most polymers. Remarkable variations of deformation and fracture modes were also observed and documented. The current research yielded results with valuable predictive capacity for modeling and engineering modeling, which hold engineering and industrial merit.

Low-Concentration Gelatin Methacryloyl Hydrogel with Tunable 3D Extrusion Printability and Cytocompatibility: Exploring Quantitative Process Science and Biophysical Properties.

Three-dimensional (3D) bioprinting of hydrogels with a wide spectrum of compositions has been widely investigated. Despite such efforts, a comprehensive understanding of the correlation among the process science, buildability, and biophysical properties of the hydrogels for a targeted clinical application has not been developed in the scientific community. In particular, the quantitative analysis across the entire developmental path for 3D extrusion bioprinting of such scaffolds is not widely reported. In the present work, we addressed this gap by using widely investigated biomaterials, such as gelatin methacryloyl (GelMA), as a model system. Using extensive experiments and quantitative analysis, we analyzed how the individual components of methacrylated carboxymethyl cellulose (mCMC), needle-shaped nanohydroxyapatite (nHAp), and poly(ethylene glycol)diacrylate (PEGDA) with GelMA as baseline matrix of the multifunctional bioink can influence the biophysical properties, printability, and cellular functionality. The complex interplay among the biomaterial ink formulations, viscoelastic properties, and printability toward the large structure buildability (structurally stable cube scaffolds with 15 mm edge) has been explored. Intriguingly, the incorporation of PEGDA into the GelMA/mCMC matrix offered improved compressive modulus (∼40-fold), reduced swelling ratio (∼2-fold), and degradation rates (∼30-fold) compared to pristine GelMA. The correlation among microstructural pore architecture, biophysical properties, and cytocompatibility is also established for the biomaterial inks. These photopolymerizable bio(material)inks served as the platform for the growth and development of bone and cartilage matrix when human mesenchymal stem cells (hMSCs) are either seeded on two-dimensional (2D) substrates or encapsulated on 3D scaffolds. Taken together, this present study unequivocally establishes a significant step forward in the development of a broad spectrum of shape-fidelity compliant bioink for the 3D bioprinting of multifunctional scaffolds and emphasizes the need for invoking more quantitative analysis in establishing process-microstructure-property correlation.

First principles study of thermo-physical and opto-electronic properties of NaCuTe, NaCuSe and NaScSn as potential photovoltaics

In this comprehensive study, we delved into the electronic, structural, elastic, optical and thermodynamic properties of sodium-based ternary semiconductors i.e NaCuTe, NaCuSe and NaScSn. Employing first-principle calculations, we precisely determined various material properties. The lattice constants, bulk modulus and equilibrium total energies were derived using the Murnaghan equation of state and demonstrate a good agreement with other theoretical methods. Analysis of the absorption spectra allowed us to identify the active window of the electromagnetic spectrum for these materials. The determination of elastic constants provided crucial insights into the materials’ ability to withstand external stress, revealing that the materials meet stability criteria with a ductile behavior. Electronic band structures and density of states calculations unveiled band gaps of 1.40 eV, 1.03 eV and 1.15 eV for NaCuTe, NaCuSe and NaScSn, respectively. This suggests their suitability for photovoltaic applications. Additionally, the materials exhibited desirable optical properties, characterized by efficient optical absorption with the highest peaks in the visible light and ultraviolet region of the electromagnetic spectrum, low reflectivity and a high dielectric constant. These findings collectively indicate the materials’ potential for utilization as solar photovoltaics

Degeneracy pressure in the presence of maximum length for non-interacting electrons

Combining quantum theory with the fundamental principles of gravity results in the modification of the uncertainty principle. In this study, we employ the extended uncertainty principle (EUP) with the maximum length derived from the cosmological particle horizon. The impact of this specific kind of modification is examined in a non-interacting electron gas system. We analytically derive the generalized relations for the degeneracy pressure and the bulk modulus. An intriguing finding is that the degeneracy pressure is reduced, as confirmed by the observed size of white dwarfs, which is smaller than what is predicted by the standard theory. Nevertheless, it is still capable of providing support against gravitational collapse.