It was possible to demonstrate in field experiments, that a ‘White Cell’ is a suitable instrument for ambient aerosol extinction measurements even under conditions of low mass concentration. Unsatisfactory agreement of measured and calculated extinction coefficients is due to insufficient information on particle bulk density. The margin within which the real and imaginary parts of the complex refractive index can be varied is sufficient to achieve agreement of measurement and calculation. Future measurements will include the explicit determination of the absorption and scattering coefficients. The additional absorption measurements will help to localize the limits of possible complex refractive index variations.