Flexible conducting polymeric composites (CPC) for applications as electromagnetic interference (EMI) shielding materials were successfully prepared by melt-mixing approach using poly (vinylidene fluoride) (PVDF) as the matrix, loaded with hybrid carbonaceous fillers, carbon nanotube (CNT) and graphene nanoplatelets (GNP). Composites with as low as 3 wt% of filler with conductivity values in between 10−3 S/m (PVDF/GNP) and 10−1 S/m (PVDF/CNT) were successfully prepared by using hybrid with different proportions. Multi-layered structure composites displayed significantly higher EMI SE values than the bulk composites, mainly those constituted by CNT and the CNT/GNP (1.5:1.5 wt%) hybrid. By stacking PVDF/CNT, PVDF/CNT/GNP and PVDF/GNP with different arrangements, on can achieve EMI SE around 22 dB (in X-band) and 27 dB (in Ku-band) with absorption contribution of 65–70 % in the X-band and 77–81 % in the Ku-band frequency ranges. The effect of the hybrid composites on the morphological, rheological and thermal properties and on the ability of the β-phase formation on PVDF composites was also investigated. By combining appropriate CNT/GNP ratio, a good compromise between flexibility, conductivity, processability and EM attenuation with absorption characteristics was achieved, thus favoring promising application in stealth technology and also in communication devices.