Applying 3D printing in construction is a promising, sustainable alternative to conventional methods. However, the thermal and energy performance of 3D-printed buildings remains underexplored, particularly regarding the interactions between geometric design, material selection, and printing parameters. This review addresses this gap by critically examining how the main steps of the printing process impact the thermal efficiency of 3D-printed buildings. Key findings indicate that material development needs to focus on mixes that balance thermal properties,printability,and structural integrity. The review demonstrates how optimising wall cross-sections and cavity shapes can reduce thermal conductivity and enhance energy efficiency. Innovative geometric designs, such as cellular and honeycomb structures, have shown improvements in thermal insulation. Optimising printing parameters, such as extrusion rate and nozzle travel speed, is crucial to minimising thermal bridges and reducing material anisotropy. Advanced numerical models, validated by experimental data and incorporating factors like inhomogeneous porosity, anisotropy, and surface roughness, are essential for accurately predicting the thermal behaviour of 3D-printed structures. The review underscores the need for large-scale, long-term performance studies of 3D-printed buildings under diverse climatic conditions. Additionally, developing standardised fabrication protocols and testing methods is essential for ensuring consistent quality and broader adoption. Addressing these research gaps is crucial to fully realising the potential of 3D printing in sustainable construction and accelerating the adoption of additive manufacturing in the construction sector.