Bubble Diameter Research Articles

The Influence of Coherent Oxide Interfaces on the Behaviors of Helium (He) Ion Irradiated ODS W.

Tungsten (W), as a promising plasma-facing material for fusion nuclear reactors, exhibits ductility reduction. Introducing high-density coherent nano-dispersoids into the W matrix is a highly efficient strategy to break the tradeoff of the strength-ductility performance. In this work, we performed helium (He) ion irradiation on coherent oxide-dispersoids strengthened (ODS) W to investigate the effect of coherent nanoparticle interfaces on the behavior of He bubbles. The results show that the diameter and density of He bubbles in ODS W are close to that in W at low dose of He ion irradiation. The radiation-induced hardening increment of ODS W, being 25% lower than that of pure W, suggests the involvement of the coherent interface in weakening He ion irradiation-induced hardening and emphasizes the potential of coherent nano-dispersoids in enhancing the radiation resistance of W-based materials.

Enhancing Fines Recovery by Hybrid Flotation Column and Mixed Collectors

The froth flotation technique can be considered one of the most efficient methods for the separation of minerals. Prior to utilizing any physicochemical separation method, the size of the mined ore must be decreased to facilitate the release of the valuable materials. This practice, along with the increased exploitation of ores that carry fine mineral particles caused the production of fine and ultrafine particles which are difficult to recover with classical enrichment methods, due to their different characteristics compared to coarser particles. It is established that fine and ultrafine particles are difficult to float, leading to losses of valuable minerals, mainly due to their low collision efficiency with bubbles. Moreover, fine particles require higher reagent consumption due to the fact that have a higher specific area, and finally, their flotation is limited by low kinetic energy. Flotation of fines can be enhanced by either decreasing bubble diameter or increasing their apparent size, or moreover, by enhancing the collector’s adsorption (their hydrophobic behavior) using alternative reagents (non-ionic co-collectors). In the present research, flotation experiments on a hybrid electrolytic flotation column that can produce microbubbles (−50 μm), were carried out for recovering fine magnesite (−25 μm) particles. In addition, the synergistic effect of anionic/non-ionic collectors were studied for the enhancement of fines recovery. Experimental flotation results so far designate the enhancement of fine magnesite particle recovery by approximately 8% with the addition of microbubbles. Finally, the synergistic effect of anionic/non-anionic collectors led to the improvement of flotation recovery by almost 12%.

Bubbles morphology, frequency and rising velocity in yield stress fluid under downward gas injection

Mixing in a reactor can be achieved mechanically or by the injection of a gas. This can be done by injecting a gas towards the bottom of the tank. The induced flow recirculation and then the stirring quality depends on the bubbles morphology, rising velocity and frequency detachment. This study focus on the case where the stirred fluid exhibits a yield stress. It is in line with previous studies on the gas cavity at the injection point [1], the induced flow recirculation [2] and the numerical simulation [3]. Here we quantified the bubbles diameters, aspect ratios and velocities as a function of the air flow rate, rheological parameters and tank size. Scaling laws and correlations based on the characteristic dimensionless numbers governing the flow have been proposed and validated experimentally. It was found that bubble frequencies and consequently bubble volumes and velocities are mainly governed by the balance between inertial and buoyancy forces. However, viscous and yield stress effects play an important role along buoyancy and inertial in defining the bubble aspect ratios. Weakly inertial flows are characterized by elongated bubbles while high inertial flows produce almost spherical bubbles. These experimental results are of practical interest for the design of reactor or digester where yield stress fluids have to be stirred.

Vapor Bubble Deformation and Collapse near Free Surface

Vapor bubbles are widely concerned in many industrial applications. The deformation and collapse of a vapor bubble near a free surface after being heated and raised from the bottom wall are investigated in this paper. On the basis of smoothed particle hydrodynamics (SPH) and the van der Waals (VDW) equation of state, a numerical model of fluid dynamics and phase change was developed. The effects of fluid dynamics were considered, and the phase change of evaporation and condensation between liquid and vapor were discussed. Quantitative and qualitative comparisons between our numerical model and the experimental results were made. After verification, the numerical simulation of bubbles with the effects of the shear viscosity ηs and the heating distance L were taken into account. The regularity of the effect of the local Reynolds number (Re) and the Ohnesorge number (Oh) on the deformation of vapor bubbles is summarized through a further analysis of several cases, which can be summarized into four major patterns as follows: umbrella, semi-crescent, spheroid, and jet. The results show that the Re number has a great influence on the bubble deformation of near-wall bubbles. For Re > 1.5 × 102 and Oh < 3 × 10−4, the shape of the bubble is umbrella; for Re < 5 × 100 and Oh > 10−3, the bubble is spheroidal; and for 5 × 100 < Re < 1.5 × 102, 3 × 10−4 < Oh < 10−3, the bubble is semi-crescent. For liquid-surface bubbles, the Re number effect is small, and when Oh > 5 × 10−3, the shape of the bubble is jet all the time; there is no obvious difference in the bubble deformation, but the jet state is more obvious as the Re decreases. Finally, the dynamic and energy mechanisms behind each mode are discussed. The bubble diameter, bubble symmetry coefficient, and rising velocity were analyzed during their whole processes of bubble growth and collapse.

Subcooled pool boiling performance on conical micro-pillars structures surfaces

Experimental investigation to evaluate the pool boiling performance and mechanisms for liquid subcooling of 0 K, 5 K, 10 K and 20 K on four conical micro-pillars structured surfaces is conducted in this study. The critical heat flux and bubble behaviors on different conical micro-pillars structured surfaces are studied specifically. The results prove that higher critical heat flux can be obtained on conical micro-pillars structured surfaces, compared to the flat surface. S500 surface exhibits the highest heat flux among different conical micro-pillars structures surfaces under saturated condition owing to the increased bubbles. Bubble diameter is clearly decreased and the intensity of agitation is reduced with the degree of subcooling increasing. Thus, more nucleation sites can be activated under subcooled condition. The CHF increases with the increasing subcooling on micro-pillars structures surface due to the enhancement effect on natural convection as well as the inhibition effect on bubble growth and coalescence.

Experimental measurements on the microbubble characteristics and dissolved oxygen (DO) in water using single and twin-Venturi type microbubble generators

The aim of this paper is to develop low cost and low power consumption microbubble generator to improve the mass transfer of gas to liquid. Microbubble aeration used in aquaculture to improve dissolve oxygen level, water recycling through dissolved air flotation (DAF), oil refinement and reduction of skin friction on ship Hull. A single Venturi and 3 twin-Venturis microbubble generators are manufactured and tested in this study. Experimental data on microbubbles diameters distribution and dissolved oxygen are presented. The main conclusions are: i) the mean microbubbles diameters produced by twin-Venturi are smaller by 10 µm than single Venturi generator; ii) the dissolved oxygen concentration was higher for twin-Venturi microbubble generator; iii) the microbubbles size distribution from twin-Venturis have a narrower distribution which reduces the probability of bubbles coalesce as they have very close values of velocities; iv) the bubbles diameters and velocities increase with the height in the water tank.

Measurement of film fluctuations and aerated characteristics during gas-liquid slug-churn flow transition by wire-mesh sensor

Vertical upward gas-liquid slug flows are frequently encountered in chemical processes and petroleum industries. The measurement of the film fluctuations and the aerated characteristics is of great significance for uncovering the mechanism of slug-churn flow pattern transitions. In this study, a conductance wire-mesh sensor (WMS) measurement system is designed based on a Field Programmable Gate Array (FPGA) to visualize the structures of vertical gas-liquid flows. Liquid film flooding is a significant factor prompting the transition from slug to churn flow. Based on the WMS data, the 3D film structures are derived to indicate film instability during the flow pattern transition. Three types of film fluctuations in stable slug flow, unstable slug flow, and churn flow are presented. Liquid slug aeration is another important factor contributing to the slug-churn flow transition. The spatial distribution and the diameters of the gas bubbles in the liquid slug are detected by the WMS. The coalescence behavior of the bubbles is uncovered. Finally, mechanistic models based on the film flooding and slug aeration are constructed to predict the boundary of the flow pattern transition. The performance of the film flooding model and slug aeration model in predicting the onset of churn flow is evaluated.

Effects of pressure and particle size on bubble behaviors in a pseudo 2D pressured fluidized bed with Geldart A/B, B and D particles

Bubble behaviors of three types of particles from Geldart A/B, B and D groups were comprehensively investigated in a pseudo 2D pressurized fluidized bed via digital image analysis. Based on the analysis of a large quantity of experimental data, the effects of pressure and particle size on the spatial distribution of bubbles, bubble diameter, rise velocity, bubble fraction and flow regimes were obtained. Results show that bubbles are smaller and uniformly dispersed throughout the bed of Geldart A/B particles, while they become densely populated and grow into much larger sizes in the bed of Geldart B particles. A single peak of large bubbles in the center and emptying of bubble near the walls is formed in the bed of Geldart D particles due to the preferable rising path of bubbles towards the center and the significant coalescence of bubbles. Bubble diameter decreases with increasing pressure, and the effect of pressure is more pronounced on Geldart D particles. Bubble rise velocity increases with the increasing particle size and decreases as pressure rises. Large bubbles/slugs hardly appear in the bed of Geldart A/B particles, while they are clearly visible in the bed of Geldart B and D particles. The flow regime transition from slugging to fast fluidization shifts to the lower gas velocity for Geldart D particles compared with Geldart B particles.

Changes in Surface Hydrophobicity of Coal Particles and the Formation of Coarse Particle–Bubble Clusters in the Process of High-Intensity Conditioning

The mechanism of high-intensity conditioning (HIC) has not been thoroughly revealed, and therefore this work investigates the effect of HIC on the surface hydrophobicity of coal with different particle sizes and the possible formation of particle–bubble clusters. The results show that different HIC conditions are required for coarse and fine particles. Coarse particles (+75 μm) require a higher turbulence intensity to increase collector dispersion, thereby increasing the adsorption of the collector. Fine particles (−75 μm) require a lower turbulence intensity to reduce the desorption of the collector. In this study, the optimum HIC conditions for coarse and fine particles are “2200 rpm + 1 min” and “1300 rpm + 1 min”, respectively. Interestingly, it seems that the adsorption capacity between fine particles and the collector is weaker than that for coarse particles. A non-enclosed HIC system produces up to 1.78 × 104/g bubbles in coarse particle–bubble clusters, and the mean bubble diameter is approximately 87 μm. The cluster achieves pre-mineralization and increases the apparent particle size, which is expected to improve flotation.

Adding dry ice into ultra-high-performance concrete to enhance engineering performances and lower CO2 emissions

Developing low-carbon cement-based materials is crucial to address the pressing sustainability concerns the construction industry faces. This study elucidates the effect of adding dry ice on the micro-meso-macro properties of ultra-high-performance concrete (UHPC). The main original points of the method were summarized as follows: simple operation, low technical difficulty, no specific equipment required, and solving the problem that the carbonation curing method is difficult to use in low water-cement ratio concrete. The results show that adding dry ice generates microscopic CO2 bubbles that react with the carbonation of Ca(OH)2 and improve the later-stage strength and electrical resistivity. And adding dry ice reduces the heat of hydration and promotes ettringite formation. The results of microscopic analyses confirmed that increasing the dry ice content results in a decrease in Ca(OH)2; hence more calcium carbonate is formed. It was also observed that the carbon conversion effect became more apparent when the curing period was 28 days. And optical micrograph analysis showed that adding dry ice increased the total bubble content of the matrix and decreased the average bubble diameter, thus affecting the change in macroscopic properties. Moreover, as the addition of dry ice increased from 0 to 15%, the CO2 emission per unit strength decreased from 6.5 to 4.5 kg·CO2·m−3·MPa−1 (30% reduction in CO2 emission). Therefore, adding dry ice to UHPC is an effective way to utilize carbon and is crucial to achieving carbon neutrality in the concrete industry.

The Mechanisms of Inhibition Effects on Bubble Growth in He-Irradiated 316L Stainless Steel Fabricated by Selective Laser Melting.

The AISI 316L austenitic stainless steel fabricated by selective laser melting (SLM) is considered to have great prospects for applications in nuclear systems. This study investigated the He-irradiation response of SLM 316L, and several possible reasons for the improved He-irradiation resistance of SLM 316L were systematically revealed and evaluated by using TEM and related techniques. The results show that the effects of unique sub-grain boundaries have primary contributions to the decreased bubble diameter in SLM 316L compared to that in the conventional 316L counterpart, while the effects of oxide particles on bubble growth are not the dominant factor in this study. Moreover, the He densities inside the bubbles were carefully measured using electron energy loss spectroscopy (EELS). The mechanism of stress-dominated He densities in bubbles was validated, and the corresponding reasons for the decrease in bubble diameter were freshly proposed in SLM 316L. These insights help to shed light on the evolution of He bubbles and contribute to the ongoing development of the steels fabricated by SLM for advanced nuclear applications.

Bubble formation at top-submerged nozzles immersed in a quiescent liquid

Mixing is one of the most common unit operations used in radiochemical plants. In such plants, air induced mixing is preferred which is an economic and efficient means for mixing of the radioactive solutions without using moving parts. Intensity of air induced mixing depends on the diameter of the bubbles produced by the device used for air induced mixing. A typical device used for air induced mixing consists of multiple holes. To predict the diameter of the bubbles formed by a mixing device, a thorough understanding of the phenomenon of bubble formation at adjacent multiple holes is needed. The present study, which focuses on bubble formation at the hole at the tip of a top-submerged nozzle, is a step in this direction. In this study, the experiments are carried out to study bubble formation at top-submerged nozzles of different diameters. Demineralized water, nitric acid of different molarities and organic phase containing 30% (v/v) tributyl phosphate dissolved in dodecane equilibrated with nitric acid of different molarities are used in the experiments. These liquids are selected due to their relevance in nuclear chemical processes. Effects of air flow rate, nozzle diameter and the liquid used on bubble diameter and bubble detachment time are quantified using high speed imaging. Previously reported correlations to estimate the diameter of bubbles formed at top-submerged nozzles are compared with the data generated in the present study and found to be inadequate. Hence, a new correlation using relevant dimensionless numbers (Bond number, Froude number and Galileo number) is regressed utilizing the experimental data.

Effect of graphene oxide coating on bubble dynamics and nucleate pool boiling heat transfer

Materials coating has been proved to be an effective mean to increase the number of active nucleating sites, and therefore generate more vapor bubbles and lead to better poolboiling heat transfer performance. In this work, graphene oxide (GO) is coated on a boiling surface by self-assembly method, to enhance critical heat flux (CHF). The pool boiling is carried out on a smooth copper surface to study the effect of GO coating using distilled water as the working fluid along with bubble dynamic visualization. GO coating facilitates bubble nucleation by providing numerous microscale cavities. The visualization investigation of bubble dynamic behavior shows that the CO-coated surface exhibits a higher bubble departure frequency, a smaller bubble departure diameter and smaller bubble diameters in the pool, indicating greatly enhanced heat transfer effects. Meanwhile, the GO-coated surface exhibited a smaller contact angle than the copper surface, revealing that surface becomes more hydrophilic after GO coating. Consequently, GO-coated surface with a coating time of 4 h provides a CHF of 224.3 W/cm2 and a heat transfer coefficient (HTC) of 8.79 W/(cm2·K), representing an improvement of 94.0% in CHF and 83.5% in HTC compared to smooth copper surface.

Assessing passive scalar dynamics in bubble-induced turbulence using direct numerical simulations

By using direct numerical simulations (DNS) of bubbly flows with passive scalars, we show a transition in the scalar spectra from a $k^{-5/3}$ to a $k^{-3}$ scaling with the wavenumber $k$ , in contrast with those of single-phase isotropic turbulence. For cases with a mean scalar gradient in the horizontal direction, the scalar spectrum decays faster than $k^{-3}$ at high wavenumbers. While the $k^{-3}$ scaling is well established in the bubbly flow velocity spectrum, the scalar spectrum behaviour is not fully understood. We find that the transition length scale of the scalar spectra is comparable to or below the bubble diameter and decreases with the molecular diffusivity of the scalar in the liquid. We use DNS to compute the scalar spectrum budget and show that the scalar fluctuations are produced by the mean scalar gradient at length scales above the bubble diameter, contrary to the velocity fluctuations. At length scales below the bubble diameter, the net scalar transfer scales as $k^{-1}$ inducing the $k^{-3}$ scaling of the scalar spectra. This finding is consistent with the hypothesis proposed by Dung et al. (J. Fluid Mech., vol. 958, 2023, p. A5) about the physical mechanism behind the $k^{-3}$ scaling. We also show dependencies of the bubble suspension's convective scalar diffusivity on the gas volume fraction and molecular diffusivity that differ based on the direction of the mean scalar gradient. For a mean scalar gradient in the vertical direction, we find and qualitatively explain a significant effect of the molecular diffusivity in the gas on the convective scalar diffusivity.

The Effect of Mechanical Shaking on the Rising Velocity of Bubbles in High‐Viscosity Shear‐Thinning Fluids

AbstractThe rising velocity of an air bubble in a non‐Newtonian shear‐thinning fluid at low Reynolds numbers is generally similar to the Newtonian case given by Stokes' law. However, when the shear‐thinning fluid is subject to mechanical oscillations, the rising velocity could significantly increase. Here, we present a series of experiments quantifying the rising velocity of single bubbles during shaking in very high‐viscosity (2,000–30,000 Pa·s) shear‐thinning silicone oils. Air bubbles (18–30 mm diameter) were injected in a tank mounted on a shaking table. The tank was horizontally oscillated, at accelerations between 0.4 and 2 g. We observed a small increase in the rising velocity of the shaking cases at our experimental conditions. The increase was larger when bubbles were large and accelerations were high. Larger accelerations experienced the largest observational errors and we emphasize the exploratory nature of our results. We also measured the change in bubble diameter during the oscillations and computed the shear rate at the bubble surface. Maximum shear rates were in the range of 0.04–0.08 s−1. At these shear rates, our analysis indicates that shear thinning behavior of our analog fluids is expected to be small and compete with elastic behavior. This transitional viscous/elastic regime helps explain the small and variable results of our experiments. Our results are relevant to the study of earthquake‐volcano interactions. Most crystal‐free silicate melts would exhibit a purely viscous, shear‐thinning behavior in a natural scenario. Seismically enhanced bubble rise could offer an explanation for the observed increased degassing and unrest following large earthquakes.

Особенности повышения надежности и эффективности газосепараторов погружных установок электроцентробежных насосов для добычи пластовой жидкости

In oil producing wells with high gas content, an increase in the efficiency of centrifugal pumps is achieved by equipping them with centrifugal gas separators, in which, before entering the pump intake, most of the free gas is taken from the pumped fluid and discharged into the annulus of the well. The efficiency of a centrifugal gas separator significantly depends on the size of the dispersity of the gas-liquid structure of the pumped fluid, on the diameters of gas bubbles, the water cut of the formation fluid, the presence of surfactants, and the pressure at the inlet and outlet of the pump. In the article, based on the analysis of the structural diagrams of the power part of gas separators of various manufacturers, the analysis of the gas-liquid mixture flow features in the separation chamber and the outlet device, recommendations are made for optimizing the separation chamber length and the gas separator head outlet design. Recommendations are proposed for changing the flow path to increase the efficiency of gas separation and reliability of operation. Explanations of the expediency of new design solutions based on empirical formulas and numerical simulations are proposed. It is shown what the information is most important and how it can be obtained in bench tests.

Bubble growth and departure behavior in subcooled flow boiling regime

Understanding the detailed dynamics of bubble ebullition cycle is central to effectively exploit coolant phase change in subcooled flow boiling. In the present study, the bubble growth rate and the bubble departure mechanism in subcooled flow boiling conditions are investigated. The bubble growth rate is estimated by employing an energy balance model, which ensures that the applied wall heat flux contribution to components, such as (i) microlayer evaporation, (ii) conduction through superheated layer region, and (iii) condensation heat transfer, are accounted. The bubble departure diameter and the type of departure (i.e., sliding or lift-off) are predicted using a simple force balance model on the vapor bubble. The implemented models are thoroughly validated against the benchmark experimental data. Furthermore, the influence of operating conditions, viz., pressure (1–3 bar), mass flux (200–1000 kgm−2s−1), heat flux (200–500 kWm−2), and the degree of subcooling (20–30 K) on the bubble dynamics, is investigated for subcooled flow boiling conditions. Based on the parameters considered, a flow regime map is developed to identify the bubble departure type and diameter for a given set of operating conditions. It was noticed that the bubble departure diameter was maximum at low pressure (1 bar), low mass flux (200 kgm−2s−1), high heat flux (500 kWm−2), and low degree of subcooling (20 °C). For all the values of pressure and degree of subcooling, the sliding mode of departure was noticed at low and high mass flux values, whereas bubble departs by lift-off for moderate values of mass flux.

Towards understanding uniformity of megasonic-assisted through-mask electrochemical micromachining based on bubble dynamics

In through-mask electrochemical micromachining (TMEMM), bubbles on the anode surface can lead to ohmic voltage drop and non-uniform conductivity distribution, resulting in lower etching accuracy. With the advantages of low cavitation effect, strong acoustic streaming and high acoustic intensity, megasonic facilitates the reduction of bubble accumulation on the anode surface, thus improving etching accuracy. In this paper, a multiphysics field simulation model is developed to predict the two-phase flow evolution and etching profile at the anode interface. The simulation results show that the gas content at the anode interface in the megasonic field is low, and the gas distribution is relatively uniform. The etching depth and etching uniformity of TMEMM are improved. Experiments demonstrate the accuracy of the proposed simulation model. In addition, micro pits array with CVdiameter and CVdepth of 2.28 % and 5.70 %, respectively, were prepared using the MA-TMEMM method. Visualization experiments systematically study the machining mechanism of MA-TMEMM. The underlying dynamic force balance on the gas bubble is analyzed to illustrate the mechanism and experimental observations. Finally, the advantage of megasonic in removing bubbles from the anode surface to improve etching uniformity was demonstrated by counting the detached bubble diameter and effective coverage.

Two-Fluid Large-Eddy Simulation of Two-Phase Flow in Air-Sparged Hydrocyclone

The two-fluid (Euler–Euler) model and large-eddy simulation are used to compute the turbulent two-phase flow of air and water in a cyclonic flotation device known as an Air-Sparged Hydrocyclone (ASH). In the operation of ASH, air is injected through a porous cylindrical wall. The study considers a 48 mm diameter hydrocyclone and uses a block-structured fine mesh of 10.5 million hexagonal elements. The air-to-water injection ratio is 4, and a uniform air bubble diameter of 0.5 mm is specified. The flow field in ASH was investigated for the inlet flow rate of water of 30.6 L/min at different values of underflow exit pressure. The current simulations quantify the effects of the underflow exit pressure on the split ratio and the overall flow physics in ASH, including the distribution of the air volume fraction, water axial velocity, tangential velocity, and swirling-layer thickness. The loci of zero-axial velocity surfaces were determined for different exit pressures. The water split ratio through the overflow opening varies with underflow exit pressure as 6%, 8%, 16%, and 26% for 3, 4, 5, and 6 kPa, respectively. These results indicate that regulating the pressure at the underflow exit can be used to optimize the ASH’s performance. Turbulent energy spectra in different regions of the hydrocyclone were analyzed. Small-scale turbulence spectra at near-wall points exhibit f−4 law, where f is frequency. Whereas for points at the air-column interface, the energy spectra show an inertial subrange f−5/3 followed by a dissipative range of f−7 law.

Silver(I) Recovery by Ion Flotation Process from Aqueous Solutions in Cells with Spargers

Extractive metallurgy has recently turned its attention to waste treatment for the recovery of precious metals through innovative metallurgical processes, such as ion flotation. This work studied the influence of several chemical and physical factors, such as the concentration of xanthate [x], frother agent [e], dithiophosphate [xl], pH, superficial gas velocity Jg, percentage of gas holdup Eg, bubble diameter (Db) calculated with the drift flux model, and the type of sparger, in the efficiency of silver(I) recovery by the ion flotation technique in sub-aerated cells. The results obtained indicate a 90.7% v/v recovery of silver(I) under conditions of 3.77 × 10−4 M [x], 1.25 × 10−4 M [e], Jg 0.5 cm/s, Jl 0.19 cm/s, Eg of 4.1% v/v, and Optimal Db of 0.11 cm, with a rigid bubble generator, achieving an apparent flotation kinetics of 4.16 1/min. The use of combinations [x]–[xl] achieve a silver(I) recovery of 86.9% with a Jg of 1.0 cm/s. The best recovery efficiencies achieved 93% w/w silver(I) are with pH 8.0, [e] of 1.25 × 10−4, Jl of 0.19 (cm/s) and a rigid sparger compared to a flexible one.