Broadband Reflection Research Articles

A novel engineered sandwich composite with ceramic-coated graphite fibre-reinforced face sheets and an auxetic core for enhanced broadband electromagnetic absorption: design using multiscale computational analysis

Abstract A novel sandwich composite is designed for enhanced broadband absorption using a multiscale computational analysis. The sandwich panel is configured with BaTiO3 coated graphite fiber reinforced polymer (C-GFRP) composite, while BaTiO3 based auxetic material is used as the core material. A computationally efficient in-house tool based on the variational asymptotic method is used to homogenise the electromagnetic properties and evaluate the reflection loss characteristics of the proposed sandwich structure using the scattering matrices. A detailed parametric study of 300 analyses is conducted to identify the optimal sandwich panel configurations for achieving broadband reflection loss under the normal incidence of transverse electric (TE) and transverse magnetic (TM) polarised waves. Two different configurations have been obtained, satisfying the requirements of broadband reflection loss in the X-band frequency range. Configuration (a) Vf = 15% without any ceramic coating, and configuration (b) Vf = 20% with ceramic coating volume fraction (Cf) of 70%. Configuration (a) and (b) maintained the desired reflection loss of greater than -10 dB up to an incidence angle of 40◦ and 60◦, respectively. With the demonstrated capability of covering the entire broadband frequency range, the proposed configurations can serve as baselines to explore novel ceramic-based engineered composite architectures for broadband absorption applications.

Broadband Circularly Polarized Luminescent Films Based on the Heterogeneous Assembly of Cellulose Nanocrystals.

Broadband circularly polarized films display promising applications for multiwavelength lasers and "smart" windows in buildings. Herein, broadband films are fabricated through the heterogeneous assembly of cellulose nanocrystals (CNCs) and thermoplastic polyurethane (TPU) particles in mixed solvents of water and DMF. During the heterogeneous assembly process, a portion of the small TPU particles coassembled with CNCs to form chiral nematic structures and another portion of the TPU particles fused together to form large aggregates. These large aggregates are located around the helical structures of CNCs and induce a twisting effect on the helical axis of the chiral nematic phase. Helical axis twisting continuously occurs in various directions, leading to broad-band reflections of the films. Additionally, multicolor and white right-handed circularly polarized luminescent (CPL) films have been attained by integrating three organic dyes into the chiral structures of CNCs. A high dissymmetry factor value of -0.47 was achieved for the white CPL film.

Electrically tunable metasurface in TN LC configuration with enhanced quality factor and metaatom-induced alignment.

Dynamic metasurface with subwavelength dimensions has emerged as a key optical technology in recent years. Although various active tuning mechanisms are being proposed, liquid crystal-based dynamic metasurface remains attractive due to its large index variation, electrical tunability, reliability, and mass fabricability. In this work, we report a dynamic metasurface for amplitude modulation in reflection, with twisted nematic liquid crystal configuration to reduce broadband reflection in the off state. The metasurface consists of coupled subwavelength grating fingers, which provide alignment for the liquid crystal without the need for an additional alignment material or process. The alignment of liquid crystal materials was examined between crossed polarizers, and the twist of nematic liquid crystal was confirmed. The coupled grating fingers exhibit a resonance quality factor of 27 at telecommunication wavelength and an amplitude modulation depth of 8 times of the minimum at 1630 nm. This work highlights the potential of liquid crystal-based tunable metasurface, combining polarization control via liquid crystal and spectrum control via metasurface. Furthermore, it also shows a way in which the interaction between liquid crystal and metasurface is used for an alignment layer-free cell assembly process.

Enhanced photoconductivity via photon down-conversion by incorporation of solution-processed 3C-SiC QDs on nanostructured black silicon

Colloidal quantum dots (CODs) have attracted attention towards the next-generation optoelectronic devices capable of tuning the bandgap to capture photons at the UV region which is the major impediment of silicon (Si) for optoelectronic applications. However, CODs convert higher-energy photons into lower-energies photons through spectral down-conversion to UV visible. This study describes the photoconductivity effects of colloidal 3C-SiC QDs onto the underlying black silicon (b-Si) for spectral down-conversion effect. The Si showed a remarkable decrease in broadband reflectance after being etched to b-Si via metal-assisted chemical etching (MACE) over a broad spectral wavelength range of 300–1100 nm. Incorporating QDs onto underlying b-Si enhanced the device responsivity from 0.034 A/W to 0.53 A/W with the formation of space charge through the down-conversion effect. Furthermore, the photovoltaic measurements demonstrate the superior performance of hybrid colloidal 3C-Si QDs/b-Si with a power conversion efficiency (PCE) of ∼7.28 % compared to b-Si without QDs (5.57 %) photovoltaic cells. Our research provides insight into the down-conversion effects of colloidal 3C-SiC QDs for photovoltaic and photodetector applications.

Inverse-designed compact silicon waveguide reflector for on-chip resonators

Waveguide reflectors are crucial components in integrated optics and on-chip resonators, with their efficiency and dimensions significantly impacting system performance and integration. This paper presents an compact silicon on-chip waveguide reflector, designed using photonics inverse design, featuring a footprint of only 1.64μm×1.78μm and a simple, smooth structure. The simulation shows a 1 dB bandwidth over 400 nm and a reflectivity above 97.6% in the 1520–1570 nm wavelength range. Experimental measurements, conducted through Fabry-Pérot resonator spectrum analysis, confirm the excellent performance of the waveguide reflector, attaining a reflectivity over 92.8%. Additionally, the study presents two more waveguide reflectors tailored for the 1.31μm and 2μm wavelength, emphasizing the scalability of the design. The compact size and broadband reflectivity characteristics of the waveguide reflector provide increased flexibility in designing cavity lengths and directional couplers, making it a promising choice for applications in resonators and highly integrated photonics systems.

A bidirectional broadband multifunctional terahertz device based on vanadium dioxide

We propose a switchable and bidirectional metamaterial terahertz absorber/reflector based on vanadium dioxide. Simulation results show that the device can achieve broadband absorption and reflection by adjusting the phase state of vanadium dioxide. When the vanadium dioxide is in the insulating phase, the device can be a perfect bidirectional broadband absorber with more than 90% absorptivity under normal forward/backward TE/TM-polarized incident wave in the frequency range from 1.9 THz to 10 THz. This excellent absorption characteristic is insensitive to the polarization angle of the incident wave. When the vanadium dioxide is in the metal phase, the device achieves more than 90% reflectivity in the low-frequency range under forward/backward TE-polarized incident wave. In the high-frequency range, the device has both reflection and absorption effects on the TE-polarized wave. When vanadium dioxide is in two different phase states, the performance of device is not sensitive to the electromagnetic wave incidence angle. The change in vanadium dioxide conductivity does not affect the stable performance of the device at high (low) frequencies when used as an absorber (reflector). The proposed device has potential applications in terahertz energy harvesting, detection, sensing, optical switching, and shielding.

Durable and robust broadband radiative cooling coatings for multi-temperature scenarios

Passive daytime radiative cooling presents a promising avenue for revolutionizing cooling solutions by reflecting sunlight and radiative heat to outer space without consuming energy. Previous studies often focus on a single temperature scenario, neglecting the complexity of real-world applications in which the target object may have heat sources. Here, we have successfully prepared a Cooling Paint for Multi-Temperature Scenarios (CPMTS) by incorporating nanometer boron nitride into the photocured monomer Tricyclodecane Dimethanol Diacrylate (DCPDA). CPMTS exhibits excellent broadband thermal emittance (∼0.955), reflectance (∼0.778, from 300 nm to 2.5 μm), and thermal conductivity (∼0.51 W m−1 K−1). Notably, it achieves a maximum cooling of 20.1 °C and 8.8 °C under ∼790 W m−2 and ∼507 W m−2 of solar irradiation in the absence and presence of a 1 W heat source continuously heating, respectively. Continuous and significant radiative cooling performance has been observed on cloudy days or at night. CPMTS shows excellent radiative cooling performance in practical application scenarios. Excellent ageing resistance, adhesion, stability, and color matching ability make CPMTS expected large-scale application through spray or brush. This research provides a potential solution for cooling in real-world diverse temperature scenarios. The obtained radiative cooling coatings demonstrate scalability and durability in practical applications.

Highly efficient nonlinear compression of mJ pulses at 2 μm wavelength to 20 fs in a gas-filled multi-pass cell

Within this work we demonstrate the highly efficient nonlinear spectral broadening and subsequent temporal compression of 1.49 mJ pulses at 101 kHz repetition rate from an ultrafast thulium-doped fiber laser system employing a gas-filled multi-pass cell (MPC). To achieve spectral broadening, we use a krypton and helium-filled Herriott-type MPC with highly reflective broadband dielectric mirrors. The spectrally broadened pulses are subsequently compressed using fused-silica plates, resulting in a pulse duration of 20 fs and an overall excellent transmission of 96%. Furthermore, the beam quality is preserved up to the maximum output power of 144 W. It provides, to the best of our knowledge, the highest average power with few-cycle pulses at 2 µm wavelength with almost 10 times more pulse energy and 3 times more average power than previous 2 µm MPCs, enabling future secondary source experiments.

Interlayer coupled dual-layer metagratings for broadband and high-efficiency anomalous reflection

Recent progress in metagratings highlights the promise of high-performance wavefront engineering devices, notably for their exterior capability to steer beams with near-unitary efficiency. However, the narrow operating bandwidth of conventional metagratings remains a significant limitation. Here, we propose and experimentally demonstrate a dual-layer metagrating, incorporating enhanced interlayer couplings to realize high-efficiency and broadband anomalous reflection within the microwave frequency band. The metagrating facilitated by both intralayer and interlayer couplings is designed through the combination of eigenmode expansion (EME) algorithm and particle swarm optimization (PSO) to significantly streamline the computational process. Our metagrating demonstrates the capacity to reroute a normally incident wave to +1 order diffraction direction across a broad spectrum, achieving an average efficiency approximately 90% within the 14.7 to 18 GHz range. This study may pave the way for future applications in sophisticated beam manipulations, including spatial dispersive devices, by harnessing the intricate dynamics of multi-layer metagratings with complex interlayer and intralayer interactions.

Broadband, High-Reflectivity Dielectric Mirrors at Wafer Scale: Combining Photonic Crystal and Metasurface Architectures for Advanced Lightsails.

Highly ambitious initiatives aspire to propel a miniature spacecraft to a neighboring star within a human generation, leveraging the radiation pressure of lasers for propulsion. One major challenge for this enormous feat is to build a meter-scale, ultralow mass lightsail with broadband reflectivity. In this work, we present the design and fabrication of a lightsail composed of two distinct dielectric layers with photonic crystal/metasurface structure covering a 4" wafer. We achieved broadband reflection of >70% spanning over the full Doppler-shifted laser wavelength range during spacecraft acceleration with a low total mass in the range of a few grams when scaled up to meter size. Furthermore, we find new paths to reliably fabricate these subwavelength structures over macroscopic areas and then systematically characterize their optical performance, confirming their suitability for future lightsail applications. Our innovative device and precise nanofabrication approaches represent a significant leap toward interstellar exploration.

Doped nanofibers achieve tunable broadband in cholesteric phase liquid crystals

ABSTRACT In this study, polymer-stabilised cholesterol-based liquid crystal (PSLC) broadband reflective films were prepared by doping UV absorbers and chiral compounds in bilayer poly (methyl methacrylate) (PMMA) nanofiber films. Broadband reflection was achieved by diffusion of the UV absorber and chiral compounds in the bilayer nanofibers into the liquid crystal layer, which resulted in the formation of an inhomogeneous pitch distribution in the liquid crystal layer. To attain an optimal reflective effect, various factors such as polymer monomer concentration, concentration of chiral compounds in the spun film, diffusion temperature, diffusion time, and intensity of polymerised light were investigated. The effects of these factors on the reflective bandwidth were explored. The method significantly broadened the reflective bandwidth of the cholesteric phase liquid crystal layer, establishing the foundation for studying the combination of nanofiber films with cholesteric phase liquid crystals to form an adjustable pitch.

Polymer Network Film with Double Reflection Bands Prepared Using a Thermochromic Cholesteric Liquid Crystal Mixture.

Cholesteric liquid crystal polymer network (CLCN) films with a single reflection band have found applications for decoration and anticounterfeiting. The CLCN films with double reflection bands were more suitable for these applications. Herein, they were prepared by using thermochromic cholesteric liquid crystals (CLCs) through a two-step photopolymerization approach. At the first step, due to oxygen inhibition, the CLC monomers near the substrate surface were polymerized at a certain temperature. At the second step, those near the air were polymerized at another temperature. The wavelengths of these two reflection bands of the CLCN film were dominated by the two polymerization temperatures. Based on this approach, patterns with composite colors were prepared, which were suitably applied for decoration. Moreover, a double-layered CLCN film with a broad reflection band was prepared that could potentially be applied for displays.

Low-voltage electrochromic behaviour of polymer-stabilised liquid crystal with considerable broadband reflection

ABSTRACT In this work, a novel method was proposed to achieve electric-induced colouration of polymer-stabilised liquid crystal (PSLC) with considerable broadband reflection. The formation of broadband reflection was due to the introduction of the UV absorber that induced a light intensity gradient within the liquid crystal system and promoted the non-uniform distribution of the pitch. Experiments were performed to optimise the components and polymerisation conditions, allowing the bandwidth to be broadened from 252 nm to 906 nm. The texture of PSLC was characterised using POM, revealing that the planar texture was not disrupted. Thereafter, the addition of ionic liquid as supporting electrolyte enabled the PSLC to be switched from colourless to coloured at DC voltage as low as 1.7 V and the colouration behaviour can be independently modulated by changing the voltage level and the duration. Meaningfully, after the DC electric field was removed, the colour of the PSLC can also disappear gradually. In addition, the as-prepared electrochromic PSLC presented enhanced UV shielding, IR thermal control efficacy and good colouration performance on flexible substrates, which can be applied to low-energy smart glass and thermal management of buildings. This study provided a promising approach for the development of smart optical devices.

The Reliability of Accretion Disk Inclination Derived from X-Ray Spectroscopy of Active Galaxies

The inclination angle of substructures in active galaxies gives insights into physical components from scales of the vicinity of the central black hole to the entire host galaxy. We use the self-consistent reflection spectral model RELXILL to measure the inclination of the inner region of accretion disks with broadband (0.3–78 keV) X-ray observations, systematically studying the reliability of this methodology. To test the capability of the model to return statistically consistent results, we analyze multiepoch joint XMM-Newton and NuSTAR data of the narrow-line Seyfert 1 galaxy I Zwicky 1 and the broad-line radio galaxy 3C 382, which exhibit different degrees of spectral complexity and reflection features. As expected, we find that adding more data for analysis narrows the confidence interval and that multiepoch joint observations return optimal measurements; however, even single-epoch data can be well fitted if the reflection component is sufficiently dominant. Mock spectra are used to test the capability of RELXILL to recover input parameters from typical single-epoch joint observations. We find that inclination is well recovered at 90% confidence, with improved constraints at higher reflection fraction and higher inclination. Higher iron abundance and corona temperature tighten the constraints as well, but the effect is not as significant as a higher reflection fraction. The spin, however, has little effect in reflection-based inclination measurements. We conclude that broadband reflection spectroscopy can reliably measure inner accretion disk inclination.

Bi‐Layer Reflection‐Transmission Dual‐Mode Metasurface with Flexible Bandwidth Control

AbstractA general strategy for designing bi‐layer reflection‐transmission integrated dual‐mode metasurfaces is presented with flexible bandwidth control. The design of such metasurfaces is enlightened by introducing a cutting hole in the ground plane, which not only acts as a filter for reflection and transmission but also has an eloquent role for bandwidth control. For proof of concept, a bi‐layer metasurface consisting of split ring resonators (SRRs) is designed on the top side and I‐shaped resonators on both sides. The proper adjustment of ground cut/hole shifts the two co‐polarized resonances (initial resonances of the SRRs) close to each other, and in addition, converts wideband cross‐polarized reflection (in between the two initial co‐polarized resonances of SRR) to co‐polarized reflection. This results in a broadband response by shifting two co‐polarized resonances close to each other and converting cross‐polarized reflection into co‐polarized reflection. It is demonstrated that a simple SRR can be responsible for broadband (7.9–12 GHz) reflection while an I‐shaped structure is used for transmission with central frequency at 17.58 GHz with independent phase controls. To endorse the proposed strategy, a metasurface prototype is fabricated and tested for the generation of vortex beams and focusing.

Multilayer dielectric reflector using low-index nanolattices.

Dielectric mirrors based on Bragg reflection and photonic crystals have broad application in controlling light reflection with low optical losses. One key parameter in the design of these optical multilayers is the refractive index contrast, which controls the reflector performance. This work reports the demonstration of a high-reflectivity multilayer photonic reflector that consists of alternating layers of TiO2 films and nanolattices with low refractive index. The use of nanolattices enables high-index contrast between the high- and low-index layers, allowing high reflectivity with fewer layers. The broadband reflectance of the nanolattice reflectors with one to three layers has been characterized with peak reflectance of 91.9% at 527 nm and agrees well with theoretical optical models. The high-index contrast induced by the nanolattice layer enables a normalize reflectance band of Δλ/λo of 43.6%, the broadest demonstrated to date. The proposed nanolattice reflectors can find applications in nanophotonics, radiative cooling, and thermal insulation.

Adjoint-based optimization of dielectric coatings for refractory metals to achieve broadband spectral reflection

Refractory metals, which include niobium, tantalum, molybdenum, and tungsten, are critical components in applications in extreme environments due to their attractive thermomechanical properties. However, their low reflectivity below 1500 nm has prompted researchers to focus on increasing their reflection at shorter wavelengths. In this study, we applied an adjoint-based optimization technique to improve the spectral reflectivity of refractory metals in the broadband spectrum (300–3000 nm). An optimized periodic multilayer consisting of SiO2/TiO2 is selected as a starting point for the process. Then, the adjoint-based method is implemented to enhance the reflection of the surfaces. This approach involves an iterative procedure that guarantees improvement in every iteration. In every iteration, both the direct and adjoint solutions of Maxwell’s equations are computed to predict the scattering characteristics of a particular microstructure on a surface and measure its effectiveness. The results of our study indicate that the final designs not only increase reflectivity to over 90% but also have thermomechanical benefits that make them suitable for use in harsh environments. We also explored the effect of initial geometry on the results. Overall, our study shows that the adjoint-based optimization technique is an effective method for creating high-performing broadband reflectors with refractory metal substrates coated with dielectric multilayers.

Sub‐0.6 eV Inverted Metamorphic GaInAs Cells Grown on Inp and GaAs Substrates for Thermophotovoltaics and Laser Power Conversion

AbstractInverted metamorphic Ga0.3In0.7As photovoltaic converters with sub‐0.60 eV bandgaps grown on InP and GaAs are presented. Threading dislocation densities are 1.3 ± 0.6 × 106 and 8.9 ± 1.7 × 106 cm−2 on InP and GaAs, respectively. The devices generate open‐circuit voltages of 0.386 and 0.383 V, respectively, under irradiance producing a short‐circuit current density of ≈10 A cm−2, yielding bandgap‐voltage offsets of 0.20 and 0.21 V. Power and broadband reflectance measurements are used to estimate thermophotovoltaic (TPV) efficiency. The InP‐based cell is estimated to yield 1.09 W cm−2 at 1100 °C versus 0.92 W cm−2 for the GaAs‐based cell, with efficiencies of 16.8 versus 9.2%. The efficiencies of both devices are limited by sub‐bandgap absorption, with power weighted sub‐bandgap reflectances of 81% and 58%, respectively, the majority of which is assumed to occur in the graded buffers. The 1100 °C TPV efficiencies are estimated to increase to 24.0% and 20.7% in structures with the graded buffer removed, if previously demonstrated reflectance is achieved. These devices also have application to laser power conversion in the 2.0–2.3 µm atmospheric window. Peak laser power converter efficiencies of 36.8% and 32.5% are estimated under 2.0 µm irradiances of 1.86 and 2.81 W cm−2, respectively.

Enhanced broadband reflection properties of PSCLCs films supported by electrospun nanofiber networks loaded with Cs0.33WO3 nanoparticles

ABSTRACT The introduction of nanoparticles into cholesteric liquid crystals has long provided inspiration for innovative device materials. A novel material design strategy was demonstrated to achieve a broadband reflection of polymer-stabilised cholesteric liquid crystals (PSCLCs) based on Cs0.33WO3 nanoparticles and the polymer nanonetworks in the PSCLCs. Through the adjustment of nanoparticle and chiral dopant (C6M) concentrations and meticulous control of polymerisation conditions, an appropriate pitch gradient distribution was achieved in the polymer-stabilised cholesteric liquid crystals (PSCLCs). This was attained by striking a delicate balance between the polymerisation speed and chiral dopant diffusion rate, resulting in optimal PSCLCs optical properties. Modification of Cs0.33WO3 nanoparticles by oleic acid was successfully accomplished as confirmed by IR spectroscopy. SEM and EDS analyses further demonstrated the distribution of nanoparticles in the spun fibre film. Moreover, POM observations showed that liquid crystals with nanofiber networks maintained the planar texture and temperature stability. The prepared broadband reflective film opens an avenue towards developing the reflection bandwidth in the PSCLCs, essential for intelligent windows and infrared shielding devices.

Near-Infrared Reflective Polymer Films Based on UV-327-Doped Zinc Oxide Nanoparticles.

We prepared cholesteric liquid crystal (CLC) films with broadband reflective properties by admixing organic dye UV-327 into inorganic zinc oxide nanoparticles (ZnO NPs), utilizing the principle of pitch distribution from a large to a small gradient along the film thickness direction, leading to broadband reflection. ZnO NPs are poorly dispersed and easy to gather, but they do not decompose easily. The addition of UV-327 makes up for the above shortcomings. UV-327 is an organic compound with good compatibility and dispersion with liquid crystal systems. Therefore, we used the method of mixing two UV-absorbing dyes (UV-327 and ZnO NPs) to obtain CLC films. UV-absorbing dyes (UV-327 and ZnO NPs) made the liquid crystal films form a UV intensity gradient in the direction of thickness, prompting the polymerizable monomers to polymerize faster on the stronger side of the light, leading to the relative diffusion of chiral molecules and polymerizable monomers, forming the concentration gradient of chiral molecules in the direction of thickness. The pitch has a gradient distribution as the chiral concentration varies. Then, anchored by the polymer network, the pitch gradient distribution no longer changes. Broadened reflective bandwidth can reach up to 881 nm. Furthermore, the film covers the near-infrared wavelength band well, which can be applied to future smart windows or laser shielding for medical and military applications. It is also believed that this achievement will optimize the preparation technology of broadband reflective CLC films in the future.