Breccia Bodies Research Articles

Tectono-Sedimentary Evolution of the Madrid Basin (Spain) during the Late Miocene: Data from Paleokarst Profiles in Diagenetically-Complex Continental Carbonates

An intra-Vallesian (Upper Miocene) paleokarst developed at the top of the Intermediate Miocene Unit in the continental intracratonic Madrid Basin is recognized. This paleokarst is an early shallow, tabular-shaped karst that shows a marked control by the depositional facies pattern and lithologies. By integrating morphological, petrological, and geochemical data, three hydrogeological zones were established throughout the paleokarstic profiles: (i) a paleo-vadose zone, characterized by vertically elongated caves and vadose cementation; (ii) a 3–7 m thick paleo-epiphreatic zone (paleo-water table fringe), with development of stratiform breccia bodies, the superimposition of both vadose and phreatic features, and the lowest Fe and Mn contents in host-rock carbonates; and (iii) a paleo-phreatic zone characterized by an increase in δ13C values and the predominance of phreatic cementation. The paleogeographic reconstruction for the intra-Vallesian paleokarst using profiles revealed relative topographic highs to the north and topographic lows to the south, drawing the paleokarst landscape. Immediately overlaying the paleokarst surface are fluvio-lacustrine facies belonging to the Miocene Upper Unit (Late Vallesian to Late Turolian). Their lowermost deposits consist of fluvial terrigenous facies deposited by approximately N–S fluvial streams, and pass upward into fluvio-lacustrine fresh-water limestones. This paleokarstic surface represents a major change in the evolution of sedimentary patterns of basin, from endorheic to exorheic conditions, as the result of a change from compressive to extensional conditions in the tectonic regime.

3D outcrop modelling of large discordant breccia bodies in basinal carbonates of the Apulian margin, Italy

Large discordant breccia bodies (LDBBs) are important record keepers of the tectonic and gravitational evolution in platform-to-basinal settings, and have important implications for fluid-flow migration and compartmentalization of tight carbonate reservoirs. In the Gargano Promontory of southern Italy, LDBBs occur within a Cretaceous slope and basinal carbonate succession. We use field mapping and Unmanned Aerial Vehicle (UAV) -based Structure from Motion (SfM) Photogrammetry to document otherwise inaccessible cliff-side exposures of seismic-to subseismic-scale vertical discordant breccias. LDBBs are up to 50 m in width, more than 80 m in height and display internal chaotic or aligned clast fabrics. The formation which generally contains the LDBBs is characterized by beds of cherty pelagic limestone intercalated with calcarenites, calciturbidites and horizons of mass transport deposits. The mass-transport deposits can be correlated across the chaotic breccia bodies, indicating only slight or no vertical displacement across the adjacent walls. The bases of the breccia bodies are always hidden below current sea level, while the rarely exposed tops are capped by bedded intervals of the host rock formation. Timing and origin of the studied breccias were determined using several lines of evidence, such as stratigraphic provenance of clasts in breccias, mutual relationships of structural and sedimentologic features, and previous studies which establish that the age of dolomitizing cements in the LDBBs formed at different times and by different processes (fault shearing and solution collapse). This work investigates the size, shape and geometry of these breccia bodies whilst also providing cm-scale detail of the textural features in otherwise inaccessible outcrops. We suggest that breccias formed as a result of solution exploiting a pre-existing fracture network characterized by large-scale vertical strike-slip or oblique-slip faults. Initial displacement along these faults created a wide fault damage zone, where fluid migration was later focused to create a zone highly susceptible to solution and subsequent periodic sidewall collapse.

The late Miocene Öksüt high sulfidation epithermal Au-Cu deposit, Central Anatolia, Turkey: Geology, geochronology, and geochemistry

The Öksüt high sulfidation (HS) epithermal Au (-Cu) deposit (35.32 million tonnes of ore at 1.22 g/t Au) is located in the Central Anatolian Volcanic Province (CAVP) at the south-eastern segment of the Central Anatolian Crystalline Complex (CACC). The deposit is hosted by large hydrothermal breccia bodies and hornblende-rich basaltic andesite porphyry of the Develidag Volcanic Complex (DVC), which were pervasively altered to form silicification and argillic assemblages. The host rocks and mineralization are covered by post-mineral pyroxene-rich basaltic andesite of DVC. The volcanic rocks have a medium-K calc-alkaline affinity similar to regional volcanic rocks of the DVC. The gold and copper mineralization is mostly associated with quartz and primary sulfides hosted by silicification and argillic alteration particularly quartz-alunite cemented breccias and subsequently enriched by supergene oxidation processes causing destabilization of the primary sulfides.The LA-ICP-MS zircon U-Pb geochronology indicates a range of 206Pb/238U ages between 5.4 and 6.0 Ma with an average mean age of autocrystic grains of 5.73 ± 0.06 Ma for the host hornblende-rich basaltic andesite porphyry and 5.67 ± 0.07 Ma for the post-mineralization basaltic andesite cover. The high-precision CA-ID-TIMS analysis of the youngest grains from both rock types defines ages 5.778 ± 0.013 Ma and 5.700 ± 0.019, respectively, which bracket the ore mineralization between 5.791 and 5.681 Ma, including the error uncertainty. Consequently, the Öksüt gold mineralization took place in a very narrow lifetime of 78 ± 32 Ka. This is the youngest age for an economic gold deposit in Turkey.

Tourmaline as a Tracer of Late-Magmatic to Hydrothermal Fluid Evolution: The World-Class San Rafael Tin (-Copper) Deposit, Peru

Abstract The world-class San Rafael tin (-copper) deposit (central Andean tin belt, southeast Peru) is an exceptionally large and rich (>1 million metric tons Sn; grades typically >2% Sn) cassiterite-bearing hydrothermal vein system hosted by a late Oligocene (ca. 24 Ma) peraluminous K-feldspar-megacrystic granitic complex and surrounding Ordovician shales affected by deformation and low-grade metamorphism. The mineralization consists of NW-trending, quartz-cassiterite-sulfide veins and fault-controlled breccia bodies (>1.4 km in vertical and horizontal extension). They show volumetrically important tourmaline alteration that principally formed prior to the main ore stage, similar to other granite-related Sn deposits worldwide. We present here a detailed textural and geochemical study of tourmaline, aiming to trace fluid evolution of the San Rafael magmatic-hydrothermal system that led to the deposition of tin mineralization. Based on previous works and new petrographic observations, three main generations of tourmaline of both magmatic and hydrothermal origin were distinguished and were analyzed in situ for their major, minor, and trace element composition by electron microprobe analyzer and laser ablation-inductively coupled plasma-mass spectrometry, as well as for their bulk Sr, Nd, and Pb isotope compositions by multicollector-inductively coupled plasma-mass spectrometry. A first late-magmatic tourmaline generation (Tur 1) occurs in peraluminous granitic rocks as nodules and disseminations, which do not show evidence of alteration. This early Tur 1 is texturally and compositionally homogeneous; it has a dravitic composition, with Fe/(Fe + Mg) = 0.36 to 0.52, close to the schorl-dravite limit, and relatively high contents (10s to 100s ppm) of Li, K, Mn, light rare earth elements, and Zn. The second generation (Tur 2)—the most important volumetrically—is pre-ore, high-temperature (>500°C), hydrothermal tourmaline occurring as phenocryst replacement (Tur 2a) and open-space fillings in veins and breccias (Tur 2b) and microbreccias (Tur 2c) emplaced in the host granites and shales. Pre-ore Tur 2 typically shows oscillatory zoning, possibly reflecting rapid changes in the hydrothermal system, and has a large compositional range that spans the schorl to dravite fields, with Fe/(Fe + Mg) = 0.02 to 0.83. Trace element contents of Tur 2 are similar to those of Tur 1. Compositional variations within Tur 2 may be explained by the different degree of interaction of the magmatic-hydrothermal fluid with the host rocks (granites and shales), in part because of the effect of replacement versus open-space filling. The third generation is syn-ore hydrothermal tourmaline (Tur 3). It forms microscopic veinlets and overgrowths, partly cutting previous tourmaline generations, and is locally intergrown with cassiterite, chlorite, quartz, and minor pyrrhotite and arsenopyrite from the main ore assemblage. Syn-ore Tur 3 has schorl-foititic compositions, with Fe/(Fe + Mg) = 0.48 to 0.94, that partly differ from those of late-magmatic Tur 1 and pre-ore hydrothermal Tur 2. Relative to Tur 1 and Tur 2, syn-ore Tur 3 has higher contents of Sr and heavy rare earth elements (10s to 100s ppm) and unusually high contents of Sn (up to >1,000 ppm). Existence of these three main tourmaline generations, each having specific textural and compositional characteristics, reflects a boron-rich protracted magmatic-hydrothermal system with repeated episodes of hydrofracturing and fluid-assisted reopening, generating veins and breccias. Most trace elements in the San Rafael tourmaline do not correlate with Fe/(Fe + Mg) ratios, suggesting that their incorporation was likely controlled by the melt/fluid composition and local fluid-rock interactions. The initial radiogenic Sr and Nd isotope compositions of the three aforementioned tourmaline generations (0.7160–0.7276 for 87Sr/86Sr(i) and 0.5119–0.5124 for 143Nd/144Nd(i)) mostly overlap those of the San Rafael granites (87Sr/86Sr(i) = 0.7131–0.7202 and 143Nd/144Nd(i) = 0.5121–0.5122) and support a dominantly magmatic origin of the hydrothermal fluids. These compositions also overlap the initial Nd isotope values of Bolivian tin porphyries. The initial Pb isotope compositions of tourmaline show larger variations, with 206Pb/204Pb(i), 207Pb/204Pb(i), and 208Pb/204Pb(i) ratios mostly falling in the range of 18.6 to 19.3, 15.6 to 16.0, and 38.6 to 39.7, respectively. These compositions partly overlap the initial Pb isotope values of the San Rafael granites (206Pb/204Pb(i) = 18.6–18.8, 207Pb/204Pb(i) = 15.6–15.7, and 208Pb/204Pb(i) = 38.9–39.0) and are also similar to those of other Oligocene to Miocene Sn-W ± Cu-Zn-Pb-Ag deposits in southeast Peru. Rare earth element patterns of tourmaline are characterized, from Tur 1 to Tur 3, by decreasing (Eu/Eu*)N ratios (from 20 to 2) that correlate with increasing Sn contents (from 10s to >1,000 ppm). These variations are interpreted to reflect evolution of the hydrothermal system from reducing toward relatively more oxidizing conditions, still in a low-sulfidation environment, as indicated by the pyrrhotite-arsenopyrite assemblage. The changing textural and compositional features of Tur 1 to Tur 3 reflect the evolution of the San Rafael magmatic-hydrothermal system and support the model of fluid mixing between reduced, Sn-rich magmatic fluids and cooler, oxidizing meteoric waters as the main process that caused cassiterite precipitation.

HYPOGENE ALUNITE FROM THE EL SALVADOR DISTRICT, CHILE, INDICATES POTENTIAL FOR A BLIND PORPHYRY COPPER CENTER

AbstractSurface samples of hypogene alunite that cement late breccia bodies from the El Salvador porphyry copper district of Chile were recently dated. One alunite sample over the principal Turquoise Gulch porphyry deposit has a 40Ar/39Ar total gas age of 40.64 ± 1.04 Ma, overlapping the age of a late latite intrusion. Two other samples associated with quartz-alunite replacement of rhyolite, ~750 m southwest of the collapse zone over the block cave of the porphyry copper deposit, are distinctly younger, at 38.12 ± 0.66 and 38.04 ± 0.22 Ma (averages of duplicate analyses, with ±2σ errors).Previously reported U/Pb ages of zircons from 15 Eocene-age diorite, granodiorite, and granite porphyry intrusions have weighted mean ages that range from about 44 to 41 Ma, with peak magmatic flux interpreted at 44 to 43 Ma. Porphyry copper ores in the El Salvador district formed at about the same time as porphyry intrusions, with intrusive centers that migrated in a south-southwest direction, from the small deposits at Cerro Pelado (~44.2 Ma), to Old Camp (~43.6 Ma) and M Gulch-Copper Hill (~43.5–43.1 Ma), to the main ore deposit at Turquoise Gulch (~42 Ma). The granodiorite porphyry intrusions at Turquoise Gulch are associated with ~80% of the known copper ore of the district; they record waning stages of magmatism at 42.5 to 42.0 Ma, followed by weakly altered latite dikes at 41.6 Ma. Molybdenite in quartz veins returned Re-Os ages of 41.8 to 41.2 Ma.The two alunite samples from our study with coincident dates of ~38 Ma provide evidence for magmatic-hydrothermal activity younger than any recognized to date, consistent with the alteration overprint of quartz-alunite on older muscovite after erosion. This younger activity must have been associated with a blind intrusion, likely located south of the Turquoise Gulch deposit, based on the distribution of alteration minerals, and offset from the zoning associated with the Turquoise Gulch center. Stable isotope values (δ34S, δ18O, δD) of the ~38 Ma alunite indicate a high-temperature hypogene origin, consistent with formation in a lithocap environment that typically is located at shallow levels over and on the shoulders of porphyry copper deposits. Both observations—alteration overprint and markedly younger age of alunite—indicate the potential for porphyry copper mineralization south of Granite Gulch, as much as 1,000 m below the level of the coeval outcropping quartz-alunite replacement, perhaps near ~2,000-m elevation; this is hundreds of meters deeper than the known copper ore of Turquoise Gulch.

Breccias of Svoboda ore area of Malmyzhskoe gold-copper porphyry deposit (Khabarovsk territory)

The texture and variety of types of breccia bodies of the ore section of the Svoboda at the Malmyzhskoye deposit have been studied and described: a large one — the complex structure of eruptive (hydrothermal-magmatic) breccias and a relatively small — the columnar body of phreatic breccias. Eruptive breccias are intra-ore with respect to gold-copper mineralization. The detrital part in them is represented mainly by metasomatically altered intrusive rocks of the 1st phase of introduction and sedimentary formations of the cretaceous Largasinsky suite. Breccia cementing material is potassium feldspar-quartz-chlorite-sericite mass, which is an intensively metasomatically altered rock of the 2nd intrusive phase of intrusion. Ore mineralization in breccias has a veindisseminated texture and is part of the clastic part of breccias and is also superimposed on the already formed breccia bodies in the process of their metasomatic alternation. Phreatic breccias formed at the final stages of the development of the porphyry system. They are distinguished by low copper and gold contents and sharp secant contacts with the rocks surrounding them. The composition of the debris is generally similar to eruptive breccia, cement is quartz-sericite-epidote-chlorite. The position of ore mineralization is similar to that in eruptive breccias, but it is manifested to a much lesser extent. According to the proposed genetic model, the formation of the body of eruptive breccias occurred as a result of fluidization of rocks located in the arches of the intrusive body, followed by the introduction of significant volumes of magmatic melt. Subsequently, when rising, the fluids interacted with the cold near-surface waters, which caused the formation of phreatic breccias. The studied features of breccia formations are in a good agreement with the classical model of copper-porphyry deposits of the world.

Geopetrological model of formation diamond-bearing fluid-explosive breccia structures (urals type)

Geopetrological model of diamond-bearing fluid-explosive breccia formations is a well-structured system of the features that are typical of several similar formations in the Cis-Ural and West Ural areas of the Perm Krai. The model reflects a number of basic common factors in these structures’ morphology, their rock composition and the conditions for their formation. Regional and local geological positions featuring diamond-bearing formations as well as the parameters common for their widespread formation areas are characterized. The necessity of mineralogical and geochemical studies of black sand, while prospecting for diamond-bearing targets is highlighted. This will help identify specific mineral associations and geochemical anomalies typical of these widespread formation areas. The description of the geological structure, which the best-studied Efimov deposit, is given in detail. The description of this deposit is used as an example of illustrating the shape of breccia bodies and their polyphase structure, as well as describing their texture and rock structure specifics. Particular attention is paid to the petrographic characteristics of all kinds of fluid-explosive breccias, which to a different extent contain clastic, protomagmatic and newly formed fluidogenic material. The paper gives the characteristics and specifics of mineral grains of various origin, many of which are abundant in gas-liquid inclusions, characterized by block extinction, while quartz possess planar elements. Brought into focus are the differences in the diamond bearing capacity of rocks belonging to different successive evolution phases of fluid breccia formations. The model considered in the paper will make it possible in the course of studies of newly discovered breccia structures with a limited number of parameters to predict their missing features and assessment criteria with respect to possible beneficial mineralization.

The multiple sulfur isotope architecture of the Golden Mile and Mount Charlotte deposits, Western Australia

The Golden Mile and Mount Charlotte deposits in the Kalgoorlie Terrane, Western Australia, display three main mineralization styles: Fimiston, comprised of interconnected shear zones associated with ankerite-pyrite ± hematite- ± magnetite-gold-telluride alteration; Oroya, made up of breccia bodies with V-muscovite-ankerite-pyrite ± pyrrhotite-gold-telluride alteration; and Mount Charlotte, which consists of vein arrays with symmetrical ankerite-sericite-albite-pyrite ± pyrrhotite ± gold alteration. Pyrite is in equilibrium with gold in all three mineralization styles and has been selected as a proxy to record the sulfur source of the mineralizing fluids as well as the nature of the hydrothermal processes. The δ34S, Δ33S, and Δ36S analyses on pyrite grains from the different mineralization styles, including oxidized and reduced sulfide-oxide assemblages, reveal (1) a large variation in δ34S (from − 12.6 to + 23.5‰), and (2) a previously unrecognized occurrence of anomalous Δ33S and Δ36S signatures (from − 1.0 to + 1.1‰ and from − 2.3 to + 0.9‰, respectively). It is argued that the mineralizing fluids that formed the Golden Mile and Mount Charlotte deposits record mixing among three components: mantle sulfur, oxidized seawater sulfur (e.g., SO4), and reduced elemental sulfur (e.g., S8). Petrographic evidence in conjunction with Δ33S and Δ36S data suggest that MIF-S was acquired during the deposition of shales and basalts present in the Kalgoorlie Terrane and later mixed with mantle-derived sulfur during the mineralization events. The negative δ34S values that predominate in Fimiston style mineralization are consistent with a prevalence of oxidized fluids during the ore-forming process, as reflected by the presence of hematite-pyrite-magnetite-gold assemblages. Conversely, the positive δ34S values that dominate in the Mt Charlotte and Oroya mineralization styles reflect a reducing environment, as reflected by the presence of pyrite-pyrrhotite-gold assemblages.

Evidences for pre-orogenic passive-margin extension in a Cretaceous fold-and-thrust belt on the basis of combined seismic and field data (western Transdanubian Range, Hungary)

Combined sedimentological and structural analysis was carried out in the field and on 2D seismic reflection profiles to recognize pre-orogenic structures in a Cretaceous fold-and-thrust belt. Detailed field observations were made in the Keszthely Hills, Western Hungary, while 2D seismic interpretation was carried out in the neighbouring Zala Basin. As a result, a fault-controlled intraplatform basin system was identified by a detailed analysis of bounding faults, and related outcrop-scale structures. The Norian–Rhaetian (227–201.3 Ma) synsedimentary faulting was associated with talus breccia formation, small-scale faulting, and dyke formation, in addition to slumping and other soft-sediment deformations. Based on the distribution of talus breccia, WNW–ESE-trending map-scale normal faults were identified in the Keszthely Hills, which is in agreement with the directly observed outcrop-scale synsedimentary faults. On seismic sections, similar WNW- or NW-trending Late Triassic normal faults were identified based on thickness variations of the syn-rift sediments and the presence of wedge-shaped bodies of talus breccia. Normal faulting occurred already in the Norian, and extensional tectonics was active through the Early and Middle Jurassic. The Late Triassic grabens of the western Transdanubian Range could be correlated with those in western part of the Southern Alps, and the Bajuvaric nappe system of the Northern Calcareous Alps. These grabens were situated on the proximal Adriatic margin, and they represent the first sign of the Alpine Tethys rifting. The locus of extension was laterally migrated westward, towards the distal Adriatic margin during Early and Middle Jurassic.

Fault Zone Evolution and Development of a Structural and Hydrological Barrier: The Quartz Breccia in the Kiggavik Area (Nunavut, Canada) and Its Control on Uranium Mineralization

In the Kiggavik area (Nunavut, Canada), major fault zones along, or close to, where uranium deposits are found are often associated with occurrence of thick quartz breccia (QB) bodies. These bodies formed in an early stage (~1750 Ma) of the long-lasting tectonic history of the Archean basement, and of the Proterozoic Thelon basin. The main characteristics of the QB are addressed in this study; through field work, macro and microscopic observations, cathodoluminescence microscopy, trace elements, and oxygen isotopic signatures of the quartz forming the QB. Faults formed earlier during syn- to post-orogenic rifting (1850–1750 Ma) were subsequently reactivated, and underwent cycles of cataclasis, pervasive silicification, hydraulic brecciation, and quartz recrystallization. This was synchronous with the circulation of meteoric fluids mixing with Si-rich magmatic-derived fluids at depth, and were coeval with the emplacement of the Kivalliq igneous suite at 1750 Ma. These processes led to the emplacement of up to 30 m thick QB, which behaved as a mechanically strong, transverse hydraulic barrier that localized later fracturing, and compartmentalized/channelized vertical flow of uranium-bearing fluids after the deposition of the Thelon Basin (post 1750 Ma). The development and locations of QB control the location of uranium mineralization in the Kiggavik area.

Structures and Implications for Fluid Migration in the Jiadi Carlin‐Type Gold Deposit, Guizhou Province, Southwest China

AbstractThe Jiadi gold deposit is a newly discovered Carlin‐type gold deposit in the Guizhou Province, Southwest China. This deposit is structurally controlled by a shallow fold–fault superimposed system along the Lianhuashan trend. Field geological investigations, structural analysis, and mathematical research are conducted to study its structures and hydrothermal fluid flow process. Geological investigations (i.e. sections, stope, and drill hole) indicate that the structures are dominated by NE‐trending folds, NWW‐trending folds, and faults. A trend‐surface analysis of the low interformational fracture zone suggests that the overall distribution of the Lianhuashan trend is controlled by the NE‐trending Lianhuashan anticline. Nearly all primary Carlin‐type gold deposits are distributed along the southeastern flank where the fold axis changes from NE to EW. Gold orebodies are hosted by the interformational fracture zones and primarily situated at the transitions from the high‐value areas to the low‐value areas of the interformational fracture zones. A stress analysis on the hydrothermal veins indicates that they are of tenso‐shear properties. The ore‐forming elements (Au, As, Sb, Hg, and Tl) of the hydrothermal veins from the interformational fracture zones and intrusive breccia body present strong positive anomalies compared with those from the adjacent wall rocks. According to the development patterns of the ore‐forming elements and hydrothermal veins, a migration process of the ore‐forming fluids is proposed: the deeply sourced ore‐forming fluids migrated vertically to shallow crust along an intrusive breccia body, subsequently flowed horizontally along the interformational fracture zones accompanied by gold precipitation in the early stage, and finally migrated outward along steep micro‐fractures during following stages.

Intrusive hyaloclastite and peperitic breccias associated to sill and cryptodome emplacement on an Early Paleocene polymagmatic compound cone-dome volcanic complex from El Guanaco mine, Northern Chile

This work explores the textural characteristics, morphology and facies architecture of well-preserved Paleocene hyaloclastic and peperitic breccias associated with subvolcanic intrusions at El Guanaco gold mine (Northern Chile). The El Guanaco mine volcanic sequence is part of a polymagmatic compound cone-dome volcanic complex grouping several dacitic domes and maar-diatremes, and subordinated subvolcanic intrusions of basaltic, andesitic and dacitic compositions. The Soledad-Peñafiel Fault System is a first order regional structure controlling the location and style of the volcanism in the region. Three different intrusive bodies (Basaltic sills, Dacitic cryptodomes and Andesitic cryptodomes) were found to intrude into a wet and poorly consolidated pyroclastic sequence representing the upper portions of a maar-diatreme. Consequently, extensive quench fragmentation and fluidization along their contacts occurred, leading to the formation of widespread breccia bodies enclosing a coherent nucleus. Differences in matrix composition allows to define two main breccias types: 1) poorly-sorted monomictic breccias (intrusive hyaloclastites) and 2) poorly-sorted tuff-matrix breccias (peperites). The observed facies architecture is interpreted as the result of the interplay of several factors, including: 1) magma viscosity, 2) the geometry of the intrusives, and 3) variations on the consolidation degree of the host rocks. Additionally, the overall geometry of each intrusive is interpreted to be controlled by the effective viscosity of the magmas along with the available magma volume at the time of the intrusions. The presence of three compositionally different subvolcanic bodies with intrusive hyaloclastite and peperite envelopes indicate, not only that all these intrusions occurred in a short period of time (probably less than 2–3Ma), but also that the volcaniciclastic pile suffer little or none compaction nor consolidation during that time. The presence of three compositionally variated synvolcanic intrusives can be explained either by the presence of a zoned magmatic chamber feeding the volcanic complex, or more likely by the influence of the Soledad-Peñafiel Fault Zone acting as a preferential pathway for different magma compositions/sources to rise to the surface.

НОВЫЙ ЗОЛОТОРУДНЫЙ РАЙОН В ТАНЗАНИИ

Tanzania is one of the leading gold mining countries in the world and the discovery of new gold resources on its territory is an actual task. Known gold deposits are concentrated mainly in the northwest of the country, in the metallogenic zone of Lake Victoria, where they are associated with the Archean greenstone belts, and to a lesser extent – in the southwest, in the ore regions of Lupa and Mpanda, confined to the Ubendian Paleoproterozoic mobile belt. With regard to the eastern regions of Tanzania, where the Proterozoic structures of the Uzagaran mobile belt are developed, until recently in this region any significant manifestations of gold mineralization were not known. As a result of our research in the northern part of the Morogoro province of the Republic of Tanzania, a new previously unknown gold deposit Mananila was discovered. It is represented by a large volume, up to 400–450 m long, up to 60–80 m thick, mineralized shear zone over intensely leached and schistosed migmatites, gneisses, amphibolites, penetrated by echelon systems of quartz veins and veinlet, steeply dipping bodies of quartz breccia up to 1.0–1.5 m thick. Gold contents range from 0.61 to 8.11 g/t, the average zone content is 2.5–3.0 g/t. Parallel to the main zone, similar structures are developed on the site, although they are of lower thickness. The forecast resources of the deposit are estimated at 20 tons of gold. 2.8 km to the east from the Mananila field, the recently discovered Mazizi gold deposit is located, and a number of small occurrences of gold are also known in the region. All these objects are located within a large shear zone of the northeastern strike, up to 4–5 km width, over 20 km in length. This serves as the basis for the identification of a new gold ore region in the northern part of the Morogoro province of the United Republic of Tanzania, within the Proterozoic mobile belt of Usagaran, the possible gold content of which has never been previously discussed in geological literature.

Late Pliocene High-Sulfidation Epithermal Gold Mineralization at the La Bodega and La Mascota Deposits, Northeastern Cordillera of Colombia

La Bodega and La Mascota are Plio-Pleistocene high- to intermediate-sulfidation epithermal gold deposits hosted in Proterozoic gneisses and Mesozoic granites of the Santander massif, eastern Cordillera of Colombia and are part of the California-Vetas mining district. Coeval volcanic rocks are not recognized in the district and volumetrically minor granodiorite porphyries dated at 10.1 Ma are the only igneous rocks younger than Jurassic known from the vicinity of the epithermal deposits. As of 2010, La Bodega and La Mascota contained an inferred resource of 3.47 Moz Au, 19.2 Moz Ag, and 84.4 Mlbs Cu at a 2 g/t Au cut off. Mineralization exhibits NE-trending, NW-dipping structural control associated with the right lateral strike-slip La Baja fault. Mineralization at La Bodega is composed of vein networks and tectonic-hydrothermal breccias while at La Mascota it is largely contained in tabular, fault-controlled tectonic-hydrothermal breccia bodies. Alteration and sulfide assemblages can be assigned to six distinct hydrothermal episodes which comprise early porphyry-style phases and a late epithermal-style phase with up to four distinct stages. Porphyry phases comprise stages 1 and 2. Stage 1 is characterized by propylitic alteration with epidote, chlorite, calcite, specularite veins, minor pyrite, and chalcopyrite. Molybdenite from veins collected 0.7 km southwest of La Mascota yielded an Re-Os age of 10.14 Ma which constrains the age of stage 1. Stage 2 is related to a separate, younger magmatic-hydrothermal system and characterized by phyllic alteration (sericite-illite, quartz, pyrite) associated with quartz-pyrite veins and its age is constrained by 40 Ar/ 39 Ar geochronology on hydrothermal muscovite (i.e., sericite) to ~3.4 Ma. The epithermal phase comprises stages 3 through 6 and is related to multiphase hydrothermal breccia development and quartz-alunite alteration. Stage 3 is defined by presence of copper sulfides such as bornite, covellite, and chalcopyrite, stage 4 by wolframite, stage 5 by enargite, and stage 6 by sphalerite. Pyrite, quartz, and alunite are common to all epithermal stages. Residual vuggy quartz is scarce. Gold-silver mineralization took place during stages 3 through 5 with some gold introduced during stage 2. Alunite 40 Ar/ 39 Ar ages constrain epithermal mineralization to between ~2.6 and ~1.6 Ma. Primary fluid inclusion assemblages representative of hydrothermal stages 4 and 5 contain liquid and vapor-rich inclusions and, together with quartz vein textures, suggest that boiling was an important ore-precipitating mechanism. Homogenization temperatures of these range from ~143° and 238°C and salinities from 0.5 to 5.6 wt % NaCl equiv. Pyrite δ 34 S ranges from −16.9 to −11.3‰ at La Mascota and −8.3 to −6.1‰ at La Bodega. The strongly negative sulfur isotope signature can be explained by fluid boiling or, alternatively, by biogenic sulfur source from the Proterozoic paragneisses. Based on δ 18 O and δ D data, alunite was precipitated from magmatic fluids and only stage 6 alunite shows clear evidence for mixing of the hydrothermal fluid with meteoric water.

The geology, petrology, and geochronology of the Archean Côté Gold large-tonnage, low-grade intrusion-related Au(–Cu) deposit, Swayze greenstone belt, Ontario, Canada

The Archean Côté Gold Au(–Cu) deposit is the first large gold deposit discovered in the Swayze greenstone belt of the Abitibi Subprovince. The deposit is a low-grade, large-tonnage type with a combined indicated and inferred resource of 8.65 M oz Au (245.2 t Au). The deposit is hosted by the Chester intrusive complex (CIC), a multiphase, subvolcanic intrusion composed of low-Al tonalite, diorite, and quartz diorite, plus magmatic and hydrothermal breccia bodies. The age of the tonalite and dioritic phases is constrained at 2741–2739 ± 1 Ma using high-precision isotope dilution – thermal ionization mass spectrometry (ID–TIMS) U–Pb zircon geochronology. Although these phases are co-temporal and co-spatial, they appear to be petrogenetically unrelated. The CIC was emplaced into mafic metavolcanic rocks of the Arbutus Formation whose geochemistry reflects a back-arc environment. The tonalite of the CIC is coeval and co-genetic with the felsic to intermediate metavolcanic rocks of the Yeo Formation. Emplacement of the CIC into a shallow crustal level is inferred based on the incorporation of screens and inclusions of the Yeo Formation and is supported by the presence of textures in tonalite and dioritic rocks (e.g., granophyres, miarolitic cavities, and pegmatites), as well as Al-in-hornblende geobarometry results of ≤1.3 ± 0.6 kbars (1 kbar = 100 MPa). The CIC is petrologically similar to other subvolcanic, low-Al tonalite–trondhjemite–diorite intrusions that underlie volcanogenic massive sulphide (VMS)-type deposits and which themselves may contain syn-intrusion mineralization. Several geochemically unrelated dykes and deformation events crosscut and postdate the CIC.

The spin zone: Transient mid-crust permeability caused by coseismic brecciation

Pore fluids migrating through the deep section of continental strike-slip fault zones have been invoked to explain such phenomena as tectonic tremor, stress transfer across the brittle-ductile transition, and short timescales of co-seismic healing. In this contribution, we describe a coseismic mechanism for forming transient vertical fluid conduits within dilational jogs in strike-slip faults.We present field observations of breccias that formed coseismically at dilational stepovers in the dextral Pofadder Shear Zone, a ∼1Ga exhumed continental strike-slip fault in South Africa and Namibia. These breccias are interpreted to have formed when tensile fractures emanating from rupture tips intersected mylonitic foliation parallel to the rupture surface, which then failed, disaggregating the rock. We used quartz textures in the mylonites determined by electron backscatter diffraction to uniquely compare the orientation of each clast to the neighboring wall rock and constrain finite clast rotation within breccia bodies. Comparison of two- and three-dimensional rotation patterns show that clast trajectories are highly scattered when decoupled from wall rock, suggesting that Pofadder breccias were not formed by gradual plucking of clasts during slip. The dilational breccia bodies have sub-vertical geometries and high porosities relative to the host mylonites. We infer that the opening of these breccias may have created instantaneous, temporary vertical pathways for fluid draining through the brittle-plastic transition. These pathways healed post-seismically by cementation or ductile creep along the fault. The connection of many adjacent and overprinting breccia bodies through time provides a mechanism for fluid transport on a 10 s of km scale though the middle crust.

Volcaniclastic dykes tell on fracturing, explosive eruption and lateral collapse at Stromboli volcano (Italy)

In the upper part of the Stromboli volcano, in the Le Croci and Bastimento areas, two dyke-like bodies of volcanic breccia up to two-metre thick crosscut and intrude the products of Vancori and Neostromboli volcanoes. We describe the lithofacies association of these unusual volcaniclastic dykes, interpret the setting of dyke-forming fractures and the emplacement mechanism of internal deposits, and discuss their probable relationships with the explosive eruption and major lateral collapse events that occurred at the end of the Neostromboli period.The dyke volcaniclastic deposits contain juvenile magmatic fragments (pyroclasts) suggesting a primary volcanic origin. Their petrographic characteristics are coincident with the Neostromboli products. The architecture of the infilling deposits comprises symmetrically-nested volcaniclastic units, separated by sub-vertical boundaries, which are parallel to the dyke margins. The volcanic units are composed of distinctive lithofacies. The more external facies is composed of fine and coarse ash showing sub-vertical laminations, parallel to the contact wall. The central facies comprises stratified, lithic-rich breccia and lapilli-tuff, whose stratification is sub-horizontal and convolute, discordant to the dyke margins. Only at Le Croci dyke, the final unit shows a massive tuff-breccia facies.The volcaniclastic dykes experienced a polyphasic geological evolution comprising three stages. The first phase consisted in fracturing, explosive intrusion related to magma rising and upward injection of magmatic fluids and pyroclasts. The second phase recorded the dilation of fractures and their role as pyroclastic conduits in an explosive eruption possibly coeval with the lateral collapse of the Neostromboli lava cone. Finally, in the third phase, the immediately post-eruption mass-flow remobilization of pyroclastic deposits took place on the volcano slopes.

Ore geology and fluid evolution of the giant Caixiashan carbonate-hosted Zn–Pb deposit in the Eastern Tianshan, NW China

The Caixiashan giant carbonate-hosted Zn–Pb deposit (~131Mt@ 3.95% Zn+Pb) formed by replacement of dolomitized marble, with stratiform massive and breccia bodies is located near the base of the Proterozoic Kawabulake Group limestone and marble. It is one of the largest carbonated-hosted massive sulfides Zn–Pb ore deposits in Northwest China to have been discovered in recent years.Abundant pyrite occurs in dolomitized marble, along fractures in dolomitized clasts in the host rocks and filling cracks in the host rock. Locally, colloform or framboidal pyrites are observed in the early period and sometimes replaced by the later sphalerite. The sulfide assemblage of the main ore stage is characterized by massive or disseminated sphalerite and galena, with less pyrite than the earlier stage, and minor pyrrhotite. Galena occurs as small veins cutting the early-formed sphalerite. Dolomite and calcite are the main gangue minerals that co-precipitated with these sulfides. Tremolite and quartz alteration commonly overprints the orebodies. According to the crosscutting relationships and the different mineral associations within the host rocks and ore bodies, three stages are recognized at Caixiashan, i.e., syn-sedimentary pyrite (stage I), pyrite alteration, sphalerite–carbonate and galena–pyrite–carbonate (stage II-1, stage II-2 and stage II-3, respectively) and magmatic/metamorphic reworking (stage III).Calcite and quartz crystals are important host minerals among the three hypogene stages (stages I–III, although quartz mainly occurred in stage III). Stage I contains only aqueous inclusions (W-type), which were homogenized from 110 to 236°C (main range of 138–198°C and average at 168°C; main range=average±σ) and the salinities are from 0.5 to 16.5 (main range of 5.1–15.1 with average of 10.1) wt.% NaCl eqv. In the pyrite alteration of stage II-1 the W-type fluid inclusions homogenized from 175 to 260°C (main range of 210–260 with average of 235) and the salinities range from 8.5 to 22.4 (main range of 16.7–20.1 with average of 18.4) wt.% NaCl eqv. In the main Zn–Pb mineralization stage (stage II-2–3), four types of fluid inclusions were identified an aqueous phase (W-type), a pure carbon phase (PC-type), a carbon phase containing (C-type) and mineral bearing inclusions (S-type). The W-type fluid inclusions of stage II-2–3 homogenized at 210 to 370°C (main range of 253–323 and average at 270) and the salinities range from 5.9 to 23.1 (main range of 13.3–20.3 with average at 16.8) wt.% NaCl eqv.; C-type homogenized at 237°C to 371°C and the salinities range from 6.4–19.7wt.% NaCl eqv.; S-type fluid inclusions homogenized at 211 to 350°C and daughter minerals melted between 340 and 374°C during heating, indicating a salinity range of 42 to 44wt.% NaCl eqv. PC-type fluid inclusions with homogenization temperatures of CO2 phase show large variation from 7.4°C to 21.2°C. Laser Raman analyses show that CH4, CO2 and SO42− coexist in the main mineralization stage fluids. The magmatic/metamorphic reworking stage only contains W-type fluid inclusions which yield homogenized between 220 and 360°C (main range of 251–325 and average at 288), with salinities ranging from 1.7 to 23.0 (main range of 14.3–20.0 and average at 18.8) wt.% NaCl eqv.The textural features, mineral assemblages and fluid geochemistry suggest that the Zn–Pb ores were formed through hydrothermal convection of hot marine waters along the faults and fractures resulting in metal (Zn, Pb and Fe) enriched stratiform orebodies. Subsequent rapid precipitation of sulfides was triggered by sulfate (SO42−) thermal reduction with the CH4 preserved in sedimentary rocks and early stage I pyrite bodies. This process occurred at moderate temperatures (ca. 270°C). Higher-temperature magmatic hydrothermal alteration overprinted the orebodies, but only provided a minor contribution to the mineralization.

Joint Simulation of Grade and Rock Type in a Stratabound Copper Deposit

This work deals with the joint simulation of copper grade (as a continuous regionalized variable) and rock type (as a categorical variable) in Lince–Estefania deposit, located in northern Chile. The region under study is heterogeneous, containing three main rock types (intrusive, andesite and breccia bodies) with different copper grade distributions. To perform joint simulation, the multi-Gaussian and pluriGaussian models are used in a combined form. To this end, three auxiliary Gaussian random fields are considered, one for simulating copper grade, up to a monotonic transformation, and two for simulating rock types according to a given truncation rule. Furthermore, the dependence between copper grade and rock types is reproduced by considering cross correlations between these Gaussian random fields. To investigate the benefits of the joint simulation algorithm, copper grade and rock types are also simulated by the traditional cascade approach and the results are compared. It is shown that the cascade approach produces hard boundaries, that is, abrupt transitions of copper grades when crossing rock-type boundaries, a condition that does not exist in the study area according to the contact analysis held on the available data. In contrast, the joint simulation approach produces gradual transitions of the copper grade near the rock-type boundaries and is more suited to the actual data.

The base-of-slope carbonate breccia system of Céüse (Tithonian, S-E France): Occurrence of progradational stratification in the head plug of coarse granular flow deposits

Once interpreted as a deep-water canyon infilling and later as some kind of tempestite deposit, the Tithonian breccias of Ceüse are here reinterpreted as a small lobe deposit, emplaced at the mouth of a gully cutting into a slope between two deep-water terraces in the eastern part of the subalpine basin. The breccias belong to two basic categories: mostly grain-supported and occasionally mud-supported. Spectacular large-scale oblique geometries (apparent lateral accretions) are observed in the grain-supported breccias, both within the infilling of the lower feeder channel and in the updip part of the lobe. Detailed analyses of these geometries show that they correspond to progradational features. Both laterally and in a more distal position on the lobe, these progradational bodies evolve into a pile of unsorted massive breccias, sometimes showing a crude, even stratification. We thus propose a depositional model for the grain-supported breccias, linking the two facies as follows: the deposition of a gravity flow begins at the toe-of-slope (mouth of the tributary gully) by a progradational head which evolves downslope and laterally to a splay of massive or crudely stratified breccia. The internal oblique stratification flattens distally over a distance of a few kilometres. Elementary beds pile up in morphological compensation to build the 100m thick breccia body of Céüse. Because the breccias are derived from the gravity-reworking of deep-water nodular carbonates, there is no sand-sized material available in the depositional system, or only a little probably produced through an erosive clast grain diminution process during transport. This explains why the thick breccia beds pass quickly eastward to thin-bedded mud turbidites.